The invention is applicable to the field of
optical fiber sensors and the field of in-situ detection of
ion batteries, and provides an in-situ detection method for an SPR type
optical fiber ion battery based on MXene modification, which comprises the following steps: placing a micro-nano
optical fiber sensor in the
ion battery and fully contacting the micro-nano optical
fiber sensor with
electrolyte; when the battery works, the ion concentration change rule is mapped through the
wavelength response distance of the
reflection spectrum of the micro-nano optical
fiber sensor so as to realize battery health state detection; the micro-nano optical
fiber sensor is a high-sensitivity
optical fiber sensing device based on an MXene composite gold
nanoparticle (AuNPs) modified micro-nano optical fiber accompanying excitation surface
plasma resonance (SPR) absorption peak phenomenon, MXene serves as an important candidate material of a new-generation
energy storage and electrochemical device, and has stable electrochemical characteristics of electric conduction,
energy storage,
catalysis and the like; according to the invention, long-term
structural stability can be maintained in a
battery electrolyte environment, AuNPs can be firmly compounded on the basis of characteristics of rich functional groups on the surface, a multilayer structure and the like, and an SPR effect is excited on the surface of the micro-nano optical fiber, so that the detection sensitivity and the
cycling stability of the sensor under long-term working of a battery are remarkably improved. According to the embodiment provided by the invention, high-sensitivity detection of the ion concentration in the battery can be realized, and the prepared sensor can be used for health state evaluation of
energy storage batteries such as a
lithium ion battery and a
sodium ion battery.