836 results about "Butyl acrylate" patented technology

Provided are a water-resistant wood-plastic reinforced composite flooring and a manufacturing method therefor. Wood flour is boiled in boiling water for 3-4 hours, filtered and dried, to obtain dried wood flour; polypropylene, butyl acrylate, methyl methacrylate, maleic anhydride and dicumyl peroxide are mixed evenly, extruded and granulated, and dried to obtain a compatibilizer; the dried wood flour and polypropylene are mixed evenly, the compatibilizer is added and mixed evenly, then extrusion and granulation, and injection molded, are performed, to obtain a wood-plastic flooring blank; a composite resin emulsion and a photoinitiator are ultrasonically mixed evenly, and the wood-plastic flooring blank is immersed therein, then taken out and dried at room temperature, and then vacuum dried and UV cured, to obtain water-resistant wood-plastic reinforced composite flooring.

The invention discloses a single-ion conductor polymer, a ternary composite binder solution, high-solid-content sulfide electrolyte slurry and a wet film forming method and application thereof, and belongs to the technical field of all-solid-state lithium batteries. The key technical problems in the wet membrane preparation of the sulfide electrolyte are solved through an innovative solvent-binder synergistic system, and the method specifically comprises the steps that 1, through the synergistic effect of a non-polar solvent and a weak-polar solvent, low-viscosity coating of high-solid-content slurry is achieved while the chemical stability of the sulfide electrolyte is guaranteed; 2, a poly (lithium styrenesulfonate-butyl acrylate), styrene butadiene rubber and polyisobutene ternary composite binder is designed, a lithium ion transmission channel is provided through a lithium sulfonate group, a benzene ring structure in the styrene butadiene rubber enhances the mechanical strength, long-chain alkane in the polyisobutene improves the interface adhesive force, and the mechanical strength is improved; the three components cooperate to realize balance of mechanical and electrochemical properties of the electrolyte membrane, so that the prepared electrolyte membrane has low porosity, high ionic conductivity and mechanical strength.

Disclosed in the present invention are a fluorosilicone-modified low-surface-energy antifouling coating and a preparation method therefor. The coating comprises the following components in parts by weight: 11-15 parts of butyl acrylate, 3-4 parts of dodecafluoroheptyl methacrylate, 3-4 parts of vinyl-terminated polydimethylsiloxane, 3-4 parts of 2-hydroxy-4-acryloyloxybenzophenone, 30-38 parts of methyl isobutyl ketone, 0.15-0.25 parts of azobisisobutyronitrile, 0.1-0.2 parts of sodium hydroxide, 2-3 parts of modified titanium dioxide nanoparticles, and 0.5-1.5 parts of 3-aminopropyltriethoxysilane. In the present invention, vinylpentamethyldisiloxane reacts with decamethylcyclopentasiloxane to prepare vinyl-terminated polydimethylsiloxane; a titanium dioxide precursor is mixed with polydopamine nanoparticles for modification to prepare modified titanium dioxide nanoparticles; and then the components above are mixed to prepare the fluorosilicone-modified low-surface-energy antifouling coating. The coating has low surface energy and good adhesion and ultraviolet resistance.

The invention belongs to the field of modified self-repairing calcium aluminate cement 3D printing, and particularly relates to a phosphate modified self-repairing calcium aluminate cement 3D printing material and a preparation method thereof. The phosphate modified self-repairing calcium aluminate cement 3D printing material prepared by the invention is prepared from the following raw materials in parts by mass: 60 to 70 parts of calcium aluminate cement, 3 to 7 parts of silica fume, 2 to 4 parts of metakaolin, 0.5 to 3.5 parts of double-template modified calcium bentonite, 0.8 to 1.5 parts of amino modified sodium polyphosphate and 0.15 to 0.8 part of basalt fiber. The invention relates to a concrete anti-microbial agent, which is prepared from the following raw materials in parts by weight: 20-30 parts of water, 20-30 parts of water, 20-30 parts of water, 20-30 parts of nano calcium carbonate, 20-30 parts of nano calcium carbonate, 20-30 parts of magnesium phosphate cement coated bacteria-loaded porous microspheres, 20-30 parts of a polycarboxylate superplasticizer, 20-30 parts of an organic silicon defoaming agent and 25-35 parts of mixing water. The technical-economic cooperation requirement of building 3D printing under complex working conditions is met, and various indexes of phosphate modified calcium aluminate cement applied to the 3D printing technology are met.

