1069 results about "Butyl acrylate" patented technology

Provided are a water-resistant wood-plastic reinforced composite flooring and a manufacturing method therefor. Wood flour is boiled in boiling water for 3-4 hours, filtered and dried, to obtain dried wood flour; polypropylene, butyl acrylate, methyl methacrylate, maleic anhydride and dicumyl peroxide are mixed evenly, extruded and granulated, and dried to obtain a compatibilizer; the dried wood flour and polypropylene are mixed evenly, the compatibilizer is added and mixed evenly, then extrusion and granulation, and injection molded, are performed, to obtain a wood-plastic flooring blank; a composite resin emulsion and a photoinitiator are ultrasonically mixed evenly, and the wood-plastic flooring blank is immersed therein, then taken out and dried at room temperature, and then vacuum dried and UV cured, to obtain water-resistant wood-plastic reinforced composite flooring.

The invention discloses a single-ion conductor polymer, a ternary composite binder solution, high-solid-content sulfide electrolyte slurry and a wet film forming method and application thereof, and belongs to the technical field of all-solid-state lithium batteries. The key technical problems in the wet membrane preparation of the sulfide electrolyte are solved through an innovative solvent-binder synergistic system, and the method specifically comprises the steps that 1, through the synergistic effect of a non-polar solvent and a weak-polar solvent, low-viscosity coating of high-solid-content slurry is achieved while the chemical stability of the sulfide electrolyte is guaranteed; 2, a poly (lithium styrenesulfonate-butyl acrylate), styrene butadiene rubber and polyisobutene ternary composite binder is designed, a lithium ion transmission channel is provided through a lithium sulfonate group, a benzene ring structure in the styrene butadiene rubber enhances the mechanical strength, long-chain alkane in the polyisobutene improves the interface adhesive force, and the mechanical strength is improved; the three components cooperate to realize balance of mechanical and electrochemical properties of the electrolyte membrane, so that the prepared electrolyte membrane has low porosity, high ionic conductivity and mechanical strength.

Disclosed in the present invention are a fluorosilicone-modified low-surface-energy antifouling coating and a preparation method therefor. The coating comprises the following components in parts by weight: 11-15 parts of butyl acrylate, 3-4 parts of dodecafluoroheptyl methacrylate, 3-4 parts of vinyl-terminated polydimethylsiloxane, 3-4 parts of 2-hydroxy-4-acryloyloxybenzophenone, 30-38 parts of methyl isobutyl ketone, 0.15-0.25 parts of azobisisobutyronitrile, 0.1-0.2 parts of sodium hydroxide, 2-3 parts of modified titanium dioxide nanoparticles, and 0.5-1.5 parts of 3-aminopropyltriethoxysilane. In the present invention, vinylpentamethyldisiloxane reacts with decamethylcyclopentasiloxane to prepare vinyl-terminated polydimethylsiloxane; a titanium dioxide precursor is mixed with polydopamine nanoparticles for modification to prepare modified titanium dioxide nanoparticles; and then the components above are mixed to prepare the fluorosilicone-modified low-surface-energy antifouling coating. The coating has low surface energy and good adhesion and ultraviolet resistance.

The invention belongs to the technical field of sewage treatment, and particularly relates to a demulsifier for eliminating an oil-water interface emulsion layer in oilfield produced liquid treatment and a preparation method of the demulsifier. The preparation method comprises the following steps: adding acrylamide, 1-allyl-3-methylimidazolium bis (trifluoromethanesulfonyl) imine salt, allyl tributyl phosphonium chloride and deionized water into a first reactor, and heating and dissolving the acrylamide, the 1-allyl-3-methylimidazolium bis (trifluoromethanesulfonyl) imine salt, the allyl tributyl phosphonium chloride and the deionized water; adding allyl (diisopropylamino) dimethylsilane, butyl acrylate, deionized water, octylphenol polyoxyethylene ether-10, lauryl sodium sulfate and monopotassium phosphate into the second reactor, and stirring to obtain an emulsion; adding an initiator and sodium hydrogen sulfite into a second reactor, carrying out heating and heat preservation reaction, pouring the mixed solution in the first reactor, and continuously carrying out reaction, heating and heat preservation to obtain a viscous liquid; and drying and granulating the viscous liquid to obtain the demulsifier. The demulsifier provided by the invention has the characteristics of simple synthesis process and high demulsification rate.

