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Method for preparing length-diameter-ratio nano-silver wire by pH-value regulation solvothermal method

The invention relates to a method for preparing a length-diameter-ratio nano-silver wire by a pH-value regulation solvothermal method. The method comprises the following steps of: preparing the following ethylene glycol solution, namely an ethylene glycol solution A of silver nitrate or silver acetate, an ethylene glycol solution B of polyvinyl pyrrolidone (PVP), an ethylene glycol solution C of water-soluble chloride and concentrated acid D; mixing the components according to a certain amount and fully stirring to form a final mixed solution; moving the final mixed solution into a reaction kettle; placing in an oven for reaction for a certain time; taking the reaction kettle out and cooling to room temperature to obtain mother liquid of the nano-silver wire; adding alcohol into the mother liquid for diluting, and removing supernatant liquor to obtain a precipitate; and repeatedly performing centrifugal separation, and thus obtaining nano-silver wire dispersion liquid uniformly dispersed in the alcohol. The method is simple, high in efficiency and low in cost, and can prepare high-quality nano-silver wires within a wider range of reaction condition; and prepared products are high in length-diameter ratio, good in length uniformity and low in impurity content.
Owner:JIANGSU NANOWELL ADVANCED MATERIALS SCI&TECH

Method and device for simultaneously measuring droplet position, particle sizes and complex refractive index

The invention relates to technology for simultaneously measuring multi-phase flow particles online through multi-parameter, and aims to provide a method and a device for simultaneously measuring droplet positions, particle sizes and a complex refractive index. The method comprises the following steps of: (1) dividing a highly coherent continuous laser beam into two beams after spatial filtering and collimating beam expansion, wherein one beam radiates particles in a detected flow field region, and the other beam is used as a reference beam; (2) mixing scattered light of a lateral 30-degree to 90-degree region of particles in the detected flow field region and the attenuated reference beam to perform interference so as to form a hologram, storing the hologram in a computer after being recorded by a digital camera through an imaging device; (3) acquiring a series of reconstructed images of the detected particles along the depth direction by utilizing digital reconstruction technology; and (4) identifying the reflective spot and the refractive spot of the particles from the reconstructed images by utilizing digital image processing technology so as to acquire space coordinates and scattered light intensity ratios. Compared with rainbow measurement technology, the measurement method has the advantages that: a light path system of the measurement device is relatively simple and is easy to implement.
Owner:ZHEJIANG UNIV

Asymmetrical Adapters And Methods Of Use Thereof

A pair of asymmetrical, partially double-stranded oligonucleotide adapters are provided wherein the pair of adapters comprise a first asymmetrical oligonucleotide adapter comprising a single-stranded 3′ overhang and a second asymmetrical double-stranded oligonucleotide adapter comprising a single-stranded 5′ overhang and at least one blocking group on the strand of said second asymmetrical oligonucleotide adapter that does not comprise the 5′ overhang. Also provided are a pair of double-stranded Y oligonucleotide adapters and a pair of double-stranded bubble oligonucleotide adapters and methods of using said asymmetrical adapters for amplification of at least one double stranded nucleic acid molecule, wherein the amplification produces a plurality of amplified nucleic acid molecules having a different nucleic acid sequence at each end are also described. Also provided is a method for exponentially amplifying one strand in a double-stranded nucleic acid molecule. Also provided are methods for preparing libraries of paired tags using COS-linkers. Also provided are cleavable adapters comprising an affinity tag and a cleavable linkage, wherein cleaving the cleavable linkage produces two complementary ends. Methods of using the cleavable adapters to produce a paired tag library are also described.
Owner:LIFE TECH CORP

Spherical porous silicon/carbon composite material as well as preparation method and application thereof

The invention discloses a spherical porous silicon/carbon composite material as well as a preparation method and application thereof. The spherical porous silicon/carbon composite material is structurally characterized in that a SiOx/C matrix, graphite with small particle size and a conductive agent are dispersed in porous amorphous carbon, wherein the average particle diameter is 12-25mu m; the method comprises the following steps of carrying out first coating on a SiOx raw material with powder pitch, and performing heat treatment so as to obtain a SiOx/C material; then performing ball milling by use of a wet method so as to reduce the particle diameter of powder, adding a carbon source adhesive, the graphite with the small particle diameter and the conductive agent, and performing high-speed dispersion, thereby obtaining pulp; and finally performing spray granulation and sintering on the pulp, thereby obtaining the final spherical porous silicon/carbon composite material. According to the invention, SiOx is dispersed in cracking carbon, the graphite and the conductive agent, so that SiOx volume expansion during a charge/discharge process is buffered, and the conductibility is enhanced; by virtue of the porous structure, the imbibition rate and cycle performance of the material can be effectively improved; by virtue of bitumencarb coating and high-heat treatment performed in advance, SiOx is prevented from being directly contacted with an electrolyte, and furthermore, the stability and first efficiency of the silicon/carbon material are improved.
Owner:ZHONGTIAN ENERGY STORAGE TECH

