589results about "Azo dyes" patented technology

Described herein are methods, compositions and articles of manufacture involving neutral conjugated polymers including methods for synthesis of neutral conjugated water-soluble polymers with linkers along the polymer main chain structure and terminal end capping units. Such polymers may serve in the fabrication of novel optoelectronic devices and in the development of highly efficient biosensors. The invention further relates to the application of these polymers in assay methods.

A light absorber 10 has a transmission spectrum satisfying the following requirements (I), (II), (III), (IV), and (V) at an incident angle of 0°. The light absorber 10 has a haze less than 0.20%. (I) An average transmittance TA0deg(460-600) is 75% or more. (II) A shorter cut-off wavelength λH0deg(s) is in a range of 390 nm to 450 nm. (III) A longer cut-off wavelength λH0deg(L) is in a range of 600 nm to 680 nm. (IV) An average TA0deg(300-380) is 1.2% or less. (V) An average TA0deg(750-1000) is 1.2% or less.

The invention belongs to the technical field of biological dyes, and discloses a bio-based melanin precursor compound, bio-based melanin as well as a preparation method and application of the bio-based melanin precursor compound and the bio-based melanin. The invention provides a bio-based melanin precursor compound 4-[5-(2, 2-diaminoethyl)-2, 3-dihydroxyphenyl]-1H-indole-5, 6-diphenol, and a preparation method of the bio-based melanin precursor compound. The bio-based melanin precursor compound is stable in chemical property and easy to store. And the catalyst can be used as a raw material to efficiently synthesize bio-based melanin through a catalytic oxidation reaction. The process for preparing the bio-based melanin is simple, mild, high in yield and suitable for large-scale industrial production. The bio-based melanin prepared by the invention has good application performance during dyeing, does not generate harmful substances, and is safe and environment-friendly.

The invention relates to the technical field of chemical synthesis of dyes, in particular to a 5, 5 '-disubstituted amino-3, 3'-dipyridyl derivative as well as a preparation method and application of the 5, 5 '-disubstituted amino-3, 3'-dipyridyl derivative. According to the 5, 5 '-disubstituted amino-3, 3'-dipyridyl derivative and the preparation method thereof, the ornamental blue is used as a parent body for derivatization reaction, different structures are introduced to amino groups, the 5, 5 '-disubstituted amino-3, 3'-dipyridyl derivative is obtained and can be used as a dye, and the dye has relatively high color development intensity, bright color, deep dyeing and comprehensive color fastness. The preparation method of the 5, 5 '-disubstituted amino-3, 3'-dipyridyl derivative is continuous in process step, high in controllability, large in treatment capacity and suitable for large-scale industrial production, the 5, 5 '-disubstituted amino-3, 3'-dipyridyl derivative is applied to fabric dyeing, and the fabric has the advantages of washing resistance, acid resistance, sublimation resistance, wet friction resistance and the like.

An optical filter includes: a substrate, an antireflection layer 1 including a dielectric multilayer film laminated on one main surface side of the substrate, and an antireflection layer 2 including a dielectric multilayer film laminated on the other main surface side of the substrate. The substrate includes a near-infrared ray absorbing glass and a resin film, the resin film includes a resin, a UV dye having a maximum absorption wavelength in 350 nm to 410 nm in the resin, and an IR dye having a maximum absorption wavelength in 700 nm to 850 nm in the resin, and the optical filter satisfies all of the characteristics (i-1) to (i-7).

The invention relates to the technical field of pigment synthesis, and particularly discloses a synthetic method of ornamental blue. According to the synthetic method, 5-hydroxy-3-iminopyridine-2, 6-diketone is adopted as a raw material, enol interconversion is performed on the raw material under the alkaline condition (under the action of an alkali catalyst), heating is performed, and chemical condensation reaction is performed to obtain the ornamental blue. The synthetic method of the ornamental blue provided by the invention is simple in process and high in reaction selectivity, the yield and purity of the product are high, the yield of the ornamental blue product is more than or equal to 80%, the purity of the ornamental blue product is more than 99%, the synthetic method has obvious advantages, no potential safety hazard exists in the process, and industrial production can be realized.

The invention provides a substituted amino bipyridine derivative as well as a preparation method and application thereof, the structure of the substituted amino bipyridine derivative is as shown in formula I. In the formula, R1, R2, R3 and R4 are independently selected from any one of H, C1-C6 alkyl, C2-C6 alkenyl, C2-C20 alkynyl, C3-C6 cycloalkyl, C5-C20 aryl or C5-C20 heterocyclic radical; when R1, R2, R3 and R4 are not methyl, no more than one of R1, R2, R3 and R4 is H; and when any one of R1, R2, R3 and R4 is methyl, the rest groups are independently selected from H or methyl. When the substituted amino dipyridyl derivative provided by the invention is used as a blue dye, the dyed blue dye is bright in color, deep in dyeing and comprehensive in dyeing fastness; the preparation process is simple, convenient to purify, safe, simple, convenient and energy-saving, the product quality is stable, the reproducibility is good, the yield is high, and the method is suitable for industrial production.