The invention belongs to the field of modified self-repairing calcium aluminate cement 3D printing, and particularly relates to a phosphate modified self-repairing calcium aluminate cement 3D printing material and a preparation method thereof. The phosphate modified self-repairing calcium aluminate cement 3D printing material prepared by the invention is prepared from the following raw materials in parts by mass: 60 to 70 parts of calcium aluminate cement, 3 to 7 parts of silica fume, 2 to 4 parts of metakaolin, 0.5 to 3.5 parts of double-template modified calcium bentonite, 0.8 to 1.5 parts of amino modified sodium polyphosphate and 0.15 to 0.8 part of basalt fiber. The invention relates to a concrete anti-microbial agent, which is prepared from the following raw materials in parts by weight: 20-30 parts of water, 20-30 parts of water, 20-30 parts of water, 20-30 parts of nano calcium carbonate, 20-30 parts of nano calcium carbonate, 20-30 parts of magnesium phosphate cement coated bacteria-loaded porous microspheres, 20-30 parts of a polycarboxylate superplasticizer, 20-30 parts of an organic silicon defoaming agent and 25-35 parts of mixing water. The technical-economic cooperation requirement of building 3D printing under complex working conditions is met, and various indexes of phosphate modified calcium aluminate cement applied to the 3D printing technology are met.

The invention relates to the technical field of plugging agents, and discloses a viscoelastic polymer type self-assembly plugging agent and a preparation method thereof. The preparation method comprises the following steps: adding acrylamide, butyl acrylate, 2-acrylamide-2-methylpropanesulfonic acid, quaternized cyclodextrin, gamma-glycidyl ether oxypropyl trimethoxy silane modified bentonite, Schiff base styrene, a sodium dodecyl benzene sulfonate emulsifier and octadecyl dimethyl allyl ammonium chloride into a reaction kettle; and adding an azodiisobutyronitrile initiator into the deionized water, uniformly mixing, and reacting for 4-5 hours at 50-65 DEG C to obtain the viscoelastic polymer type self-assembled plugging agent after the reaction is finished. The plugging agent disclosed by the invention has a relatively good plugging effect, and effectively solves the problem that the gel strength is weakened or the gelling is not thorough due to the formation shearing effect in a continuous gel migration process.

The invention relates to the technical field of dispersing agents, and particularly discloses a high-concentration water-based graphene dispersing agent. The high-concentration water-based graphene dispersing agent is prepared from the following raw materials in parts by weight: 25 to 30 parts of a modified nonionic surfactant, 8 to 12 parts of sodium lignin sulfonate, 0.4 to 0.8 part of a de-foaming agent and 90 to 100 parts of de-ionized water, the modified nonionic surfactant is prepared by the following steps: carrying out dehydration esterification reaction on 1-pyrene butyric acid and N-hydroxysuccinimide, carrying out nucleophilic substitution reaction on the obtained product and polyethylene glycol monododecyl ether to obtain modified 1-pyrene butyric acid, and finally polymerizing the modified 1-pyrene butyric acid and n-butyl acrylate. The method is easy to operate, graphene does not need to be subjected to oxidation reduction, the integrity of a graphene sheet layer can be completely kept, and the performance of the graphene can be fully exerted; the prepared graphene dispersing agent realizes efficient dispersing effect, excellent stability and environment-friendly safety characteristics, and provides solid technical support for wide application of graphene in multiple fields.

