2837results about "Nanotechnology" patented technology

The invention discloses a method for preparing a single-layer tungsten diselenide nanoband based on a space confinement strategy. By changing the flow and the growth time of hydrogen, effective control on the width and the thickness of a nanoband can be realized. The method comprises the following steps: uniformly spraying tungsten trioxide powder to one substrate, then covering the substrate by the other substrate, and forming micro reaction space which is of a 'sandwich'-like structure. Growth of a tungsten diselenide nanoband is carried out by utilizing a constant-pressure chemical vapor deposition method; physicochemical characteristics of a one-dimensional transition metal chalcogenide strongly depend on suspension key types on the edge of the one-dimensional transition metal chalcogenide, metallic properties are displayed by an ultranarrow band, and conversion from the metallic properties to semiconductor properties can be displayed from the edge to the center of a wider band; the tungsten diselenide nanoband is widely applied to micro-nano photoelectric devices due to the special property; industrial production of the tungsten diselenide nanoband can be realized through an experimental method of the invention.

The invention belongs to the technical field of conductive carbon paste, and discloses a method for efficiently preparing single-walled carbon nanotube paste, which comprises the following steps of: 1, mixing single-walled carbon nanotube powder with a dispersing agent and a solvent, and dispersing the mixture into uniform carbon nanotube bundle paste in manners of mechanical stirring, emulsifying and the like; and step 2, enabling the uniform carbon nanotube bundle slurry to pass through different micropore channels for multiple times in a high-pressure environment, so that the carbon nanotube bundle slurry is dispersed into uniform single carbon nanotube slurry. Through a special high-pressure homogenizing channel, the adhered and wound single-walled carbon nanotube bundles can be dispersed into the slurry of the single single-walled carbon nanotubes on the premise of ensuring the lengths of the single-walled carbon nanotubes as much as possible. The uniform dispersion is realized, the tube diameter of the single-walled carbon nanotubes is relatively long, and the excellent conductivity of the slurry is ensured by the single single-walled carbon nanotubes and the microcosmic number of the single single-walled carbon nanotubes.

The invention relates to the technical field of sensors, in particular to a high-sensitivity pressure-temperature dual-mode sensor and a preparation method thereof.The preparation method comprises the steps that a carbon nano tube is subjected to acid treatment and then reacts with a silane coupling agent KH550, and an aminated carbon nano tube is prepared; the method comprises the following steps: carrying out hydrothermal reaction on a phosphorus source and a graphene oxide aqueous solution to prepare phosphorus-doped reduced graphene oxide; the preparation method comprises the following steps: synthesizing Au-Ag heterojunction nano dispersion liquid through an Au nano seed method; mixing the three components and carrying out ultrasonic treatment to obtain mixed dispersion liquid; the preparation method comprises the following steps: modifying a PDMS substrate with KH560 and polyethylene glycol diamine to prepare a modified PDMS substrate; and coating the mixed dispersion liquid on a modified substrate to form a sensitive layer, and preparing an electrode to obtain the sensor. The aminated carbon nanotubes and the phosphorus-doped reduced graphene oxide construct a three-dimensional conductive network, so that high-sensitivity pressure detection is realized; the phosphorus-doped reduced graphene oxide and the Au-Ag heterojunction form a Schottky barrier, so that stable temperature sensing is realized; and the modified PDMS and the sensitive layer are strongly combined to improve the mechanical durability.

The invention relates to the technical field of gas sensors, and particularly discloses an electrochemical formaldehyde sensor electrode, a preparation method thereof and an electrochemical formaldehyde sensor. The electrochemical formaldehyde sensor comprises an electrochemical formaldehyde sensor electrode and a binary electrolyte, the electrochemical formaldehyde sensor electrode comprises a polytetrafluoroethylene film, the polytetrafluoroethylene film is coated with slurry for an electrochemical formaldehyde sensor electrode; and the slurry is formed by mixing nano manganese dioxide, platinum carbon and a Nafion solution. According to the electrochemical formaldehyde sensor, the electrode prepared from the slurry formed by mixing the nano manganese dioxide, the platinum carbon and the Nafion solution has relatively high catalytic activity, so that the sensor shows extremely high sensitivity and extremely good linearity on formaldehyde, and the electrochemical formaldehyde sensor has relatively high catalytic activity by regulating and controlling the proportion of the binary electrolyte. The electrochemical formaldehyde sensor has the advantages of high sensitivity, low cost, fast response, high detection precision and the like.

