380results about "Azo dyes" patented technology

A light absorber 10 has a transmission spectrum satisfying the following requirements (I), (II), (III), (IV), and (V) at an incident angle of 0°. The light absorber 10 has a haze less than 0.20%. (I) An average transmittance TA0deg(460-600) is 75% or more. (II) A shorter cut-off wavelength λH0deg(s) is in a range of 390 nm to 450 nm. (III) A longer cut-off wavelength λH0deg(L) is in a range of 600 nm to 680 nm. (IV) An average TA0deg(300-380) is 1.2% or less. (V) An average TA0deg(750-1000) is 1.2% or less.

The invention belongs to the technical field of biological dyes, and discloses a bio-based melanin precursor compound, bio-based melanin as well as a preparation method and application of the bio-based melanin precursor compound and the bio-based melanin. The invention provides a bio-based melanin precursor compound 4-[5-(2, 2-diaminoethyl)-2, 3-dihydroxyphenyl]-1H-indole-5, 6-diphenol, and a preparation method of the bio-based melanin precursor compound. The bio-based melanin precursor compound is stable in chemical property and easy to store. And the catalyst can be used as a raw material to efficiently synthesize bio-based melanin through a catalytic oxidation reaction. The process for preparing the bio-based melanin is simple, mild, high in yield and suitable for large-scale industrial production. The bio-based melanin prepared by the invention has good application performance during dyeing, does not generate harmful substances, and is safe and environment-friendly.

The invention provides a substituted amino bipyridine derivative as well as a preparation method and application thereof, the structure of the substituted amino bipyridine derivative is as shown in formula I. In the formula, R1, R2, R3 and R4 are independently selected from any one of H, C1-C6 alkyl, C2-C6 alkenyl, C2-C20 alkynyl, C3-C6 cycloalkyl, C5-C20 aryl or C5-C20 heterocyclic radical; when R1, R2, R3 and R4 are not methyl, no more than one of R1, R2, R3 and R4 is H; and when any one of R1, R2, R3 and R4 is methyl, the rest groups are independently selected from H or methyl. When the substituted amino dipyridyl derivative provided by the invention is used as a blue dye, the dyed blue dye is bright in color, deep in dyeing and comprehensive in dyeing fastness; the preparation process is simple, convenient to purify, safe, simple, convenient and energy-saving, the product quality is stable, the reproducibility is good, the yield is high, and the method is suitable for industrial production.

The present invention relates to photohardenable compositions and methods of forming an object, the method preferably including a photohardenable composition described herein. Preferred photohardenable compositions and methods include a photohardenable resin component, a first photoinitiator that is activatable by exposure to light at a first wavelength and light at a second wavelength, and a second photoinitiator that is activatable by exposure to light at a third wavelength, wherein the first, second, and third wavelengths are not the same, and the third wavelength is shorter than the first wavelength and the second wavelength. Preferred first photoinitators include photoswitchable photoinitiators. Preferably the second light-activated photoinitiator comprises a free-radical photoinitiator. Hardenable resin compositions and methods of forming an object including the hardenable resin composition are also disclosed.

The invention relates to the technical field of microbial fermentation, and particularly discloses a composite blue dye and a fermentation process thereof. According to the method, the fermentation temperature and pH are controlled, the flux of synthesized mesoscopic blue is limited, part of the flux is led to synthesis of pyridone, the mesoscopic blue in the fermentation liquor is regulated and controlled to be mixed with pyridone in a certain proportion, and the purified product mesoscopic blue is compounded with pyridone to form the composite blue dye with a stable specific color. The cost of separately purifying the ornamental blue and the pyridone and then mixing the ornamental blue and the pyridone according to a certain proportion to obtain the composite blue dye is reduced, so that the composite blue dye can be better applied to a subsequent dyeing process. According to the invention, a blue-viewing product form is added, a better dyeing effect can be achieved on the premise of not increasing the production cost, and the application market is widened.

The invention belongs to the technical field of organic dye synthesis and application, and discloses a conjugated compound containing a benzothiophenazine structure as well as a preparation method and application thereof, and the conjugated compound containing the benzothiophenazine structure has excellent photophysical properties, singlet oxygen yield and superoxide anion generation capacity. The novel conjugated compounds ENBO-NI and ENBS-NI containing benzothiophenazine structures are successfully prepared by replacing a benzene ring of Nile blue with a cycloalkane structure and adjusting the electron donating ability of an R1 group. The two compounds have near infrared fluorescence emission, good solubility and relatively high ROS yield. Compared with a classical photosensitizer NB, the singlet oxygen yield of ENBO-NI is increased by about 117.65%, and the singlet oxygen yield of ENBS-NI is as high as 70%. The absorption wavelength of the conjugated compound is in a red light wave band. The preparation process is simple and efficient, large-scale production is easy, and the preparation method has a wide clinical application prospect.

