The invention relates to a white organic light-emitting device of a diboron azaanthracene derivative and a preparation method of the white organic light-emitting device. The diboron azaanthracene derivative, namely BNAnti-OMe, is a diboron
nitrogen doped
anthracene micromolecular material, and the material has the characteristics of relatively
wide band gap, relatively strong blue
fluorescence emission, relatively high
triplet state energy level and the like. Double light-emitting
layers of the organic light-emitting device comprise an intrinsic blue
fluorescent light-emitting layer of BNAL-OMe, a red phosphorescent light-emitting layer of BNAL-OMe gradient doped Ir (MDQ) 2acac, a transparent conductive ITO glass substrate, a
hole injection layer HATCN and a
hole transport layer TAPC, wherein the transparent conductive ITO glass substrate, the
hole injection layer HATCN and the
hole transport layer TAPC are located on the left side of the intrinsic blue
fluorescent light-emitting layer of BNAL-OMe in sequence. And an n-type doped hole
barrier layer BCP: TmPyPb, an
electron transport layer TmPyPb, an
electron buffer layer LiF and a
metal back
electrode Al are sequentially arranged on the right side of the BNAL-OMe: Ir (MDQ) 2acac light-emitting layer. According to the double-
boron azaanthracene derivative light-emitting layer and the double-
boron azaanthracene derivative gradient doped red phosphorescent dye light-emitting layer,
white light emission is achieved through light color
complementation, and the color stability and the brightness of a
white light device can be effectively improved through the fluorescent / phosphorescent double-light-emitting-layer design of the double-
boron azaanthracene derivative light-emitting layer and the double-boron azaanthracene derivative gradient doped red phosphorescent dye light-emitting layer.