The invention relates to the technical field of coatings, in particular to an acrylate-epoxy resin composite coating and a preparation method thereof. According to the technical scheme, the coating is prepared from 25 to 35 parts of methyl methacrylate, 15 to 25 parts of butyl acrylate, 10 to 20 parts of epoxy resin E-5110, 8 to 15 parts of organic silicon modified acrylate prepolymer, 5 to 12 parts of fluorocarbon modified epoxy resin, 4 to 8 parts of core-shell structure corrosion inhibition nano container, 1 to 3 parts of functionalized graphene quantum dots and 4 to 10 parts of polyhedral oligomeric silsesquioxane maleimide modified amine curing agent. And 1-3 parts of a hindered amine light stabilizer. By integrating the core-shell structure corrosion inhibition nano container, the functionalized graphene quantum dots and the photo-thermal dual responsive curing agent component, the sensing, response and self-repairing of the coating on damage are realized, and long-acting corrosion resistance, weather resistance, bacteria resistance, mechanical property balance and intelligent maintenance are considered; and efficient and economical full-period protection is provided for equipment in an extreme environment.

The invention discloses an OCA (Optical Clear Adhesive) solution for a folding screen protective film, the OCA solution comprises an optical raw adhesive, a curing agent and a first solvent, the raw adhesive is prepared from the following raw materials in parts by mass: 270-283 parts of 2-ethylhexyl acrylate, 50-62 parts of butyl acrylate, 318-330 parts of methyl acrylate, 40-55 parts of acrylic acid, 1-2 parts of gamma-acryloyloxypropyltrimethoxysilane, 2.1-2.3 parts of an initiator and 1250-1350 parts of a second solvent; the second solvent comprises methylbenzene and ethyl acetate. According to the OCA optical glue solution for the folding screen protection film, raw glue is prepared from the isooctyl acrylate, the butyl acrylate, the methyl acrylate, the acrylic acid, the gamma-acryloyloxy propyl trimethoxy silane and the initiator in a toluene and ethyl acetate compounded solvent system, and an OCA glue layer with excellent stripping force, light transmittance, holding power and bending resistance is obtained after curing; and the cost of the raw materials is optimized, and the method is more economical.

The invention relates to the technical field of fabric waterproofing agents, in particular to a polyurethane modified organic silicon fluoride-free waterproofing agent and a preparation method thereof. The polyurethane modified organic silicon fluoride-free waterproof agent is prepared from the following raw materials in parts by mass: 5 to 15 parts of hexamethylene diisocyanate, 5 to 15 parts of butyl acrylate, 1 to 5 parts of methyl methacrylate, 40 to 60 parts of octamethylcyclotetrasiloxane, 10 to 30 parts of alpha, omega-dihydroxy polydimethylsiloxane and 5 to 10 parts of gamma-aminopropyl methyl diethoxy silane. The invention relates to a silane coupling agent, which is prepared from the following raw materials in parts by weight: 1 to 5 parts of glycidyl ether oxypropyl trimethoxy silane, 0.1 to 1 part of tetramethylammonium hydroxide, 0.1 to 1 part of triethylamine, 2 to 5 parts of tetraethoxysilane, 0.2 to 0.75 part of ammonia, 0.1 to 1 part of silane coupling agent KH-570, 0.01 to 0.1 part of dibutyltin dilaurate, 1 to 5 parts of epsilon-caprolactam, 1 to 2 parts of emulsifier and 0.1 to 1 part of initiator. The fabric treated by the method has good softness and excellent hydrophobic effect.