The invention provides an oriented ultrathin FER zeolite molecular sieve membrane as well as a preparation method and application thereof. The preparation method comprises the following steps: firstly, synthesizing a monodisperse FER zeolite nanosheet with a high length-depth ratio through a hydrothermal method; preparing a seed crystal liquid, and coating the surface of a porous carrier with the seed crystal liquid to form an oriented seed crystal layer; and carrying out hydrothermal epitaxial growth in a secondary growth solution. Through innovative design of seed crystal synthesis and epitaxial growth, the FER zeolite membrane prepared by the method has a structure with high alpha-axis preferred orientation, submicron controllable thickness, compactness and no defect. The membrane can be used for accurately screening gas molecules with small size difference by utilizing six-membered ring pore channels uniformly arranged along an a axis. When helium and methane or carbon dioxide are separated, the membrane shows permeation flux and separation selectivity far superior to those in the prior art, provides a brand new technical approach for efficient and low-energy-consumption recovery of helium and other high-value gases in the industry, and has great industrial application value.

The invention discloses a three-dimensional micro-nano multistage micro-channel structure and a preparation method thereof, and the channel structure comprises a substrate, a nano honeycomb layer located on the surface of the substrate, and a Tesla valve micro-channel and a micron fence member formed on the nano honeycomb layer. The micron fence piece is provided with a plurality of rib columns which are close to each other and are arranged along the side wall direction of the Tesla valve micro-channel; the high wicking capacity of the nano porous medium and the macroscopic fluid guiding capacity of the micron channels are organically combined, so that fluid can be rapidly transported in the multi-stage channels, the transporting capacity and the heat exchange efficiency of liquid are effectively improved, especially during boiling, the liquid supplementing rate and the steam discharging rate can reach dynamic balance, and the heat exchange efficiency of the liquid is improved. The friction loss of gas-liquid two-phase flow is reduced, and different thermal management requirements are met; in addition, according to the preparation method, nano-first and micro-second processing is adopted, high compatibility of the structure morphology and the material interface is achieved, good repeatability and process window are achieved, and the preparation method is suitable for large-area preparation and industrial production.

The invention discloses a functionalized carbon quantum dot modified all-vanadium redox flow battery electrolyte. The functionalized carbon quantum dot has a large specific surface area and a carboxyl functional group on the surface; the electrolyte of the flow battery is a dilute sulfuric acid solution of vanadium; the main evaluation indexes of the electrochemical performance are the cycle efficiency, the capacity retention ratio and the battery performance of the electrolyte; the invention aims to discuss the catalytic action of the surface functional groups of the functionalized carbon quantum dots on the oxidation-reduction reaction of vanadium ions in the electrolyte of the all-vanadium redox flow battery by using the functionalized carbon quantum dots as an additive of the electrolyte. Meanwhile, the influence of the concentration and doping of the carbon quantum dots on the electrochemical performance of the electrolyte of the all-vanadium redox flow battery is researched, so that the working efficiency and the overall performance of the battery are improved, the characteristics of the electrolyte are improved, and the energy consumption of the battery is reduced.

The invention relates to the technical field of nano particle heterogeneous reaction kinetic research, in particular to a nano single particle reaction rate measuring system and method based on optical surface wave dark field imaging. The method comprises the following steps: preparing a nano single particle sample; the humidity of the environment where the nano single particles are located is adjusted; starting a heterogeneous reaction of the nano single particulate matter, performing in-situ dark field imaging on the nano single particulate matter in the reaction process, and collecting scattering hot spot imaging data under different reaction times and different humidity; and based on the acquired imaging data, the reaction rate of the nano single particulate matter is inversed in combination with a kinetic model. According to the invention, the defects in the existing nano-particle reaction rate measurement technology can be overcome, and the reaction rate of a single particle as low as 50 nanometers in the heterogeneous reaction process can be accurately measured and inverted under the high-humidity standard atmospheric pressure condition.

