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228 results about "Laser-induced breakdown spectroscopy" patented technology

Laser-induced breakdown spectroscopy (LIBS) is a type of atomic emission spectroscopy which uses a highly energetic laser pulse as the excitation source. The laser is focused to form a plasma, which atomizes and excites samples. The formation of the plasma only begins when the focused laser achieves a certain threshold for optical breakdown, which generally depends on the environment and the target material. In principle, LIBS can analyze any matter regardless of its physical state, be it solid, liquid or gas. Because all elements emit light of characteristic frequencies when excited to sufficiently high temperatures, LIBS can (in principle) detect all elements, limited only by the power of the laser as well as the sensitivity and wavelength range of the spectrograph & detector. If the constituents of a material to be analyzed are known, LIBS may be used to evaluate the relative abundance of each constituent element, or to monitor the presence of impurities. In practice, detection limits are a function of a) the plasma excitation temperature, b) the light collection window, and c) the line strength of the viewed transition. LIBS makes use of optical emission spectrometry and is to this extent very similar to arc/spark emission spectroscopy.

Waste metal classification and identification method and system based on image identification

The invention relates to the technical field of industrial visual inspection, and particularly discloses a waste metal classification and recognition method and system based on image recognition, and the method comprises the steps: obtaining metal surface visual information through an image collection system, extracting multi-level depth features after preprocessing, and generating a preliminary classification result and confidence evaluation; when the confidence coefficient is insufficient, starting a multi-mode verification mechanism, acquiring element composition data by adopting a laser-induced breakdown spectroscopy technology, and acquiring surface topological characteristics by adopting a structured light three-dimensional scanning technology; matching the element data with a component database to generate a component verification result, and comparing the morphology features with a morphology database to generate a morphology verification result; and finally, three types of results are integrated based on a weighted fusion algorithm to generate a final classification decision, and a sorting mechanism is controlled to complete accurate sorting.
Owner:JIANGXI JIANGLING NON-FERROUS METAL DIE-CASTING CO LTD

LIBS spectrum noise reduction method, system and device based on adaptive threshold wavelet transform and storage medium

The invention relates to the technical field of laser spectrum detection, in particular to an LIBS (Laser-induced Breakdown Spectroscopy) spectrum noise reduction method, system and equipment based on adaptive threshold wavelet transform and a storage medium. Acquiring an original spectral signal of the laser-induced breakdown spectroscopy; performing five-layer multi-layer wavelet decomposition on the original spectral signal by adopting a db4 wavelet basis function to obtain a high-frequency coefficient and a low-frequency coefficient of each layer; calculating a noise intensity standard deviation based on the detail coefficient of the highest decomposition layer; dynamically determining the optimal value of the regulation factor through a double-layer optimization strategy combining a grid search method and a golden section iterative optimization method; constructing an adaptive threshold value based on the noise intensity standard deviation and the adjustment factor; carrying out threshold value processing on the high-frequency coefficient by adopting a self-adaptive threshold value; and performing wavelet reconstruction on the processed high-frequency coefficient and low-frequency coefficient, and outputting a denoised spectral signal. While the LIBS spectral signal-to-noise ratio is remarkably improved, the spectral feature form is completely reserved, and reliable technical support is provided for laser-induced breakdown spectroscopy detection in a complex industrial environment.
Owner:GUIZHOU POWER GRID CO LTD +1

Dovetail welding seam automatic grinding control method based on robot visual positioning

The invention discloses an automatic dovetail welding seam grinding control method based on robot visual positioning, and relates to the technical field of visual positioning. The method comprises the steps that after welding is completed, a dovetail welding seam image is collected and converted into a three-dimensional coordinate through a vision algorithm, and a three-dimensional point cloud is generated; smooth interpolation is performed on the three-dimensional point cloud through a B spline curve method to obtain a parameterized curve, and a control point set is optimized through a genetic algorithm to generate a global optimal polishing path; the polishing robot executes a task according to a path, a tail end sensor collects a real-time path and calculates a deviation value with a global path, and when the deviation value exceeds a preset threshold value, inverse kinematics is triggered to solve and correct the path; the hardness of the dovetail weld is measured through laser-induced breakdown spectroscopy, a comprehensive hardness value is obtained in combination with a matrix hardness database, meanwhile, a visual sensor collects the surface state, and polishing process parameters are dynamically adjusted according to the surface state; after the task is completed, the welding seam angle and flatness are detected. According to the method, the optimal path is generated through visual positioning, and automatic grinding of the dovetail welding seam is achieved.
Owner:QINGDAO SHENGHENG ELECTROMECHANICAL TECH CO LTD

