The invention discloses a preparation method of a ternary positive
electrode material, the ternary positive
electrode material and application, and relates to the technical field of
lithium ion batteries. Through in-situ construction of a core-shell / gradient structure, surface side reactions are inhibited, high capacity characteristics are maintained, and
energy density and
cycling stability are both considered. Through
nanopore channels are constructed in
single crystal particles, particle
cracking is inhibited, and the rate capability is improved; through
plasma treatment,
lithium ion de-intercalation active sites are increased, the wettability of an
electrolyte is improved, interface contact is optimized, and the reaction
kinetics performance is improved;
boron /
phosphorus-containing functional molecules are introduced to react with surface residual
lithium, a stable CEI film containing components such as Li3PO4 and LiF is generated in situ, interface
side reaction is inhibited, interface stability is improved, and
metal impurities are not introduced. The
energy density, the
cycling stability and the rate capability of the material can be considered at the same time through the preparation processes of core-shell gradient structure construction,
nanopore modification, surface defect regulation and control modification and
surface coating modification.