939 results about "Nanocellulose" patented technology

The invention discloses a perfluoropolyether blended PEGDE-based solid electrolyte and a preparation method thereof, and belongs to the technical field of lithium metal battery solid electrolyte materials. Adding SnCl4 and TAA into the nanocellulose precursor solution, stirring, carrying out suction filtration, and drying to obtain a SnS2 (at) NC support layer; and mixing and stirring PEGDE, LiDFOB, LiTFSI and PFPE to obtain PEGDE-based solid electrolyte slurry, coating the SnS < 2 > (at) NC supporting layer with the PEGDE-based solid electrolyte slurry, and performing in-situ polymerization in a drying oven to obtain the PEGDE-based solid electrolyte. The ultrathin perfluoropolyether blended PEGDE-based solid electrolyte prepared based on PEGDE in-situ polymerization and perfluoropolyether blending and in combination with nanocellulose enhancement has the advantages of stable anode interface, high mechanical strength, high decomposition voltage and high ion transference number.

The invention discloses a cellulose paper-based diaphragm for a zinc-iodine battery as well as a preparation method and application of the cellulose paper-based diaphragm. The diaphragm is of a three-layer composite structure and comprises a matrix layer formed by paper pulp fibers such as softwood pulp, hardwood pulp, bamboo pulp or straw pulp through a wet papermaking technology, and compact functional layers which cover the two sides of the matrix layer and are formed by oxidized nanocellulose (TOCN). The preparation method mainly comprises the following steps: preparing the paper-based diaphragm matrix through wet papermaking, coating the two sides of the paper-based diaphragm matrix with TOCN aqueous dispersion, and finally carrying out hot-pressing drying treatment to enable the three layers to be tightly combined. According to the invention, the nano aperture and the surface negative electricity functional group of the TOCN layer are utilized, so that physical blocking and electrostatic repulsion of polyiodide ions can be realized at the same time, and the shuttle effect is effectively inhibited; and the uniform pore channels can guide zinc ions to uniformly deposit and inhibit dendritic crystal growth. The diaphragm is green in raw material, simple in process and low in cost, and the cycle life and coulombic efficiency of the battery can be remarkably improved when the diaphragm is applied to the zinc-iodine battery.

The invention belongs to the technical field of mineral flotation, and particularly relates to a nanocellulose-based coal slime collecting agent and a preparation method and application thereof. Wet-grinding the dried absorbent cotton, drying again, acidizing, filtering, washing and centrifugally drying to obtain precursor cellulose; dissolving the precursor cellulose in deionized water, adjusting the pH value to 10, adding an ethanol solution of alkyltriethoxysilane, heating, stirring for reaction, naturally cooling, centrifuging, washing and drying to obtain hydrophobic nano cellulose; and the hydrophobic nanocellulose and the non-polar hydrocarbon oil are evenly mixed, and the coal slime collecting agent is obtained. The prepared coal slime collecting agent contains the hydrophobic nanocellulose which is high in softness and has a net-shaped structure, in the flotation process, adhesion of bubbles and minerals can be promoted, diffusion of the bubbles is promoted, and the flotation efficiency and the recovery rate are improved.

The invention belongs to the technical field of corrugated paperboards, and is characterized in that wood fibers and modified bamboo fibers prepared by reaction of allyl bamboo fibers, 1, 4-butanediol di (mercaptoacetate) and magnolol are pulped, a biodegradable water-resistant auxiliary agent is added for hydrophobic modification, papermaking and shaping are carried out to prepare water-resistant base paper, and the water-resistant base paper is prepared by the following steps: pulping the modified bamboo fibers and the biodegradable water-resistant auxiliary agent. And finally, preparing a surface paper layer, a corrugated medium paper layer and an inner paper layer from the water-resistant raw paper, and bonding and pressing to obtain the corrugated board. Magnolol groups grafted on the surfaces of the modified bamboo fibers can improve the water absorption performance of the fibers, and the hydrophobicity of the corrugated board is improved through the synergistic effect of the magnolol groups and the biodegradable water-resistant auxiliaries; the surface of the biodegradable water-resistant auxiliary agent is embedded with a carboxylated nano-cellulose structure, so that the biodegradable water-resistant auxiliary agent has deformation resistance; the epoxidized soybean oil is used as a core part and has excellent hydrophobicity; through combination of a polyphenol structure of tannic acid and hydrogen bonds of water-resistant base paper fibers, the mechanical properties of the corrugated board are improved, and the corrugated board has excellent biodegradability, hydrophobicity and mechanical strength.