The invention relates to a biodegradable composite material as well as a preparation method and application thereof, and belongs to the technical field of compositions of high-molecular compounds. The biodegradable composite material is prepared from the following components in parts by weight: 46 to 87 parts of PBAT resin, 2 to 10 parts of PLA resin, 10 to 40 parts of calcium carbonate, 0.5 to 2 parts of a slipping aid and 0.5 to 2 parts of an edge sealing aid, the molar content of D-lactic acid in the PLA resin is greater than or equal to 2%; the particle size D50 of the calcium carbonate is less than 1.8 microns; the edge sealing auxiliary agent is an ethylene-acrylic acid copolymer, an ethylene-vinyl acetate copolymer, an ethylene-methyl acrylate copolymer, an ethylene-methyl acrylate-glycidyl methacrylate terpolymer, an ethylene-butyl acrylate copolymer, an ethylene-butyl acrylate-glycidyl methacrylate terpolymer, an ethylene-vinyl acetate copolymer, an ethylene-vinyl acetate copolymer, an ethylene-vinyl acetate copolymer, an ethylene-vinyl acetate copolymer, an ethylene-vinyl acetate copolymer, an ethylene-vinyl acetate copolymer, an ethylene-vinyl acetate copolymer and an ethylene-vinyl acetate copolymer. And at least one of epoxy resin. The biodegradable composite material has excellent long-acting edge sealing performance.

The invention relates to the technical field of coatings, in particular to an acrylate-epoxy resin composite coating and a preparation method thereof. According to the technical scheme, the coating is prepared from 25 to 35 parts of methyl methacrylate, 15 to 25 parts of butyl acrylate, 10 to 20 parts of epoxy resin E-5110, 8 to 15 parts of organic silicon modified acrylate prepolymer, 5 to 12 parts of fluorocarbon modified epoxy resin, 4 to 8 parts of core-shell structure corrosion inhibition nano container, 1 to 3 parts of functionalized graphene quantum dots and 4 to 10 parts of polyhedral oligomeric silsesquioxane maleimide modified amine curing agent. And 1-3 parts of a hindered amine light stabilizer. By integrating the core-shell structure corrosion inhibition nano container, the functionalized graphene quantum dots and the photo-thermal dual responsive curing agent component, the sensing, response and self-repairing of the coating on damage are realized, and long-acting corrosion resistance, weather resistance, bacteria resistance, mechanical property balance and intelligent maintenance are considered; and efficient and economical full-period protection is provided for equipment in an extreme environment.

The invention discloses an OCA (Optical Clear Adhesive) solution for a folding screen protective film, the OCA solution comprises an optical raw adhesive, a curing agent and a first solvent, the raw adhesive is prepared from the following raw materials in parts by mass: 270-283 parts of 2-ethylhexyl acrylate, 50-62 parts of butyl acrylate, 318-330 parts of methyl acrylate, 40-55 parts of acrylic acid, 1-2 parts of gamma-acryloyloxypropyltrimethoxysilane, 2.1-2.3 parts of an initiator and 1250-1350 parts of a second solvent; the second solvent comprises methylbenzene and ethyl acetate. According to the OCA optical glue solution for the folding screen protection film, raw glue is prepared from the isooctyl acrylate, the butyl acrylate, the methyl acrylate, the acrylic acid, the gamma-acryloyloxy propyl trimethoxy silane and the initiator in a toluene and ethyl acetate compounded solvent system, and an OCA glue layer with excellent stripping force, light transmittance, holding power and bending resistance is obtained after curing; and the cost of the raw materials is optimized, and the method is more economical.

The invention relates to the technical field of fabric waterproofing agents, in particular to a polyurethane modified organic silicon fluoride-free waterproofing agent and a preparation method thereof. The polyurethane modified organic silicon fluoride-free waterproof agent is prepared from the following raw materials in parts by mass: 5 to 15 parts of hexamethylene diisocyanate, 5 to 15 parts of butyl acrylate, 1 to 5 parts of methyl methacrylate, 40 to 60 parts of octamethylcyclotetrasiloxane, 10 to 30 parts of alpha, omega-dihydroxy polydimethylsiloxane and 5 to 10 parts of gamma-aminopropyl methyl diethoxy silane. The invention relates to a silane coupling agent, which is prepared from the following raw materials in parts by weight: 1 to 5 parts of glycidyl ether oxypropyl trimethoxy silane, 0.1 to 1 part of tetramethylammonium hydroxide, 0.1 to 1 part of triethylamine, 2 to 5 parts of tetraethoxysilane, 0.2 to 0.75 part of ammonia, 0.1 to 1 part of silane coupling agent KH-570, 0.01 to 0.1 part of dibutyltin dilaurate, 1 to 5 parts of epsilon-caprolactam, 1 to 2 parts of emulsifier and 0.1 to 1 part of initiator. The fabric treated by the method has good softness and excellent hydrophobic effect.