Boiler combustion multi-objective collaborative optimization control method and system

The invention relates to the technical field of boiler combustion control, in particular to a boiler combustion multi-target collaborative optimization control method and system. The method comprises the following steps: firstly, acquiring coal quality parameters in real time through a laser-induced breakdown spectrum analyzer, carrying out qualitative and quantitative analysis on spectral data by utilizing a machine learning algorithm, constructing a boiler combustion digital twinborn model fusing a combustion mechanism model and a data driving model, and predicting combustion characteristics, NOx generation trends and coking risks under different blending schemes; and then, dynamically generating an optimization instruction combination according to a prediction result of the digital twinborn model, establishing a safety interlocking mechanism while executing the optimization instruction, and automatically switching to a manual control mode when detecting that the working condition fluctuates severely or the model prediction deviation exceeds a preset threshold value. According to the method, the problems of coal quality information lag and untimely combustion adjustment caused by traditional manual sampling are effectively solved, and the economical efficiency, the safety and the environmental protection property of boiler operation are improved.
Owner:HUANENG POWER INT ENERGY DEV CO LTD

Spectral feature and artificial intelligence fused grain heavy metal detection method and system

The invention relates to a data analysis technology, and discloses a spectral feature and artificial intelligence fused grain heavy metal detection method and system.The method comprises the steps that a near-infrared diffuse reflection spectrum, a laser-induced breakdown spectrum and a surface enhanced Raman spectrum of a grain sample are obtained, a matrix accumulation area thermodynamic diagram is constructed according to the near-infrared diffuse reflection spectrum, and the matrix accumulation area thermodynamic diagram is obtained; the method comprises the following steps: optimizing a laser-induced breakdown spectrum based on a thermodynamic diagram of a matrix accumulation area, carrying out dual-channel spatial-temporal feature extraction on a surface enhanced Raman spectrum and the optimized laser-induced breakdown spectrum to obtain a fusion feature vector, carrying out weighted fusion optimization on the fusion feature vector based on a signal-to-noise ratio of multispectral data to obtain an optimized fusion feature vector, and finally obtaining a fusion feature vector. And carrying out migration adaptation on a pre-trained grain detection model by using a pre-marked new grain sample, and carrying out heavy metal content identification on the grain sample by using the adaptive grain detection model according to the optimized fusion feature vector to obtain a heavy metal detection result. The precision of grain heavy metal detection can be improved.
Owner:SHENZHEN SINO ASSESSMENT GRP

Probe type mineral multi-element laser-induced breakdown spectroscopy detection equipment

The invention provides probe type mineral multi-element laser-induced breakdown spectroscopy detection equipment. The equipment is characterized in that a sealed quartz optical window is mounted on the side surface of a probe box; the laser faces the sealed quartz optical window and emits laser pulses to the detected mineral; the convex surface of the quartz crescent focusing lens faces the laser, the concave surface of the quartz crescent focusing lens faces the sealed quartz optical window, and laser pulses are focused on the surface of detected mineral to generate plasma; the dichroscope is used for reflecting the plasma emission light to the double-lens group; the emitted light is converged through the double-lens group to form a plasma image with weakened chromatic aberration; the spectrograph is coupled with the plasma image through an optical fiber mechanism and records spectrums of different wavebands; therefore, after the focus point of the reflected light of the crescent focusing lens is pushed far to the laser, the optical element is prevented from being damaged; the imaging chromatic aberration of a plasma image is reduced by the double-lens group; the optical fiber mechanism balances spectral intensities of different wavebands and suppresses a continuous spectrum through spatial resolution.
Owner:ALUMINUM CORP OF CHINA LTD +2

Molten steel element content on-line detection system based on laser-induced breakdown spectroscopy technology