This invention belongs to the field of polymer material reinforcement and toughening, specifically relating to a spiked-mesoporous silica nanosphere, its preparation method, and its application in polymer material reinforcement and toughening. The basic steps for synthesizing this spiked-mesoporous silica nanosphere include: firstly, synthesizing low-crosslinked, smooth-surfaced mesoporous silica nanospheres through an oil-water two-phase reaction system; subsequently, inducing normal shrinkage of the pore walls through secondary deep crosslinking to form a rigid nanospike surface structure while maintaining the original mesoporous structure. This spiked-mesoporous silica nanosphere exhibits good monodispersity, high particle size uniformity (50-100 nm adjustable), centrally divergent mesopores with high pore size uniformity (6-8 nm adjustable), highly open pores on the sphere surface, and spike height adjustable from 3-5 nm. This material is suitable for reinforcing and toughening various elastomers, resins, and other polymer materials, effectively overcoming the "strength-toughness mutual exclusion" problem and synergistically enhancing existing mechanical property reinforcement systems.

A method for synergistically preparing lithium sulfide by vacuum molten salt based on hydrogen sulfide-lithium salt reaction belongs to the technical field of battery materials, and comprises the following steps: placing a lithium salt solid in a reactor, introducing a molten salt medium on the surface of the lithium salt or in a reaction system, introducing purified hydrogen sulfide gas under a vacuum auxiliary condition, controlling the reaction temperature to be 200-500 DEG C, and reacting for 1-2 hours; and adjusting the flow rate of hydrogen sulfide to be 50-1000mL / min and the retention time to be 5-180min, continuously exhausting gas to discharge water vapor in the reaction process, stopping introducing hydrogen sulfide gas after the reaction is finished, cooling the system to room temperature under the protection of inert gas, taking out the product, washing to remove residual fused salt, and carrying out vacuum drying to obtain the high-purity lithium sulfide. The prepared lithium sulfide has high purity (greater than or equal to 99.90%), low defect density and an excellent crystal structure, and can be widely applied to lithium-sulfur batteries, all-solid-state batteries and novel energy storage technologies, so that the energy density is improved, the cycle life is prolonged, and the energy consumption is reduced.

The invention discloses a preparation method of a rare earth element doped nickel-based selenide nano-material and application of the rare earth element doped nickel-based selenide nano-material in electro-catalysis water full-hydrolysis reaction. According to the method, nickel salt, cerium salt, selenium dioxide and potassium chloride are prepared into electrolyte, and the electrolyte is subjected to electro-deposition on a foamed nickel substrate to obtain Ce-doped Ni0.85Se nanoparticles growing on foamed nickel. The crystal structure and electron distribution of Ni0.85Se are optimized by doping trace rare earth element cerium, so that the HER and OER performances of the Ni0.85Se are greatly improved. The prepared catalyst is self-supporting closely-packed nanoparticles, the formed amorphous structure is easy to expose more active sites, the catalyst has good electrocatalytic hydrogen evolution and oxygen evolution performance under alkaline conditions, the overpotential in electrocatalysis of nickel-based selenide is greatly reduced, and the electrocatalytic performance of nickel-based selenide is improved. And excellent electro-catalytic activity is shown in electro-catalytic water full hydrolysis. And the self-supporting electrode is not easy to fall off due to generation of bubbles in the reaction process, so that the working stability of the catalyst is improved.

The invention discloses an alkaline electrolyzed water diaphragm based on nickel oxyhydroxide and a preparation method and application of the alkaline electrolyzed water diaphragm, and relates to the technical field of composite diaphragms.The alkaline electrolyzed water diaphragm is prepared through a phase inversion method, and nanometer nickel oxyhydroxide NiOOH particles are selected as inorganic nanometer filler; the mass percent of the nickel oxyhydroxide in the membrane casting solution is 15-30%. A strong chemical bond formed by nickel ions and hydroxyl in the hydroxyl nickel oxide crystal endows the material with excellent structural stability, and the material shows excellent solubility resistance, hydrolysis resistance and structural collapse resistance in a strong alkaline electrolysis environment and can tolerate high-concentration OH <-> erosion for a long time; meanwhile, the intrinsic high-oxidation-resistance characteristic is achieved.