The present invention relates to the field of food packaging, and in particular to a mixed coating liquid and a fluorine-free oil-proof barrier paper and a preparation method thereof, which are prepared by uniformly mixing the following raw materials in percentage by mass: component A: 1-5% silica gel; component B: 1-5% methylhydrogensiloxane / polysiloxane; component C: 5-15% styrene; component D: 3-10% acrylic acid; component E: 5-20% butyl acrylate; component F: 20-70% water; the sum of the mass percentages of the above components is 100%. At the same time, a fluorine-free oil-proof barrier paper is provided, which is formed by coating a mixed coating liquid on at least one surface of a paper substrate. This scheme completely excludes the use of fluoride-containing materials, realizes green packaging product materials that are harmless to the human body, and conforms to the concept of environmental protection and health. At the same time, through a specific silicon nano-modified material mixed coating liquid, this scheme reaches the oil-proof level of 6 and above (up to 12) required by the market, effectively preventing grease penetration and keeping the outer surface of the package clean.

The invention provides an environment-friendly water-based acrylic emulsion adhesive without containing an organic solvent. The environment-friendly water-based acrylic emulsion adhesive is prepared from the following raw materials: 55-60 wt% of eleostearic acid hydroxyethyl acrylate (TMA), 15-25 wt% of butyl acrylate (BA), 3-10 wt% of acrylic acid (AA), 2-5 wt% of a cross-linking agent, 3-8 wt% of modified soil and 0.5-1 wt% of an initiator as a solid phase; the liquid phase is deionized water, and the environment-friendly water-based acrylic emulsion adhesive is prepared through semi-continuous emulsion polymerization. The prepared environment-friendly water-based acrylic emulsion adhesive is high in biodegradability and low in VOC content, has the mechanical property matched with that of a traditional acrylic emulsion adhesive and also has the self-repairing capacity, waste materials can be treated by changing the temperature or pH condition, the environment-friendly water-based acrylic emulsion adhesive can be recycled for multiple times, and the recycling cost is reduced.

The invention relates to the technical field of cables, and provides a wear-resistant cable and a preparation method thereof. The wear-resistant cable sequentially comprises an outer protective layer, an insulating layer and a conductor from outside to inside, and the outer protective layer comprises the following components in parts by weight: 80 parts of polyurethane, 18-24 parts of high-density polyethylene, 4-6 parts of an ethylene-butyl acrylate copolymer, 5-8 parts of an ethylene-vinyl acetate copolymer, 10-20 parts of sillimanite, 4-8 parts of a lubricating component, 20-30 parts of a flame retardant, 1-3 parts of an antioxidant and 2-4 parts of a plasticizer; the lubricating component comprises N, N-di (hydroxyethyl) cocamide and aluminum dihydroxy stearate in a weight ratio of (1: 9)-(9: 1). According to the technical scheme, the problem of poor wear resistance of the outer sheath of the cable in the prior art is solved.

The invention discloses a high-toughness polyethylene composite film and a preparation method thereof, and belongs to the field of high polymer materials. The outer layer is prepared from linear low-density polyethylene, an ethylene-butyl acrylate copolymer, an antioxidant 1010 and an ultraviolet light absorber UV-531; the middle layer is prepared from linear low-density polyethylene, a polyolefin elastomer, an ethylene-butyl acrylate copolymer, stearic acid modified calcium carbonate, an antioxidant and an ultraviolet light absorber; and the inner layer is composed of linear low-density polyethylene, an ethylene-butyl acrylate copolymer, an antioxidant 1010 and an ultraviolet light absorber UV-531. Drying the raw materials; mixing heavy calcium carbonate with stearic acid; each layer is mixed at a low speed according to a ratio; and carrying out three-layer co-extrusion film blowing, two-way stretching, corona and annealing. The surface tension of the composite film reaches 40 mN / m, the maximum longitudinal and transverse tensile strength is 23 MPa, the tearing strength is 120 kN / m, the elongation at break is 700%, and the performance of the composite film is superior to that of traditional casting and blow molding process products.