The invention discloses a molten steel element content on-line detection system based on a laser-induced breakdown spectroscopy technology, and relates to the technical field of molten steel element content on-line detection, the molten steel element content on-line detection system comprises an excitation system, an acquisition system, a data preprocessing module and a component detection module; the excitation system is used for emitting laser to the molten steel surface to generate plasma; the acquisition system is used for collecting signal light radiated by the plasma; the data preprocessing module is used for carrying out baseline correction and noise reduction processing on the collected original spectral signals; and the component detection module comprises an element content prediction model based on a gating specific expert attention network LSEA-Net and is used for carrying out quantitative analysis on the preprocessed spectral data to obtain the element content of the molten steel. The technology has the advantages that sample preparation is not needed, online rapid analysis and multi-element synchronous detection are achieved, and the technology is suitable for the high-temperature environment and the like, and the requirement of a steelmaking site for real-time component detection is met very well.
Owner:Liupanshan Laboratory

Self-adaptive window width symmetric zero area transformation LIBS peak searching method, system and device

The invention discloses an LIBS (Laser-induced Breakdown Spectroscopy) peak searching method, system and device for adaptive window width symmetric zero area transformation, and belongs to the technical field of laser-induced breakdown spectroscopy element analysis. According to the method, firstly, a spectrum base is deducted through an SNIP method, Savitzky-Golay filtering preprocessing is carried out, then data segments are segmented, the window width is dynamically adjusted by combining the peak resolution, the full width at half peak and the horizontal distance at the maximum slope value, the resolution is improved by using a narrow window in an adjacent peak region, the noise reduction effect is enhanced by using a wide window in a noise or single peak region, and finally symmetric zero area transformation is substituted to complete peak searching. Experiments show that the peak searching accuracy rate of the method reaches 97.4%, the false drop rate is 1.75%, the error compared with an NIST database is smaller than or equal to 0.071 nm, the noise robustness is superior to that of a traditional method, adjacent peaks can be accurately recognized, noise interference can be restrained, and the method is suitable for high-precision LIBS element analysis.
Owner:CHANGCHUN UNIV OF TECH

Spectral analysis monitoring method for aluminum alloy component detection

The invention relates to the technical field of metal materials, and discloses a spectral analysis monitoring method for aluminum alloy component detection, and the method comprises the following steps: carrying out standardized surface pretreatment on an aluminum alloy sample; collecting spectral data of the sample by adopting a laser-induced breakdown spectroscopy technology; performing noise filtering and background correction on the spectral data through a wavelet transform algorithm; establishing a spectral feature database for element qualitative identification; carrying out element quantitative analysis by adopting an internal standard method, and calculating the content of each element through a calibration curve; comparing a detection result with a standard mark component range to generate component conformity evaluation; performing deviation analysis and performance prediction on samples which do not meet the standard; and finally, generating a quality grading report based on the multi-dimensional evaluation indexes. According to the method, the accuracy of component qualitative identification is ensured, the detection error is reduced, the repeatability and efficiency of detection are improved, and the effectiveness of risk management and control and the overall reliability of a detection result are improved.
Owner:SHAANXI CHUNCHEN BOFA ALUMINUM TECH CO LTD

High-speed laser-induced breakdown spectroscopy imaging device and method

The invention provides a high-speed laser-induced breakdown spectral imaging device and method. The high-speed laser-induced breakdown spectral imaging device comprises an optical fiber laser, a marking table, a high-speed scanning galvanometer, a flat-field scanning lens, a dichroic spectroscope, a laser isolation head, a focusing lens, a high-speed spectrograph, a delay pulse generator, an electronic control card and a computer. The electronic control card is connected with the computer, the fiber laser, the high-speed scanning galvanometer and the delay pulse generator; the delay pulse generator is connected with the high-speed spectrometer; the high-speed spectrometer is connected with the computer; geometric centers of the high-speed scanning galvanometer, the dichroic spectroscope and the laser isolation head and a straight line where laser is located are on the same straight line; and a flat field scanning lens is arranged below the high-speed scanning galvanometer. By applying the technical scheme, the task of single-point laser emission sampling exceeding 10000 Hz and dot matrix data acquisition exceeding 2000 Hz can be completed.
Owner:XIAMEN MEDICAL COLLEGE

Waste metal fine sorting system and method using robot and laser-induced breakdown spectroscopy