The invention belongs to the technical field of photoresists, and relates to a wide-color-gamut yellow dye for a color filter, a synthesis method of the wide-color-gamut yellow dye, a green photoresist and a preparation method of the green photoresist. The green photoresist is prepared from the following raw materials in parts by weight: 4 to 8 parts of green pigment, 3 to 8 parts of resin, 3 to 10 parts of acrylic monomer, 0.5 to 2 parts of photoinitiator, 0.2 to 0.4 part of auxiliary agent and 75 to 85 parts of organic solvent. The synthesized yellow dye has good photoresist system adaptability and high molar absorption coefficient, and meanwhile, due to the fact that acrylic acid is grafted, acrylic acid on the yellow dye has carbon-carbon double bonds, under the action of a photoinitiator, after bond breaking, the yellow dye can react with resin or an acrylic monomer and is cured in a film, and the yellow dye has good chemical resistance.

The invention discloses a near-infrared dichroic dye, a liquid crystal composition and application of the near-infrared dichroic dye and the liquid crystal composition. The structural general formula of the disclosed dichroic dye is as shown in formula I in the specification. According to the invention, a hydrogenated quinoline ring, a hydrogenated benzopyran ring and a hydrogenated naphthalene ring are introduced into a molecular skeleton, so that the novel near-infrared dichroic dye with high light stability, high solubility, high order parameter and high light modulation capability is obtained. Compared with the near-infrared dichroic dye disclosed in the prior art, the absorption band is further subjected to red shift, and the light modulation capability is remarkably improved; ordering parameters are greatly improved, and the application bottleneck is solved.

The invention discloses an ether chain modified rhodamine fluorescent dye, an ether chain modified rhodamine fluorescent dye probe and a preparation method and application thereof, through modification of an ether chain, the water solubility of the rhodamine dye is improved, the aggregation quenching effect is reduced, meanwhile, the intramolecular torsional charge transfer (TICT) is reduced through the electron withdrawing effect of oxygen atoms, and the fluorescence sensitivity is improved. Finally, the quantum yield of the rhodamine dye is greatly improved. The quantum yield of ether chain modified oxygen rhodamine water is increased from 0.31 to 0.70, and the quantum yield of silicon-based rhodamine water is increased from 0.19 to 0.41. The rhodamine dye disclosed by the invention has the characteristics of high brightness, easiness in functional derivation and the like, and has application prospects in the fields of fluorescent probes, fluorescent labels, super-resolution fluorescence imaging and the like.

The application relates to the technical field of microbial fermentation, and specifically discloses a kind of compound blue dye and its fermentation process. The application controls the fermentation temperature and pH, limits the flux of observing blue, makes part of the flux to the synthesis of pyridone, regulates and controls the mixed pyridone in the fermentation liquor at a certain proportion, and after purification, the product is formed into a compound blue dye with stable specific color, reduces the cost of mixing the compound blue dye at a certain proportion after separately purifying observing blue and pyridone, and makes it better applied to the subsequent dyeing process. The application increases the product form of observing blue, can achieve better dyeing effect under the premise of not increasing production cost, and widens the application market.

Photohardenable compositions comprising a photohardenable component and a photoswitchable photoinitiator, wherein the photoswitchable photoinitiator is activatable by exposure to light having a first wavelength and light having a second wavelength to induce a crosslinking or polymerization reaction in the photohardenable component, and wherein the photohardenable composition displays non-Newtonian rheological behavior are disclosed. Methods including such photohardenable compositions for printing one or more objects are also disclosed.

The present invention relates to: a novel compound having excellent carrier transport ability, light emission ability, and thermal stability; and an organic electroluminescent element having improved characteristics such as light emission efficiency, driving voltage, and lifespan by containing the compound in one or more organic material layers.