The invention discloses a high-flexibility anti-cracking coating and a preparation method thereof, and belongs to the technical field of building coatings. The coating is prepared from the following components in parts by mass: 50 to 70 parts of acrylic acid-organic silicon copolymer elastic emulsion with a core-shell structure, 3 to 8 parts of nano cellulose and polyester staple fiber composite fiber reinforced system, 20 to 30 parts of modified mica powder and fumed silica functional filler with a high radius-thickness ratio, 5 to 10 parts of auxiliaries and 10 to 15 parts of deionized water. A core layer of the elastic emulsion is a butyl acrylate-styrene elastomer, a shell layer of the elastic emulsion is a methyl methacrylate-organosiloxane copolymer, and a coating is endowed with high elongation at break and low-temperature crack resistance through the synergistic effect of a flexible network of the core layer and a rigid-flexible gradient structure of the shell layer. The nano cellulose and the polyester staple fiber form a dual-scale reinforcing system, so that cracks are bridged, and stress is dispersed; and the modified mica powder and fumed silica are compounded to improve the compactness and wear resistance of the coating.

The invention discloses an anti-aging and anti-corrosion coating and a preparation method thereof, and relates to the technical field of coatings. When the anti-aging and anti-corrosion coating is prepared, firstly, tetramethyl tetravinyl cyclotetrasiloxane, n-butyllithium and dimethyl-3-chloropropyl chlorosilane react to obtain modified polysiloxane, then 4-vinylpyridine, methyl methacrylate and n-butyl acrylate are copolymerized and then react with the modified polysiloxane, and then bis (4-chlorphenyl) phosphine is grafted to obtain the anti-aging and anti-corrosion coating. Finally, reacting with p-aminodiphenylamine to obtain modified acrylic resin; secondly, enabling the titanium dioxide nanosheet pretreated by 3-aminopropyltrimethoxysilane to react with ester phthalocyanine, and then hydrolyzing to obtain a modified titanium dioxide nanosheet; finally, mixing the modified acrylic resin, the modified titanium dioxide nanosheet, a solvent, a dispersing agent and a defoaming agent to obtain the anti-aging and anti-corrosion coating. The anti-aging and anti-corrosion coating prepared by the invention has excellent anti-aging, anti-corrosion, flame-retardant and antibacterial properties.

The invention relates to the technical field of high polymer materials, and discloses a high-durability pressure-sensitive adhesive with low VOCs release and a preparation method thereof.The high-durability pressure-sensitive adhesive is prepared from, by weight, 50-80 parts of acrylate copolymer, 0.5-5 parts of cross-linking agent, 10-30 parts of tackifying resin, 1-10 parts of inorganic filler, 0.1-2 parts of antioxidant and 20-50 parts of solvent. Wherein the tackifying resin is at least one of hydrogenated petroleum resin and glycerol ester of rosin, and the inorganic filler is one of nanoscale silicon dioxide and calcium carbonate. Butyl acrylate is used as a main monomer, 2-ethylhexyl acrylate is used as a comonomer, acrylic acid is used as a functional monomer, benzoyl peroxide is used as an initiator, free radical polymerization is carried out at the temperature of 60-85 DEG C under the protection of nitrogen for 4-8 hours, and a copolymer chain with the molecular weight distribution index (PDI) smaller than or equal to 2.5 is formed, so that the viscosity and elasticity of colloid can be balanced; the peeling strength and the weather resistance are improved, and the colloid is prevented from being too soft or embrittled.

