The application belongs to the technical field of photoelectrochemical sensors, and particularly relates to a preparation method of a novel photoelectrochemical sensor for simultaneously detecting
micrometer and nanometer plastics based on a biosensing strategy, which comprises the following steps: S1, substrate cleaning: ITO conductive glass is sequentially placed in appropriate
acetone,
ethanol and deionized water for ultrasonic cleaning to remove contaminants such as
grease and dust on the surface of the substrate, and the substrate is blown dry after cleaning; S2, ITO / BiOI nanometer array prepared by electrodeposition: an
electrolyte containing Bi(NO3)3 and KI is prepared, and a BiOI nanometer array is prepared on the ITO conductive surface by using an electrodeposition method, the deposition
voltage is-0.1V to-0.3V (vs. Ag / AgCl), and the deposition time is 1-5 min; by constructing a two-dimensional inorganic / organic van der Waals Z-type
heterojunction (FeTCPP / BiOI), the separation of photoinduced
electron-hole pairs is effectively promoted, the visible light
absorption capacity is enhanced, the transient photoelectric value of ITO / BiOI / FeTCPP is 91.7 times and 7.4 times that of ITO / FeTCPP and ITO / BiOI respectively, and the
photoelectric conversion efficiency is significantly improved.