The invention discloses a recyclable lawn and a preparation method thereof, and belongs to the technical field of artificial turfs. The lawn sequentially comprises artificial grass yarns, a base cloth layer and a back glue layer from top to bottom, the artificial grass yarns and the base cloth layer are made of polyolefin; the back adhesive layer is prepared from the following components in parts by weight: 4 to 8 parts of polyolefin elastomer, 10 to 20 parts of olefin block copolymer, 20 to 30 parts of hydrogenated styrene-butadiene copolymer, 8 to 12 parts of styrene-isoprene copolymer, 10 to 12 parts of butadiene-styrene rubber, 2 to 6 parts of ethylene-acrylic acid copolymer, 15 to 30 parts of plasticizer, 0.1 to 0.4 part of antioxidant, 3 to 6 parts of compatilizer and 2 to 4 parts of modified filler; according to the lawn, the artificial grass yarns, the base cloth layer and the gum layer are similar in component, so that the lawn can be conveniently and integrally recycled subsequently, the utilization rate of the lawn gum is increased, and resource waste is reduced.

The invention relates to the technical field of adhesives, and particularly discloses a low-formaldehyde environment-friendly adhesive and a preparation method thereof. The invention relates to a low-formaldehyde environment-friendly adhesive which is prepared from the following raw materials in parts by mass: 30-50 parts of modified starch, 15-25 parts of vegetable protein, 5-10 parts of modified nano cellulose, 2-5 parts of a composite cross-linking agent and 80-150 parts of water, the composite cross-linking agent comprises amino silane and polyaspartic acid; the modified starch is prepared by performing graft copolymerization on starch subjected to enzymolysis by alpha-amylase and composite anhydride; the vegetable protein is subjected to alkalization and heat treatment before being used; the modified nano-crystalline cellulose is prepared by performing ring-opening etherification reaction on nano-crystalline cellulose, epoxypropane and ethylene oxide in sequence. The low-formaldehyde environment-friendly adhesive prepared by the invention has relatively good bonding strength and relatively low formaldehyde emission.

The invention belongs to the technical field of polymer composite materials, and particularly relates to a polycarbonate modified composite material as well as a preparation method and application thereof, and the polycarbonate modified composite material comprises 60-85 parts of a PC base material, 10-30 parts of a bio-based monomer, 1-8 parts of surface modified nano cellulose and 0.1-2 parts of a transesterification catalyst. According to the polycarbonate modified composite material as well as the preparation method and the application thereof provided by the invention, chemical bonding of a bio-based monomer and a PC main chain is realized through transesterification, phase separation is avoided, and the core pain point of traditional blending modification is solved; the biodegradation rate is increased by 30% or above compared with pure PC, and meanwhile, the excellent mechanical properties (the tensile strength is larger than or equal to 60 MPa, and the notch impact strength is larger than or equal to 5 kJ / m) of PC are reserved; the melt flow rate is increased by more than 25%, the processing energy consumption is reduced, and the application scene is widened; the carboxylic acid modified nano cellulose and the block copolymer form a synergistic network, so that the mechanical property, the thermal stability and the degradation uniformity are synchronously improved.

The invention relates to the field of coatings, and discloses a high-chroma corrosion-resistant yellow coating and a preparation method thereof. The coating is prepared from the following components in parts by weight: 50 to 60 parts of waterborne epoxy modified organic silicon resin, 25 to 35 parts of modified bismuth vanadate, 1 to 2 parts of nano cellulose, 0.3 to 0.8 part of dispersing agent, 0.2 to 0.5 part of defoaming agent, 0.2 to 0.5 part of flatting agent and 2 to 3 parts of corrosion inhibition pigment. The formula system of the high-chroma corrosion-resistant yellow coating is innovative, a waterborne epoxy modified organic silicon resin-modified bismuth vanadate-nanocellulose ternary synergistic system is constructed, and the high-chroma corrosion-resistant yellow coating has excellent chroma and corrosion resistance. According to the coating, flaky bismuth vanadate generated through microwave method induction is adopted, lattice defects are few, chromaticity is broken through, and high corrosion resistance is achieved.

