202 results about "Surface plasmon resonance" patented technology

The invention relates to a cardiovascular disease risk prediction system, which comprises a user terminal module, an edge computing module, a cloud intelligent module, an application service module and a system support module, wherein the user terminal module comprises an intelligent sensing equipment cluster unit and a mobile terminal data entry unit; and the intelligent sensing equipment cluster unit adopts a millimeter wave radar-PPG fusion sensor, monitors subcutaneous 0.5 mm depth arterial vibration through a 60GHz radar array, is aligned with a photoplethysmogram signal in a space-time manner, and performs user data acquisition based on a surface plasma resonance chip. According to the cardiovascular disease risk prediction method and system, real-time signal processing is realized by adopting JetsonAGX through a heterogeneous calculation architecture, medical image accelerated calculation is performed by using NVIDIAClara, non-out-of-domain joint modeling of data of hospitals is supported through federal learning, privacy protection reasoning based on homomorphic encryption is realized, and full-process closed-loop management is realized by adopting a layered modular architecture. And the accuracy of cardiovascular disease risk prediction is improved.

The invention discloses a peanut oil impurity detection method based on image recognition analysis, and relates to the technical field of computer vision, and the peanut oil impurity detection method comprises the following steps: carrying out impurity targeted marking on an oil sample; adopting dual-wavelength laser to excite the oil sample subjected to impurity target marking, synchronously acquiring a fluorescence image, and marking the coordinates of a suspicious composite impurity region by utilizing an FRET fluorescence intensity ratio; metal impurities and fiber impurities are distinguished according to the plasma formant position, and nanoscale impurity morphology data are formed; detecting unmarked transparent nanoparticles, triggering surface acoustic wave assisted detection, and outputting impurity motion feature codes; inputting the FRET fluorescence intensity ratio, the nanoscale impurity morphology data and the impurity motion trail features into a graph neural network classifier based on an attention mechanism, and performing joint interpretation on impurity types; and sorting and filling the oil sample according to an impurity classification result. The comprehensive performance of impurity detection is remarkably improved through a multi-mode sensing cooperation mechanism.

The invention provides a titanium nitride doped fluoride-free photo-thermal super-hydrophobic coating and a preparation method and application thereof.The titanium nitride doped fluoride-free photo-thermal super-hydrophobic coating is prepared from polydimethylsiloxane modified titanium nitride, hydrophobic nanoparticles and an adhesive and has the excellent local surface plasma resonance effect and photo-thermal effect; meanwhile, the coating is of a rough and uniform micro-nano hierarchical structure, dynamic water can be efficiently removed, icing can be delayed, the surface temperature can reach 12 DEG C only through irradiation of one sunlight intensity in the environment of-30 DEG C, and rapid deicing can be achieved. The coating has good functions of self-cleaning, anti-icing, deicing, defrosting and the like, renewable solar energy is utilized, and the coating is green, environment-friendly, energy-saving and emission-reducing. Meanwhile, the super-hydrophobic surface of the coating can effectively delay icing and inhibit ice adhesion. According to the coating, organic combination of an active deicing strategy and a passive deicing strategy is achieved based on the synergistic effect of the super-hydrophobicity and the photothermal effect.

The invention provides a micro-nano optical fiber probe for biochemical component detection based on infrared spectroscopy and detection equipment, and a preparation method of the micro-nano optical fiber probe comprises the following steps: S1, selecting one section of a multimode quartz optical fiber as a sensing area, and then removing a cladding layer and a coating layer of the sensing area to expose a bare fiber; s2, dripping a mixed acid solution prepared from hydrofluoric acid and citric acid to the bare fiber to corrode the bare fiber, and then cleaning and blow-drying; immersing the treated multimode quartz optical fiber into a silane coupling agent solution, reacting for 0.5-1 hour, and then drying; s3, immersing the multimode quartz optical fiber treated in the step S2 into a solution containing silver nanoparticles, and reacting for 10-20 minutes to obtain an optical fiber modified by the silver nanoparticles; and S4, sputtering a gold layer on the surface of the silver-modified optical fiber by adopting a vacuum magnetron sputtering technology to obtain the micro-nano optical fiber probe with the silver-gold film layer. After the surface of the silver nanostructure is covered with the gold film, oxygen, water, corrosive molecules and the like are effectively prevented from making direct contact with silver. In addition, both the gold and the silver can support a surface plasmon resonance (SPR) effect, and particularly, the prepared detection equipment can ensure the sensitivity of the SPR.