The invention provides an acrylate assistant for PVC (polyvinyl chloride) and a preparation method of the acrylate assistant, and belongs to the technical field of acrylate assistants. The preparation method comprises the steps of nano montmorillonite functionalization, synthesis of a core layer, synthesis of a middle layer and synthesis of a shell layer. The synthesis step of the core layer comprises the following steps: adding a core layer emulsion into a reaction kettle, adding an ammonium persulfate solution for the first time, heating to 64-68 DEG C, adding an ammonium persulfate solution for the second time, and reacting for 48-55 minutes to obtain a functionalized core emulsion; the core layer emulsion is prepared from deionized water, functionalized nano montmorillonite, sodium allyloxy hydroxypropyl sulfonate, butyl acrylate, 2-ethylhexyl acrylate, hydroxyethyl methylacrylate and gamma-methacryloyloxypropyltrimethoxysilane through ultrasonic treatment, and the core layer emulsion is prepared from the deionized water, the functionalized nano montmorillonite, the sodium allyloxy hydroxypropyl sulfonate, the butyl acrylate, the 2-ethylhexyl acrylate, the hydroxyethyl methylacrylate and the gamma-methacryloyloxypropyltrimethoxysilane through ultrasonic treatment; the prepared acrylate auxiliary agent is used in PVC, the fluidity can be improved, and meanwhile the impact resistance, the strength performance and the high-temperature stability performance are enhanced.

The invention discloses a high-temperature-resistant flame-retardant CPVC power cable protection pipe and a preparation method thereof, and relates to the technical field of cable protection pipes. The high-temperature-resistant flame-retardant CPVC power cable protection pipe at least comprises the following raw materials in parts by mass: 100 parts of chlorinated polyvinyl chloride; 15 to 25 parts of high impact resistance type MCS resin; 8 to 12 parts of poly (1, 2-propylene glycol adipate); 12 to 20 parts of a sepiolite-methyl methacrylate-butyl acrylate compound; 8-15 parts of aluminum-titanium composite coupling agent modified magnesium-aluminum-lanthanum hydrotalcite; 3-6 parts of a rare earth composite heat stabilizer; 2-4 parts of a processing aid; 0.5 to 1.5 parts of an antioxidant; and 1-2 parts of a lubricant. The prepared high-temperature-resistant flame-retardant CPVC power cable protection pipe has high heat resistance, high flame retardance and high impact resistance, and is excellent in comprehensive performance, high in safety and reliability and long in service life.

The invention discloses an intaglio printing ink composition and an intaglio printing method, and belongs to the technical field of ink preparation, the intaglio printing ink composition comprises the following components by weight: 40-80 parts of a polyacrylic acid emulsion and / or a polyacrylate emulsion, 5-15 parts of a hydroxyl acrylate monomer, 4-12 parts of a cross-linking agent, and 5-15 parts of a low alcohol solvent, 8-26 parts of pigment filler, 1-8 parts of an initiator and 3-10 parts of an auxiliary agent; the cross-linking agent is formed by taking pentaerythritol as a matrix, preparing pentaerythritol ester containing bromo-isobutyl through acylation reaction ester formation, and then polymerizing with tert-butyl acrylate through atom transfer radical polymerization reaction. By introducing the cross-linking agent, the curing speed of the resin binder is increased, and meanwhile, the adhesive force and the stability of the ink are improved.

The invention relates to the technical field of semiconductor wafer processing, and particularly discloses an adhesive tape for semiconductor wafer thinning and a preparation process thereof. The adhesive tape for semiconductor wafer thinning comprises a base material layer and a bonding layer arranged on the surface of the base material layer, the base material layer is made of polyolefin, and the bonding layer is a modified acrylic acid adhesive layer; the modified acrylic acid adhesive layer is prepared from the following raw materials in parts by weight: 60 to 70 parts of 2-ethylhexyl acrylate, 15 to 25 parts of butyl acrylate, 5 to 10 parts of methyl methacrylate, 2 to 5 parts of hydroxyethyl acrylate, 0.5 to 2 parts of glycidyl methacrylate, 1 to 3 parts of a modifier, 0.8 to 1.2 parts of an isocyanate cross-linking agent, 0.3 to 0.8 part of an epoxy cross-linking agent and 0.3 to 0.8 part of azodiisobutyronitrile. According to the adhesive tape for semiconductor wafer thinning, the fixing and protecting effects on the wafer are improved.

