The present disclosure provides a process for synthesis of
metal sulfide semiconductor nanocrystals. The process includes mixing a
metal precursor solution with a
sulfur precursor solution at a temperature of no more than 200 °C to form a reaction solution. The
metal precursor solution includes a metal compound dissolved in a
solvent, and the
sulfur precursor solution includes a
sulfur compound dissolved in a
solvent. The metal is present at a concentration of no more than about 1.2 mmol / mL, and the metal and sulfur are present at a S : M
molar ratio of at least 1.5 : 1. The metal is lead (Pb),
zinc (Zn) or
cadmium (Cd). The sulfur compound is a volatile sulfur compound having a
boiling point of up to 100°C and / or a low molecular weight sulfur compound having a molecular weight of up to 500 g / mol. Also disclosed are
semiconductor nanocrystals made according to the process, a
quantum dot
solar cell incorporating the
semiconductor nanocrystals, use of the
semiconductor nanocrystals in a
solar cell, and a method of preparing a
quantum dot
solar cell. Figure 1 to be published with the Abstract.