The invention relates to the technical field of optical metasurface and light field regulation and control, in particular to a light pressure multi-dimensional regulation and control method and device based on a metasurface microstructure array. The method comprises the following steps: designing and preparing a metasurface microstructure array, wherein the microstructure array is composed of a plurality of sub-wavelength scale three-dimensional microstructure units arranged on a dielectric substrate; surface plasmon resonance is excited by adjusting structural parameters of the three-dimensional microstructure units and adjusting working parameters of a light source acting on the microstructure array, and near-field localization and enhancement are achieved. And calculating, regulating and controlling the light pressure borne by the metasurface microstructure array based on the Maxwell stress tensor. The method can keep a remarkable light pressure enhancing effect in a wide spectrum range of 380-1300 nm, and is suitable for various material systems such as silver, gold and the like. The method can be applied to the fields of optical tweezers systems, optical control devices, precision measurement and the like, and has the advantages of flexible design, simplicity and convenience in preparation, high regulation and control precision and the like.

The invention provides a Cu2O-based heterogeneous composite material as well as a preparation method and application thereof. The preparation method comprises the following steps: coating the surface of a Cu2O hollow sphere substrate with a carbon layer, and depositing layered double hydroxides (LDHs) and metal palladium (Pd) nanoparticles on the carbon layer. According to the material, through a Cu2O-carbon layer-LDHs-Pd multistage heterostructure design, space optimization of light absorption, charge transfer and catalytic sites is realized; cu2O-carbon layer-LDHs interface coupling promotes directed migration of photo-induced electron-hole pairs, and the surface plasmon resonance effect of Pd nanoparticles enhances the charge separation efficiency; the LDHs optimizes a charge transfer path through surface oxygen vacancy or metal valence cycle, so that synergistic oxidation of non-free radicals and free radicals is realized, the organic matter degradation efficiency is remarkably improved, the oxidation path is widened, and the performance bottleneck of a single material is broken through.

The invention discloses an SPR (Surface Plasmon Resonance) image optimization processing method based on image segmentation and edge enhancement, which comprises the following steps: acquiring SPR image data, and preprocessing to generate standardized SPR image data; inputting a structure boundary extraction model constructed based on CGNet, generating a structure boundary label graph, and aligning the structure boundary label graph with the image; gradient amplitude and local entropy mutation detection is executed, and an artifact guide graph is generated; respectively inputting the standardized image into details and context branches of the improved CSDNet, and extracting edge and semantic feature maps; inputting a guide perception gating module, executing structure enhancement and artifact suppression fusion, and generating a fusion feature map; inputting into a multi-scale detail recovery module, and outputting an edge enhanced image; and executing structural similarity and marginal definition scoring based on the original image and the enhanced image, and generating an optimization result. According to the method, synchronous optimization of SPR image edge enhancement and structure maintenance is realized, and the image definition and diagnosis availability are remarkably improved.

The invention belongs to the technical field of surface enhanced Raman spectroscopy, and particularly relates to a high-activity surface enhanced Raman scattering substrate as well as a preparation method and application thereof. Comprising the following steps: by utilizing a three-phase liquid-liquid interface self-assembly method, adding dichloromethane into an AuNPs dispersion liquid, uniformly mixing, adding a halide salt solution, uniformly mixing to form a mixed solution, then adding normal hexane into the mixed solution, standing, performing interface self-assembly until a gold nano-film is formed on a liquid surface, fishing out the gold nano-film, and drying to obtain the gold nano-film. The high-activity surface enhanced Raman scattering substrate is obtained. According to the method, the halide salt solution is innovatively introduced in the self-assembly process of the AuNPs, so that the assembly arrangement mode of the AuNPs is remarkably changed, the AuNPs are arranged more tightly, local surface plasma resonance coupling is enhanced, more hot spot areas are generated in a unit area, and the sensitivity of the self-assembly nano array SERS substrate is effectively improved.

