192 results about "Singlet state" patented technology

An organic EL device includes a pair of electrodes and an organic compound layer between pair of electrodes. The organic compound layer includes an emitting layer including a first material and a second material. The second material is a fluorescent material. Singlet energy EgS(H) of the first material and singlet energy EgS(D) of the second material satisfy a relationship of the following formula (1). The first material satisfies a relationship of the following formula (2) in terms of a difference ΔST(H) between the singlet energy EgS(H) and an energy gap Eg_77K(H) at 77K.

EgS(H)>EgS(D)  (1)

ΔST(H)=EgS(H)−Eg_77K(H)<0.3 (eV)  (2)

The invention provides an organic electroluminescent device and a display device. The organic electroluminescent device comprises an organic luminescent layer; the organic luminescent layer comprisesa main body material, a sensitizing agent material and a resonance thermally activated delayed fluorescence (TADF) material; the main body material is a broad-band gap material; the sensitizing agentmaterial is a thermally activated delayed fluorescence material; a singlet-state energy level of the thermally activated delayed fluorescence material is located between a singlet-state energy level of the broad-band gap material and a singlet-state energy level of the resonance thermally activated delayed fluorescence material; and a triplet-state energy level of the thermally activated delayed fluorescence material is located between a triplet-state energy level of the broad-band gap material and a triplet-state energy level of the resonance thermally activated delayed fluorescence material.With the organic electroluminescent device and the display device, the defects of short life time and wide spectrum of the device caused by a condition that the traditional TADF material is adopted to emit light at the present stage can be overcome.

An organic electroluminescence device includes a pair of electrodes and an organic compound layer interposed therebetween. The organic compound layer includes a plurality of emitting layers at least including a first emitting layer and a second emitting layer. The first emitting layer contains a first host material and a fluorescent first luminescent material. The second emitting layer contains a second luminescent material that is different from the first luminescent material. A difference ΔST(H1) between singlet energy EgS(H1) of the first host material and an energy gap Eg_77K(H1) at 77[K] of the first host material satisfies a specific relationship. One of the first luminescent material and the second luminescent material has a main peak wavelength from 400 nm to less than 500 nm and the other of the first luminescent material and the second luminescent material has a main peak wavelength from 500 nm to 700 nm.

The invention provides a novel OELD (Organic Electroluminescent Device). The novel OELD comprises an anode, a hole transmission layer, a luminous layer, an electronic transmission layer and a cathode which are mutually laminated, wherein the energy level difference between triplet state and singlet state of a main body material of the luminous layer is less than 0.15 eV. The invention also provides a preparation method of the OELD. The OELD provided by the invention has increased luminous efficiency by using the main body material.

The present invention relates to an organic light emission diode device (OLED) structure, especially to a high-efficiency organic light emission diode device of a B-containing compound. The organic light emission diode device structure comprises an anode, a cavity injection/transmission layer, a luminescent layer, an electron injection/transmission layer and a cathode, wherein the luminescent layer comprises main body materials and doped materials; the main body materials are formed by signal materials and are also formed by mixing materials with different structures; and the doped materials are organic compounds containing boron, the energy level difference of the singlet state and the triplet state is not larger than 0.2ev, and the energy level of the singlet state and the energy level of the triplet state of the of the main body materials are both higher than that of the doped materials to prevent energy from passback and avoid reduction of the device luminescence efficiency. The present invention further provides a preparation method of the organic light emission diode device. The preparation method is utilized to obtain the organic light emission diode device which is high in efficiency, long in life and high in purity.

The invention provides carbon quantum dots with room-temperature phosphorescence and delayed fluorescence properties. The carbon quantum dots can generate fluorescence under the excitation of ultraviolet light with the wavelength of 315-475nm, wherein the fluorescence intensity reaches the maximum when the excitation wavelength is 375nm. The particle size distribution range of the carbon quantum dots is 2-6nm. The brand-new carbon quantum dots with room-temperature phosphorescence and delayed fluorescence properties are synthesized from isocyanate under the action of microwaves. The carbon quantum dots have high yield, are oil-soluble, and can be compounded into a polymer material in situ without aggregation. The structure of the carbon quantum dots contains certain amounts of O, N and other heteroatoms with lone electron pairs, thereby increasing the transition probability from singlet state to triplet state under excitation. Meanwhile, the matrix performs the functions of reducing the nonradiative transition and quenching the triplet-state oxygen, so that the prepared carbon quantum dots have the visible stable room-temperature phosphorescence and delayed fluorescence properties in the matrix.