The invention provides a preparation method of grain size grading iron phosphate and high compaction type lithium iron phosphate. Removing impurities from the titanium dioxide byproduct ferrous sulfate, and filtering to obtain a purified ferrous sulfate base solution; the method comprises the following steps: reacting phosphoric acid with ammonia water to prepare ammonium phosphate solutions with different reaction pH values and phosphorus molar concentrations, respectively mixing the ammonium phosphate solutions with a certain amount of hydrogen peroxide, and sequentially adding an iron source, a first phosphorus salt solution, a second phosphorus salt solution and a third phosphorus salt solution into a tubular reactor for reaction to obtain iron phosphate slurry; and sequentially converting, filtering, washing, drying and calcining the completely reacted slurry to finally prepare the anhydrous iron phosphate. According to the invention, a mode of controlling solution nucleation and growth is adopted, nucleation and growth rates are controlled by preparing phosphorus salt solutions with different concentrations, size grading of precursor particles is directly realized in a synthesis reaction section, and slurry grading uniformity is further realized through aging crystal transformation. Lithium iron phosphate prepared from the iron phosphate precursor has high compaction density.

The invention relates to a nano silicon carbide whisker and a preparation method thereof, and the preparation method comprises the following steps: (1) carrying out acid process treatment on fly ash by using an acid solution, so that the content of key impurity elements in the fly ash accounts for 2-11% of the total mass of the treated fly ash, and obtaining acid-treated fly ash; (2) mixing the acid-treated fly ash with a first carbon source to obtain a mixture; and (3) covering the mixture with a second carbon source, roasting in a reducing atmosphere to obtain a roasted material which comprises a nano silicon carbide whisker layer and a total impurity layer positioned below the silicon carbide whisker layer, and removing the total impurity layer to obtain the nano silicon carbide whisker. According to the preparation method, the low-cost fly ash is taken as a raw material, the advantages of low preparation cost and relatively high product yield can be taken into account through the synergistic effect of moderate acid treatment, raw material position setting and roasting in the reducing atmosphere, and good morphology and relatively high purity of the nano silicon carbide crystal whiskers are ensured.

The invention belongs to the field of reinforcing and toughening of high polymer materials, and particularly relates to spike-mesoporous silica nanospheres, a preparation method thereof and application of the spike-mesoporous silica nanospheres in reinforcing and toughening of high polymer materials. The method for synthesizing the spur-mesoporous silica nanosphere comprises the following basic steps: synthesizing a smooth-surface mesoporous silica nanosphere with low crosslinking degree through an oil-water two-phase reaction system, and inducing normal shrinkage of a pore wall by utilizing secondary deep crosslinking to form a rigid nano spur surface structure and maintain an original mesoporous structure. The spur-mesoporous silica nanosphere is good in monodispersity, high in particle size uniformity and adjustable in 50-100 nm, has center divergent mesopores, high in pore diameter uniformity and adjustable in 6-8 nm, the pore opening height of the surface of the sphere is open, and the spur height is adjustable in 3-5 nm. The material is suitable for reinforcing and toughening high polymer materials such as various elastomers and resins, can effectively overcome the problem of'toughness mutual exclusion ', and can achieve synergistic interaction with an existing mechanical property reinforcing system.

The invention relates to the technical field of pharmaceutical preparations, in particular to a preparation process of carbon dots for killing helicobacter pylori and application of the carbon dots in oral pharmaceutical preparations. The preparation method comprises the following steps: mixing microcrystalline cellulose and glycerol, freezing and crushing at an ultralow temperature, and selectively hydrolyzing by combining citric acid-malic acid mixed acid liquor to efficiently prepare a high-crystallinity cellulose nanocrystal template; the controllable synthesis of the carbon dots is realized by utilizing the hydrogen-bond interaction of hydroxyl / carboxyl on the surface of the cellulose nanocrystal and the nitrogen doping effect in the polymerization and carbonization process of citric acid and urea. Besides, when a sodium alginate-chitosan double-layer structure is constructed, carbon dots are introduced into the inner layer to endow the inner layer with special performance, a protein-polysaccharide network is formed on the outer layer through transglutaminase enzymatic crosslinking, and the oxidation resistance and mechanical strength are enhanced through secondary curing of tea polyphenol. According to the invention, food-grade raw materials are used for realizing high-efficiency antibiosis, the oral preparation safety specification is met, and the clinical transformation potential is realized.