The invention provides an environment-friendly water-based acrylic emulsion adhesive without containing an organic solvent. The environment-friendly water-based acrylic emulsion adhesive is prepared from the following raw materials: 55-60 wt% of eleostearic acid hydroxyethyl acrylate (TMA), 15-25 wt% of butyl acrylate (BA), 3-10 wt% of acrylic acid (AA), 2-5 wt% of a cross-linking agent, 3-8 wt% of modified soil and 0.5-1 wt% of an initiator as a solid phase; the liquid phase is deionized water, and the environment-friendly water-based acrylic emulsion adhesive is prepared through semi-continuous emulsion polymerization. The prepared environment-friendly water-based acrylic emulsion adhesive is high in biodegradability and low in VOC content, has the mechanical property matched with that of a traditional acrylic emulsion adhesive and also has the self-repairing capacity, waste materials can be treated by changing the temperature or pH condition, the environment-friendly water-based acrylic emulsion adhesive can be recycled for multiple times, and the recycling cost is reduced.

The invention discloses a high-toughness polyethylene composite film and a preparation method thereof, and belongs to the field of high polymer materials. The outer layer is prepared from linear low-density polyethylene, an ethylene-butyl acrylate copolymer, an antioxidant 1010 and an ultraviolet light absorber UV-531; the middle layer is prepared from linear low-density polyethylene, a polyolefin elastomer, an ethylene-butyl acrylate copolymer, stearic acid modified calcium carbonate, an antioxidant and an ultraviolet light absorber; and the inner layer is composed of linear low-density polyethylene, an ethylene-butyl acrylate copolymer, an antioxidant 1010 and an ultraviolet light absorber UV-531. Drying the raw materials; mixing heavy calcium carbonate with stearic acid; each layer is mixed at a low speed according to a ratio; and carrying out three-layer co-extrusion film blowing, two-way stretching, corona and annealing. The surface tension of the composite film reaches 40 mN / m, the maximum longitudinal and transverse tensile strength is 23 MPa, the tearing strength is 120 kN / m, the elongation at break is 700%, and the performance of the composite film is superior to that of traditional casting and blow molding process products.

The invention discloses a high-flexibility anti-cracking coating and a preparation method thereof, and belongs to the technical field of building coatings. The coating is prepared from the following components in parts by mass: 50 to 70 parts of acrylic acid-organic silicon copolymer elastic emulsion with a core-shell structure, 3 to 8 parts of nano cellulose and polyester staple fiber composite fiber reinforced system, 20 to 30 parts of modified mica powder and fumed silica functional filler with a high radius-thickness ratio, 5 to 10 parts of auxiliaries and 10 to 15 parts of deionized water. A core layer of the elastic emulsion is a butyl acrylate-styrene elastomer, a shell layer of the elastic emulsion is a methyl methacrylate-organosiloxane copolymer, and a coating is endowed with high elongation at break and low-temperature crack resistance through the synergistic effect of a flexible network of the core layer and a rigid-flexible gradient structure of the shell layer. The nano cellulose and the polyester staple fiber form a dual-scale reinforcing system, so that cracks are bridged, and stress is dispersed; and the modified mica powder and fumed silica are compounded to improve the compactness and wear resistance of the coating.

The invention relates to the technical field of high polymer materials, and discloses a high-durability pressure-sensitive adhesive with low VOCs release and a preparation method thereof.The high-durability pressure-sensitive adhesive is prepared from, by weight, 50-80 parts of acrylate copolymer, 0.5-5 parts of cross-linking agent, 10-30 parts of tackifying resin, 1-10 parts of inorganic filler, 0.1-2 parts of antioxidant and 20-50 parts of solvent. Wherein the tackifying resin is at least one of hydrogenated petroleum resin and glycerol ester of rosin, and the inorganic filler is one of nanoscale silicon dioxide and calcium carbonate. Butyl acrylate is used as a main monomer, 2-ethylhexyl acrylate is used as a comonomer, acrylic acid is used as a functional monomer, benzoyl peroxide is used as an initiator, free radical polymerization is carried out at the temperature of 60-85 DEG C under the protection of nitrogen for 4-8 hours, and a copolymer chain with the molecular weight distribution index (PDI) smaller than or equal to 2.5 is formed, so that the viscosity and elasticity of colloid can be balanced; the peeling strength and the weather resistance are improved, and the colloid is prevented from being too soft or embrittled.