A singlet telescope is provided for reshaping the laser beam to a larger or smaller diameter while maintaining the inherent quality of the beam. Applications for the singlet telescope include intercavity expansion to accommodate the damage thresh-old of various components, expansion of beams to match the size of different wavelengths for final collimation, and shrinking of beams to provide high irradiance for nonlinear processes such as optical parametric oscillation and frequency doubling, with the above applications usually requiring low power magnification or demagnification. Problems involving the utilization of these telescopes over wide temperature ranges and ghost reflections in which a light is reflected back to a pumping laser are minimized with the singlet construction, with the ghost reflections potentially creating damage of components including self-damage or breakdown of air, as well as damage to a Q-switched resonator which causes pre-lasing.

An organic EL device includes a pair of electrodes and an organic compound layer between pair of electrodes. The organic compound layer includes an emitting layer including a first material, a second material and a third material, in which singlet energy EgS(H) of the first material, singlet energy EgS(H2) of the second material, and singlet energy EgS(D) of the third material satisfy a specific relationship.

An organic electroluminescent device and a method for manufacture thereof. The body material of the light-emitting layer (06) of the organic electroluminescent device is a material that the triplet state energy level of CT excited state is higher than that of n-πexcited state by 0-0.3 eV; Or, the body material of the light-emitting layer (06) is a material that the triplet state energy level of CT excited state is higher than that of n-πexcited state by more than 1.0 eV, and the difference between the second triplet state energy level of n-π excited state and the first singlet state energy level of CT excited state is -0.1-0.1 eV. A Luminescent dye is a fluorescent dye. The organic electroluminescent device can fully take advantage of the triplet state of the light-emitting layer (06), so the 100% luminescence efficiency of fluorescent device can be obtained, and the use of noble metal is avoided so as to reduce costs.

A white organic light emitting device which has high color temperature characteristics and no change in color coordinates according to luminance change, includes a first electrode and a second electrode opposite to each other on a substrate, a charge generation layer formed between the first electrode and the second electrode, a second stack including a second light emitting layer formed between the charge generation layer and the second electrode, and a first stack including a first light emitting layer formed between the first electrode and the charge generation layer, wherein the first emitting layer has low singlet-triplet exchange energy to change triplet excitons into a singlet state by triplet-triplet annihilation and a dopant concentration of the first light emitting layer is adjusted according to a luminance change curve of the second stack.

The invention provides an organic electroluminescent device and a preparation method and a display device thereof. The organic electroluminescent device comprises a luminescent layer; the luminescentlayer comprises a host material and a dye; the host material is a triplet-triplet annihilation material; the dye comprises a thermally activated delayed fluorescent material; the singlet state energylevel of the triplet-triplet annihilation material is greater than the singlet state energy level of the thermally activated delayed fluorescent material; and the triplet state energy level of the triplet-triplet annihilation material is less than the triplet state energy level of the thermally activated delayed fluorescent material. According to the organic electroluminescent device provided by the invention, the defect that the service life of the device is short due to high-energy excitons in the device at the present stage can be overcome.

The present disclosure relates to the field of organic optoelectronics. More particularly, the present disclosure relates to photovoltaic structures and to methods to produce the same. One aspect of the disclosure is a photovoltaic structure comprising:

• • an electron acceptor material, and
  • an electron donor material, wherein the electron donor material comprises:
    • a host material, and
    • a guest material,

wherein the energy of the lowest excited singlet state of the guest is smaller than the energy of lowest excited singlet state of the host, wherein the fluorescence emission spectrum of the host overlaps with at least part of the absorption spectrum of the guest and wherein the energy of the lowest excited triplet state of the guest is larger than the energy of the lowest excited triplet state of the host.