The invention provides a plasma resonance enhanced microstructure of an infrared photoelectric detector and a preparation method, and belongs to the technical field of medium-wave infrared photoelectric detectors, and the method comprises the steps: enabling incident light to irradiate downwards from the upper part of a top resonance layer when the medium-wave infrared photoelectric detector is used, and enabling the incident light to irradiate downwards from the lower part of the top resonance layer; the bottom resonance layer, the dielectric blocks and the top resonance layer form an array-arranged microstructure which can excite a plasmon mode, a surface plasmon resonance effect is triggered near the surface of the photosensitive layer through the combined action of the top resonance layer and the bottom resonance layer, the dielectric blocks are embedded in the bottom resonance layer, and the surface plasmon resonance effect is achieved. Incident light is localized in a shallower depth in a photosensitive surface, the intensity of a local electric field is enhanced, the reflection phenomenon of the photosensitive surface is reduced, the light absorption rate of the detector is improved, and the quantum efficiency of the medium-wave infrared photoelectric detector is further improved.

The invention relates to the field of photoelectrocatalytic materials, and discloses a photoelectrocatalytic material and a preparation method and application thereof.The photoelectrocatalytic material is formed by a bismuth molybdenum oxide and nickel-doped cobalt oxide heterostructure, the surface plasma resonance effect of gold nanoparticles and a conductive network of nitrogen-doped graphene and carbon quantum dots are combined, and a graded micro-nano structure is constructed; according to the present invention, the material has characteristics of high light current density, low charge transfer resistance and excellent catalytic activity and long-term stability in liquid-phase degradation and gas-phase oxidation through the built-in electric field and the optimization of the conductive network, such that the material has characteristics of high light current density and low charge transfer resistance, and can be used in liquid-phase degradation and gas-phase oxidation. The material is widely applicable to the fields of pollutant degradation, gas conversion, water photoelectrolysis and the like, and an efficient solution is provided for innovative development of a photocatalysis technology.

The invention discloses a preparation method of a flexible infrared super-surface absorber based on MDM, and belongs to the field of micro-nano machining patterning. The method comprises the following steps: pretreating a polymer material; depositing a layer of bottom metal film on the pretreated substrate by adopting magnetron sputtering; a metal reflecting layer, a dielectric insulating layer and a metal surface functional layer are sequentially deposited through magnetron sputtering, a periodic nano microstructure is constructed on the surface of a flexible composite film, a nano round pit array is etched in situ on a surface metal layer of an MDM structure by using a femtosecond laser selective etching process, and an MDM laminated structure is formed. According to the invention, stable integration of the MDM structure and the flexible substrate can be realized, and meanwhile, high absorptivity and good flexibility of the device in an infrared band are ensured. The absorber prepared by the invention can generate resonance absorption on incident infrared electromagnetic waves through a surface plasmon and F-P cavity resonance coupling mechanism, and meanwhile, the characteristic size variation is changed through physical excitation, so that effective absorption and frequency regulation of the electromagnetic waves at the infrared band of 3-14 microns are realized.

The invention relates to the technical field of semiconductor packaging, and discloses a bonding wire welding method based on bare chip interconnection, and the method comprises the steps: collecting and fusing acoustic response and optical reflection signals of a bonding interface in real time through a multi-mode in-situ sensing mechanism integrating acoustic resonance and surface plasmon resonance; dynamically calculating the thickness, the mechanical coupling deformation and the energy dissipation state of the intermetallic compound layer; and the ultrasonic power and the bonding force are subjected to closed-loop adjustment in combination with a model prediction control algorithm, so that the welding process is evolved along a preset optimal physical path all the time. The system comprises a multi-mode sensing welding head, a synchronous data acquisition module, a state resolving module and a self-adaptive control module. The transparent and intelligent welding process is realized, and the bonding consistency, reliability and yield of high-density interconnection are remarkably improved.