The application discloses a kind of nanocellulose modified acrylic water-based emulsion and its preparation method and application, it is related to the technical field of polymer composite.A kind of modified acrylic water-based emulsion includes 180-220 parts of acrylate monomer, 45-60 parts of functional monomer, 3-5 parts of nanocellulose liquid, 4-6 parts of emulsifier, 1.5-2 parts of initiator, 2-3 parts of sodium bicarbonate and 275-300 parts of deionized water, wherein functional monomer includes hydroxy acrylate, acrylonitrile and fluorine-containing acrylate.By using fluorine-containing acrylate with nanocellulose to modify acrylic emulsion, water-based emulsion with good film-forming performance can be prepared, and the formed coating has good adhesion, stain resistance, heat oil resistance and mechanical strength, if the water-based emulsion is applied to the surface modification of filter material, not only can improve the hand feeling of filter material, but also can improve the stain resistance and service life of filter material surface.

The invention provides a post-added nanocellulose enhancing auxiliary agent for latex paint coating and a preparation method and a use method thereof, and the preparation method comprises the following steps: mixing, stirring and heating butanetetracarboxylic acid, sodium hypophosphite and a nanocellulose solution to obtain an esterified nanocellulose solution; adding a silane coupling agent solution into the esterified nanocellulose solution to obtain a modified nanocellulose solution; dispersing nano silicon dioxide into absolute ethyl alcohol to obtain silicon dioxide dispersion liquid; adding a silane coupling agent solution into the silicon dioxide dispersion liquid, mixing, stirring and heating for reaction to obtain modified silicon dioxide powder; dispersing the modified silicon dioxide powder into absolute ethyl alcohol to obtain modified silicon dioxide dispersion liquid; adding the compound emulsifier solution into the modified silicon dioxide dispersion liquid, and shearing and emulsifying to obtain modified silicon dioxide emulsion; and adding a compatilizer into the modified nano cellulose solution, dropwise adding the modified silicon dioxide emulsion, and finally adjusting the viscosity.

The invention provides a Lewis acid metal ion-piperazine modified nanocellulose film as well as a preparation method and application thereof, and belongs to the technical field of battery materials. The preparation method comprises the following steps: mixing carboxylated nanocellulose with Lewis acidic metal salt in a solution, and carrying out pre-crosslinking reaction to obtain Lewis acidic metal ion modified carboxylated nanocellulose; a piperazine ligand compound and dopamine hydrochloride are added into the Lewis acidic metal ion modified carboxylated nano-cellulose, a cross-linking reaction is carried out with Lewis acidic metal ions as the center, suction filtration is carried out, and a film is formed. The metal in the Lewis acid metal salt is metal cations with the valence of more than bivalent. The carboxylated nanocellulose, the Lewis acid metal ion-piperazine complex and the solid polymer electrolyte are organically combined together for the first time and are applied to the lithium metal battery, the unique advantages of the lithium metal battery in the field of batteries are shown, and the rate capability and the cycling stability are greatly improved.

The application provides an octadecane-loaded cellulose-based composite phase change material evaporator and a preparation method and application thereof in seawater desalination, and belongs to the fields of photo-thermal conversion materials and separation technologies. Nanocellulose and polyvinyl alcohol are mixed to prepare an aerogel, octadecane is encapsulated in the pores of the aerogel by a vacuum impregnation method to obtain a composite phase change material aerogel, and the composite phase change material aerogel is coated with a non-woven fabric loaded with polypyrrole to obtain the octadecane-loaded cellulose-based composite phase change material evaporator. The evaporator is a composite phase change material evaporator based on the coupling of interfacial evaporation and phase change energy storage, solves the problems of discontinuous evaporation and low solar energy utilization rate caused by day and night alternation, has excellent light absorption performance, good heat insulation performance and sufficient water supply and the like, can be used for seawater desalination, and has the advantages of high evaporation rate, high energy conversion efficiency, salt precipitation prevention and the like.