Controllable crystalline form titanium dioxide and graphite alkene composite material with high efficient photoelectricity activity and preparation method thereof

The invention discloses controllable crystalline form titanium dioxide and a graphite alkene composite material with high efficient photoelectricity activity and a preparation method thereof. The composite material is formed by mixing TiO2 powder and graphite alkene or scattering the TiO2 powder in oxidized graphite alkene dispersing agents to perform hydro-thermal reaction. The mass ratio of TiO2 powder and graphite or graphite alkene is 1:1 to 500:1. The preparation method is simple, low in cost and environmental-friendly. The controllable crystalline form titanium dioxide and a graphite alkene composite material with high efficient photoelectricity activity can control crystalline form of the obtained TiO2 according to the ratio of alcohol and water or amount of titanium sources. When the amount is amplified, the controllable crystalline form titanium dioxide and a graphite alkene composite material with high efficient photoelectricity activity have good performances. After the graphite alkene is composed, photocatalysis is greatly improved. All obtained products are applied to fields of dye sensitization solar cells, catalysts, lithium ion cells, sensing and the like.
Owner:NANJING UNIV OF TECH

Flexible lithium ion battery black phosphorus nanosheet-graphene composite film anode, and preparation thereof

The invention belongs to the field of electrochemistry battery, and more specifically relates to a black phosphorus nanosheet-graphene composite film anode used for flexible lithium ion batteries, and a preparation method thereof. According to the preparation method, high purity and large scale black phosphorus blocks are synthesized via mineral substance assistant vapor transporting method with high efficiency; a large amount of clean and high quality black phosphorus sheets are prepared in water via ultrasound treatment; the clean and high quality black phosphorus sheets and high conductive graphene nanosheets prepared via intercalation stripping method are subjected to mixing ultrasonic dispersion; and flexible high-strength laminated composite film is prepared via vacuum filtration. The preparation process of the flexible high-strength laminated composite film is simple and controllable; large scale low cost preparation can be realized; black phosphorus nanosheets are high in capacity, graphene is high in electrical conductivity, and the black phosphorus nanosheets and graphene both possess two-dimensional structures high in flexibility and strength, so that problems the black phosphorus is poor in electrical conductivity and stability are solved, lithium ion battery capacity, cycling stability, and entire energy density are increased, and lithium ion battery electrode integrated flexible design is realized.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI +1

Mesoporous graphene foam as well as preparation method thereof

The invention belongs to the technical fields of a novel material as well as preparation, and particularly relates to mesoporous graphene foam as well as a preparation method thereof. The invention realizes hydrothermal preparation of a magnesium oxide texture structure and preparation of the mesoporous graphene foam by using textured magnesium oxide as a template. The mesoporous graphene foam material has abundant mesoporous structures and excellent electric property and can be used as an electrode material of batteries and supercapacitors, so that the energy density and the power density of the batteries or the supercapacitors are expectedly improved to a great extent. The cycling stability of the mesoporous graphene foam material is increased, and the mesoporous graphene foam material combined with materials with high draw ratio or the mesoporous graphene foam material can soften energy storage apparatuses. The advantages have important meaning for realization of commercialization of a new generation of energy storage apparatuses for electromobiles and development of smaller, lighter and flexible portable mobile power supplies. The business prospect is wide. Meanwhile, preparation processes of the high temperature hydrothermal method and a fluidized bed can realize engineering enlargement, so that the method is expected to be industrialized.
Owner:TSINGHUA UNIV

Method and device for preparing low-tar combustible gas through biomass gasification

ActiveCN101906323AHigh cracking rateMake up for the problem of low conduction rateGranular/pulverulent flues gasificationFixed bedCombustible gas
The invention discloses a method and a device for preparing a low-tar combustible gas through biomass gasification. The method comprises the followings steps of: pulverizing and gasifying biomass, and rapidly separating obtained gasification gas products and biomass char; heating and activating the biomass char in a microwave field; catalytically cracking tar in the gasification gas products by introducing the gasification gas products to pass through a treated biomass char layer, and carrying out secondary reaction on the gasification gas and the biomass char to produce the combustible gas. The device comprises a spiral-flow gasifier 1, a fixed bed reactor 2 and a microwave generator 3 which are connected through ducts, and the middle part of the fixed bed reactor is connected with the microwave generator 3 through a microwave duct 11. The microwave technology is applied to tar cracking, so that the problem of low heat transfer speed due to porous and loose biomass char is solved. Meanwhile, the cracking rate of tar and the secondary reaction activity between the char and the gasification gas are increased by using the 'hot spot effect' of microwaves. The device has the advantages of strong adaptability, simple and compact structure and easy enlargement.
Owner:GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI
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