The invention discloses a coupling-based non-contact temperature measurement system, which comprises a controller, a drive circuit, a switch circuit, a resonant circuit, a temperature sensor and a signal detection circuit, wherein the drive circuit is connected with the controller, the switch circuit is connected with the drive circuit, the resonant circuit is connected with the switch circuit, the temperature sensor is coupled to the resonant circuit, and the signal detection circuit is connected with the resonant circuit and the controller. The temperature sensor is separated from other devices of the system, non-contact temperature measurement of an object is achieved by electromagnetic coupling, and the system with the simple circuits is low in cost, suitable for miniature design, andapplicable to a plurality of places. The invention further discloses a coupling-based non-contact temperature measurement method, which includes: transmitting temperature signals by electromagnetic coupling, calculating and analyzing according to the temperature signals, and accordingly achieving non-contact temperature measurement of the object. The method is applicable to reliable temperature measurement of inner core wires of a high-tension power cable.