The invention provides ternary copolymerized
polyimide, a
polyimide film and a preparation method and application thereof, the ternary copolymerized
polyimide is prepared from the following
monomer raw materials through
polymerization and imidization reaction:
diamine monomer: 9, 9-bis (4-aminophenyl)
fluorene; the dianhydride
monomer comprises hexafluorodianhydride and 9, 9-bis (3, 4-dicarboxyphenyl)
fluorene dianhydride; wherein the total
molar weight ratio of the
diamine monomer to the dianhydride monomer is 1: 1; in the dianhydride monomer, the
molar ratio of the 6FDA to the BPAF is (0.8-1.2): 1. According to the present invention, the traditional thought that the transparency is improved by introducing the fluorenyl monomer at the low content is abandoned, and the high-proportion rigid double fluorenyl structure (BAFL and BPAF) and the flexible
fluorine-containing structure (6FDA) are innovatively adopted to perform the ternary
polymerization at the specific ratio so as to produce the significant synergistic effect; the obtained polyimide film has
high heat resistance (Tg is greater than or equal to 420 DEG C), low
thermal expansion coefficient (CTE is less than or equal to 20 ppm / K), low
dielectric constant (Dk is less than or equal to 3.5 under 10 GHz) and high transparency (light
transmittance at 450 nm is greater than or equal to 85%), and is especially suitable for high-performance
flexible display substrates.