The invention provides an acrylate assistant for PVC (polyvinyl chloride) and a preparation method of the acrylate assistant, and belongs to the technical field of acrylate assistants. The preparation method comprises the steps of nano montmorillonite functionalization, synthesis of a core layer, synthesis of a middle layer and synthesis of a shell layer. The synthesis step of the core layer comprises the following steps: adding a core layer emulsion into a reaction kettle, adding an ammonium persulfate solution for the first time, heating to 64-68 DEG C, adding an ammonium persulfate solution for the second time, and reacting for 48-55 minutes to obtain a functionalized core emulsion; the core layer emulsion is prepared from deionized water, functionalized nano montmorillonite, sodium allyloxy hydroxypropyl sulfonate, butyl acrylate, 2-ethylhexyl acrylate, hydroxyethyl methylacrylate and gamma-methacryloyloxypropyltrimethoxysilane through ultrasonic treatment, and the core layer emulsion is prepared from the deionized water, the functionalized nano montmorillonite, the sodium allyloxy hydroxypropyl sulfonate, the butyl acrylate, the 2-ethylhexyl acrylate, the hydroxyethyl methylacrylate and the gamma-methacryloyloxypropyltrimethoxysilane through ultrasonic treatment; the prepared acrylate auxiliary agent is used in PVC, the fluidity can be improved, and meanwhile the impact resistance, the strength performance and the high-temperature stability performance are enhanced.

The invention discloses a high-temperature-resistant flame-retardant CPVC power cable protection pipe and a preparation method thereof, and relates to the technical field of cable protection pipes. The high-temperature-resistant flame-retardant CPVC power cable protection pipe at least comprises the following raw materials in parts by mass: 100 parts of chlorinated polyvinyl chloride; 15 to 25 parts of high impact resistance type MCS resin; 8 to 12 parts of poly (1, 2-propylene glycol adipate); 12 to 20 parts of a sepiolite-methyl methacrylate-butyl acrylate compound; 8-15 parts of aluminum-titanium composite coupling agent modified magnesium-aluminum-lanthanum hydrotalcite; 3-6 parts of a rare earth composite heat stabilizer; 2-4 parts of a processing aid; 0.5 to 1.5 parts of an antioxidant; and 1-2 parts of a lubricant. The prepared high-temperature-resistant flame-retardant CPVC power cable protection pipe has high heat resistance, high flame retardance and high impact resistance, and is excellent in comprehensive performance, high in safety and reliability and long in service life.

The invention relates to the technical field of semiconductor wafer processing, and particularly discloses an adhesive tape for semiconductor wafer thinning and a preparation process thereof. The adhesive tape for semiconductor wafer thinning comprises a base material layer and a bonding layer arranged on the surface of the base material layer, the base material layer is made of polyolefin, and the bonding layer is a modified acrylic acid adhesive layer; the modified acrylic acid adhesive layer is prepared from the following raw materials in parts by weight: 60 to 70 parts of 2-ethylhexyl acrylate, 15 to 25 parts of butyl acrylate, 5 to 10 parts of methyl methacrylate, 2 to 5 parts of hydroxyethyl acrylate, 0.5 to 2 parts of glycidyl methacrylate, 1 to 3 parts of a modifier, 0.8 to 1.2 parts of an isocyanate cross-linking agent, 0.3 to 0.8 part of an epoxy cross-linking agent and 0.3 to 0.8 part of azodiisobutyronitrile. According to the adhesive tape for semiconductor wafer thinning, the fixing and protecting effects on the wafer are improved.

