5175 results about "Carvacryl acetate" patented technology

The invention provides an irradiation cross-linking oil resistance type soft low smoke zero halogen flame-retardant cable material which comprises the following components in parts by weight: 60-90 parts of ethylene-vinylacetate copolymer, ethylene-propylene-diene rubber and ethylene-octylene copolymer, 0-20 parts of nitrile rubber, 10-30 parts of interface compatilizer, 80-130 parts of flame retardant, 2-15 parts of flame-retardant synergist, 0.5-1.0 part of antioxidant, 1-2 parts of cross-linking sensitizing agent and 0.5-1.0 part of lubricant. The preparation method of the cable material in the invention mainly comprises the steps of silane surface modification treatment of the flame retardant, mixing and extruding of a double screw mixer-extruder unit or an internal mixer unit, brace water cooling or water ring particle cutting and the like. The cable material provided by the invention has the advantages of superior flame resistance (single cable can vertically burn), good mechanical properties, especially high softness, oil resistance, high-temperature resistance (the cable material can be used in a range of minus 40 DEG C-125 DEG C), low smoke, low toxicity and excellent processability.

The invention discloses a radiation pre-crosslinked ethylene-vinyl acetate (EVA) resin film which comprises the following components in parts by weight: 51-99.58 parts of EVA resin, 0.3-2 parts of organic peroxide crosslinking agent, 0.01-5 parts of assistant crosslinking agent, 0.1-2 parts of antioxidant, 0.01-2 parts of silane coupling agent, 0-40 parts of pigment and 0-40 parts of polyolefin elastomer. The invention also discloses a preparation method of the radiation pre-crosslinked EVA resin film, which comprises the steps of sufficiently mixing 51-99.58 parts of EVA resin, 0.3-2 parts of organic peroxide crosslinking agent, 0.01-5 parts of assistant crosslinking agent, 0.1-2 parts of antioxidant, 0.01-2 parts of silane coupling agent, 0-40 parts of pigment and 0-40 parts of polyolefin elastomer, and adding into an extruder; extruding and forming a film through a T-shaped flat mould; rolling and radiating to obtain the radiation pre-crosslinked EVA resin film. Since the film is partially crosslinked before use, the dimensional stability and heat resistance of the film are remarkably improved, thus the film is suitable for large-scale popularization and application.

A coating composition in the form of a one or multi-part system, and method of applying such a composition under conditions of controlled humidity, for use in coating device surfaces to control and/or improve their ability to release bioactive agents in aqueous systems. The coating composition is particularly adapted for use with medical devices that undergo significant flexion and/or expansion in the course of their delivery and/or use, such as stents and catheters. The composition includes the bioactive agent in combination with a first polymer component such as polyalkyl(meth)acrylate, polyaryl(meth)acrylate, polyaralkyl(meth)acrylate, or polyaryloxyalkyl(meth)acrylate and a second polymer component such as poly(ethylene-co-vinyl acetate).

The invention discloses a filler masterbatch used for increasing the polarity of polypropylene and a preparation method thereof. The filler masterbatch is characterized by comprising the following components by weight percent: 50%-79% of inorganic filler, 15%-30% of carrier, 5%-17% of polar additive and 1%-3% of processing additive; and the polar additive is one or more of thermoplastic polyurethane resin (TPU), maleic anhydride grafted polypropylene, epoxy resin, ethylene acrylate, ethylene vinyl acetate, polyether amine and polybutylene polyol. In the preparation method of the invention, the added carrier can not improve the polarity of polypropylene, the inorganic filler is used to increase the rigidity of the material; the key is to introduce the polar additive with high unipolarity, thus the filler masterbatch used for increasing the polarity of polypropylene can be prepared; when the filler masterbatch is combined with the polypropylene material for production, the surface polarity of the filled and modified polypropylene material can be increased, the surface energy of the filled and modified polypropylene can be reduced, the dimension stability can be increased, the modified polypropylene material can have good paint adhesion and the material can be used to form exterior trimming parts such as bumpers and interior trimming parts such instrument panels.