The invention discloses a high-valued utilization method of waste biomass, which comprises the following steps: firstly, applying current to the waste biomass containing carbon element to generate Joule heat, and generating a high-temperature environment in an extremely short time, so as to realize rapid carbonization of the biomass; then conductive carbon black or other auxiliaries do not need to be additionally added, current is applied again to generate Joule heat, a higher-temperature environment is generated within an extremely short time, and graphitization transformation of the biochar is achieved. Compared with traditional pyrolysis, hydrothermal, roasting or chemical vapor deposition methods, the flash Joule thermal method has the advantages of being easy and convenient to operate, short in consumed time, low in energy consumption, high in efficiency, high in safety, environmentally friendly and the like, and is suitable for high-value utilization of various biomass resources and green preparation of graphene materials.

The invention belongs to the field of functional nano materials, and relates to a method for large-scale preparation of monoclinic phase vanadium dioxide nano powder, a heat insulation film and application of the heat insulation film, and large-scale preparation of the monoclinic phase vanadium dioxide nano powder is successfully achieved by combining a coprecipitation method with low-temperature calcination. The obtained product has excellent size uniformity (the average particle size is 65 + / -10 nm) and an adjustable phase change characteristic (61-68 DEG C). The polymer-based composite film prepared based on the nano powder shows excellent optical performance, and the method has the advantages of mild reaction conditions (less than or equal to 600 DEG C), controllable product morphology and phase transition temperature and the like, and provides a reliable solution for industrial production of nano functional materials for intelligent windows.

The invention discloses a comprehensive two-dimensional vertical structure metal-semiconductor field effect transistor and a preparation method thereof. A source electrode, a lower isolation layer, a drain electrode and an upper isolation layer which are vertically stacked are formed on the surface of a substrate, an inclined side wall is formed, a channel covers the inclined side wall, a grid electrode and the channel are self-aligned, and a semi-metal grid electrode and a semiconductor channel are in direct contact to form a Schottky junction; based on a comprehensive two-dimensional material system, the Fermi pinning effect and unintentional doping are effectively inhibited, and the performance of the device is optimized by optimizing the grid control capability and the electric contact performance; a gate dielectric layer is not arranged, so that the problems of electrical performance deterioration and the like under a limit miniature scale are avoided; the integration density of the device is improved and the research and development and manufacturing cost is controlled while excellent performance is kept; the channel length and the contact length are synchronously and accurately reduced by utilizing a side wall vertical structure; the method is applied to the industrial application fields of next-generation integrated circuit chips, high-density memories, flexible and wearable electronics and the like which break through the silicon-based physical limit.

The invention relates to the technical field of control systems, and discloses a multi-zone cooperative control method and system for a temperature field of a carbon nanotube CVD growth furnace, and the method comprises the steps: obtaining the real-time temperatures of a plurality of temperature zones, and calculating the temperature deviation of each temperature zone; the actual temperature gradient is calculated, if the change rate of the actual temperature gradient exceeds a preset threshold value, the gradient maintaining deviation is calculated, and otherwise, the gradient maintaining deviation is zero; calculating a gain weight; calculating predictive thermal disturbance compensation amount of each temperature zone; calculating a first control item; the predictive thermal disturbance compensation amount forms a second control item; the gradient feed-forward correction value forms a third control item, and the gradient feed-forward correction value is proportional to the gradient maintenance deviation of the temperature zone; and taking the sum of the first control item, the second control item and the third control item as the power control quantity of the temperature zone. Unification and coordination of local temperature control and overall temperature are realized, a stable thermal environment is provided for growth of the carbon nanotubes, and consistency and uniformity of growth of the carbon nanotubes are improved.

The invention belongs to the technical field of preparation and application of nano materials, and relates to a preparation method and application of amino-functionalized cerium oxide nano enzyme, and the preparation method comprises the following steps: adding 3-aminophenylboronic acid into a cerous nitrate hexahydrate aqueous solution to obtain a mixed solution; dropwise adding a sodium hydroxide aqueous solution into the mixed solution, carrying out hydrothermal reaction, cooling after the reaction is finished, centrifuging, washing and drying to obtain milk white powder, namely the amino-functionalized cerium oxide nano-enzyme. The boron element is introduced in the preparation of the cerium oxide nano-enzyme, and the amino-functionalized cerium oxide nano-enzyme is prepared by adopting a simple one-step hydrothermal synthesis method, so that the nano-enzyme has good phosphatase-like activity, has high selectivity and sensitivity to LPS, and is short in detection time, high in sensitivity, low in detection limit, simple in preparation process and high in preparation efficiency; the product is good in quality, high in stability, environment-friendly and extremely wide in market prospect.