The present invention relates to photohardenable compositions and methods of forming an object, the method preferably including a photohardenable composition described herein. Preferred photohardenable compositions and methods include a photohardenable resin component, a first photoinitiator that is activatable by exposure to light at a first wavelength and light at a second wavelength, and a second photoinitiator that is activatable by exposure to light at a third wavelength, wherein the first, second, and third wavelengths are not the same, and the third wavelength is shorter than the first wavelength and the second wavelength. Preferred first photoinitators include photoswitchable photoinitiators. Preferably the second light-activated photoinitiator comprises a free-radical photoinitiator. Hardenable resin compositions and methods of forming an object including the hardenable resin composition are also disclosed.

The invention relates to the technical field of fluorescent dyes, in particular to a citric acid-based fluorescent dye for distinguishing dead cells from living cells as well as a preparation method and application of the citric acid-based fluorescent dye. The invention discloses a citric acid-based fluorescent dye for distinguishing dead cells from living cells. The citric acid-based fluorescent dye comprises at least one of a compound 1 and a compound 2, the citric acid-based fluorescent dye can specifically enter dead cells and specifically dye cytoplasm of the dead cells, so that the dead cells can be dyed or imaged. The citric acid-based fluorescent dye is difficult to dye living cells, so that dead cells and living cells can be quickly and accurately distinguished, and the citric acid-based fluorescent dye can be applied to the field of biological medicines.

The invention relates to the technical field of microbial fermentation, and particularly discloses a composite blue dye and a fermentation process thereof. According to the method, the fermentation temperature and pH are controlled, the flux of synthesized mesoscopic blue is limited, part of the flux is led to synthesis of pyridone, the mesoscopic blue in the fermentation liquor is regulated and controlled to be mixed with pyridone in a certain proportion, and the purified product mesoscopic blue is compounded with pyridone to form the composite blue dye with a stable specific color. The cost of separately purifying the ornamental blue and the pyridone and then mixing the ornamental blue and the pyridone according to a certain proportion to obtain the composite blue dye is reduced, so that the composite blue dye can be better applied to a subsequent dyeing process. According to the invention, a blue-viewing product form is added, a better dyeing effect can be achieved on the premise of not increasing the production cost, and the application market is widened.

The invention discloses a red xanthene dye for blue photoresist color paste and a synthesis method of the red xanthene dye, and the synthesis method comprises the following steps: (1) sulfonyl chlorination reaction: carrying out sulfonyl chlorination reaction on xanthene molecules B containing two sulfonate radicals by using a chlorination reagent, and carrying out post-treatment to obtain a sulfonyl chloride intermediate C; and (2) esterification reaction: carrying out esterification reaction on the sulfonyl chloride intermediate C obtained in the first step by utilizing an esterification reagent, and carrying out post-treatment to obtain the target red xanthene dye A with methacrylamide at the tail end. The invention provides a novel xanthene dye molecule which can be mixed with a blue pigment color paste to prepare a blue photoresist color paste for improving the brightness of the color paste. In addition, the liquid crystal composition has the advantages of high transparency, high contrast ratio, good dispersity, relatively high covering power, tinting strength and the like, and is good in thermal stability and light stability; meanwhile, the synthesis method provided by the invention is simple, low in cost and easy for large-scale production.

The invention relates to the technical field of chemical synthesis of dyes, and particularly discloses a 5, 5 '-disubstituted hydroxyl-3, 3'-dipyridyl derivative as well as a preparation method and application of the 5, 5 '-disubstituted hydroxyl-3, 3'-dipyridyl derivative. The structure of the 5, 5 '-disubstituted hydroxy-3, 3'-dipyridyl derivative is as shown in a formula (I) in the specification, the 5, 5 '-disubstituted hydroxy-3, 3'-dipyridyl derivative obtained by the preparation method has the advantages of high yield, stable structure, high temperature resistance and higher color development intensity, can be used as a dye to be applied to dyeing of fabrics made of different materials, and has the advantages of safe, simple and energy-saving preparation process, stable product quality and good reproducibility.

