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444results about How to "Aperture adjustable" patented technology

Preparation method of high-temperature-resistant aerogel and aerogel-type porous ceramics

The invention discloses a preparation method of high-temperature-resistant aerogel. The method comprises: adding high-temperature-resistant powder or crystal whiskers to sol, performing in-situ compounding of sol and high-temperature-resistant powder or crystal whiskers, and performing aging, modification and drying to obtain high-temperature-resistant aerogel. The invention further discloses a preparation method of aerogel-type porous ceramics. Porous ceramics having an aerogel hole structure kept is obtained by sintering the high-temperature-resistant aerogel. The prepared high-temperature-resistant aerogel and aerogel-type porous ceramics can resist high temperature of 1000-1800 DEC C or more, keep the nanometer hole structure from collapse, have high porosity and strength and have hole diameters which can be adjusted from micropores to large holes. The aerogel and aerogel-type porous ceramics can be used as a super thermal insulation material and can be widely applied to fields of purification separation, adsorption, chemical industrial catalytic carriers, sound absorption and damping, sensing elements and electrochemistry. The method is simple and easy to carry out and suitable for massive production, and allows high temperature resistance of aerogel to be improved and application fields of aerogel to be broadened.
Owner:浙江圣润纳米科技有限公司

Hollow mesoporous silica microsphere, preparation method and application thereof

InactiveCN102432024ARealize internal and external transmissionIncrease dissolution rateSilicaPharmaceutical non-active ingredientsMicrosphereDrug carrier
The invention discloses a hollow mesoporous silica microsphere with hollow core and adjustable mesopore and penetrating through a shell, preparation method and application thereof. The hollow mesoporous silica microsphere is obtained by the following steps: under the condition of acid or alkaline solution, taking hexadecyl trimethyl ammonium bromide or PEO-PPO-PEO triblock copolymer as template, adding non-polar solvent, stirring at a certain temperature, emulsifying, then adding silica source, after hydrolysis and condensation, filtering, drying, and roasting to remove the template. The preparation method has simple technique and short time, easy operation and low cost, the prepared microsphere comprises both macropore and mesopore structures, the mesopore penetrates through the shell, the aperture thereof is larger than 5nm and is adjustable within the range of 5-20nm, and by relatively large mesopore channel, internal and external transmissions of large guest molecules can be realized. The microsphere can be used as drug carrier, the drug loading amount can exceed 50% (mass percentage), and the drug release can be controlled by adjusting aperture of the mesopore and dissolutionrate of indissolvable drug can be improved.
Owner:广州万泽医药科技有限公司

Preparation method of orderly porous matrix shaping composite phase change material

The invention provides a preparation method of an orderly porous matrix shaping composite phase change material, and belongs to the field of a composite phase change material. The preparation method comprises the following steps: firstly preparing an orderly mesoporous silica carrier, and designing, adjusting and controlling the porous-channel structure, pore size and surface property of the carrier; secondly, using a phase change core material for preparing corresponding liquor, dispersing the prepared porous carrier in prepared phase change core material liquor, adsorbing the phase change core material by using the relatively strong capillary action, surface tension and the like of the porous carrier material so as to realize the high-efficiency filling of the core material in combination of the bonding effects of functional groups on the surface of the carrier on the core material, and drying so as to obtain the composite phase change material with relatively good heat storage capacity and relatively high stability. The composite phase change material has the advantages that the carrier is large in specific surface area, high in porosity and small in pore diameter, has orderly porous-channels and strong immobilization capacity on the phase change core material and is difficult to leak, the filling quantity of the core material is large, and the composite phase change material is high in energy storage density, good in heat stability, widely applied, difficult to burn, green and safe in use.
Owner:UNIV OF SCI & TECH BEIJING

Hyaluronic acid modified polycaprolactone/polylactic acid three-dimensional stephanoporate compound stent and preparation

The invention relates to a hyaluronic acid modified polycaprolactone/polylactic acid three-dimensional porous composite scaffold and a preparation method thereof. The composite scaffold comprises the components of polycaprolactone PCL, polylactic acid PLA and hyaluronic acid HA. The preparation method comprises: (1) dissolving PCL and PLA into a cosolvent to derive transparent blend solution; (2) adjusting electrostatic spinning process, spinning the blend solution to a nanometer/submicron graded fibrofelt, and vacuumizing in a vacuum oven to remove residual solvents; (3) overlapping and filling the fibrofelt to a die of specific shape and placing in the vacuum oven, cooling, demoulding, modifying a plasma, and immersing in hyaluronic acid HA solution; (4) placing the HA modified composite scaffold in the vacuum oven to be dried, sterilizing with epoxy ethane and deriving the three-dimensional porous composite scaffold. The three-dimensional porous tissue engineering composite scaffold material of the invention has the advantages of uniform internal pore structure, stable architecture and simple preparation method, and can be used as the scaffold of bone and cartilage tissue engineering cell.
Owner:DONGHUA UNIV