The invention provides a self-healing-shape memory phase change microcapsule for cooling drilling fluid as well as a preparation method and application of the self-healing-shape memory phase change microcapsule, and belongs to the technical field of cooling of the drilling fluid and underground heat management. The preparation method of the phase change microcapsule comprises the following steps: fully dispersing a polyurethane prepolymer, a polyimide solution and hydrophobic nanocellulose in an organic solvent to obtain an oil phase; dissolving a phase change material in deionized water to obtain a water phase; under a shearing condition, dropwise adding the oil phase into the water phase, and emulsifying to form a stable oil-in-water type Pickering emulsion; and adding an aqueous solution of a chain extender, and carrying out interfacial polymerization reaction, centrifugation, washing and drying. The phase change microcapsule disclosed by the invention shows excellent cyclic service performance under the underground high-temperature and high-shear conditions, and structure repair and morphology recovery can still be realized by virtue of self-healing and shape memory effects even if a shell layer is damaged, so that the service life of the phase change microcapsule is prolonged, and the cooling persistence of the drilling fluid is improved.

The invention discloses a method for catalyzing melamino-formaldehyde resin methylation reaction by solid acid. According to the invention, epoxy silane coupling agent grafted modified nanocellulose is introduced into sulfonated styrene-divinyl benzene cross-linked copolymer microspheres for in-situ crystal cross-linking, so that the problems that the traditional sulfonated polystyrene resin is poor in mechanical strength and solution solubility resistance, low in cycle index, easy to swell and fall off and the like are effectively solved; the prepared solid acid resin has the characteristics of high reaction activity, high proton transfer rate, high mechanical strength, high cyclicity and easiness in solid-liquid separation, and by utilizing the solid acid resin to catalyze the etherification reaction of the melamino-formaldehyde resin, the reaction temperature and the production energy consumption are reduced, the reaction time is shortened, the product quality and the production efficiency are improved, and the production cost is reduced. The problems of environmental protection and energy consumption caused by the generation of a large amount of VOCs in the etherification reaction of the traditional liquid catalyst for synthesizing the high-etherified melamine formaldehyde resin and the by-product inorganic salt in the subsequent process are solved.

The invention discloses nano cellulose with high lignin content, a preparation method thereof and application of a barrier coating. The preparation method comprises the following steps: mixing a lignocellulose raw material with dilute sulphuric acid for acid pretreatment, and selectively depolymerizing hemicellulose to obtain lignin-rich residues of which the relative content of lignin is higher than that of the raw material; and carrying out mechanical nano fibrillation treatment to obtain the high-lignin-content nano cellulose with the lignin content of 29-60%. The prepared nano cellulose with high lignin content has excellent thermal stability, hydrophobicity and organic compatibility. The surface of paper is coated with the coating material, after hot pressing treatment, the Cobb value of the coated paper is as low as 3.3 g / m < 2 >, the water vapor permeability is only 12.1 g / (m < 2 >. D), grease permeation can be completely blocked, and the coating material has wide application prospects in the field of food packaging.

The application relates to the technical field of ink solvents, and particularly discloses an environmentally-friendly water-based ink solvent with high drying efficiency and a preparation method thereof, the environmentally-friendly water-based ink solvent with high drying efficiency comprises the following raw materials in parts by weight: 40-60 parts of water, 30-50 parts of a bio-based alcohol compound, 5-15 parts of n-propyl acetate, 0.3-1 part of tripropylene glycol n-butyl ether, 1-3 parts of nano-cellulose, 0.5-1 part of calcium chloride, 1-2 parts of a pH regulator and 0.2-0.4 parts of a chelating agent. The environmentally-friendly water-based ink solvent with high drying efficiency and the preparation method thereof can be used for ink printing, and have the advantages of high drying efficiency and good stability.

The invention belongs to the technical field of desulfurization gas purification, and particularly relates to a desulfurizing agent and a preparation method thereof. The desulfurizing agent is an iron-zinc-calcium composite oxide material with a hierarchical porous structure, and the preparation method of the desulfurizing agent comprises the following steps: performing amination modification on xanthan gum, then mixing the modified xanthan gum with nano cellulose, and then preparing slurry with a metal salt solution containing Fe, Zn and Ca; performing two-way temperature gradient freezing casting and freeze drying to obtain a precursor; and finally, roasting and activating under programmed temperature control. According to the preparation method, nano-scale dispersion of active components is realized by virtue of strong coordination of aminated xanthan gum and metal ions, and a high-strength and through hierarchical pore framework is constructed by virtue of nanocellulose enhancement and freezing casting. The obtained desulfurizer has ultrahigh one-time sulfur capacity, high mechanical strength and excellent structural stability, is complete in form after being used, is convenient for resource recovery, and is suitable for efficient removal of hydrogen sulfide in industrial gases such as refinery gas.