The invention belongs to the technical field of organic dye synthesis and application, and discloses a conjugated compound containing a benzothiophenazine structure as well as a preparation method and application thereof, and the conjugated compound containing the benzothiophenazine structure has excellent photophysical properties, singlet oxygen yield and superoxide anion generation capacity. The novel conjugated compounds ENBO-NI and ENBS-NI containing benzothiophenazine structures are successfully prepared by replacing a benzene ring of Nile blue with a cycloalkane structure and adjusting the electron donating ability of an R1 group. The two compounds have near infrared fluorescence emission, good solubility and relatively high ROS yield. Compared with a classical photosensitizer NB, the singlet oxygen yield of ENBO-NI is increased by about 117.65%, and the singlet oxygen yield of ENBS-NI is as high as 70%. The absorption wavelength of the conjugated compound is in a red light wave band. The preparation process is simple and efficient, large-scale production is easy, and the preparation method has a wide clinical application prospect.

The invention discloses a preparation method of a high-temperature-resistant benzidine yellow pigment, and belongs to the technical field of pigment synthesis, and the high-temperature-resistant benzidine yellow pigment is prepared by diazotizing 3, 3 '-dichlorobenzidine, coupling the diazotized 3, 3'-dichlorobenzidine with a sulfonimide modified acetoacetanilide derivative to obtain a pigment compound, and finally compounding the obtained pigment compound with sulfanilamide group grafted polyethersulfone. According to the high-temperature-resistant benzidine yellow pigment prepared by the preparation method disclosed by the invention, the high-temperature-resistant performance of the benzidine yellow pigment is remarkably improved and the use performance of the benzidine yellow pigment is improved by introducing the sulfonimide group and the polyethersulfone grafted with the sulfanilamide group for synergistic modification.

The invention belongs to the technical field of photoresists, and relates to a wide-color-gamut yellow dye for a color filter, a synthesis method of the wide-color-gamut yellow dye, a green photoresist and a preparation method of the green photoresist. The green photoresist is prepared from the following raw materials in parts by weight: 4 to 8 parts of green pigment, 3 to 8 parts of resin, 3 to 10 parts of acrylic monomer, 0.5 to 2 parts of photoinitiator, 0.2 to 0.4 part of auxiliary agent and 75 to 85 parts of organic solvent. The synthesized yellow dye has good photoresist system adaptability and high molar absorption coefficient, and meanwhile, due to the fact that acrylic acid is grafted, acrylic acid on the yellow dye has carbon-carbon double bonds, under the action of a photoinitiator, after bond breaking, the yellow dye can react with resin or an acrylic monomer and is cured in a film, and the yellow dye has good chemical resistance.

The invention discloses a near-infrared dichroic dye, a liquid crystal composition and application of the near-infrared dichroic dye and the liquid crystal composition. The structural general formula of the disclosed dichroic dye is as shown in formula I in the specification. According to the invention, a hydrogenated quinoline ring, a hydrogenated benzopyran ring and a hydrogenated naphthalene ring are introduced into a molecular skeleton, so that the novel near-infrared dichroic dye with high light stability, high solubility, high order parameter and high light modulation capability is obtained. Compared with the near-infrared dichroic dye disclosed in the prior art, the absorption band is further subjected to red shift, and the light modulation capability is remarkably improved; ordering parameters are greatly improved, and the application bottleneck is solved.

The invention discloses an ether chain modified rhodamine fluorescent dye, an ether chain modified rhodamine fluorescent dye probe and a preparation method and application thereof, through modification of an ether chain, the water solubility of the rhodamine dye is improved, the aggregation quenching effect is reduced, meanwhile, the intramolecular torsional charge transfer (TICT) is reduced through the electron withdrawing effect of oxygen atoms, and the fluorescence sensitivity is improved. Finally, the quantum yield of the rhodamine dye is greatly improved. The quantum yield of ether chain modified oxygen rhodamine water is increased from 0.31 to 0.70, and the quantum yield of silicon-based rhodamine water is increased from 0.19 to 0.41. The rhodamine dye disclosed by the invention has the characteristics of high brightness, easiness in functional derivation and the like, and has application prospects in the fields of fluorescent probes, fluorescent labels, super-resolution fluorescence imaging and the like.

The present invention addresses the problem of providing: a composition and a polymer compound which are each capable of suppressing aggregation of a dye that has a nonlinear optical effect in a nonlinear optical material, and exhibiting a higher electro-optic effect with respect to the absorbance after poling; a nonlinear optical element which is obtained using the composition; and an optical modulator which comprises the nonlinear optical element and operates on the basis of an electro-optic effect. The present invention pertains to a composition which contains a compound represented by formula (1) and a compound represented by formula (3), wherein the content of the compound represented by formula (3) is 0.0001 mol% to 25 mol% inclusive relative to the total content of the compound represented by formula (1) and the compound represented by formula (3).　(Definitions of groups are as set forth in the description.)