The invention discloses an insulating and sheathing material of ultraviolet light crosslinking expanding type phosphorus nitrogen flaming resistance polyolefine cables and a preparation method thereof. The invention is characterized in that polyethylene/PEMA and/or ethylene vinyl acetate or maleic anhydride grafted ethylene vinyl acetate or acid amide grafted ethylene vinyl acetate copolymer are taken as base, added with expanding type phosphorus nitrogen halogen-free flame retardants, light trigger, polyfunctional group cross linker and chemical inhibitor and matched with flaming retardant synergistic agent, antismoke agent and processing aid, and then squeezed out and pelleted into photo-crosslinking flame retardant cable materials; and then the flame retardant cable materials are melted and extruded on a cable conductor wire core and clad into an insulating layer and a sheathing layer; hereupon the ultraviolet light irradiation crosslinking is carried on the insulating layer or the sheathing layer. Via detecting, the oxygen index of the insulating layer or the sheathing layer is larger than 30%, the vertical flaming experiment passes through UL-94 V0 level, the tensile strength is larger than 12Mpa, the elongation at break is larger than 350%, and the electric volume resistivity is larger than 8*10 omega.cm.

The invention provides an EVA adhesive film without adding uvioresistant absorbent, which is prepared mainly by the raw materials according to the mass ratio as follows: ethylene-vinyl acetate copolymer, 100 parts; peroxide type crosslinking agent 0.1 to 10 parts, phenolic or phosphite type antioxidant 0.05 to 5 parts; and hindered amine light stabilizer, 0.01 to 5 parts. As the ultraviolet absorbent is not used, the EVA adhesive film obtained does not produce ultra-violet cut-off, leads the solar modules to receive UV district light energy, thereby having higher photoelectric conversion efficiency and excellent uvioresistant anti-aging property, and guaranteeing the service life of PV modules.

The invention discloses a soft low-smoke halogen-free flame-retardant polyolefin cable material and a preparation method thereof. The cable material comprises the following components (based on by mass part ratio): 80-90 parts of copolymer of ethylene-vinylacetate, 10-20 parts of linear low-density polyethylene, 65-130 parts of an inorganic fire retardant through surface treatment, 10-30 parts of high-effective flame retardant synergist, 10-20 parts of high molecular compatilizer, 0.9-1.5 parts of antioxidant and 1-2 parts of processing aid. The preparation method comprises the steps of resin blending extrusion; surface treatment of the inorganic fire retardant; batching, mixing, extrusion, granulation and the like. Compared with the prior art, the invention has the characteristics of predominant flame retardation (an oxygen index up to 36), excellent toughness, excellent bending resistance, low density (density is only 1.28g/cm<3>), low smoke, low corrosion, low toxicity, environmental protection, good processability, bright surface of extrudates and the like.

A soluble antiscale wax control ball is disclosed. The soluble antiscale wax control ball comprises surfactants, wax cleaning agents and an antiscale agent RX-613. The surfactants comprise sodium alkylbenzenethiosulphonate, Ninol and polyoxyethylene alkyl ether. The wax cleaning agents comprise ethylene-vinyl acetate copolymer and polyethylene. The soluble antiscale wax control ball is advantaged by being soluble and having functions of preventing scaling and wax precipitation of pipelines, being capable of not blocking pipelines, and the like. The soluble antiscale wax control ball can dissolve old scale into crude oil and can prevent crude oil components from scaling onto walls of pipelines, and therefore problems of mechanical wax-cleaning antiscale balls at present, such as pipeline blockage and high running costs, which are caused by pipeline transfiguration, and the like are overcome. Experiment research shows that the soluble antiscale wax control ball can achieve wax-cleaning effects of rubber balls in site and has multiple functions comprising chemical wax cleaning and scale prevention, the comprehensive wax cleaning rate is 85.2%, and the antiscale rate is 82.18%.