The invention discloses a composite coating diaphragm and a preparation method thereof and a secondary battery, the composite coating diaphragm comprises a base membrane and a composite functional coating compounded on the surface of the base membrane, the composite functional coating comprises a first functional coating relatively close to the base membrane and a second functional coating relatively far away from the base membrane, the porosity of the first functional coating is smaller than that of the second functional coating, and the raw material components of the first functional coating comprise modified nanocellulose obtained by double-grafting cis-1, 4-polybutadiene and polyethylene glycol chain segments and gas-phase aluminum oxide. By constructing a diaphragm coating with a gradient pore structure and combining an advanced material modification technology, the composite coating diaphragm integrates high thermal stability, excellent electrolyte wettability and low-temperature adaptability, and can still keep stable structure and interface characteristics under an extreme temperature working condition; therefore, the method has good expandability and industrial application prospects, and is suitable for development and application requirements of high-performance lithium ion batteries and next-generation energy storage devices.

The invention relates to the technical field of polyurethane, and discloses an elastic waterproof biomimetic membrane as well as a preparation method and application thereof. Polylactic acid dihydric alcohol, an isocyanate monomer, a chain extender and cardanol siloxane-based cellulose are subjected to a polymerization chain extension reaction, and the elastic waterproof biomimetic membrane is obtained. The nano cellulose containing a benzene ring structure, a cardanol flexible long carbon chain and a siloxane structure are introduced into polyurethane, so that the tensile strength and the elongation at break of a polyurethane film are improved. Meanwhile, the hydrophilicity of cellulose is reduced, the water contact angle of the polyurethane film is increased, the waterproof performance is enhanced, and the good practical application is achieved in the waterproof finishing aspect of fabric such as bionic waterproof and moisture permeable films and outdoor jackets.

The invention belongs to the technical field of nanocellulose materials, and discloses a dissolved nanocellulose high-strength film and a preparation method thereof. The method comprises the following steps: 1) dissolving a cellulose raw material with a solvent to obtain a cellulose solution; 2) mixing the cellulose solution with a mixed solvent of water and ethanol, and performing nanoscale dispersion to obtain a dissolved nano cellulose dispersion; and 3) washing the dissolved nanocellulose dispersion, and forming a film to obtain the nanocellulose high-strength film. The method is simple, green and environmentally friendly, the prepared nano-cellulose high-strength film is high in light transmittance, the strength can reach 140-200 MPa, additional auxiliaries are not needed, the problem that an existing nano-cellulose film is poor in mechanical strength is solved, the contradiction between traditional plastic pollution and material strength and degradability is effectively solved, and conversion from the material industry to greenization and high performance is promoted.

The invention relates to the technical field of 3D printing materials, and belongs to a nanofiber reinforced PETG composite material for 3D printing of large parts and a preparation method thereof, and the nanofiber reinforced PETG composite material for 3D printing of large parts is a blend containing nanofibers treated by a physical modifier, PETG, a compatilizer and a plasticizer. The preparation method of the nanofiber reinforced PETG composite material comprises the following steps: preparing the modified nanofiber; blending the modified nanofiber, PETG, a compatilizer and a plasticizer through a high-speed mixer to form a blended material; carrying out melt blending extrusion and granulation on the blended material by using a twin-screw extrusion method; after being dried, the prepared composite material particles can be processed into monofilaments through a single-screw extruder, and the particles can also be directly used for 3D printing. According to the material disclosed by the invention, the tensile strength, the bending strength and the bending modulus of the material are improved by utilizing the characteristics of relatively high softening point of PETG and high rigidity of nano cellulose.