The invention discloses a C60-BODIPY triplet photosensitizer as well as a preparation method and photodynamic antibacterial application thereof. In the preparation process, a fullerene pyrrole ring compound and a BODIPY molecule are connected together through a benzene bridge group, and two ends of a bridge bond are respectively connected to a C atom on a fullerene pyrrole ring and a 6th site of the BODIPY molecule; a BODIPY-C60 binary molecule is formed; the preparation method comprises the following steps: reacting 9-anthracene formaldehyde with 2, 4-dimethyl pyrrole to generate a boron-dipyrromethene molecule of which the meso position is substituted by 9-anthryl, brominating the boron-dipyrromethene molecule at the 6 position by N-bromosuccinimide, coupling the boron-dipyrromethene molecule with p-formylphenylboronic acid, and carrying out Prato reaction on the coupled boron-dipyrromethene molecule with C60 and N-methylglycine to prepare the BODIPY-C60 binary triplet photosensitizer. The triplet photosensitizer has excellent photodynamic activity and relatively high reactive oxygen quantum yield, and can effectively kill bacteria.

The application relates to the technical field of microbial fermentation, and specifically discloses a kind of compound blue dye and its fermentation process. The application controls the fermentation temperature and pH, limits the flux of observing blue, makes part of the flux to the synthesis of pyridone, regulates and controls the mixed pyridone in the fermentation liquor at a certain proportion, and after purification, the product is formed into a compound blue dye with stable specific color, reduces the cost of mixing the compound blue dye at a certain proportion after separately purifying observing blue and pyridone, and makes it better applied to the subsequent dyeing process. The application increases the product form of observing blue, can achieve better dyeing effect under the premise of not increasing production cost, and widens the application market.

Provided are a novel ultraviolet absorber that has an excellent absorbing property for UV-A or UV-B, furthermore specifically absorbs only ultraviolet ray at a specific wavelength, and is capable of being used for general purposes, and an ultraviolet absorbing resin excellent in bleed-out resistance in addition to the characteristics described above. The ultraviolet absorber is a fluorene compound represented by the general formula (1) or a resin comprising the fluorene compound as a constituent unit.

The invention discloses a preparation method of gardenia blue pigment. The preparation method comprises the following steps: (1) precipitating and removing impurities by copper sulfate: precipitating and removing impurities from column liquid after gardenia yellow is extracted by copper sulfate to obtain supernate; (2) oxidizing and decoloring by potassium permanganate and removing excessive copper ions: performing neutral oxidation on the supernate by potassium permanganate to obtain decolored supernate; (3) nanofiltration concentration and spray drying: carrying out alkaline nanofiltration concentration and spray drying on the decolorized supernatant to obtain a geniposide solid crude product; (4) extracting geniposide with propyl alcohol and recrystallizing: extracting the crude product with ethyl acetate and recrystallizing to obtain a fine geniposide product; (5) ethyl acetate two-phase acid hydrolysis: carrying out ethyl acetate two-phase acid hydrolysis and recrystallization on the refined product to obtain a genipin pure product; and (6) preparing a gardenia blue pigment pure product: reacting the genipin pure product with sodium isoleucine to obtain the gardenia blue pigment. The method is simple and easy to implement, convenient to operate, outstanding in product characteristics, easy in equipment type selection and matching, low in equipment investment, high in product additional value, good in economic benefit and capable of being mechanized.

Photohardenable compositions comprising a photohardenable component and a photoswitchable photoinitiator, wherein the photoswitchable photoinitiator is activatable by exposure to light having a first wavelength and light having a second wavelength to induce a crosslinking or polymerization reaction in the photohardenable component, and wherein the photohardenable composition displays non-Newtonian rheological behavior are disclosed. Methods including such photohardenable compositions for printing one or more objects are also disclosed.

Electrically neutral complex compounds of formula I including any stereoisomer or E / Z isomer thereof wherein: M is Fe < 2 + >, Ru < 2 + >, Os < 2 + >, Co < 3 + >, Rh < 2 + >, Rh < 3 + >, Ir < 3 + >, Ni < 2 + >, Pd < 2 + >, Pt < 2 + > or Pt < 4 + >, in particular Ru < 2 + >; t and T'are H or (C1-C3)-alkyl; lig is a bidentate ligand, in particular 2, 2 '-dipyridyl (bpy) or 4, 7-diphenyl-1, 10-phenanthroline (BPhen); and A is an anion from a pharmaceutically acceptable acid, the electrically neutral complex compounds of formula I are useful in human therapy, in particular as photosensitizers (PS) in photodynamic therapy (PDT) of cancer, skin diseases, fungal infections or microbial infections. They are almost non-toxic under dark conditions at therapeutic doses and exhibit good to excellent photoactivity under hypoxic conditions. They can be used for PDT treatment of deep hypoxia tumors by using light within a far-infrared to near-infrared light treatment window.