The invention provides a construction method and system of a non-reciprocal emission / absorption device with a Fizeau dragging effect. The construction method comprises the following steps: selecting a metal substrate, a dielectric grating and a two-dimensional material; applying a bias voltage in the x-axis direction to the two-dimensional material layer to generate a Fizeau dragging effect; the bias voltage is adjusted under TM polarization, so that the electron drift speed is close to the Fermi speed, asymmetric surface plasmon resonance is excited, and unequal emissivity and absorptivity are achieved; an adjustable singular point is generated in an angle-frequency space by adjusting the filling ratio of the grating, so that the numbers of spectral formants of emissivity and absorptivity near the singular point are different, and the wavelength integral nonreciprocity intensity is improved. The non-reciprocal heat radiation characteristic can be realized through voltage regulation and control without an external magnetic field.

The invention relates to the technical field of virus detection, in particular to a method for enhancing animal virus detection sensitivity through optical fiber SPR probe surface modification, which comprises the following steps: S1, optical fiber SPR probe surface pretreatment: obtaining a hydroxylated surface; s2, gradient nanostructure modification: forming a gradient aperture surface topological structure; s3, carboxyl functionalization: immersing the substrate into a 3-aminopropyltriethoxysilane / methacrylic acid mixed solution, and constructing a carboxyl activation layer on the surface; s4, fixation of the aptamer: realizing directional fixation of the aptamer through EDC / NHS mediated carboxyl-amino coupling reaction; s5, non-specific site closing: carrying out cross-linking closing on the non-binding sites by adopting a thioacetamide / polydopamine composite solution; s6, virus detection: acquiring the surface refractive index variation through a phase modulation type SPR detection system; according to the invention, accurate fitting and quantitative correction of virus concentration are realized, and the stability and accuracy of detection are improved.

The invention discloses a perovskite narrow-band photoelectric detector based on local plasma enhancement and a preparation method thereof, and the perovskite narrow-band photoelectric detector utilizes specially-made metal nanoparticles to accurately adjust a local surface plasma resonance band of the perovskite narrow-band photoelectric detector, thereby achieving the purpose of overlapping with a perovskite target narrow-band response range. Therefore, penetrating long-wavelength incident photons and an electromagnetic field around the metal nanoparticles generate strong coupling interaction, light absorption is effectively improved through a near-field enhancement induction excitation effect, light current is remarkably enhanced, a local surface plasmon resonance band is regulated and controlled, harmonious enhancement of a detection wave band is achieved, and the detection sensitivity is improved. And the detection performance regulation and control enhancement in the spectral response range of the photoelectric detector is further realized.

The invention discloses a tetrahydro-beta-carboline compound as well as a preparation method and application thereof. The tetrahydro-beta-carboline compound is shown as a formula P. The tetrahydro-beta-carboline compound has good RANKL inhibitory activity, the preparation method is simple, raw materials are easy to obtain, and the yield is high. The inhibition activity of the compound on generation of RANKL-induced osteoclasts is determined through a tartrate acid phosphatase (TRAP) staining experiment, it is determined through a surface plasmon resonance (SPR) that the compound has high combining capacity with RANKL protein, and the compound can be used for preparing drugs for preventing and / or treating diseases caused by abnormal osteoclast activity. # imgabs0 #

The invention relates to the technical field of solid crystal glue materials, in particular to a reflective solid crystal glue material based on a nanoparticle dispersion technology, a preparation process and application. The coating comprises a resin matrix, a nanometer functional filler and an auxiliary agent system, wherein the resin matrix at least comprises epoxy resin, cyanate ester resin and benzoxazine resin; the nano functional filler is one of a nano particle material or a nano filler; through the synergistic effect of the surface-modified zinc oxide nanoparticles and the surface-modified cerium oxide nanoparticles and in combination with the total reflection characteristic of the titanium dioxide coated glass beads, an efficient reflection-refraction synergistic enhancement system is constructed; the plasma resonance effect of the surface-modified cerium oxide nanoparticles is matched with the high-refractive-index zinc oxide nanoparticles, so that the initial luminous flux of an LED is improved by 18%-22% compared with that of traditional solid crystal glue, the light utilization rate is improved by 20%-25%, the six-surface luminous potential of a chip is excavated, and therefore the quality of the solid crystal glue is improved.