The application provides a triarylmethane derivative, a pigment dispersion liquid, a preparation method thereof and a photoresist, and relates to the field of photoresists. The structural general formula of the triarylmethane derivative is: wherein X1 is selected from one of long-chain alkyl groups with a length of C1-C12, X2 is selected from hydrogen or an alkyl group, X3 is selected from one of H, an alkyl group and an aromatic group, and Q is selected from one of a carboxyl group, a sulfonic acid group and a phosphoric acid group. The triarylmethane derivative can generate strong van der Waals force and pi-pi conjugation effect with pigment molecules in a colorant by virtue of the large-plane conjugated triarylmethane skeleton, so as to be firmly anchored on the surface of the pigment particles; the strong polar functional groups such as the sulfonic acid group in the molecular structure of the triarylmethane derivative are combined with the alkaline dispersant, the side long-chain alkyl groups fully act on the dispersion medium, and the re-aggregation of the nano pigment particles is effectively prevented through strong steric hindrance and electrostatic stabilization mechanism, so that the problem of poor dispersion stability is solved.

A portable device which detects a Raman signal from an analyte of interest contained in or suspected to contain in a sample. The portable device includes a laser source in optical communication with a dichroic mirror, an objective lens optically positioned to consolidate the laser from the laser source to the sample, (i) a pair of rotatable filters in optical communication with the dichroic mirror and an optical transmission module or (ii) a first band-pass filter in optical communication with the dichroic mirror and an optical transmission module, and a detector optically positioned to receive and detect a Raman signal produced from the laser incident on the analyte of interest. The dichroic mirror directs the laser from the laser source to the sample through the objective lens and transmits any Raman signal from the sample toward the detector. The detector is absent of a spectrometer and detects the Raman signal.

The present application provides a reversible thermochromic microcapsule pigment which is easily changed to a colored state from a colorless state by heating at a temperature in a living environment temperature range or a temperature close to a daily life temperature, and is sensitively recovered to the colorless state again. The reversible thermochromic microcapsule pigment of the present application is formed by enclosing a reversible thermochromic composition in a microcapsule, the reversible thermochromic composition comprising (A) an electron-donating colored organic compound, (B) a 4-hydroxybenzoic acid ester compound represented by the following general formula (1) as an electron-accepting compound (in the formula, R represents a linear or branched alkyl group having 12 to 22 carbon atoms), (C) a chain hydrocarbon compound or the like as a reaction medium in which reversible electron transfer reactions based on the above (A) and (B) occur, (D) a linear dibasic acid compound having 3 to 22 carbon atoms, and (E) an aromatic hydrocarbon compound or the like having a melting point of 50°C or higher.

A wavelength selective absorption filter contains a resin, a coloring agent, and a compound having at least one polar group of a carboxylic acid ester bond, a carboxylic acid amide bond, a sulfonic acid amide bond, a urethane bond, or a sulfonyl bond and a MW≤1,000 where dye includes at least one of dye A having a main absorption wavelength range at a wavelength of 390 to 440 nm and dye D having a main absorption wavelength range at a wavelength of 680 to 780 nm, a 20% value wavelength A with respect to an absorbance maximal value exhibited by a main absorption wavelength is 455 nm or less where dye A is contained, and a 20% value wavelength D with respect to the absorbance maximal value exhibited by the main absorption wavelength is 640 nm or more where dye D is contained, and a display device.

This invention relates to compounds and methods for treating cancer. In various embodiments, the compound includes a heptamethine carbocyanine dye (HMCD) component, a camptothecin derivative component, and a linker moiety (L) connecting the HMCD component and the camptothecin derivative component. In various embodiments, the method includes administering a therapeutically effective amount of the compound to a subject, thereby contacting a tissue of the subject with the compound such that the compound binds to the tissue; detecting the compound bound to the tissue, wherein the presence of the compound bound to the tissue is indicative of the cancer in the subject; and delivering the compound to the tissue thereby treating the cancer in the subject.

The application discloses an aggregation-induced emission microsphere with colorimetric-fluorescent double signals and a preparation method and application thereof. The aggregation-induced emission microsphere comprises carboxyl polystyrene microspheres and aggregation-induced emission dyes embedded in the carboxyl polystyrene microspheres; and the structural formula of the aggregation-induced emission dyes is as follows: The aggregation-induced emission microsphere has colorimetric-fluorescent double signals, is red under natural light, has strong absorption at 600 nm, and shows high light-emitting efficiency at 725 nm, effectively avoids the interference of biological autofluorescence, reduces background interference, has good light stability and light bleaching resistance, and has high molar extinction coefficient, so that the aggregation-induced emission microsphere has colorimetric and fluorescent double signal output capabilities. In addition, the preparation process of the aggregation-induced emission microsphere has high reproducibility, has the potential for large-scale synthesis, and meets the needs of industrial batch production.