The invention discloses a near-infrared organic fluorescent dye with mechanical responsiveness, and relates to the technical field of organic fluorescent dyes, the near-infrared organic fluorescent dye with mechanical responsiveness is prepared through seven-step reaction, an intermediate M1 containing a hydroxyl active end is firstly prepared, then intermediates M2, M3 and M4 are obtained through multi-step reaction, a target dye is obtained after purification, and finally surface functionalized nano-particles are self-assembled, so that the near-infrared organic fluorescent dye with mechanical responsiveness is obtained. The preparation method has the advantages that by designing a conjugate regulation and control structure of a rigid chromophore core and a flexible bridging unit, a mechanical response group is directionally grafted to the tail end of the flexible bridging unit through a CuAAC click chemical reaction; the problems of low fluorescence quantum yield and high response threshold caused by conjugation conflict of a traditional mechanical response group and a near-infrared chromophore are solved, the mechanical response threshold is reduced to a low stress range required by biomechanical detection, collaborative optimization of mechanical responsiveness and near-infrared fluorescence performance is realized, and the method is suitable for the fields of high-sensitivity biological stress monitoring and the like.

The present invention relates to: a novel compound having excellent carrier transport ability, light emission ability, and thermal stability; and an organic electroluminescent element having improved characteristics such as light emission efficiency, driving voltage, and lifespan by containing the compound in one or more organic material layers.

The present invention relates to: a compound for an organic optoelectronic device represented by Chemical Formula 1A or Chemical Formula 1B; and an organic optoelectronic device and a display device including the same. The detailed description of the chemical formula 1A and the chemical formula 1B is defined in the specification.

To provide a compound that exhibits absorption in the near-infrared light region and has high thermal resistance.SOLUTION: A squarylium compound represented by the following general formula (1): in the formula, L1 and L2 represent a single bond, an alkenylene group, a divalent aromatic hydrocarbon group, or a divalent aromatic heterocyclic group; R1 and R2 represent an alkyl group, alkenyl group, alkynyl group, cycloalkyl group, aromatic hydrocarbon group, or aromatic heterocyclic group; Ar1 and Ar2 represent a hydrogen atom, amino group, aromatic hydrocarbon group, or aromatic heterocyclic group; and m and n each represent an integer of 1 or 2.SELECTED DRAWING: None

The invention discloses thermochromic dye as well as preparation and application thereof, and belongs to the technical field of fine chemical engineering. The preparation method comprises the following steps: firstly, taking a fluorane dye as a raw material, and introducing an amino group into a fluorane dye structure by utilizing a reaction between lactone and alkyl diamine; and then preparing the thermochromic dye by utilizing the aldehyde amine reaction between the amino fluorane dye and the benzyloxy hydroxy benzaldehyde. The parent structure of the prepared thermochromic dye fluorane is connected with an alkyl chain and a benzylbenzaldehyde structure through a stable covalent bond, and latent heat of phase change comes from Van der Waals force between methylene on the alkyl chain and conformation overturning energy of the alkyl chain in the structure. And two benzene rings in the benzyloxy hydroxy benzaldehyde structure are used for hindering temperature crystallization below the melting point, so that the material melting and crystallization processes are regulated and controlled.

The application provides a triarylmethane derivative, a pigment dispersion liquid, a preparation method thereof and a photoresist, and relates to the field of photoresists. The structural general formula of the triarylmethane derivative is: wherein X1 is selected from one of long-chain alkyl groups with a length of C1-C12, X2 is selected from hydrogen or an alkyl group, X3 is selected from one of H, an alkyl group and an aromatic group, and Q is selected from one of a carboxyl group, a sulfonic acid group and a phosphoric acid group. The triarylmethane derivative can generate strong van der Waals force and pi-pi conjugation effect with pigment molecules in a colorant by virtue of the large-plane conjugated triarylmethane skeleton, so as to be firmly anchored on the surface of the pigment particles; the strong polar functional groups such as the sulfonic acid group in the molecular structure of the triarylmethane derivative are combined with the alkaline dispersant, the side long-chain alkyl groups fully act on the dispersion medium, and the re-aggregation of the nano pigment particles is effectively prevented through strong steric hindrance and electrostatic stabilization mechanism, so that the problem of poor dispersion stability is solved.