The invention discloses a zwitter-ion modified acrylate dielectric elastomer film and a preparation method thereof. Zwitter-ions can be selected from sulfobetaine methacrylate (SBMA), carboxyl betaine methacrylate (CBMA), sulfobetaine acrylamide (SBAA) and the like. The acrylate monomer can be butyl acrylate (BA), dodecyl acrylate (LA), isoamyl acrylate (EHA) and the like. Zwitterions (special compounds which simultaneously carry equal positive and negative charges on the same molecule and are electrically neutral on the whole) are copolymerized into an acrylate dielectric elastomer through photo-initiated free radical polymerization reaction, zwitterionic clusters uniformly distributed in the dielectric elastomer can construct traps for capturing high-energy electrons, the leakage current of the material is reduced, and the dielectric property of the material is improved. And the intrinsic breakdown field strength of the material is improved. In addition, the mutual attraction effect between dipole ions with positive and negative charges in the structure provides driving force for intrinsic self-repairing. And after being electrically and mechanically damaged, the material can be self-recovered, so that the service life of the material is prolonged.

The invention discloses a wear-resistant environment-friendly PET base material adhesive tape and a preparation method thereof, and belongs to the technical field of adhesive tapes, raw materials comprise a PET adhesive tape film and an EB curing modified adhesive, the surface of the modified PET adhesive tape film subjected to corona treatment is coated with the EB curing modified adhesive, then electron beam radiation curing is carried out, the absorbed dose of electron beams is 38-42 kGy, and the EB curing modified adhesive is prepared. And then cooling, rolling and curing to obtain the wear-resistant environment-friendly PET base material adhesive tape. The modified PET adhesive tape film is prepared from the following raw materials: PET resin and modified polyolefin elastomer master batch; the EB curing modified adhesive is prepared from the following raw materials: butyl acrylate, 2-ethylhexyl acrylate, tripropylene glycol diacrylate, acrylate resin, urethane acrylate and starch modified core-shell microsphere powder. According to the mode, a modification process is added in the preparation process of the PET adhesive tape film and the adhesive, and finally the environment-friendly PET base material adhesive tape with excellent comprehensive performance is prepared.

The invention provides an adhesive composition, an optical adhesive, a preparation method of the optical adhesive and a flexible display device. The adhesive composition comprises a polymeric monomer raw material and a photoinitiator, wherein the light absorption peak wavelength of the photoinitiator is 200 nm to 460 nm; the photoinitiator accounts for 0.23%-0.52% of the mass percentage of the polymeric monomer raw material; the polymeric monomer raw material is prepared from the following components in parts by weight: 50 to 180 parts of acrylic matrix resin, 20 to 50 parts of acrylic resin containing a flexible long chain and 5 to 30 parts of acrylic ester with a hydroxyl group; the acrylic matrix resin is selected from at least one of acrylic acid-2-ethylhexyl acrylate, n-hexyl acrylate and butyl acrylate. The bending performance of the flexible display device can be met, the stable performance is achieved under sunlight irradiation, and meanwhile lossless separation can be achieved.

The present invention relates to a matting agent for HAA powder coatings and a preparation method thereof. The matting agent is a matting polymer containing special groups such as hydroxyl and epoxy groups with significantly different activities. The matting polymer is mainly prepared from glycidyl methacrylate, methyl methacrylate, butyl acrylate, 5-norbornene-2-methanol, 2-methyl-3-butene-2-ol, dicyclopentadiene dioxide, a hydroxyl polyester resin, and an accelerator. Due to the presence of hydroxyl and epoxy groups of varying activities in its structure, supplemented by the accelerator and the physical dispersion effect during the preparation process, the product has excellent matting ability and good storage and matting stability. It can reduce the gloss of HAA system powder coatings to 3-10%.