The invention discloses a surface plasmon resonance (SPR) hydrogen sensor based on an Ag / PDMS / Pt-WO3 multilayer structure. The SPR hydrogen sensor is characterized by comprising a halogen lamp light source, two sections of multimode optical fibers, a spectrometer and an SPR hydrogen sensing head, wherein the SPR hydrogen sensing head is composed of a different-core structure formed by multimode-single-mode-multimode optical fibers, a silver film, PDMS (polydimethylsiloxane) and Pt-WO3 (platinum-tungsten trioxide). The SPR hydrogen sensor based on the Ag / PDMS / Pt-WO3 multi-layer structure, which is simple to prepare, high in sensitivity and capable of being repeatedly used for a long time, is provided aiming at the defects that an existing optical fiber SPR hydrogen sensor is low in sensitivity and complex in device manufacturing, and PdH is changed from an alpha phase to a beta phase when Pd is used as a hydrogen sensitive material, so that the use of the device is influenced, and the like. When the hydrogen concentration is increased, the Pt-WO3 reacts with the hydrogen to generate heat, so that the refractive index of the PDMS film is changed, the SPR resonance spectrum is moved, and the hydrogen concentration is obtained by observing the offset of the PDMS film. The high refractive index sensitivity of SPR is brought into full play by utilizing the high refractive index change of PDMS, so that high-precision detection of hydrogen leakage is realized.

The application relates to a functionalized glass for SERS detection and a preparation method thereof, characterized by the following steps: a. tetraethyl orthosilicate and oxalic acid are mixed into a 0.02-0.10 moL / L sol in anhydrous ethanol according to a molar ratio of 1:2-5, a stabilizer with a volume of 5-50% is added, and then the mixture is stirred and transferred into a four-necked flask; b. after being heated and stirred for 12-16 hours, an anhydrous ethanol emulsion of polystyrene small balls with a mass fraction of 5-20% and a volume of 6-18% is added; c. an anhydrous ethanol solution of a surfactant P123 with a total mass of 2-8% and a weight concentration of 3-8% is added, and then the mixture is stirred and aged; d. a wet film is prepared on a glass substrate, and then the wet film is dried and kept warm; (2) a nano-silver particle dispersion liquid with a concentration of 5-25 mg / mL is prepared; and (3) the glass substrate prepared in the step d is coated with the nano-silver particle dispersion liquid and dried. The application has the advantages of simple process and low cost; the surface of the porous structure silica nano-particles has a large number of nanoscale gap structures, which is beneficial to obtaining an enhanced silver nano-particle surface plasmon resonance electromagnetic field, and greatly enhances the Raman signal of the adsorbed molecules.

The invention provides a surface plasma imaging method and a surface plasma imaging device, which are used for imaging surface plasma signals caused by interaction of biomolecules. More specifically, the invention provides a method and a device capable of imaging a surface plasmon resonance mode in a frequency domain through tiny change by comparing the light intensity in two sections of surface plasmon frequency domains.

The application discloses a kind of light field regulation detection method and device based on computing spectral reconstruction, belong to spectral analysis technical field.The method is by introducing medium-metal composite nanostructure, integrates metal nanoisland array and silicon nitride nanocolumn array on quartz substrate, realizes electric field enhancement using the local surface plasmon resonance effect excited by metal nanoisland array, simultaneously realizes wide spectral range phase coding by medium nanocolumn array;Super surface chip is integrated with single point detector, combines pre-calibrated super surface sensing matrix A and enhancement factor matrix E, and reconstructs spectrum using compressed sensing or Tikhonov regularization algorithm.The application keeps the advantages of miniaturization and no moving parts, realizes directional high sensitivity detection to weak signal, and signal-to-noise ratio is improved.