The invention discloses a preparation method of a CoMnFe-PBA hollow superstructure material, which combines seed induced self-assembly with an in-situ ligand / metal ion exchange growth method, and comprises the following steps: dissolving MOF-74 and potassium ferricyanide in deionized water, and carrying out ultrasonic treatment to form a solution A; dissolving polyvinylpyrrolidone, ferric chloride and manganese chloride tetrahydrate in a mixed solvent of ethanol and deionized water, and stirring for a certain time to obtain a solution B; dropwise adding the solution B into the solution A, stirring, carrying out centrifugal collection, ethanol washing and freeze drying on a reaction product, and collecting a sample to obtain the CoMnFe-PBA hollow superstructure material. According to the CoMnFe-PBA hollow superstructure material prepared through the method, a construction unit of a self-assembly superstructure is expanded to PBA nanoparticles, and the synthesis strategy, the construction unit, the structural level and the application range of the self-assembly superstructure can be further expanded.

This invention relates to an in-situ detection system for a rotating microliquid film reactor (MFR) for monitoring the nucleation behavior of nanomaterials. The reactor comprises a rotor and a stator, with a stator base angle of 70-85°, a rotational speed of 500-5000 rpm, and a slit width of 10-500 μm to ensure that fluid passing through the slit does not undergo backmixing and to create a strong shear field. A micro-negative pressure sampler is fabricated to capture nucleating particles within the high-speed shear field and bring them into the visible observation area. A high-speed camera and microscope objective are connected in situ, thereby acquiring instantaneous images of the nucleation process at the nanoscale and capturing the transient evolution behavior of crystal nuclei. The construction of this rotating MFR in-situ detection system solves the problems of poor micro-mixing effects and uncontrollable nucleation and growth in traditional stirred tank reactors, leading to poor quality in large-scale preparations, and the inability to observe phase transitions and instantaneous nucleation processes in a closed reactor. The obtained hydrotalcite nucleation results enrich non-classical nucleation theories and provide guidance for the large-scale preparation of nanomaterials.

The application relates to a preparation method and application of a ball milling-calcination process-prepared cesium vanadium tungstate mixed heat insulation coating, and belongs to the technical field of heat insulation coatings. The application aims to solve the problems of high preparation cost, strict requirement on equipment, long preparation time and difficult morphology control of vanadium dioxide and cesium tungsten bronze used in the existing cooling coating. The prepared cesium vanadium tungstate mixed heat insulation coating is coated on the surface of glass, mainly aiming at blocking the infrared light thermal radiation in sunlight, the new type of high-efficiency heat insulation film utilizes the light absorption and phase change reflection characteristics of nanometer cesium tungsten bronze and vanadium dioxide to realize heat insulation. The application adjusts the proportion of cesium, vanadium and tungstate to adjust the heat insulation performance, the heat insulation coating is prepared through different proportions of acrylic resin / organic silicon resin, solvent, cesium vanadium tungstate mixed heat insulation coating and the like, and the heat insulation film with excellent infrared blocking property, good stability and excellent light transmittance is obtained.

The present application belongs to the technical field of nanometer material, and discloses a kind of sheet porous nanometer zinc oxide and its preparation method and application.The present application first prepares basic zinc carbonate precursor, then nitrogen is passed into, the pressure of system is >0.4MPa and <0.6MPa, hydrothermal reaction is carried out, and the reaction product is calcined, and sheet porous nanometer zinc oxide is prepared.The sheet porous nanometer zinc oxide prepared by the method of the present application has uniform and regular sheet porous structure, the holes on the sheet are uniform and regular, dense, small in particle size, large in specific surface area, and can be widely applied in the degradation of organic pollutants in photocatalytic system and the field of heavy metal adsorption.The preparation method of the present application can obtain raw materials easily and can be mass-produced.