Fluorescent whitening agents (FWA) or optical brighteners based on bicyclic heterocyclic compounds (I) and (II) are suitable for use in consumer products: Wherein the variables are as defined in claim

A reversibly thermochromic microcapsule pigment according to the present invention has a reversible thermochromic composition encapsulated in microcapsules, the reversibly thermochromic composition consisting of a compound such as(A) an electron-donating color-developing organic compound,(B) a 4-hydroxybenzoic acid ester compound represented by General Formula (1) below as an electron-accepting compound,(C) a compound such as a chain hydrocarbon as a reaction medium that reversibly induces an electron transfer reaction by the (A) and (B),(D) a linear dibasic acid compound having 3 to 22 carbon atoms, and(E) an aromatic hydrocarbon having a melting point of 50° C. or higher,wherein R represents a linear or branched chain alkyl group having 12 to 22 carbon atoms.

The invention provides powder with reversible photochromic performance as well as a preparation method and application thereof, and the powder with reversible photochromic performance is a photochromic microcapsule and consists of a core material and a wall material, the core material accounts for 30%-50% of the total weight of the microcapsule, and the wall material accounts for 50%-70% of the total weight of the microcapsule; the core material is an indoline spiroheterocyclic compound, and the wall material is a biocompatible polymer. The core material is an indoline spiroheterocyclic compound, and the wall material is a biocompatible polymer; the powder is prepared by taking indoline spiropyran as a photochromic core material through a microcapsule coating process, has reversible response characteristics of developing under ultraviolet irradiation and decolorizing under strong light irradiation, and can be compounded with a tattooing pigment matrix to obtain a tattooing product with active developing and decolorizing regulation and control functions. The problem that the photochromic tattoo pigment is irreversible in color change is solved, and meanwhile the photochromic tattoo pigment has good stability and biocompatibility.

The present invention provides compositions, films, optical filters, solid-state image sensors, and compounds that can form films with excellent heat resistance and suppressed color transfer. [Solution] A composition comprising a compound represented by formula (1) or formula (2), a curable compound, and a solvent. JPEG2026054591000046.jpg46170

The present application relates to an optical filter having a substrate and a dielectric multilayer film laminated on at least one main surface side of the substrate and serving as an outermost layer, wherein the substrate has a resin film containing a pigment (U) having a maximum absorption wavelength in the range of 360 nm to 395 nm in dichloromethane, a pigment (A) having a maximum absorption wavelength in the range of 600 nm to 800 nm in dichloromethane, and a resin, and the optical filter satisfies specific spectral characteristics.

The present invention relates to a novel fluorescent marker that selectively binds to tau protein, its use, a method for imaging neurofibrillary tangles of tau protein in the retina of a subject, as well as an apparatus allowing said method to be carried out.

The present invention relates to a process, an apparatus and a photoswitchable photoinitiator for locally polymerizing a starting material by bichromatic photopolymerization, as well as a method for volume printing (xolography) of shaped bodies. In particular, photoinitiators are provided that induce the curing of photopolymerizable formulations upon irradiation with two different wavelengths and can be used for volume printing (xolocure initiators).

The present application relates to a kind of fluorane compound, thermosensitive dye dispersion and its preparation method, the fluorane compound has the structure shown in formula I, wherein, R is selected from 4-trifluoromethylphenyl, n-hexyl, aminomethyl, -CH2CH2OH, -CH2CH2Br, -CH2OCH3 Or one of esterified PEO groups.The fluorane compound of the present application can be used as thermosensitive dye, and the 1,2,3-triazole structure can enhance the color ability of fluoran mother nucleus.

The invention belongs to the technical field of organic dyes, and particularly relates to an anti-ultraviolet dye taking tannic acid as a coupling component as well as a preparation method and application of the anti-ultraviolet dye. Under a stirring condition, adding a diazonium salt solution of an arylamine derivative into the mixed solution for reaction, and continuously stirring for reaction after the diazonium salt solution is added, so as to obtain a reaction solution; adjusting the pH value of the reaction liquid, evaporating, filtering and drying to obtain the anti-ultraviolet dye taking tannic acid as the coupling component. The uvioresistant dye taking tannic acid as a coupling component can endow real silk with color and uvioresistant function during dyeing; the dyeing process is simple and short in time, damage to real silk is small, dye liquor composition is simple, follow-up wastewater is easy to treat, and the whole dyeing process is low-carbon and environment-friendly.