The invention relates to a lightweight foaming sole material, which comprises the following raw materials by mass: 20-30% of a PA / EBA modified blend; 10% to 20% of a TPEE / EBA modified blend; 10%-30% of an ethylene-butyl acrylate copolymer (EBA); 8%-15% of an ethylene-octylene copolymer POE; 8%-15% of brominated butyl rubber BIIR; 2%-3% of talcum powder; 5%-10% of a coupling agent; 0.5%-1% of a lubricant; 1%-2% of a foaming aid; 0.3%-1% of a cross-linking agent; and 3%-7% of a foaming agent. The foaming sole material provided by the invention has the advantages of high elasticity, tear resistance and wrinkle resistance; the preparation method is simple and low in production cost, and has a wide application prospect in the field of foamed sole materials.

The invention relates to the technical field of well drilling plugging agents, in particular to a high-strength consolidation type plugging agent. Comprising the following components in parts by weight: 30-68 parts of a polymer matrix, 15-36 parts of composite gel, 8-16 parts of a coagulator, 5-12 parts of an initiator, 7-12 parts of a nano material, 6-21 parts of a flexibilizer, 6-13 parts of a cross-linking agent and 2-8 parts of a flame retardant, the polymer matrix is prepared by taking ethyl acrylate and butyl acrylate as main monomers, methoxyethyl acrylate as a functional monomer and monobutyl itaconate as a vulcanization point monomer through copolymerization; the mass ratio of the ethyl acrylate to the butyl acrylate to the methoxyethyl acrylate to the monobutyl itaconate is (2-3): (1-2): (1-3): 1. The plugging agent has controllable curing time, is suitable for fractured and karst cave leakage layers, is high in plugging success rate, and can effectively improve the pressure-bearing capacity of stratums. And the plugging agent has good temperature resistance and is suitable for plugging construction in a high-temperature environment.

The invention provides a preparation method and application of a silicon dioxide anti-blocking agent for a thin film, and relates to the technical field of anti-blocking agents. The preparation method of the silicon dioxide anti-blocking agent comprises the following steps: uniformly mixing and stirring tetraethoxysilane, ethanol, water and ammonia water, adding polyethylene glycol, stirring, carrying out water bath reaction, centrifuging, washing and calcining to obtain porous silicon dioxide microspheres; the preparation method comprises the following steps: dispersing porous silicon dioxide in absolute ethyl alcohol, adding a silane coupling agent, reacting, centrifuging, washing and drying to obtain silanized porous silicon dioxide microspheres; dispersing the silanized porous silicon dioxide microspheres in deionized water, adding a surfactant lauryl sodium sulfate and a methyl methacrylate and butyl acrylate monomer mixture, adding an initiator azodiisobutyronitrile for reaction, and centrifuging, washing and drying after the reaction is completed; and finally, carrying out heat treatment on the obtained product. The binding force between existing silicon dioxide anti-blocking agent particles and a film substrate is improved, and long-term effectiveness is maintained.

The invention relates to the technical field of coatings, in particular to a high-performance styrene-acrylic emulsion, a preparation method thereof and application of the high-performance styrene-acrylic emulsion in coatings. The preparation method of the styrene-acrylic emulsion comprises the following steps: adding a surfactant, a buffer agent, 2-ethylhexyl acrylate, n-butyl acrylate, styrene, ethylene glycol dimethacrylate and monomer acrylic acid into a first part of water, and uniformly dispersing to obtain a prefabricated emulsion; heating the first part of the prefabricated emulsion, adding the first part of the initiator solution, and keeping the temperature; adding a second part of the prefabricated emulsion and a second part of the initiator solution, and heating and preserving heat after the addition is finished; and cooling the system, adding a third part of the initiator solution, continuously keeping the temperature, then cooling, and regulating the pH value of the system by using a second neutralizer, thereby obtaining the product. The styrene-acrylic emulsion is used as a component of the water-based heat insulation and heat preservation coating and can absorb more hollow microspheres and SiO2 aerogel cement in the coating, so that the coating has higher heat insulation and heat preservation performance, and the coating also has higher mechanical performance.