The application belongs to the technical field of biological medicine, and discloses a cyclic peptide molecule specifically targeting CD5 and purposes thereof. The surface receptor CD5 of immune cells (T cells, B cells) has been proved to be a potential tumor treatment target, the present application uses the phage display technology widely applied to the development of polypeptide or antibody drugs to carry out multiple rounds of in vitro screening on human CD5 protein, and obtains a cyclic peptide molecule with drug potential and capable of specifically combining with CD5 through second-generation sequencing. The cyclic peptide molecule contains two cysteines, is modified into a ring through a specific chemical crosslinking agent, and the affinity of the cyclic peptide molecule to CD5 is determined to be in the low micromolar level through surface plasmon resonance technology, thereby laying a foundation for the development of a CD5-targeting inhibitor.

The present invention belongs to the field of surface plasmon nanolasers, and particularly relates to a surface plasmon laser based on a pair of silver nanowires for a Fabry-Perot cavity. The laser includes a single-crystalline pair of silver nanowires, a gain medium, and a super-smooth metal film. An isolation layer is provided on the super-smooth metal film, the gain medium is disposed on the isolation layer, and the single-crystalline pair of silver nanowires are respectively disposed on both sides of the gain medium, so that the pair of silver nanowires and the super-smooth gold film form a surface plasmon resonance cavity of a composite structure, providing strong electric field confinement and directional scattering characteristics. The surface plasmon laser proposed by the present invention has a simple preparation process and is easy to operate. It can effectively convert pump light into surface plasmons and well confine them in the resonance cavity, realizing efficient excitation of the laser, obtaining an ultra-low excitation threshold, and being more suitable for micro-nano on-chip optical integration; by virtue of the scattering directivity of the surface plasmon resonance cavity, the problem of poor directivity of the plasmon laser can be improved. The present invention expands the application of surface plasmon lasers in the field of integrated optics.

The invention discloses an on-chip spectrum sensing structure, a pixel unit and a preparation method and application thereof. The on-chip spectrum sensing structure comprises a metal layer, a dielectric layer and a detector, nano-pore channels are formed in the metal layer and the dielectric layer, and the nano-pore channels extend into the dielectric layer from the surface of the metal layer; near-infrared light forms surface plasmon resonance at the interface of the metal layer and the dielectric layer in the nanopore channel, so that part of near-infrared light in a selected narrow wavelength range is transmitted to the detector, and a corresponding electric signal is formed. According to the on-chip spectrum sensing structure provided by the invention, near-infrared broadband calculation spectrum sensing with high spectral fidelity can be realized, radiation and ohmic loss are effectively inhibited by a nonlinear parameterized design framework, and high transmission efficiency is ensured; the multi-channel super-pixel system structure generated by the method realizes simultaneous point spectrum and snapshot hyperspectral imaging, and shows the potential of the compact platform for field deployment and chip spectrum sensing application.

The invention provides a preparation method and application of a doxycycline (DOX) molecularly imprinted surface plasmon resonance (SPR) sensing chip. According to the chip, an SPR bare gold chip is used as a substrate, DOX is used as a template molecule, a molecularly imprinted polymer (MIP) recognition membrane is constructed on the surface of the chip, and collaborative integration of the MIP technology and the SPR technology is achieved. According to the strategy, the chip is endowed with specific recognition capability on template molecules DOX, and local refractive index change caused by combination of the DOX and the recognition film can be detected in real time in an unmarked manner, so that the detection sensitivity and accuracy are remarkably improved. By utilizing an SPR (Surface Plasmon Resonance) analyzer, the chip can realize rapid quantitative detection of DOX in a low concentration range, shows good reproducibility, and can be applied to detection of actual samples.

The invention relates to the technical field of thin films, and discloses a colorful ITO conductive film with heat insulation performance and a preparation method thereof, the conductive film is characterized in that a functional lamination layer is arranged between two transparent conductive layers, and the functional lamination layer comprises a first composite functional layer, an optical isolation layer and a second composite functional layer from bottom to top. The first composite functional layer and the second composite functional layer are both composed of silver nanoparticles dispersed in a high-refractive-index dielectric matrix, and the silver nanoparticles in the two layers have different size distributions. According to the structure, a precursor film is co-deposited through a magnetron sputtering method, and then silver is self-assembled into nanoparticles through in-situ rapid thermal annealing. By arranging the double composite functional layers and utilizing surface plasmon resonance of two groups of silver nanoparticles with different sizes formed after annealing, broadband high-efficiency blocking of near infrared spectrum is realized, and meanwhile, the film is endowed with stable and non-iridescent color by resonance scattering of the nanoparticles; the film has the advantages of high visible light transmittance, low square resistance and excellent environmental stability.