The invention discloses a waste metal fine sorting system and method based on laser-induced breakdown spectroscopy (LIBS). The system comprises a conveyor belt transportation module, a structured light visual identification module, a robot sorting module, an LIBS (laser-induced breakdown spectroscopy) detection module and a system control module. The structured light three-dimensional vision sensor is arranged in the mode that hands are outside eyes, scrap metal is conveyed into the visual field of the structured light three-dimensional vision sensor through a conveying belt, primary shooting is carried out, the position and posture of the scrap metal are recognized, and after the robot grabs the scrap metal and adjusts the posture, secondary shooting is carried out, and the optimal detection point of the scrap metal is calculated. And the pose of the scrap metal is adjusted so that the optimal detection point can coincide with the laser focus position, LIBS detection is conducted, and the scrap metal is put into a corresponding metal collecting box according to the detection result. The system can adapt to scrap metals with different sizes and forms, accurately extract a detection area, stably obtain a high-quality spectrum, and realize efficient and accurate scrap metal mark classification.
Owner:NANJING UNIV OF AERONAUTICS & ASTRONAUTICS

Deep sea in-situ multispectral detection system and use method thereof

The invention provides a deep-sea in-situ multispectral detection system. The deep-sea in-situ multispectral detection system comprises a pressure-resistant cabin, a spectrum acquisition and analysis module, a laser emission and excitation module, a laser path switching and signal regulation and control module, a system control and power supply management module and a data communication and platform interface module, the pressure-resistant cabin body is composed of a main cabin body cylinder section, a front cabin cover, a rear cabin cover and annular reinforcing ribs evenly distributed outside the main cabin body cylinder section. The front cabin cover is provided with a main power supply control base, an external power supply control sealing base, a laser-induced breakdown spectroscopy detection window, a pressure-resistant optical cable cabin penetrating piece and a deflation valve; and various functional modules are arranged on a partition plate in the cabin body. According to the system, an in-situ multispectral detection system which has multispectral joint recognition capability, adapts to deep sea extreme environments and can carry various types of operation platforms is constructed, so that efficient, stable and full-chain in-situ recognition of complex objects such as deep sea fluid, sediment pore water and hydrates is realized, and the detection efficiency and the operation safety are improved.
Owner:崂山国家实验室

Rare earth element online detection device and method based on laser-induced breakdown spectroscopy

The invention relates to the technical field of material analysis, in particular to a rare earth element online detection device and method based on laser-induced breakdown spectroscopy. According to the invention, the laminar flow lining plate is arranged, and the to-be-detected liquid is conveyed to the laminar flow lining plate through the liquid conveying device, so that the laminar flow of the to-be-detected liquid is formed on the laminar flow lining plate. Then, an LIBS signal of the to-be-detected liquid laminar flow is collected through an LIBS signal collection device, and the to-be-detected liquid laminar flow can reduce laser energy consumed by solvent evaporation, so that the signal intensity is improved; and the to-be-detected liquid laminar flow can also reduce the fluctuation of the liquid level, so that the signal stability is improved. In addition, the acoustic signal of the liquid laminar flow to be detected is acquired through the acoustic signal acquisition device, and the LIBS signal and the acoustic signal are jointly analyzed, so that the accuracy of rare earth element detection can be improved.
Owner:EAST CHINA JIAOTONG UNIVERSITY

Micron-sized single particle quantitative analysis method and system based on silver nanoparticle signal enhancement

The application discloses a kind of microscale single particle quantitative analysis method and system based on nano-silver signal enhancement, it is related to spectral analysis technical field, the method includes: using laser-induced breakdown spectroscopy system to the carbon black particle target sample is carried out spectral data acquisition, obtains target full spectrum data and is pretreated, and then obtains target spectral data matrix;Variable importance measurement algorithm and continuous projection algorithm are used to the variable in the target spectral data matrix is screened, and target variable is obtained;Target variable is input into carbon black particle metal content prediction model, and the content of metal element in carbon black particle target sample is obtained.The application can quickly and accurately determine the content of metal element in carbon black particle target sample.
Owner:NORTHWEST UNIV

Heat treatment process for spring processing and production

The invention discloses a heat treatment process for spring processing and production, and belongs to the technical field of metal material heat treatment, the heat treatment process for spring processing and production comprises the following steps: detecting element content through laser-induced breakdown spectroscopy, and dynamically adapting parameters such as quenching temperature by using a reinforcement learning algorithm; calculating the critical concentration of titanium carbide based on JMatPro, monitoring the component gradient of a cladding layer in real time, and adjusting the laser power, the powder feeding rate and the cladding path; acquiring temperature field and stress field data by using a sensor, and adjusting the magnetic field intensity, the pre-deformation amount and the flow velocity of a cooling medium; a metallographic image is analyzed through a convolutional neural network, subzero treatment is intelligently triggered, and tempering parameters are optimized; and according to the surface roughness, parameters are reversely corrected, and self-optimization is carried out through the block chain. Intelligent and accurate regulation and control of the whole process of component detection, process control and quality detection are achieved, the mechanical property and production efficiency of the spring are improved, and the method has the advantages of dynamic adaptation, real-time monitoring, multi-field coupling control, data closed-loop optimization and the like.
Owner:TAICANG HUIDELI SPRING