The invention discloses a slow-rebound memory sponge and a preparation method thereof, and belongs to the technical field of sponge material preparation, and the slow-rebound memory sponge comprises the following components by weight: 100 parts of diisocyanate, 100-150 parts of polyether polyol, 40-80 parts of slow-rebound polyether, 1-8 parts of organic silicon resin, 4-24 parts of modified resin, 3-20 parts of polycaprolactone resin, 1-3 parts of silicone oil, and 2-5 parts of an opening agent. The modified resin is a polymerization product obtained by taking 2-acrylic acid-2-[[(butylamino)-carbonyl] oxo] ethyl ester and butyl acrylate as blending monomers, and the modified resin is a polymerization product obtained by taking 2-acrylic acid-2-[[(butylamino)-carbonyl] oxo] ethyl ester and butyl acrylate as the blending monomers; through a blending strategy, the organic silicon resin, the modified resin and the polycaprolactone resin are added into the foamed polyurethane, so that the slow rebound resilience of the memory foam material is improved while the air permeability is kept.

The invention discloses an optical paste film and a preparation method thereof, and relates to the technical field of optical functional materials. The optical slurry film is prepared by taking a polyethylene glycol terephthalate film as a base material and coating an optical slurry coating, the optical slurry coating is prepared from the following raw materials in parts by weight: 12 to 16 parts of nano silicon dioxide, 22 to 28 parts of acetone and butanone mixed solvent, 7 to 9 parts of modified titanium dioxide, 4 to 6 parts of nano zirconium oxide, 30 to 35 parts of modified epoxy resin, 18 to 22 parts of butyl acrylate, 4 to 6 parts of dioctyl sebacate, 2.5 to 3.5 parts of silane coupling agent KH-570, 1 to 1.5 parts of organic silicon flatting agent and 0.6 to 1 part of organic silicon defoaming agent. 1.2-1.8 parts of an antioxidant 1010, 3-4 parts of a photoinitiator 184 and 6-8 parts of bis (4-tert-butylphenyl) iodine hexafluorophosphate; the polyethylene glycol terephthalate film pretreatment material comprises absolute ethyl alcohol and deionized water. The raw materials are scientifically proportioned, the titanium dioxide and the epoxy resin are clearly modified, the preparation process is complete, and the finished product is high in light transmittance, good in weather resistance, adaptive to the requirements of the optical field and high in practicability.

The application provides a kind of fire-retardant heat-conducting polyacrylic acid fireproof paint and its preparation method, according to mass fraction includes the following raw materials: methyl methacrylate 3-24 parts, butyl acrylate 3-30 parts, acrylic acid 0.5-9 parts, intumescent monomer 2-15 parts, modified ceramic material 0.6-10 parts, composite emulsifier 0.6-3 parts, buffer 0.8-1.8 parts and initiator 0.2-1.5 parts;Intumescent monomer is obtained by the reaction of bio-based material, methyl methacrylate phosphate and melamine;The modified ceramic material is the ceramic material modified by silane coupling agent.The fire-retardant heat-conducting polyacrylic acid fireproof paint of the application has the advantages of simple formula, no environmental pollution, low toxicity, low VOC content, no irritating odor, etc.;High efficiency of flame retardancy, can quickly generate high-quality intumescent carbon layer after fire.

The invention relates to the technical field of high polymer materials, and provides fireproof flame-retardant ceramic silicone rubber and a preparation method thereof. The fireproof flame-retardant ceramic silicone rubber is prepared from, by mass, 100 parts of silicone rubber, 5-20 parts of fumed silica, 10-65 parts of a modified flame retardant, 20-50 parts of ceramic powder, 5-20 parts of a fluxing agent, 0.5-2 parts of a vulcanizing agent and 1-7 parts of a coupling agent, and the modified flame retardant is prepared from butyl acrylate-sodium p-styrenesulfonate-vinyltriethoxysilane copolymer and an inorganic flame retardant. According to the technical scheme, the problems that in the prior art, the compatibility of the inorganic flame retardant and the silicone rubber is poor, and consequently the flame retardant effect and the mechanical property of the ceramic silicone rubber are poor are solved.