Composite zeolite membrane, and preparation method and application thereof

The invention discloses a composite zeolite membrane, and a preparation method and application thereof. The composite zeolite membrane comprises a support body layer and a zeolite membrane layer, wherein the support body layer is prepared from nanometer stage or submicron stage ceramic powder materials or ceramic material precursors through a static spinning process; the porosity of the support body layer is as high as 83 percent, and is adjustable and controllable between 40 percent and 83 percent. The composite zeolite membrane provided by the invention has the advantages that the porous ceramic prepared by the static spinning process is used as the support body layer; the surface structure of the support body layer is flat and continuous; the porosity is high; the pore diameter is uniform; the size of the pore diameter is adjustable and controllable; the pore passage sinuosity is small; the mechanical intensity is high; the flux of the composite zeolite membrane is improved; in addition, through the fiber-shaped pore passage structure of the support body layer, seed crystals can be effectively attached; the loading quantity of the seed crystals can be ensured; meanwhile, the matching degree and the compatibility between the zeolite membrane layer and the support body layer are greatly improved; the stability of the zeolite membrane layer is improved.
Owner:PEKING UNIV SHENZHEN GRADUATE SCHOOL +1

CuxSe/TiO2 nanotube array of p-type semiconductor nano material and preparation method thereof

The invention discloses a CuxSe / TiO2 nanotube array of a p-type semiconductor nano material and a preparation method thereof. The method comprises the following steps: putting a TiO2 nanotube array in 5mmol-20mmol of CuSO4 solution; electrodepositing elementary substance Cu on the TiO2 nanotube array by adopting pulse plating in a standard three-electrode system to obtain a Cu / TiO2 compound nanotube array; carrying out electrooxidation in an NaOH alkaline solution for a certain time after deposition is ended to obtain a superfine Cu2O nanowire-modifying TiO2 nanotube array; and then putting the Cu2O / TiO2 nanotube array in a selenium ion solution, and stirring for 30-60 min under light to obtain a copper selenide nanotube array. Based on the superfine Cu2O nanowire-modifying TiO2 nanotube array, the absorption range of TiO2 in a visible light area can be effectively expanded and the compounding probability of an electron hole pair can be reduced, and more photoelectrons and photoholes can be generated under visible light, thereby being more beneficial to Cu2O to react with the selenium ion solution to generate copper selenide. The CuxSe / TiO2 nano material with a novel structure has potential application in the aspects of solar batteries, solar radiation absorbers, nano switches, thermoelectric photoelectric converters, superconductors, air-sensitive sensors and the like.
Owner:HUNAN UNIV

Starch-based nitrogen doped mesoporous molding carbon as well as preparation method and application thereof

The invention provides starch-based nitrogen doped mesoporous molding carbon. A preparation method of the carbon comprises the following steps: mixing natural starch with a template agent, adding water of a water absorption volume capacity equal to that of the mixture, uniformly stirring, performing extrusion modeling, leaving to stand for a time, and drying in an oven so as to obtain a mesoporous carbon precursor; putting the obtained mesoporous carbon precursor into a tubular furnace; in the presence of an inert gas, heating to 400-1000 DEG C, and roasting for 1-5 hours at a constant temperature so as to obtain a carbonized material; removing the template agent from the obtained carbonized material, washing till being neutral with deionized water, and drying, so as to obtain a finished product. The starch-based nitrogen doped mesoporous molding carbon provided by the invention is simple in preparation process, low in ash range and impurity content, free of extract nitrogen source, rich in pore, high in mesoporous structure ratio, adjustable in aperture and excellent in catalysis property in reaction for preparing vinyl chloride monomers by using a calcium carbide method, and can be used as a mercury-free catalyst or a catalyst carrier.
Owner:ZHEJIANG UNIV OF TECH

Method for preparing PLGA/PCL/nHA composite bone repair porous scaffold by 3D printing technology as well as product and application of method

The invention relates to a method for preparing a PLGA/PCL/nHA composite bone repair porous scaffold by a 3D printing technology as well as a product and application of the method. The method comprises the following steps: mixing 1,4-dioxane which is used as a solvent with PLGA and PCL according to a mass ratio of 9:(1-5):5, adding nHA powder according to a mass fraction of 10-25%, and finally adding tributyl citrate as a compatibilizer to improve the uniformity of the material; using the solution as 3D printing 'ink', carrying out 3D printing with a 3D printer, selecting a 150-micron discharging needle, and setting printing parameters as follows: parallel printing is adopted for each layer with gaps of 0.1-0.3mm, the Z-axis direction is raised by 0.2mm each time, the layers are verticallycrossed and stacked, the extrusion speed is set to 1.5-2mm/s, and the temperature of a receiving platform is -20 to -10 DEG C; and after the scaffold is printed, carrying out freeze-drying for 48 hours, and then drying the scaffold in a vacuum oven at 50 DEG C for 24 hours or more to prepare a PLGA/PCL/nHA composite bone repair porous scaffold. The preparation method provided by the invention issimple and feasible; the prepared porous bone repair scaffold has proper pore size and porosity, good biocompatibility and mechanical strength, thereby providing a new idea for clinical treatment of large bone defects, and having a wide clinical application prospect.
Owner:SHANGHAI NAT ENG RES CENT FORNANOTECH
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