Laser-induced breakdown spectroscopy (LIBS) enabled field equipment

A soil analysis apparatus may comprise a vehicle, at least one control-logic processor, a sensor housing, and a Laser-induced Breakdown Spectroscopy (LIBS) sensor. The LIBS sensor may be contained, at least in part, in the sensor housing. The vehicle may be configured to traverse an agricultural field. The LIBS sensor may be in connection to the vehicle and in communication with the control-logic processor. The LIBS sensor may comprise a laser source, a spectrometer, and at least one light collecting element. The laser source and / or the spectrometer may be in non-contacting proximity with the soil. The LIBS sensor may be configured to traverse a surface of the agricultural field via the connection to the vehicle. The LIBS sensor may be configured to conduct in situ soil analysis of the agricultural field during the traverse of the surface of the agricultural field.
Owner:PRECISION PLANTING LLC

Quantitative analysis method and system for rare earth elements of geological rock based on laser-induced breakdown spectroscopy

The invention discloses a geological rock rare earth element quantitative analysis method and system based on laser-induced breakdown spectroscopy, and belongs to the technical field of element spectral analysis, and the geological rock rare earth element quantitative analysis method comprises the following steps: constructing a dual-acquisition system to obtain a spectral signal and a plasma image of a rock sample, and preprocessing the spectral signal and the plasma image; determining rock lithology through a classification model, calculating plasma temperature based on the spectral signal, calculating brightness based on the plasma image, and correcting the plasma temperature; and constructing a multi-category bimodal quantitative analysis model, and inputting the lithology, the corrected temperature and the preprocessed image to complete quantitative analysis. The system comprises a data acquisition subsystem and a quantitative analysis subsystem, and data acquisition time sequence consistency and analysis reliability are guaranteed. According to the method, a bimodal data architecture is adopted, temperature correction and an advanced feature fusion network are combined, the limitation of single spectral data is broken through, the analysis precision and stability are improved, and popularization and application in geological exploration scenes are facilitated.
Owner:JILIN UNIVERSITY

Underwater intelligent detection machine system and method based on laser-induced breakdown spectroscopy

The invention relates to the technical field of spectral analysis, and particularly discloses an underwater intelligent detection machine system and method based on laser-induced breakdown spectroscopy, and the system comprises an underwater carrying platform, an orthogonal double-pulse laser-induced breakdown spectroscopy probe, a multi-sensor cooperative sensing module, a mechanical arm, a central control unit and a water surface control station. The method comprises the following steps: a first pulse vertically builds bubbles, and a second pulse parallelly enters the bubbles and is triggered according to delay time; the central control unit maintains a working distance of 1-2cm based on a distance measurement closed loop, and adaptively adjusts delay time and energy in combination with water depth pressure and cavitation feedback; and the water surface control station carries out denoising normalization on the spectrum calibration and carries out element qualitative and quantitative operation to generate an element distribution atlas. According to the method, plasma is excited in a cavitation bubble gas environment through orthogonal double pulses, and in-situ real-time high-sensitivity element detection of an underwater target is realized in combination with distance closed loop and parameter self-adaption.
Owner:YANTAI VOCATIONAL COLLEGE

A residual learning lightweight convolutional neural network quantification method for LIBS

The application discloses a residual learning lightweight convolutional neural network quantitative method for LIBS. The method comprises the following steps: collecting laser-induced breakdown spectroscopy (LIBS) original spectrum data of training samples; performing spectrum selection on each original spectrum and taking the mean value of the selected spectrum; establishing and training a residual learning lightweight convolutional neural network model by using the selected original spectrum; and performing quantitative analysis on test samples by using the trained residual learning lightweight convolutional neural network model. The application performs quantitative analysis of LIBS by using the residual learning convolutional neural network model. The residual module in the model improves the signal-to-noise ratio and retains the details of the spectrum signal, combines data preprocessing and quantitative analysis organically, and makes the preprocessing more targeted. Attention is concentrated on different effective information to different degrees, and feature selection is completed. The expression ability of the complex nonlinear relationship of the model is improved, and the precision of the LIBS quantitative analysis is improved.
Owner:SHENYANG INST OF AUTOMATION - CHINESE ACAD OF SCI