The invention discloses a zwitter-ion modified acrylate dielectric elastomer film and a preparation method thereof. Zwitter-ions can be selected from sulfobetaine methacrylate (SBMA), carboxyl betaine methacrylate (CBMA), sulfobetaine acrylamide (SBAA) and the like. The acrylate monomer can be butyl acrylate (BA), dodecyl acrylate (LA), isoamyl acrylate (EHA) and the like. Zwitterions (special compounds which simultaneously carry equal positive and negative charges on the same molecule and are electrically neutral on the whole) are copolymerized into an acrylate dielectric elastomer through photo-initiated free radical polymerization reaction, zwitterionic clusters uniformly distributed in the dielectric elastomer can construct traps for capturing high-energy electrons, the leakage current of the material is reduced, and the dielectric property of the material is improved. And the intrinsic breakdown field strength of the material is improved. In addition, the mutual attraction effect between dipole ions with positive and negative charges in the structure provides driving force for intrinsic self-repairing. And after being electrically and mechanically damaged, the material can be self-recovered, so that the service life of the material is prolonged.

The present invention therefore relates to aqueous polymer latices of copolymers obtainable by aqueous emulsion polymerisation of ethylenically unsaturated monomers M, which comprise i. 5 to 90% by weight, in particular 10 to 70% by weight, especially 10 to 50% by weight, based on the total amount of monomers M, of a monomer M1, which is 1-hexyl acrylate; ii. 0 to 70% by weight, based on the total amount of monomers M, of at least one monomer M2, which is selected from C2-C5-alkyl esters of acrylic acid, except for tert-butyl acrylate, C7-C20-alkyl esters of acrylic acid and C5-C20-alkyl esters of methacrylic acid and mixtures thereof; iii. 5 to 70% by weight, based on the total amount of monomers M, of at least one monomer M3, which is selected from tert-butyl acrylate, C1-C4-alkyl esters of methacrylic acid, C5-C20-cycloalkyl esters of acrylic acid, C5-C20-cycloalkyl esters of methacrylic acid, C5-C20-cycloalkylmethyl esters of acrylic acid, C5-C20-cycloalkylmethyl esters of methacrylic acid, where cycloalkyl in the aforementioned monomers is mono-, bi- or tricyclic and where 1 or 2 nonadjacent CH2 moieties of cycloalkyl may be replaced by oxygen atoms and where cycloalkyl may be unsubstituted or carry 1, 2, 3 or 4 methyl groups, and monovinyl aromatic monomers, methylene-gamma-butyrolactone and mixtures thereof; where the total amount of monomers M1 and M2 is in the range from 10 to 90% by weight, based on the total amount of ethylenically unsaturated monomers M, and where the total amount of monomers M1, M2 and M3 is at least 90% by weight, based on the total amount of ethylenically unsaturated monomers M. The present invention also relates to a process for producing the aqueous polymer latices of the present invention. The present invention also relates to the use of these polymer latices as binders in waterborne coating compositions and waterborne adhesive compositions, in particular as binders in waterborne coating compositions.

The invention discloses a wear-resistant environment-friendly PET base material adhesive tape and a preparation method thereof, and belongs to the technical field of adhesive tapes, raw materials comprise a PET adhesive tape film and an EB curing modified adhesive, the surface of the modified PET adhesive tape film subjected to corona treatment is coated with the EB curing modified adhesive, then electron beam radiation curing is carried out, the absorbed dose of electron beams is 38-42 kGy, and the EB curing modified adhesive is prepared. And then cooling, rolling and curing to obtain the wear-resistant environment-friendly PET base material adhesive tape. The modified PET adhesive tape film is prepared from the following raw materials: PET resin and modified polyolefin elastomer master batch; the EB curing modified adhesive is prepared from the following raw materials: butyl acrylate, 2-ethylhexyl acrylate, tripropylene glycol diacrylate, acrylate resin, urethane acrylate and starch modified core-shell microsphere powder. According to the mode, a modification process is added in the preparation process of the PET adhesive tape film and the adhesive, and finally the environment-friendly PET base material adhesive tape with excellent comprehensive performance is prepared.