The invention provides a preparation method of a PdSe2 / Bi2O2Se Van der Waals heterojunction self-driven photoelectric detector, and relates to construction of a two-dimensional material heterostructure and application of the two-dimensional material heterostructure to a photoelectric device. The method comprises the following steps; the preparation method comprises the following steps: preparing nanosheets through a chemical vapor deposition (CVD) process; respectively preparing a PdSe2 nanosheet and a Bi2O2Se nanosheet by adopting the CVD process; and preparing a heterostructure: transferring the PdSe2 nanosheet to the surface of the Bi2O2Se nanosheet in a dry transfer mode to form a Van der Waals heterojunction structure with a clean interface and tight interlayer coupling. The transfer technology keeps the lattice and morphology of the two-dimensional material complete, and reduces organic residues and solvent pollution influences. The heterojunction structure is combined with the narrow band gap of PdSe2 and the broad spectrum response characteristic of Bi2O2Se, and efficient photoelectric conversion from visible light to near-infrared light is achieved. And an electric field is built in the p-n type heterojunction, so that the device is self-driven without external bias voltage, and has the performance of low power consumption and the like. And the method is low in process thermal budget, high in compatibility and suitable for various substrates, and a technical path is provided for construction of the flexible photoelectric detector.

The invention relates to the technical field of preparation of single-walled carbon nanotubes, in particular to a chemical vapor deposition reactor, an FCCVD reaction device and a batch continuous preparation method of single-walled carbon nanotubes. By optimizing the structure of the reactor, the flow field in the reactor is further optimized, uniform distribution of gas is realized, and in-situ growth of catalyst particles and uniformity of the particle size are maintained. Results of the embodiment show that the reaction process is strengthened through optimization design of the reactor, batch continuous preparation of the single-walled carbon nanotubes can be achieved, the utilization efficiency of the catalyst is greatly improved, the yield of the unit catalyst is greatly improved, and the prepared SWCNT is high in quality.

This invention relates to a method for preparing monodisperse doped titanium dioxide with in-situ lattice strain, belonging to the field of nanomaterial dispersion preparation. The titanium dioxide prepared by this method possesses abundant oxygen vacancies and surface active sites. The method employs a secondary titanium source injection followed by a rapid solvothermal reaction with increasing temperature. Lattice strain is controlled by the difference in lattice contraction rates at the amorphous-crystalline interface, reducing the oxygen vacancy formation energy. Doping with low-valence metal ions further stabilizes the oxygen vacancy structure. Surface modifiers can regulate the particle surface properties to adapt to various solvent systems, facilitating the preparation of highly transparent composite functional materials.

The invention discloses a spodumene concentrate resourceful treatment method which comprises the following steps: carrying out wet treatment on spodumene acid clinker to prepare lithium-removed filter residues and leachate; carrying out neutralization treatment and desulfurization treatment on the leachate to obtain a lithium-containing purified solution, gypsum and iron oxide red, and carrying out lithium extraction treatment on the lithium-containing purified solution to obtain a lithium salt and mirabilite; the lithium-removed filter residues are treated through a process combining a beneficiation method and a chemical method, and water glass, nano kaolinite, ceramsite aggregate and tantalum-niobium concentrate are obtained. According to the method, whole-process slag-free production of the spodumene concentrate is achieved, and meanwhile the lithium-containing compound with the high purity and the high quality is obtained; and various valuable products can be obtained.

The invention relates to the technical field of cosmetics and transdermal drug delivery, in particular to a resveratrol-tocoxolam nano-micelle and application of the resveratrol-tocoxolam nano-micelle in preparation of antioxidant and skin whitening products. The preparation method comprises the following steps: adding resveratrol or a derivative thereof into a first organic solvent (the weight percentage is 0.1-2%), and heating and dissolving at a first temperature of 80-100 DEG C to obtain a first solution; adding tocoxolam into the first solution, mixing (the weight percentage is 0.5-20%), and heating and dissolving at a second temperature (80-100 DEG C) to obtain a second solution; adding the second solution into the deionized water at a first rate (1mL / min to 3mL / min), and stirring and dispersing at a third temperature (50 DEG C to 70 DEG C); the nano-micelle is high in stability, excellent in transdermal absorption performance and good in anti-light aging effect, and has good skin whitening and anti-oxidation effects.