The invention discloses a mildewproof preservative film and a preparation method thereof. The mildewproof preservative film comprises a base layer and a mildewproof preservative coating arranged on the base layer, wherein the mildewproof preservative coating is prepared from a mildewproof preservative paint. The mildewproof preservative paint comprises the following components in percentage by weight: 20-60% of resin, 30-70% of solvent, 0.5-10% of mildew preventive and 0.3-5% of aid. The resin is composed of at least one of polyurethane, an acrylate copolymer, polyvinyl alcohol, polyvinylidene chloride, modified polyvinylidene chloride, an ethylene-vinyl acetate copolymer, a polyvinyl acetate copolymer and a vinyl acetate-butyl ester copolymer; and the solvent is composed of at least one of water and ethanol. The mildewproof preservative coating of the mildewproof preservative film has the advantages of compact surface and no void; and by adding the mildew preventive, the mildewproof preservative coating has the favorable effects of keeping the moisture constant and preventing mildewing. The mildewproof preservative film is especially suitable for preserving fruits, bread, tobacco and other foods which have shorter storage period, can easily mildew in a short time and need to be eaten in time.

The invention belongs to the technical field of materials and discloses a flexible low-smoke halogen-free flame-retardant wire and cable material and a preparation method thereof. The wire and cable material is prepared by using the following raw materials in parts by weight: 100 parts of ethylene-vinyl acetate copolymer, 1 to 70 parts of polyethylene, 30 to 100 parts of flame retardant, 5 to 20 parts of smoke suppressor, 0.1 to 5 parts of coupling agent, 1 to 20 parts of plasticizer, 0.1 to 10 parts of crosslinking agent, 3 to 15 parts of lubricant and 0.1 to 1 part of antioxidant. The wire and cable material disclosed by the invention is a thermoplastic sulfurized elastomer material, can be used for preparing insulating layers and sheath layers of wires and cables, and has the characteristics that no halogen is contained, the flame-retardant effect is good, the smoking amount is low, the surfaces of the insulating layers and sheath layers are smooth and do not stick with one another, the flexibility is good, the mechanical strength is high, the wear resistance is good, the processing fluidity is good, the process is simple and the material can be recycled.

The invention provides a low-smoke halogen-free inflaming-retarding cable material and preparation method thereof. The cable material comprises 5 to 15 parts (part by weight) of compatilizer that comprises maleic anhydride functional group grafted ethylene-vinyl acetate copolymer and maleic anhydride functional group grafted ethylene propylene terpolymer; 85 to 95 parts of base material formed by blending two or more than two of linear low-density polyethylene, ethylene-vinyl acetate copolymer and ethylene propylene terpolymer granular materials; 2 to 6 parts of composite antioxidant composed of the following antioxidants in terms of weight ratio: hindered phenol antioxidants : thiol ester antioxidants = 1 : (2 to 6); 20 to 40 parts of ammonium polyphosphate; 10 to 20 parts of pentaerythritol; 8 to 15 parts of melamine; 50 to 100 parts of composite inorganic fire retardant composed of the following fire retardants: magnesium hydroxide : zinc borate = (2 to 4) : 1; 2 to 6 parts of lubricant; 0 to 0.5 parts of metal passivator; 0 to 3 parts of crosslinking assistant agent; and 0 to 5 parts of halogen-free master batch. The invention has provided a harmless halogen-free inflaming-retarding cable material having high temperature tolerance, high tension, high elongation and high fire resistance.

The invention discloses a halogen-free cable material which is irradiation cross-linked, has less smoke and can retard the inflaming of polyolefine, and consists of the following components by mass: 30 to 50 percent of ethylene-vinyl acetate copolymer, 0 to 20 percent of high-density polyethylene, 30 to 60 percent of magnesium hydrate, 0 to 10 percent of red phosphorus, 1 to 5 percent of resin acceptor, 0.1 to 1.5 percent of cross linker, 1 to 5 percent of compatilizer, 0.1 to 1.5 percent of antioxidizer and 0.1 to 1.5 percent of lubricating agent. The halogen-free cable material which is irradiation cross-linked, has less smoke and can retard the inflaming of polyolefine overcomes the harm to the environment and the human bodies when retarding the inflaming of polyolefine material by using traditional halogen-containing flame retardants, has less smoke, innoxiousness, green and environment protection, and can ensure good mechanical performance, flame retarding performance and processing performance.