Miniaturized laser differential confocal Raman-LIBS microscopic imaging method and device

The invention discloses a miniaturized laser differential confocal Raman-LIBS (laser-induced breakdown spectroscopy) microscopic imaging method and device, and belongs to the technical field of microscopic spectral imaging. The device comprises a double-laser light source system for generating excitation light beams, an optical filter for separating spectral signals, a double-two-dimensional galvanometer light beam scanning system, a microscope objective, an axial scanning system, a differential confocal microscopic detection system, a mixed spectrum detection system and a computer control and display system. A double-two-dimensional micromirror scanning technology and a differential confocal microscopy technology are combined to carry out three-dimensional scanning on a sample, so that high-spatial-resolution detection of the geometrical morphology of the sample is realized; a same-light-path continuous laser and a pulse laser are respectively used as excitation light sources of Raman spectrum and laser-induced breakdown spectrum, and detection is carried out at a focal point on the surface of a sample, so that high-precision spectral information detection on the surface of the sample is realized. The sensor has the advantages of high sensitivity, multiple information, miniaturization, simple structure, wide applicability and the like, and is particularly suitable for the fields of environmental science, biomedicine, geological exploration and the like.
Owner:BEIJING INST OF TECH

Method for improving quantitative accuracy of LIBS (laser-induced breakdown spectroscopy) based on double-standard-sample multi-spectral-line correction

The invention discloses a double-standard-sample multi-spectral-line correction LIBS quantitative accuracy improving method. The method comprises the following steps: acquiring LIBS spectral data of a to-be-detected sample and two standard samples; acquiring multiple pieces of characteristic spectral line data of to-be-detected elements of the to-be-detected sample and the two standard samples from the LIBS spectral data; calculating a spectral line intensity correction factor of the second standard sample according to the characteristic spectral line data; calculating the characteristic spectral line theoretical intensity of the to-be-detected sample according to the spectral line intensity correction factor of the second standard sample; establishing a correction curve according to the actual spectral line intensity of the first standard sample and the theoretical intensity of the characteristic spectral line of the to-be-detected sample; and calculating the to-be-detected element content of the to-be-detected sample according to the correction curve. By adopting a double-standard-sample multi-spectral-line correction algorithm, the accuracy of quantitative analysis of a single-point multi-spectral-line correction method can be remarkably improved, and meanwhile, the defect that the calculation process of a calibration-free laser-induced breakdown spectroscopy algorithm is tedious is overcome.
Owner:NORTHWESTERN POLYTECHNICAL UNIV

Backpack type laser-induced breakdown spectroscopy analysis system

The invention relates to the technical field of spectral analysis, in particular to a knapsack type laser-induced breakdown spectroscopy analysis system which comprises a laser, an optical control system, a probe, a spectrometer, an industrial personal computer, a sample to be detected and a knapsack, and the laser, the spectrometer and the industrial personal computer are all arranged in a main bin of the knapsack. The industrial personal computer is electrically connected with the laser, the optical control system and the spectrograph, one side of the backpack main bin is connected with a handheld probe, and the optical control system is arranged in the probe; laser emitted by the laser enters the optical control system to be focused, the focused laser is output from the probe and is used for burning a to-be-detected sample, plasma radiation generated by the to-be-detected sample is received by the probe and is transmitted to the spectrograph, and the spectrograph is used for completing spectrum detection and transmitting a detection result to the industrial personal computer; and the industrial personal computer performs qualitative and quantitative analysis on elements contained in the to-be-detected sample according to the detection result. The invention provides a portable spectral analysis system.
Owner:CHANGZHOU COLLEGE OF INFORMATION TECHNOLOGY

Method and device for correcting rotating matrix effect of surface enhanced laser-induced breakdown spectroscopy technology

