The invention relates to a preparation method of a carbon /
graphite /
tin composite
anode material. The carbon /
graphite /
tin composite
anode material adopts the following raw materials in percentage by weight and particle size: 1.5-2.5% of
carbon black, 5-8% of
natural graphite with the particle size being smaller than or equal to 1 mm, 3-10% of nanosized
tin with the particle size being smaller than or equal to 100 nm, 25-30% of calcined
petroleum coke powder with the particle size being smaller than or equal to 0.075 mm, 15-20% of calcined
petroleum coke with the particle size being 1-4 mm, 10-15% of electric calcined
anthracite with the particle size being 4-10 mm, 5-10% of electric calcined
anthracite with the particle size being 10-16 mm, 5-15% of calcined
pitch coke with the particle size being 10-16 mm, 18-20% of
coal pitch, and short carbon
fiber, wherein short carbon
fiber accounts for 1-3% the total amount of the raw materials. The carbon /
graphite / tin composite
anode material is prepared by adopting the steps of burdening, mixing, kneading,
roasting, graphitizing, smashing, and spheroidizing. The carbon / graphite / tin composite anode material prepared by adopting the preparation method provided by the invention combines respective advantages of carbon material, graphite material and tin
powder when serving as anode materials, and the prepared carbon / graphite / tin composite anode material has the characteristics of high first-cycle capacity, high initial charge-
discharge efficiency,
electrolyte solvent resistance and isotropic homogeneity and the like.