A resin combination mainly comprises: (1) epoxy resin containing silicon atomic compounds; (2) thermoplastic resin; (3) organic elastic powder; (4) a hardener; (5) thermal-conductive inorganic fillers; (6) a phosphorus-containing burning resistant agent; (7) ethylene-vinyl acetate; (8) a catalyst.

The present invention is directed to an oxygen scavenger composition comprising a mixture of (i) a polyester polymer composed of polymer segments containing cycloalkenyl group or functionality; and (ii) an ester type polymer selected from (a)a polyester having a high content of alkylene groups; (b) a polylactone; and (c) a polyvinylacetate having at least about 50 weight percent vinyl acetate mer units therein. The present polymer composition has been found to act as an oxygen scavenger agent under both ambient and refrigerated conditions, to be compatible with conventional film forming packaging materials, to provide compositions exhibiting low tack, and to be capable of being readily processed using conventional film forming equipment.

A low-smoke and non-halogen poly-olefine material with radiant graft maleic anhydride vinyl-vinyl acetate multi-polymer as compatilizer is prepared by dissolving maleic anhydride 1-5 proportion into acetone, mixing with vinyl-vinyl acetate multi-polymer 100 proportion, volatilizing for acetone, granulating in double-screw extruder, and electronic-ray or gamma-ray radiating by electronic accelerator with 5-30KGy. The compatilizer graft rate is greater than or equal to 1%, it has better poly-olefine material performance, more white fire retardant and no need for anti-smoke agent. It can be used to make poly-olefine thermal shrinkage pipe with VW-1 vertical burning performance according to UL224 standard.

The invention discloses an EVA (Ethylene Vinyl-Acetate) packaging glue film with high gas-water barrier property and a preparation method thereof. The glue film is prepared from the following raw materials in parts by weight: 100 parts of an EVA copolymer, 0.5-5 parts of a crosslinking agent, 0.1-0.5 part of an antioxidant, 0.1-0.5 part of an ultraviolet absorber, 0.05-0.5 part of a light stabilizer, 0.1-3 parts of a silane coupling agent and 0.01-55 parts of a water resistant. The preparation method comprises the following steps: plastifying and extruding; stretching; drawing; rolling and the like. The glue film disclosed by the invention has the beneficial effects that the EVA glue film obtained by the invention has good gas-water barrier property and hydrolysis resistance as well as better damp-heat aging resistance.

The invention relates to a thermoplastic oil-resistant halogen-free low-smoke flame-retardant polyolefin cable material. The material is characterized in that: the material is prepared from raw materials of: substrate resin, a fire retardant, a lubricating agent, and an anti-oxidant. The substrate resin is composed of metallocene linear low-density polyethylene (MLLDPE), an ethylene-vinyl acetate polymer, and an interface compatibilizing agent. The preparation method comprises the steps that: the raw materials are well mixed in a high-speed mixing machine; the mixture is subjected to mixed extrusion under a processing temperature of 125-145 DEG C on a same-direction double-screw extruder; and the material is subjected to hot-cut granulation, such that a finished product is obtained. Compared with a traditional thermoplastic halogen-free low-smoke flame-retardant polyolefin cable material, the cable material provided by the invention has good oil resistance. When the cable material is soaked in mineral oil, the change rates in tensile strength and breaking elongation are low.

The invention discloses a high temperature resistant flexible low-smoke zero-halogen flame-retardant polyolefin compound. The material formula thereof consists of the following materials: an ethylene-vinyl acetate copolymer, a propylene-ethylene copolymer, an interfacial compatilizer, a flame retardant, an antioxidant silane coupling agent and a lubricant, wherein, the Shore A hardness of the ethylene-vinyl acetate copolymer is less than 75, the weight content of the vinyl acetate in the raw material monomer is 30 percent to 70 percent, the Shore A hardness of the propylene-ethylene copolymer is less than 90, and the Shore A hardness of the interfacial compatilizer is less than 80. The invention can meet the high temperature resistant conditions of an aging test (135 DEG C 168h), and has the advantage of low cost.

