194results about How to "Uniform diameter distribution" patented technology

The invention discloses an arc plasma torch preparing nanometer charcoal fibrous material method, which comprises the following steps: placing untreated leavings of liquefying coal directly in direct current arc plasma torch to carry on heat-treatment; using nitrogen for arc working gas under atmosphere pressure; getting nanometer charcoal fibrous material after 120-175 seconds, wherein there is no need to add in any activators in preparing process. The method is characterized by the following: the craft route is simple; the raw material is the waste of coal hydrogenant liquefaction craft; it's a good way to use coal liquification leavings to prepare high-added value, functional carbon material; the nanometer charcoal fibrous material can be used for accelerating agent, catalyst carrier, lithium ion secondary cell anode material, double-layer capacitor electrode, highly effective active solid, release agent and construction reinforced materials.

The invention discloses a preparation method for a composite material of cellulose nanofiber and reinforced polyurethane. The method comprises the following steps: 1) pretreating in a chemical method; 2) unfastening fibers in a mechanical method. According to the invention, chemical treatment and mechanical treatment are adopted to separate the cellulose nanofiber, which has a high length diameter ratio and is used for reinforced polyurethane, from newspaper; the transparent nano composite material with high-intensity is prepared; wood meal and newspaper are adopted as raw materials to prepare cellulose nanofiber through the chemical treatment combined with the mechanical treatment; the diameter range of the cellulose nanofiber is 30-100 nm, and the length diameter ratio is higher than 1000.

The invention relates to a method for preparing silicon carbide and precursor composite fibers. A silicon carbide precursor polymer is dissolved in at least one organic solvent to form uniform oil phase solution with the mass fraction of 10-70%; a water-soluble fiber-forming polymer is dissolved in water, surfactants are added, uniform water phase solution with the mass fraction of 1-50% is formed, and the quantity of the surfactants is 0.1-10% of the mass of the solution; the precursor solution and the water-soluble polymer solution are mixed according to the volume ratio of 1:10-1:1 to obtain stable oil-in-water (O/W) spinning solution; spinning precursor fibers with the spinning solution by a solution jet spinning method to obtain a precursor composite fiber with the diameter ranging from 50 nanometers to 50 micrometers; and the precursor fibers are not melted and calcined at high temperature to obtain silicon carbide fibers. The method has the advantages of high production efficiency, simple process, uniformity of fiber diameter distribution and the like, and is suitable for large-scale production.

The invention relates to a preparation method of an organic/inorganic hybridization nano super-hydrophobic fiber film. The method comprises the steps of dissolving a polymer carrier in water, and heating and stirring to obtain a polymer carrier solution; mixing tetraethoxysilane, water, zinc acetate and phosphoric acid, and stirring at the room temperature to obtain a mixing solution; uniformly mixing the mixed solution and the polymer carrier solution, then performing electrostatic spinning, drying in vacuum, forging, cooling and dipping in HCl solution, and drying to obtain a SiO2 porous nano fiber film; compositing and laminating the SiO2 porous nano fiber film, pouring a liquid, and drying in vacuum to obtain the organic/inorganic hybridization nano super-hydrophobic fiber film. The super-hydrophobic nano inorganic fibers have superhigh hydrophobic performance which can be maintained under the conditions of humidity, low temperature and the like without the FAS processing, is smooth and soft in hand feeling, gets rid of the limitation of the economic cost of an organic fluorocarbon and APEO and the environment-friendly limitation, and has the advantages of low price, no pollution, wide applicable range and the like.

The invention discloses a method for preparing conducting polymer micro-nanofibers in a magnetic spinning mode. The method comprises the steps that 1, a magnetic spinning device is built, wherein the magnetic spinning device comprises a rotary collection disc with a permanent magnet; 2, a spinning precursor solution is prepared, wherein magnetic nano particles, high-molecular polymer and conducting polymer are mixed and dissolved in an organic solvent solution; 3, the magnetic spinning device is utilized for preparing conducting polymer micro-nano complex fibers, wherein the spinning precursor solution is injected into a feeding device, the feeding device is started, liquid drops on an opening of a spinning nozzle forms a jet flow under the effect of magnetic field force to be connected with the permanent magnet to be a bridge, a brushless direct-current motor is started to drive the collection disc to rotate, the ferrofluid jet flow is continuously pulled out under the effect of magnetic field force, and conducting polymer micro-nanofibers are wound and formed among vertical supporting columns of the collection disc. The method does not need the high voltage effect, reduces the production cost and potential safety hazards, is suitable for large-scale production and has the good application prospect, and the fibers are distributed in order.