The invention discloses an insulating nano ceramic resin composite coating. The preparation method comprises the following steps: 1, mixing methyl methacrylate and butyl acrylate, and dropwise adding the mixture into an aqueous solution containing an emulsifier, an initiator and a buffer agent under a protective atmosphere for reaction to obtain a seed emulsion; and 2, emulsifying the modified filler, methyl methacrylate, butyl acrylate, an emulsifier and water, adjusting the pH value, and dropwise adding into the seed emulsion and the initiator under a protective atmosphere to react. And then cooling and adding a redox initiation system for continuous reaction to finally obtain the composite coating. The preparation method has the beneficial effects that the hexagonal boron nitride nanosheets are subjected to surface functionalization treatment by synthesizing a multifunctional modifier, so that the dispersity and interface bonding performance of filler in a resin matrix are remarkably improved, and the coating has excellent insulativity, strong adhesive force, good flame retardance and outstanding corrosion resistance at the same time.

The present invention discloses a preparation method and application of a single-ion conductor composite binder. The binder is prepared by compounding and modifying a copolymer of butyl acrylate and lithium 2-acrylamido-2-methylpropanesulfonate with polyisobutylene. Its main features are as follows: First, the binder can be completely dissolved in the non-polar solvent toluene, solving the problem of incompatibility between traditional binders and sulfide electrolytes; Second, the unique molecular structure design endows it with excellent adhesion performance and ion conduction ability at the same time, which can significantly reduce the interfacial impedance. The flexible chain segment of butyl acrylate provides elastic support, and the sulfonic acid groups of lithium 2-acrylamido-2-methylpropanesulfonate form strong chemical bonds with the surface of sulfide particles, enhancing the binding force with the electrolyte. The preparation process of the binder of the present invention is simple, the cost is controllable, and it is suitable for large-scale production, providing an important material solution for promoting the industrialization of sulfide all-solid-state batteries.

The invention discloses a modified polylactic acid composite material and application thereof. The modified polylactic acid composite material comprises the following raw materials in percentage by weight: 15-50% of polylactic acid; 15 to 50% of poly (butylene succinate); 15 to 50% of poly (butylene adipate-co-terephthalate); 1-5% of a compatibilizer; 0.1-1% of an antioxidant; 0.1-5% of a release agent; 0.1-1% of a melt flow regulator; 0.1-5% of a nucleating agent; 0.1-1% of an anti-hydrolysis agent; wherein the compatibilizer comprises an elastomer containing an epoxy group, an elastomer containing a maleic anhydride group, an ethylene-methyl acrylate random copolymer and an ethylene-butyl acrylate copolymer, and the weight ratio of the elastomer containing the epoxy group to the elastomer containing the maleic anhydride group is 1: 4-4: 1. The modified polylactic acid composite material has good fluidity and mechanical properties, and is suitable for preparing the cable tie by adopting an injection molding mode.

The invention discloses a high-temperature-resistant flame-retardant wire harness and a preparation method thereof, and relates to the technical field of electric harnesses. The method comprises the following steps: firstly, introducing phosphorus and silicon flame-retardant elements on a polyethylene molecular chain through plasma activation and free radical grafting reaction to prepare phosphorus-silicon grafted modified polyethylene, then compounding aminated silicon dioxide and organic intercalated montmorillonite by using isophorone diisocyanate as a bridging agent to prepare the phosphorus-silicon grafted modified polyethylene composite material. The preparation method comprises the following steps: preparing an isocyanate-bridged silicon dioxide-montmorillonite composite filler to improve the dispersity and compatibility of the filler in a matrix, carrying out extrusion granulation on modified polyethylene, an ethylene-butyl acrylate copolymer, maleic anhydride grafted polyethylene, the composite filler, nano magnesium hydroxide and other additives to prepare polyethylene wire harness particles, and finally, carrying out extrusion granulation on the polyethylene wire harness particles to prepare the cable harness. And coating the surface of a copper core wire with the particles through a single-screw extrusion coating machine, and carrying out subsequent water cooling, steam treatment, drying and rolling to obtain a finished wire harness. The wire harness prepared by the invention has excellent high temperature resistance and flame retardance.