PendingCN121783952ASimple sample preparationImprove the accuracy of quantitative analysisPreparing sample for investigationAnalysis by thermal excitationLaser-induced breakdown spectroscopyParticle physics
The invention belongs to the technical field of spectral analysis, and discloses a method and a device for correcting a rotating matrix effect of a surface-enhanced laser-induced breakdown spectroscopy technology. The method comprises the following steps: 1, preparing a sample by a standard addition method; step 2, performing Youden calibration and sample preparation; step 3, performing SENLIBS sample preparation and spectrum acquisition; respectively carrying out SENLIBS sample preparation and spectrum collection on the sample solutions obtained in the step 1 and the step 2 to obtain corresponding absolute spectrum intensities of the two layers to be analyzed; step 4, establishing a calibration curve of the SENLIBS technology assisted by the standard addition method; step 5, obtaining a constant error through Youden calibration; step 6, constant error correction is carried out; and calculating the element concentration in the corrected solution to be detected. According to the invention, the constant error introduced by converting the carrier from a liquid phase to a metal carrier can be corrected, and the quantitative analysis accuracy of the SENLIBS technology is improved.
Owner:ANHUI CONCH GRP +2

Sample surface automatic control device and method for component detection

The invention belongs to the technical field of spectral analysis, and particularly relates to an automatic sample surface control device and method for component detection. The device comprises a mounting cylinder, an electrode fixing plate, a pressing block, an electrode assembly, a spring probe, a probe fixing piece, a control system, a lifting module and a container, a light outlet is formed in the bottom of the mounting cylinder, the electrode fixing plate is mounted at the light outlet of the mounting cylinder through the pressing block, and the electrode assembly is fixed to the electrode fixing plate; the spring probe is mounted in the mounting cylinder through a probe fixing piece, the spring probe is matched with the electrode assembly and connected with the control system through a wire, the control system is electrically connected with the lifting module, and the lifting module drives the container to ascend and descend, so that the relative positions of the sample, the electrode assembly and the laser focus are adjusted. The position of the sample in the vertical direction is adjusted in real time through a closed-loop feedback mechanism, the detection deviation of the samples with different heights is accurately compensated, and the focusing light spot of the laser-induced breakdown spectroscopy always stably acts on a target area.
Owner:SHENYANG INST OF AUTOMATION - CHINESE ACAD OF SCI

Shell molding material performance on-line quantitative evaluation system and method based on wax mold surface modification

The application discloses a shell slurry performance online quantitative evaluation system and method based on wax mold surface modification, and the system comprises a multi-state wetting wax mold preparation module, an automatic coating and multi-parameter rheological observation module and a precise wax residue analysis module which are sequentially connected and cooperatively work; the multi-state wetting wax mold preparation module selectively manufactures patterned areas with different hydrophilic and hydrophobic characteristics including hydrophilic, hydrophobic and super-hydrophobic on the surface of a standard test wax mold by controlling ultraviolet laser processing parameters; the automatic coating and multi-parameter rheological observation module is used for automatically completing slurry coating and quantifying the leveling behavior of the slurry based on machine vision; the precise wax residue analysis module adopts laser-induced breakdown spectroscopy technology and is used for quantitatively detecting the wax residue on the inner surface of the shell after dewaxing. The application also discloses an online quantitative evaluation method, which can provide direct and reliable data support for optimizing the slurry formula and the shell preparation process, thereby realizing automatic, high-precision and low-cost online quality control and reducing the casting scrap rate from the source.
Owner:XI AN JIAOTONG UNIV +1

Angle-adjustable laser-induced breakdown spectroscopy acquisition device

The utility model discloses an angle-adjustable laser-induced breakdown spectrum acquisition device which comprises an objective table, a support frame, an acquisition lens, an ablation angle adjusting assembly, an acquisition distance adjusting assembly and an acquisition angle adjusting assembly, the ablation angle adjusting assembly comprises a first rotary driving part arranged on one side of the supporting frame, and an output shaft of the first rotary driving part is fixed to the side wall of the objective table; the acquisition distance adjusting assembly comprises a linear moving mechanism arranged right above the objective table, and the moving end of the linear moving mechanism is connected with the acquisition lens; the acquisition angle adjusting assembly comprises a second rotary driving part and a connecting frame; in the laser paint removal spectrum monitoring process, spectrum characteristic signals can be obtained when the laser ablation angle, the collection angle and the collection distance serve as single variables, when any one of the spectrum collection angle, the ablation angle and the spectrum collection distance serves as a single factor variable, the other two are kept unchanged, and the spectrum characteristic signals are obtained. Therefore, the influence on the real value of the spectral characteristic signal is reduced.
Owner:CIVIL AVIATION FLIGHT UNIV OF CHINA