The present invention relates to an electroluminescence device based on a boron-containing organic compound, wherein a main body material comprises a first organic compound and a second organic compound, the difference between a singlet state energy level and a triplet state energy level of the first organic compound is not greater than 0.2 eV, the singlet energy level of the second organic compound is greater than the singlet energy level of the first organic compound by more than 0.1 eV, and the triplet energy level of the second organic compound is greater than the triplet energy level of the first organic compound by more than 0.1 eV; the first organic compound and the second organic compound have the different carrier transport characteristics, wherein an object material is the boron-containing organic compound, the singlet energy level of the object material is lower than that of the first organic compound, and the triplet energy level of the object material is lower than that ofthe first organic compound. An organic light-emitting device prepared by the method has the characteristics of high efficiency and long service life.

The invention relates to a singlet state oxygen generation method, and belongs to the technical field of chemical oxygen-iodine lasers. The method comprises the following steps: mixing an alkaline ionic liquid insoluble in water with an aqueous hydrogen peroxide solution to form a two phase transfer system, and reacting the transferred ionic liquid phase with chlorine to generate singlet state oxygen in order to realize water and singlet state oxygen isolation. The method is helpful for reducing the quenching effect of water on singlet state oxygen, and reduces the content of water in the singlet state oxygen, and the alkaline ionic liquid has an enrichment effect on hydrogen peroxide to make effective solving of the bottleneck problem of hydrogen peroxide concentration restriction in the raw material regeneration process of chemical oxygen-iodine lasers under traditional technological conditions be possible, so the method is of great significance to improve the singlet state oxygen yield of the chemical oxygen-iodine lasers, reduce the water content of the singlet state oxygen and solve the raw material regeneration problem.

The invention discloses a malononitrile-substituted aryl anthracene-phenanthrene organic electroluminescent material and a preparation method and application thereof. The organic electroluminescent material uses malononitrile-substituted aryl anthracene-phenanthrene as a parent nucleus and a structural formula of the organic electroluminescent material is as shown in a formula (I). The malononitrile-substituted aryl anthracene-phenanthrene organic electroluminescent material provided by the invention is simple in preparation process; HOMO and LUMO energy level electron cloud can be effectivelyseparated; a singlet state and triplet state energy gap (delta EST) is small; triplet-state excitonic luminescence can be converted into singlet-state excitonic luminescence by RIST (Reverse InterSystem Traversing); the malononitrile-substituted aryl anthracene-phenanthrene organic electroluminescent material has the thermal activation delayed fluorescence property; when the malononitrile-substituted aryl anthracene-phenanthrene light-emitting material provided by the invention is applied to an OLED (Organic Light-Emitting Diode) light-emitting device, high device efficiency is obtained. (theformula (I) is shown in the specification).

The invention discloses an organic electroluminescent device. A light-emitting layer comprises a host material and a guest material. The host material is an exciplex formed by an electron donor material and an electron acceptor material, and the guest material is a thermally activated delayed fluorescent material. The singlet-state energy level of the host material is lower than the singlet-stateenergy level of the guest material. Since the singlet-state energy level of the exciplex as the host material in the light-emitting layer is lower than the singlet-state energy level of the thermallyactivated delayed fluorescent material, the generation of high-energy excitons is prevented, and molecular bond breakage due to high excitation energy is effectively suppressed. The singlet-state energy level of the exciplex is low, which is beneficial to reduce the excitation energy of the excitons in the device, and suppress the triplet state-triplet state annihilation, the triplet state-polaronquenching and the singlet state-triplet annihilation phenomena in the device, thereby reducing the efficiency roll-off of the device and prolonging the service life of the device.

The invention discloses a fused ring compound, which has a structure shown as a formula (I) or a formula (II). The effective conjugation of aromatic rings and heterocyclic rings is controlled in the fused ring compound; the hole performance is improved; meanwhile, the electronic transmission performance is favorably balanced; the compound has high triplet state energy level and glass transition temperature; material molecules cannot easily crystallize; when the fused ring compound is used as a luminescent layer host material, the efficient transfer of energy to guest materials can be guaranteed. The substituent group of the fused ring compound is regulated, so that the electron and hole transmission performance is further improved; the singlet state and triplet state energy level difference is reduced; the compound region of carriers is expanded; the triplet state exciton annihilation is prevented. The invention also discloses an organic electroluminescence device; at least one function layer contains the fused ring compound; the fused ring compound is used as the host material of the luminescent layer and is matched with the adjacent carrier transmission layer energy level; the luminous efficiency of the device is improved; meanwhile, the driving voltage of the device is reduced.