The invention belongs to the technical field of mineral flotation, and particularly relates to a cellulose-based coal slime collecting agent and a preparation method and application thereof. The method comprises the following steps: performing wet grinding on recycled waste paper to obtain a paper pulp solution, stirring until paper pulp fibers are uniformly dispersed, adding excessive lithium chloride and sodium periodate, performing stirring reaction, cleaning and centrifuging to obtain precursor cellulose, performing amino alkylation modification to obtain amino alkyl cellulose, preparing the amino alkyl cellulose into a 20 g / L solution, and performing vacuum drying to obtain the lithium ion battery cathode material. And then uniformly mixing with non-polar hydrocarbon oil according to the volume ratio of 1: 2 to obtain the coal slime collecting agent. The prepared coal slime collecting agent contains the hydrophobic nanocellulose with the large length-diameter ratio, in the flotation process, adhesion of bubbles and minerals can be promoted, diffusion of the bubbles is promoted, and the flotation efficiency and the recovery rate are improved.

The invention discloses lignin-containing nanocellulose based on camellia oleifera fruit and cattail as well as a preparation method and application thereof, and relates to the technical field of production of biomass nanomaterials, the lignin-containing nanocellulose based on camellia oleifera fruit and cattail comprises the following components in percentage by mass: 8%-15% of lignin, 3%-8% of hemicellulose and 70%-90% of cellulose; the preparation method of the lignin-containing nanocellulose comprises the following steps: S1, treating oil tea fruit cattail; s2, performing DES pretreatment on the Camellia oleifera fruit powder; s3, performing acidolysis and centrifugation on the fruit peel cellulose to obtain lignin-containing nano cellulose; s4, dialyzing the nano cellulose containing the lignin; the lignin-containing nanocellulose is used for preparing the LCNF / PVA composite film, and the LCNF / PVA composite film can be used as a food preservative film; the lignin-containing nanocellulose prepared by the preparation method disclosed by the invention has high specific surface area, high surface chemical activity and good biocompatibility and degradability, and is widely applied to the field of food industry.

The invention belongs to the technical field of photo-thermal material engineering, and particularly relates to a salt-resistant hydrogel evaporator utilizing solar evaporation for power generation and a preparation method and application thereof. The salt-tolerant hydrogel evaporator is prepared from the following raw materials: polyvinyl alcohol, hydrophilic conductive nanoparticles, bacterial nanocellulose and carbon nanotubes. Polyvinyl alcohol (PVA) is used as a framework, bacterial cellulose (BC) jointly forms a hydrogel structure with a hierarchical nanostructure, modified polyaniline conductive nanoparticles (CPs) are used for enhancing the electric signal transmission capacity of the hydrogel evaporator, and the salt-resistant hydrogel solar evaporator capable of realizing seawater desalination and electric power generation is prepared by adopting a simple and convenient method.

The invention provides a moisture-proof corrugated board and a production process thereof. The moisture-proof corrugated board comprises inner paper, core paper and surface paper which are sequentially arranged, and the surfaces of the inner paper and the core paper are coated with moisture-proof coatings; the invention relates to a preparation method of an anti-aging agent. The moisture-proof coating is prepared from the following raw materials: 35 to 45 parts of waterborne acrylic resin, 10 to 16 parts of fluorine modified shape memory polyurethane, 8 to 12 parts of waterborne polyurethane dispersion, 4 to 8 parts of bamboo charcoal loaded nano silver-zinc oxide composite particles, 3 to 6 parts of hydrophobic nano silicon dioxide, 5 to 9 parts of chitosan modified nano cellulose, 1.5 to 2.5 parts of silane coupling agent, 0.8 to 1.2 parts of dispersing agent, 0.2 to 0.4 part of defoaming agent and 0.5 to 0.9 part of wetting leveling agent. The corrugated board provided by the invention has excellent moisture resistance, mildew resistance and structural stability.