A device and method for detecting the purity of a copper alloy melt in a vacuum environment

The application discloses a kind of detection device and method of copper alloy melt purity under vacuum environment, belong to copper alloy purity detection technical field.Detection device includes vacuum smelting cavity module, laser-induced breakdown spectroscopy detection module, temperature monitoring module, central data processing and control module and man-machine interactive display module.Detection method includes system initialization, laser-induced breakdown spectroscopy multi-pulse acquisition, spectrum adaptive baseline compensation, inclusion distribution uniformity quantification and purity comprehensive evaluation.Through segmented polynomial iterative threshold truncation algorithm, adaptive eliminate blackbody radiation and plasma continuous radiation superposition in vacuum high-temperature environment and form complex nonlinear baseline drift;Inclusion distribution uniformity index and concentration purity sub-index are weighted and fused, realize the comprehensive quantitative characterization of melt purity concentration dimension and uniformity dimension, and realize the real-time online quality determination of refining process by comparing with qualified threshold.
Owner:SHENYANG YIFAN METAL MATERIAL CO LTD

Method and device for obtaining local gas temperature and equivalence ratio of a combustion field

PendingCN122651681AHydrogenHydrogen atom
The application discloses a method and device for obtaining local gas temperature and equivalence ratio of a combustion field. Laser-induced breakdown spectroscopy technology is used to form a target plasma by laser-induced breakdown of a flame to be measured. Firstly, reference signals of the target plasma are collected to obtain a reference signal set, and current hydrogen atomic spectral line broadening and current plasma temperature of the target plasma are calculated. Then, the reference signals are input into a gas temperature characterization model to obtain a local gas temperature. The reference signals and spectral line intensities are input into a spectral line intensity correction model to obtain a corrected spectral line intensity set. Finally, the corrected spectral line intensity set, the current plasma temperature and the current hydrogen atomic spectral line broadening are input into an equivalence ratio measurement model to obtain the equivalence ratio of the flame to be measured. Through step-by-step correction of spectral intensity, the application can avoid the influence of temperature on equivalence ratio measurement, improve the accuracy of equivalence ratio measurement, and realize local gas temperature measurement.
Owner:TSINGHUA UNIVERSITY +1

Conveyor belt ore quality real-time online analysis method based on flight time three-dimensional camera and laser-induced breakdown spectroscopy technology

The invention relates to the technical field of ore quality analysis, in particular to a conveyor belt ore quality real-time online analysis method based on a flight time three-dimensional camera and a laser-induced breakdown spectroscopy technology. According to the method, the three-dimensional camera is used for shooting the surface of the ore on the conveying belt, the point cloud coordinates of a target detection point are accurately obtained, and the core problem that three-dimensional positioning of a traditional LIBS technology is low in efficiency is solved; according to the method, point cloud coordinates are mapped into laser coordinates through coordinate conversion, dynamic tracking and accurate excitation of laser on a target detection point are achieved, a full-process closed loop of positioning, excitation, analysis and prediction is formed in cooperation with a spectral analysis and quality prediction model, and the real-time performance and accuracy of ore component detection are remarkably improved.
Owner:HEFEI INSTITUTE OF PHYSICAL SCIENCE CHINESE ACADEMY OF SCIENCES +1

LIBS Quantitative Analysis Method Combining Wavelet Transform and Lightweight Convolutional Neural Networks

This invention relates to the field of spectral analysis, specifically a quantitative analysis method for LIBS combining wavelet transform and lightweight convolutional neural networks. The specific steps are as follows: (1) Spectral acquisition. Spectral data is acquired based on laser-induced breakdown spectroscopy (LIBS) technology; (2) Data set partitioning. The data is divided into training, validation, and test sets; (3) One-dimensional LIBS spectra are transformed into two-dimensional image representations using wavelet transform; (4) The images are downsampled; (5) The image data obtained in step (4) is modeled using a lightweight convolutional neural network (L-CNN), and model parameters are determined based on the evaluation metrics of the validation set; (6) A regression model is re-established using the training set under optimized model parameters; (7) The generalization performance of the model is verified using test set data; (8) The elemental concentrations of unknown samples are estimated using the established regression model. The proposed quantitative analysis method for LIBS combining wavelet transform and lightweight convolutional neural networks can be practically applied to on-site monitoring of slurry grade in mineral processing plants.
Owner:SHENYANG INST OF AUTOMATION - CHINESE ACAD OF SCI