The invention belongs to the technical field of aflatoxin detection, and relates to an aflatoxin detection method based on a surface plasma resonance effect, a kit and application. Comprising the following steps: S1, preparing a lysine functionalized gold / silver nanoparticle solution; s2, adding an aflatoxin standard solution with known concentration into the Hg < 2 + > standard solution, oscillating and incubating, and then adding the lysine functionalized gold / silver nanoparticle solution to construct an aggregation colorimetric reaction system; and a series of aggregation colorimetric reaction systems. S3, acquiring color data by a machine image recognition technology, wherein the color data comprises an R value, a G value and a B value; s4, constructing a standard curve; s5, color data of a to-be-detected sample are obtained, and the content of aflatoxin in the to-be-detected sample is obtained through the standard curve. Visual quantitative analysis detection of aflatoxin is realized, the sensitivity is ensured, the detection process is simple, and the test efficiency is high.

The application discloses a preparation method of a bismuth single element / bismuth oxide / carbon nitride composite material and application of the bismuth single element / bismuth oxide / carbon nitride composite material as a chlorine removal agent, and the bismuth single element / bismuth oxide / carbon nitride composite chlorine removal agent is prepared by taking bismuth nitrate pentahydrate as raw material and introducing melamine precursor. In the process of calcination, the melamine generates elemental carbon and carbon monoxide, and plays a regulating role in the morphology of the chlorine removal agent; the reducing property generated in the forming process can convert Bi 3+ into Bi single element, and the surface plasmon resonance effect of the Bi single element is utilized to improve the photocatalytic chlorine removal performance of the composite chlorine removal agent.

The application relates to the technical field of trace molecule detection, in particular to a photoelectric detection and sensing integrated digital metasurface infrared spectrum chip and a preparation method thereof. The chip comprises, from bottom to top, a substrate, a metal reflection layer, a metal nanoparticle layer, a pyroelectric photosensitive layer and a digital metasurface structure layer; the digital metasurface structure layer is in a discrete pattern composed of a pixel array in the transverse direction of the device, the digital metasurface structure layer can excite surface plasmon resonance under the irradiation of preset light waves, the light field energy is localized in the target molecules and the pyroelectric photosensitive layer, so that the responsivity and sensing sensitivity of the infrared spectrum chip are improved; and the array coding of the discrete pattern of the digital metasurface structure layer is designed through a preset algorithm, so that the electric field intensity at the preset spatial position is enhanced. The chip has the advantages of high responsivity, high sensing sensitivity and high signal-to-noise ratio.

The invention discloses a UCNPs modified AgNPs (at) MgAl LDH composite material and a preparation method of the UCNPs modified AgNPs (at) MgAl LDH composite material. According to the preparation method, MgAl LDH is synthesized through a solvothermal method, AgNPs is loaded on the MgAl LDH through a reduction precipitation method, and the AgNPs-coated MgAl LDH composite material is successfully prepared; liYF4: Yb and Tm-coated LiYF4 UCNPs are prepared at the same time, the LiYF4: Yb and Tm-coated LiYF4 UCNPs are subjected to hydrophilic modification by adopting a ligand exchange method, and finally the LiYF4: Yb and Tm-coated LiYF4 UCNPs and the LiYF4: Yb and Tm-coated LiYF4 UCNPs are compounded to prepare the AgNPs-coated MgAl LDH / According to the ternary composite system, through surface plasma resonance (SPR) of AgNPs, the up-conversion luminescence effect of UCNPs and the layered structure synergistic effect of MgAl LDH, efficient degradation of TCH can be achieved, and meanwhile a new thought is provided for the near-infrared driven environment restoration technology.