The invention provides an interface-stable and anti-fatigue Janus conductive hydrogel, a preparation method and sensing application, and the preparation method comprises the following steps: uniformly mixing acrylic acid, ethylene glycol dimethacrylate, a photoinitiator, ferric chloride hexahydrate and deionized water to obtain a support layer precursor solution; mixing acrylic acid, lauryl methacrylate, N, N '-methylene bisacrylamide and the nanocellulose suspension, performing ultrasonic treatment to obtain a Pickering emulsion, adding a photoinitiator into the Pickering emulsion, and uniformly mixing to obtain an adhesion layer precursor solution; and pouring the support layer precursor solution into a mold, then slowly pouring the adhesion layer precursor solution onto the support layer precursor solution, carrying out ultraviolet curing, taking out from the mold, and cleaning to obtain the Janus conductive hydrogel. According to the method, the Pickering emulsion phase separation and the charge shielding effect are combined through a simple and convenient one-step method, and the problems that a traditional multi-layer assembly process is complex in operation and unstable in interface are effectively solved.

The invention relates to the technical field of papermaking and food packaging materials, in particular to a preparation method of full-degradable plastic-substituted high-strength food packaging paper. Preparing a fiber layer by taking plant fiber as a base material; the preparation method comprises the following steps: grafting a methyl methacrylate-butyl acrylate block copolymer on nano-cellulose through an atom transfer radical polymerization technology to prepare enhanced nano-cellulose; dialdehyde starch rich in aldehyde groups and chitosan are subjected to a Schiff base reaction to form a dynamic cross-linked network, polylactic acid microspheres modified by beta-cyclodextrin are introduced to serve as supramolecular enhancement units, and functional coating liquid is prepared; and finally, coating the functional coating liquid on the fiber layer, and drying, cross-linking and curing to obtain a finished product. Through cooperation of chemical grafting, dynamic covalent bonds and supramolecular action, the packaging paper is endowed with extremely high strength and toughness and excellent oil and moisture resistance and heat sealability, meanwhile, it is ensured that the packaging paper can be completely biodegraded in the natural environment, and functional replacement of traditional plastic packaging is successfully achieved.

The invention provides nano cellulose as well as a preparation method and application thereof. The preparation method comprises the following steps: (1) carrying out heating reaction on a mixed solution containing a biomass material and a eutectic solvent, and filtering to obtain fibers; (2) mixing the fiber with a solvent, and performing ultrasonic treatment to form the nano cellulose; wherein the eutectic solvent comprises a hydrogen bond donor and a hydrogen bond acceptor, the hydrogen bond donor is selected from 2-aldehyde acetic acid and / or chloroacetic acid, and the hydrogen bond acceptor is selected from choline chloride. The preparation method provided by the invention can effectively reduce the cost and energy consumption for synthesizing the nano cellulose.

The invention provides a bamboo nanofiber diaphragm and application thereof in an aqueous zinc ion battery, and the bamboo nanofiber diaphragm is prepared by the following method: (1) mixing bamboo powder with an alkaline solution, and then carrying out ball milling and ultrasonic dispersion to form a micro-nano bamboo powder mixed solution; (2) a delignification reagent is added into the micro-nano bamboo powder mixed solution, lignin is partially removed through heat treatment, and a mixed solution is obtained; and (3) carrying out suction filtration on the mixed solution in the step (2) to form a film, drying, and soaking and activating in a zinc source. The preparation method of the bamboo nanofiber diaphragm provided by the invention is simple, the raw materials are easy to obtain and low in cost, and the prepared lignin-containing aperture-controllable nanocellulose diaphragm has good stability, liquid retention capability and ionic conductivity, and shows excellent cycle capacity and service life when being applied to an aqueous zinc ion battery.

The invention discloses an environment-friendly waterborne polyurethane glove and a preparation method thereof. The environment-friendly waterborne polyurethane glove comprises a glove core and an environment-friendly waterborne polyurethane layer wrapping the surface layer of the glove core. The environment-friendly waterborne polyurethane layer is prepared from the following raw materials in parts by mass: 20 to 35 parts of isocyanate, 40 to 60 parts of bio-based polyol, 3 to 8 parts of a fluorine-containing chain extender, 0.5 to 3 parts of nano cellulose, 1 to 5 parts of an environment-friendly cross-linking agent, 0.3 to 1.5 parts of a nonionic emulsifier, 2 to 6 parts of an environment-friendly plasticizer, 0.1 to 0.5 part of a low-toxicity preservative and 15 to 30 parts of deionized water. The preparation method has the advantages that no organic solvent is contained, no VOCs are discharged in the production process, the green chemistry principle is met, and the overall strength and performance are higher.