The invention provides a conjugated polymer and a preparation method thereof. The polymer provided by the invention has a structure represented by a formula (I). The energy level difference between the first excitation singlet state and the first excitation triplet state of the polymer is relatively low, such that the polymer has E-type delayed fluorescence emission. The polymer has good luminescence properties when applied in electroluminescent devices.

This invention relates to an organic electroluminescent element comprising a substrate, an anode, an organic layer and a cathode placed in layer one upon another; at least one layer in the organic layer is a luminescent layer comprising a host agent and a doping agent and an azole compound having an oxadiazole structure and a triazole structure in its molecule is used in at least one layer in the organic layer. This azole compound is used as a host agent in the luminescent layer and it can also be used in a hole blocking layer or electron transporting layer. This organic EL element is suitable for use in full-color and multicolor panels and shows a higher luminous efficiency and better driving stability than EL elements utilizing the luminescence from the singlet state.

The invention provides an electroluminescent compound, an OLED display panel and electronic equipment. The electroluminescent compound is provided with a structure of a formula (I); the OLED display panel comprises an anode, a cathode and at least one organic film layer positioned between the anode and the cathode, and the organic film layer comprises a luminescent layer; the luminescent layer comprises any one or a combination of at least two of the electroluminescent compounds; and the electronic equipment comprises the OLED display panel. The electroluminescent compound provided by the invention has an energy electrode difference Delta Est between the lowest singlet state S1 and the lowest triplet state T1, wherein the Delta Estwhich is equal to ES1 minus ET1 being less than or equal to0.30 eV, and even the Delta Est which is equal to ES1 minus ET1 being less than or equal to 0.15 eV; and the electroluminescent compound has an TADF (Thermal Activation Delayed Fluorescence) materiallight-emitting mechanism, can be used in the field of organic photoelectric devices, and improves light-emitting efficiency, so thatthe electronic equipment comprising the electroluminescent compoundhas more excellent performance.

The invention discloses a red light organic electroluminescence device including a substrate, and a first electrode, a light emitting layer and a second electrode layer formed on the substrate in sequence. The light emitting layer includes body material and red phosphorescence dye. The body material includes first body material and second body material. The doping proportion of the second body material is 5 to 50 wt%. The doping proportion of the first body material is 50 to 95wt%. The triplet state energy level of the first body material T1<H1> is greater than 2.7eV while the wide energy gapEg is greater than 3.0 eV. According to the invention, by utilizing the extremely small energy level difference between the triplet state and the singlet state of thermal activation delayed fluorescence material, excitons on the T1 of the body can be transferred to S1 of the body quickly, so that the singlet state excitons and the triplet state excitons can be utilized effectively. Then through Forest energy transfer to phosphor material T1, device efficiency is improved to 18% to 23%.

The invention provides an organic electroluminescence device and a display device. The organic electroluminescence device comprises an organic luminescent layer, wherein the organic luminescent layercomprises a main body material and a resonant thermal activation delayed fluorescence material; the main body material is an exciplex; the singlet state energy level of the exciplex is greater than that of the resonant thermal activation delayed fluorescence material, and the triplet state energy level of the exciplex is greater than that of the resonant thermal activation delayed fluorescence material. The organic electroluminescence device can overcome the defects of short device lifetime and wide spectrum caused by the fact that a traditional TADF material is used for luminescence at the present stage.

Novel hydrocarbons which are excellent in heat resistance and light resistance and in solubility in organic solvents and which exhibit high energy levels of excited singlet and triplet states and wide electric oxidation-reduction potentials have partial structures represented by the general formula (I) in the molecule: (I) wherein G is a substituent represented by the general formula (II); and R<1> and R<2> are each independently an arbitrary hydrocarbon group, with the proviso that the benzene ring to which R<1>, R<2> and G are bonded has no substituent except R<1>, R<2> and G: (II) wherein R<3> to R<5> are each independently hydrogen or an arbitrary hydrocarbon group, with the proviso that the terphenyl group in the general formula (II) has no substituent except R<3> to R<5>.