The invention relates to a preparation method of SiC sub-micron fibers. The method includes the steps that a precursor polymer is mixed with a fiber-forming polymer according to a mass ratio of (5:20)-(20:5) and dissolved in a solvent to produce an even and stable spinning solution; the spinning solution is supplied to a spinneret at a rate of 5-30mL/h for each spinneret orifice and extruded through the spinneret orifice to form solution trickles, and simultaneously, the spinning solution trickles are drafted and refined by high-speed injection airflow with an injection pressure of 0.1-1.5MPa to form precursor fibers with diameters of 50nm-10mum; the precursor fibers are subjected to oxidation treatment under an atmospheric condition of 160-250DEG C to obtain infusible fibers; and the infusible fibers are subjected to high-temperature calcinations under an inert gas atmosphere of 1000-1600DEG C to obtain the SiC sub-micron fibers with diameters of 10nm-5mum. The preparation method has the advantages of being high in production efficiency, simple in process, even in fiber diameter distribution, suitable for scale production and the like.

The invention discloses a nitrogen-doped carbon nanofiber electrocatalyst and a preparation method and application thereof. The method comprises: dissolving copper chloride dihydrate, polyvinylpyrrolidone and polyacrylonitrile in an N, N-dimethylformamide (DMF) solvent to obtain a spinning solution, then carrying out electrospinning through an electrospinning technique to obtain a copper chloride/polyvinylpyrrolidone/polyacrylonitrile nanofiber membrane, and orderly carrying out hydrothermal treatment, post-treatment, pre-oxidation treatment and carbonization treatment on the nanofiber membrane to obtain the porous nitrogen particle-loaded nitrogen-doped carbon nanofiber electrocatalyst with a certain mechanical strength. The preparation method is simple and is suitable for large-scale production. The nitrogen-doped carbon nanofiber electrocatalyst can be used for electric reduction of carbon dioxide.

The invention relates to a cobaltosic oxide bead-chain-shaped fiber and a preparation method thereof. The preparation method comprises the following steps: adding a cobalt source to N,N-dimethylformamide (DMF), and fully stirring till the cobalt source is completely solved; and adding polyvinylpyrrolidone (PVP) to the solution, stirring to obtain a spinning solution, spinning the spinning solution by utilizing an electrostatic spinning technique to obtain fibers, and forging fiber samples to obtain the cobaltosic oxide bead-chain-shaped fiber. According to the cobaltosic oxide bead-chain-shaped fiber and the preparation method thereof, the one-step electrostatic spinning technique is utilized; a bead-chain-shaped structure is formed by controlling the property of a precursor raw material; the process is simple; the bead-chain-shaped structure is a one-dimensional structure formed by connecting Co3O4 monocrystal grains of similar granularity, the diameter is distributed uniformly, the shape is regular, the grains are completely exposed and are connected closely, and the specific surface area is relatively large; the cobaltosic oxide bead-chain-shaped fiber and the preparation method thereof have the wide application prospect in the fields of battery electrode materials, chemical catalysts, gas sensing and the like.

The invention discloses a preparation method of a material based on a bismuth oxycarbonate or bismuth oxide nano tube. The preparation method of the material based on the bismuth oxycarbonate or bismuth oxide nano tube comprises the following steps: firstly dissolving bismuth nitrate in dilute nitric acid or dissolving bismuth nitrate into dilute nitric acid solution dispersed with oxidized graphene, and uniformly stirring, so as to obtain first reaction solution; secondly, dropwise adding ammonia water in the first reaction solution until pH value of a system generated by mixing the first reaction solution and the ammonia water to be alkaline, so as to obtain second mixed liquor; and thirdly, stirring the second mixed liquor in CO2-containing atmosphere or CO2-free atmosphere, so as to obtain the material based on the bismuth oxycarbonate or bismuth oxide nano tube. The obtained material is a bismuth oxycarbonate nano tube, a bismuth oxide nano tube, a graphene-based bismuth oxycarbonate nano tube or a graphene-based bismuth oxide nano tube and can be applied to the fields of photocatalysis degradation, sterilization, adsorption, gas sensing, energy storage and pharmacy.

The invention discloses a preparation method of polycrystalline Al2O3-Y3Al5O12 complex-phase fibers or pure YAG fibers. The preparation method comprises the following steps that (1) precursor colloids of the polycrystalline Al2O3-Y3Al5O12 complex-phase fibers and the pure YAG fibers are prepared; (2) centrifugal spinning is performed, namely a home-made centrifugal spinning machine is adopted to perform centrifugal spinning so as to obtain uniform-diameter gel fibers under the conditions of appropriate wind seed, appropriate rotation speed and relative humidity; (3) the polycrystalline Al2O3-Y3Al5O12 complex-phase fibers and the YAG fibers are prepared, namely the obtained gel fibers are dried at the temperature of 55-75 DEG C for 12 hours, then heat processing is performed at the temperature interval of 800-1400 DEG C for 2 hours to obtain the required polycrystalline Al2O3-YAG complex-phase fibers and continuous YAG fibers. The fibers prepared by means of the preparation method have good flexibility, higher in high-temperature-resistance degree and better in creep resistance performance, and industrial production can be considered.

