The invention discloses a preparation method and application of a spirofluorene
xanthene-based grignarene fluorescent material. [spirofluorene
xanthene-
fluorobenzene]-based grignarene (G-DSFX) is synthesized by adopting a C-H bond activation gridding method. The optimal
reaction conditions are as follows: the catalyst is
palladium acetate Pd (OAc), the ligand is tri-tert-butylphosphine
tetrafluoroborate PtBu2Me-HBF4, the alkali is
potassium carbonate K2CO3, the
solvent is N, N-
dimethylacetamide DMAc, the temperature is 120 DEG C, the reaction is performed for 48 hours, the reaction concentration is 20 mmol. L <-1 >, and the yield is as high as 19%. The
OLED is prepared by adopting a solution
processing method, I-shape, U-shape, m-shape and G-DSFX are used as
OLED light-emitting
layers for device testing by utilizing the solution
processing method, and turn-on voltages are 3.9 V, 6.9 V, 4.5 V and 6.4 V respectively; the maximum brightness is 67.9 cd.m <-2 >, 56.69 cd.m <-2 >, 45.43 cd.m <-2 > and 72.2 cd.m <-2 > respectively; the maximum external
quantum efficiency EQEmax is 0.08%, 0.06%, 0.03% and 0.15%, which proves that the lattice strategy can also improve the brightness and the external
quantum efficiency of the device, and provides a reference for preparing an
OLED by a solution
processing method.