The invention provides an adhesive composition, an optical adhesive, a preparation method of the optical adhesive and a flexible display device. The adhesive composition comprises a polymeric monomer raw material and a photoinitiator, wherein the light absorption peak wavelength of the photoinitiator is 200 nm to 460 nm; the photoinitiator accounts for 0.23%-0.52% of the mass percentage of the polymeric monomer raw material; the polymeric monomer raw material is prepared from the following components in parts by weight: 50 to 180 parts of acrylic matrix resin, 20 to 50 parts of acrylic resin containing a flexible long chain and 5 to 30 parts of acrylic ester with a hydroxyl group; the acrylic matrix resin is selected from at least one of acrylic acid-2-ethylhexyl acrylate, n-hexyl acrylate and butyl acrylate. The bending performance of the flexible display device can be met, the stable performance is achieved under sunlight irradiation, and meanwhile lossless separation can be achieved.

The present invention relates to a matting agent for HAA powder coatings and a preparation method thereof. The matting agent is a matting polymer containing special groups such as hydroxyl and epoxy groups with significantly different activities. The matting polymer is mainly prepared from glycidyl methacrylate, methyl methacrylate, butyl acrylate, 5-norbornene-2-methanol, 2-methyl-3-butene-2-ol, dicyclopentadiene dioxide, a hydroxyl polyester resin, and an accelerator. Due to the presence of hydroxyl and epoxy groups of varying activities in its structure, supplemented by the accelerator and the physical dispersion effect during the preparation process, the product has excellent matting ability and good storage and matting stability. It can reduce the gloss of HAA system powder coatings to 3-10%.

The invention relates to the field of ink preparation, and particularly discloses durable antibacterial cooking-resistant ink as well as a preparation method and application thereof. The ink comprises the following components in parts by weight: 20-30 parts of waterborne acrylic resin, 20-30 parts of waterborne polyurethane resin, 10-20 parts of modified carbon black, 3-8 parts of an antibacterial component, 1-2 parts of a wetting dispersant, 1-2 parts of a defoaming agent and 25-35 parts of water, the water-based acrylic resin is prepared from the following raw materials: 30 to 40 parts of acrylic acid, 15 to 20 parts of butyl acrylate, 10 to 20 parts of methyl methacrylate, 5 to 10 parts of phenyl-containing monomer, 20 to 30 parts of hydroxyl-containing monomer, 0.5 to 2 parts of initiator and 20 to 40 parts of solvent. The phenyl-containing monomer comprises styrene and allyl benzyl ether; the hydroxyl group-containing monomer is prepared from hydroxyethyl acrylate and 4-hydroxybutyl acrylate. The printing ink prepared by the invention has steaming and boiling resistance and lasting antibacterial property.

The invention relates to a lightweight foaming sole material, which comprises the following raw materials by mass: 20-30% of a PA / EBA modified blend; 10% to 20% of a TPEE / EBA modified blend; 10%-30% of an ethylene-butyl acrylate copolymer (EBA); 8%-15% of an ethylene-octylene copolymer POE; 8%-15% of brominated butyl rubber BIIR; 2%-3% of talcum powder; 5%-10% of a coupling agent; 0.5%-1% of a lubricant; 1%-2% of a foaming aid; 0.3%-1% of a cross-linking agent; and 3%-7% of a foaming agent. The foaming sole material provided by the invention has the advantages of high elasticity, tear resistance and wrinkle resistance; the preparation method is simple and low in production cost, and has a wide application prospect in the field of foamed sole materials.

The invention relates to the technical field of well drilling plugging agents, in particular to a high-strength consolidation type plugging agent. Comprising the following components in parts by weight: 30-68 parts of a polymer matrix, 15-36 parts of composite gel, 8-16 parts of a coagulator, 5-12 parts of an initiator, 7-12 parts of a nano material, 6-21 parts of a flexibilizer, 6-13 parts of a cross-linking agent and 2-8 parts of a flame retardant, the polymer matrix is prepared by taking ethyl acrylate and butyl acrylate as main monomers, methoxyethyl acrylate as a functional monomer and monobutyl itaconate as a vulcanization point monomer through copolymerization; the mass ratio of the ethyl acrylate to the butyl acrylate to the methoxyethyl acrylate to the monobutyl itaconate is (2-3): (1-2): (1-3): 1. The plugging agent has controllable curing time, is suitable for fractured and karst cave leakage layers, is high in plugging success rate, and can effectively improve the pressure-bearing capacity of stratums. And the plugging agent has good temperature resistance and is suitable for plugging construction in a high-temperature environment.