The invention provides a high-safety high-energy long-cycle lithium iron phosphate type 18650 lithium battery and a preparation method thereof. The cathode active material of the battery is carbon doped coated lithium iron phosphate with a small particle size and uniform particle size distribution, with the specific capacity being not less than 155 mAh/g and the compaction density being 2.0 - 2.8g/cm<3>; the anode active material is graphite with the specific capacity being 350 - 375 mAh/g and the compaction density being not less than 1. 7 g/cm<3>; a membrane is a PE base membrane coated with a nanometer Al2O3 ceramic membrane. The method comprises the steps of homogenizing, coating, rolling, cutting, winding, shelling, liquid injection, cleaning, oiling, forming and mixing. The batteryenergy density of the invention is as high as 390Wh/L, the discharge capacity of the monomer cell 0.2 C is not less than 2000 mAh, the cycle performance is excellent, the capacity retention rate of the cell 0.5 C/0. 5C100% DOD after 1000 cycles is above 80%, the thermal stability is good, and the overcharge performance is good.

The present invention provides a titanium dioxide nanotube and its preparing method. The method is first dripping titanium tetrachloride in de-ionized water containing organic additive to form homogeneous solution; then mixing to homogeneous buffer alkaline solution according to a certian mol ratio of ammonia and urea, adding the solution in homogeneous solution containing titanium to proceed ultrasonical reaction after being mixed; the nano titanium dioxide powder obtained by preheating reactant which granularity is homogeneous; then mixing nano titanium dioxide powder and NaOH solution containing organic additive, placing in reactor, processing kaline ultrasonical reaction, then obtaining titanium dioxide nanotube after being dried. The titanium dioxide nanotube has a simple process, convenient operation, the diameter of the titanium dioxide nanotube is homogeneous.

The invention relates to a nitrogen doped carbon nanofiber/molybdenum disulfide composite. The nitrogen doped carbon nanofiber/molybdenum disulfide composite takes a polymethyl methacrylate nanofiberas a template, polypyrrole is polymerized on the surface of the nanofiber in situ, the molybdenum disulfide is then grown in situ, the composite has a hollow tubular structure, a molybdenum disulfidesheet is evenly distributed on the surface of the nitrogen doped carbon nanofiber, the size of the nitrogen doped carbon nanofiber is uniform, a preparation method comprises synthesis of a polymethylmethacrylate spinning solution, synthesis of a polymethyl methacrylate nanofiber membrane, synthesis of the polypyrrole/polymethyl methacrylate nanofiber membrane, synthesis of the nitrogen doped carbon nanofiber/molybdenum disulfide nanofiber membrane, and synthesis of the nitrogen doped carbon nanofiber/molybdenum disulfide composite. The method is simple, is easy to operate and is environmentally friendly; the prepared nitrogen doped carbon nanofiber/molybdenum disulfide composite has the advantages of high specific surface area, high cycle stability, high electric conductivity, high rate capability and high specific capacity, and is used as a negative electrode material for a lithium ion battery.

The present invention relates to the field of nanometer fibers, specifically to a glass carbon nanometer fiber preparation method, which is characterized by comprising: 1) adopting cellulose acetate as a precursor, adopting acetone and N,N-dimethylacetamide as a mixed solvent, carrying out magnetic stirring to prepare a spinning solution, and adopting an electrostatic spinning method to prepare cellulose acetate nanometer fibers; 2) carrying out hydrolysis on the cellulose acetate nanometer fibers for 24 h by using an ethanol solution containing 0.1 mol/L NaOH, washing with distilled water to achieve a neutral state, draining for 8 h under an atmospheric environment, and carrying out vacuum drying for 12 h at a temperature of 70 DEG C to obtain cellulose nanometer fibers; and 3) placing the cellulose nanometer fibers in a tube furnace to carry out a stabilization and carbonization treatment to obtain the glass carbon nanometer fibers. The preparation method has characteristics of low cost, low pollution and simple process. With the preparation method, diameter and morphology of the fibers can be controlled by adjusting composition of the spinning solution and electrospinning parameters, the prepared fibers have uniform diameter distribution, and the method is suitable for mass production.