A process for preparing self-adhesive polyethene-base protecting film includes such steps as extruding out basic film, middle layer and self-adhesive layer, and blowing film to obtain a composite film. Said basic film is prepared from low-density polyethene and low-density linear polyethene. Said middle layer is prepared from the polyethene of basic film and ethene-vinyl acetate. Said self-adhesive layer is prepared from 6 chemicals including ethene-vinyl acetate, polyethene of basic film, dioctyl adiptate, etc.

The invention relates to a pair of soles and particularly relates to a pair of soles of ejection foamed rubber-plastic sports shoes and a manufacturing method of the soles. The pair of soles of the ejection foamed rubber-plastic sports shoes consists of the following raw materials: an ethylene-vinyl acetate copolymer, an ethylene-octene copolymer, a hydrogenated styrene-butadiene-styrene block copolymer, an ethylene propylene diene monomer, polysiloxane resin, talcum powder, stearic acid, zinc stearate, zinc oxide, dicumyl peroxide, azobisformamide and masterbatch. The manufacturing method comprises the steps of: mixing the dicumyl peroxide and an azo foaming agent for later use, mixing other raw materials and then pouring into an internal mixer for first-stage internal mixing, then adding a mixture of the dicumyl peroxide and the azo foaming agent for second-stage internal mixing to obtain an internally mixed mixture, thinning the mixture on a roller machine, conveying the material which is evenly mixed by the roller machine into a granulator for granulation, proportioning aggregates after granulation according to set ratios, injecting the aggregates into a shoe mould by using an injection molding machine for molding, and sizing the molded soles into foamed profile products by using an incubator.

The invention relates to an environmental protection based red mud combination modification synergism fire-retardant polyethylene, and belongs to the technical field of compressive utilization and fire-retardant plastics. The fire-retardant polyethylene is suitable for fire safety protection in important public places in the fields of electric products, building materials and transportation. The fire-retardant polyethylene consists of the following components in percentage by weight: 30 to 35 percent of polyethylene, 34 to 39 percent of red mud, 6 to 13 percent of red phosphorus, 5 to 17 percent of zinc borate, 3 to 8 percent of ethylene-vinyl acetate copolymer, 2 to 7 percent of grafted polyethylene, and 2 to 8 percent of silicone oil. The preparation process comprises the following steps of: grinding and drying the red mud; blending the ground red mud with other raw materials according to the blending ratio; mixing the mixture with polyethylene resin by fully stirring at a high speed; fusing, co-mixing and processing the mixture; and preparing a sample. The processing conditions comprise that: the roll temperature of a double-roller mixing mill is between 140 and 150 DEG C; and the forming temperature of the flat vulcanizing machine sample is between 120 and 130 DEG C, the heating time is between 4 and 8 minutes, and the pressure is between 10 and 20MPa. The fire-retardant system meets the requirements of industrial application on mechanical property, and simultaneously has comprehensive properties such as good fire-retardant effect, low cost, environmental protection and the like; moreover, the application field of the red mud is widened, and the red mud product with high added value is prepared.

The invention provides an ultraviolet light crosslinking low-smoke zero-halogen flame-retardant cable material. The cable material comprises polyolefin, a compatilizer, an inorganic flame retardant, an organic phosphorus-nitrogen-containing flame retardant, a flame-retardant synergist, a photoinitiator, an assistant crosslinker, a surfactant, an antioxidant and a lubricant, wherein polyolefin contains low-density polyethylene, an ethylene-octylene copolymer and an ethylene-vinyl acetate copolymer in the weight proportion being (10-25):(20-35):(55-65); the compatilizer is polyethylene for grafting of maleic anhydride; the inorganic flame retardant is selected from magnesium hydroxide and aluminum hydroxide; the organic phosphorus-nitrogen-containing flame retardant contains polyphosphoric acid, pentaerythritol and melamine in the weight proportion being (10-20): (4-8): (15-30); the flame-retardant synergist contains zinc borate and/or polydimethylsiloxane. The cable material has good thermal resistance and anti-aging performance, can be used at the temperature of 125 DEG C for a long time and is excellent in comprehensive mechanical performance and better in flame retardance.