The invention provides a method for preparing a boron nitride nanowire by cracking of a polymer. The method comprises the following steps: synthesizing a polyalkylamino borazine precursor according to the prior art: grinding the precursor under the protective condition of inert gas and screening the grinded precursor through a 1000-mesh sieve; placing the precursor powder in a graphite boat, rising the temperature to 100-200 DEG C at the speed of 3-10 DEG C/min in the presence of high-pure nitrogen in a tubular furnace, and then insulating for 1-3 hours; rising the temperature to 500-700 DEG C at the speed of 3-10 DEG/min, and then insulating for 1-3 hours; at the atmosphere of nitrogen, heating to 1000-1600 DEG C at the rising speed of 3-10 DEG C/min, then insulating for 0.5-5 hours, and then cooling along with the furnace so as to obtain the boron nitride nanowire. The diameter of the nanowire prepared by the method is about 13-18 nm and is evenly distributed, no catalyst is used, preparation temperature is low, and energy is saved, thereby reducing the cost; and the method is simple in process, is convenient for operation and is easy to achieve large scale; and as a structure reinforced material, a semiconductor material, a wave-transparent material and the like, the prepared boron nitride nanowire has a good prospect of application.

The invention discloses a flexible CO room temperature sensor which includes a polyaniline fiber film which is mainly formed by coating a nano fiber thin film with polyaniline. The polyaniline fiber film is electrically connected to an electrode. The invention also discloses a preparation method of the flexible CO room temperature sensor. The method includes the steps of: soaking the nano fiber thin film in a solution containing aniline and an acid, adding an oxidizing agent to polymerize the aniline and coat the nano fiber thin film with polyaniline to obtain a flexible polyaniline fiber film; and electrically connecting the polyaniline fiber film to the electrode to form the flexible CO room temperature sensor. The flexible CO room temperature sensor has simple structure, high sensitivity, wide detection range and high detection speed. The flexible fiber film can be combined with substrates in different materials easily. The sensor is simple in preparation method, is low in cost and is suitable for large-scale production and application.

The invention discloses a preparation method of zinc oxide nanowire array/carbon nanofiber composite material, relates to preparation methods of nano composite materials, and aims to solve the problems that existing carbon nanofibers are low in surface area, and the contact area of the carbon nanofibers with solution is limited during application. The preparation method includes the steps of firstly, using an electrospinning method; secondly, using a hydrothermal synthesizing method. The zinc oxide nanowire array/carbon nanofiber composite material is large in surface area, excellent in conductivity, and the like. The preparation method is mainly used for preparing the zinc oxide nanowire array/carbon nanofiber composite material.

The invention discloses a deep filter element with a crude and fine fiber mixed structure. The deep filter element at least comprises two filtering layers; each filtering layer comprises a crude fiberset and a fine fiber set which are interwoven with each other; the average diameter of the crude fiber set of each filtering layer is reduced from the outer side to the inner side; the average diameter of the fine fiber set of each filtering layer is reduced from the outer side to the inner side; the fiber diameter of the fine fiber set of the innermost filtering layer is not larger than 1 micrometer; the fiber diameter of the crude fiber set of the outermost filtering layer is not smaller than 5 micrometers. The invention further discloses a preparation method of the deep filter element withthe crude and fine fiber mixed structure. The preparation method comprises the following steps of: 1) melt spinning; and 2) receiving a finished screen. The crude coarse fiber sets play a role in bonding the fine fiber sets and play a role in supporting, and therefore, the filter element is prevented from being compressed in a using process, and a dirt containing amount is increased, the fine fiber sets play a role in filtering and intercepting, so that filtering precision is improved, and the filter element has the functions of high filtering precision, high dirt containing capacity and longservice life and is good in filtering effect.

The invention relates to a method for preparing a pure hyaluronic acid nano fiber membrane. The method is that hyaluronic acid powder is dissolved in mixed solvent formed by water, formic acid and DMF to prepare solution, the solution is statically placed in ultrasonic wave for one hour to enable all bubbles to be precipitated to obtain transparent hyaluronic acid solution; and the prepared hyaluronic acid electrostatic spinning solution is added into an injection pump, spinning voltage, distance between a spinning nozzle and a collecting plate and flow of the spinning solution sprayed by the spinning nozzle are properly adjusted, and electrostatic spinning is conducted within 5-60 DEG C to spin the solution on a folding fan-shaped aluminum foil to obtain the hyaluronic acid nano fiber non-woven fabric with average fiber diameter of 200-600nm. The preparation process and the post-treatment process are simple, the hyaluronic acid nano fiber non-woven fabric can be obtained within the wide temperature range and the diameter distribution of the obtained hyaluronic acid nano fiber is even.