70results about How to "Reduced bandgap width" patented technology

The invention discloses a condensed-ring compound and a preparation method and an application thereof. The condensed-ring compound has a structure represented by formula (I) or formula (II). The HOMOand LUMO energy levels of the fused-ring compound are completely separated, so that the energy gap width of the material is reduced, the three-wire energy level is improved, and the energy backflow from the object material to the main material is avoided to reduce the luminous efficiency; HOMO and LUMO energy levels are matched with adjacent materials, and the driving voltage is small. The devicehas large molecular structure size and good intramolecular conjugation, so it has good thermal stability, can avoid thermal decomposition of materials during film formation or use, avoids loss of material layer function, and improves luminous efficiency and luminous performance of the device. The invention also provides a preparation method of the fused-ring compound and its application as an organic electroluminescent material.

The invention discloses a modified graphite phase carbon nitride photocatalyst as well as a preparation method and application thereof. The modified graphite phase carbon nitride photocatalyst is prepared from urea and salicylic acid serving as raw materials by virtue of calcination, wherein a mass ratio of urea to salicylic acid is 1:(0.002-0.02). The modified graphite phase carbon nitride photocatalyst disclosed by the invention has the advantages of being high in specific surface area, wide in light absorption range, low in electron-hole pair recombination rate, excellent in photocatalyticperformance and the like, and has multiple reactive sites, excellent application value and application prospects. The preparation method has the advantages of being simple in process, wide in raw material source, low in cost, high in preparation efficiency, high in yield and the like, is suitable for large-scale preparation and is favorable for industrial production. The modified graphite phase carbon nitride photocatalyst disclosed by the invention can be used for degrading organic pollutants, has the advantages of being simple in process, convenient to operate, low in cost, high in treatmentefficiency, excellent in degradation effect and the like, and has excellent effects of degrading the various organic pollutants.

The invention discloses a copolymerization-modified graphite-phase carbon nitride hollow ball visible-light-driven photocatalyst as well as a preparation method and an application thereof and belongs to the technical fields of material preparation and photocatalysis. A carbon nitride hollow ball is synthetized by taking cyanamide and a small organic molecule monomer as precursors, a mesoporous silicon dioxide ball as a template and through the steps of thermal polymerization and template removing. The copolymerization-modified graphite-phase carbon nitride prepared by adopting the method disclosed by the invention is shaped like a hollow ball and is uniform in grain size and proper in band gap; compared with traditional-phase carbon nitride, the graphite-phase carbon nitride is capable of effectively increasing the specific surface area and increasing the utilization rate of sunlight and has the efficient photocatalytic hydrogen generation performance in visible light. The visible-light-driven photocatalyst disclosed by the invention is simple in synthetic process, low in cost and high in catalytic efficiency, meets the actual production requirements and has the broad application prospect in the photocatalysis field.

The invention discloses a preparation method of metastable phase bismuth oxide and application thereof in photocatalytic degradation of organic pollutants. The preparation method comprises the following steps: carrying out hydrothermal reaction on an aqueous solution which contains ammonium bismuth citrate, urea and hexadecyl trimethyl ammonium bromide to obtain bismuthyl carbonate microflowers; and calcining the bismuthyl carbonate microflowers in an air environment to obtain the metastable phase bismuth oxide beta-Bi2O3/Bi2O2.33@Bi2O2CO3. The preparation method is simple and controllable to operate, and is environmentally friendly. The synthesized metastable phase bismuth oxide has the advantages of visible-light response, large specific surface area, high catalytic activity and the like, has the characteristics of rapidness and high efficiency in a process of visible-light catalytic degradation of the organic pollutants, and can be widely applied to the technical field of treatment of the organic pollutants.

The invention discloses a method for treating organic pollutants and photocatalytic sterilization by using a modified carbon quantum dot loaded hollow tubular carbon nitride photocatalyst, which comprises the following steps: the modified carbon quantum dot loaded hollow tubular carbon nitride photocatalyst and organic pollutant wastewater or bacteria solution are mixed for photocatalytic treatment to finish the treatment of the organic pollutant or bacteria, the modified carbon quantum dot loaded hollow tubular carbon nitride photocatalyst is prepared by taking hollow tubular carbon nitride as a carrier and the carrier is loaded with modified carbon quantum dots, wherein the hollow tubular carbon nitride is prepared from urea and melamine in a molar ratio of 1-5:1 and melamine through hydrothermal treatment and calcination. The method has the advantages of simple process, convenient operation, simple equipment, low cost, high treatment efficiency/photocatalysis efficiency, good removal effect/sterilization effect, cleanness, no pollution and the like, and has high application value and commercial value.

The invention discloses a preparation method of a polypyrrole graphite-phase carbon nitride composite material for treating uranium-containing wastewater through photocatalytic reduction and an application thereof. The preparation method comprises the following steps: calcining melamine to obtain graphite phase carbon nitride, mixing and oscillating the graphite phase carbon nitride and sodium dodecyl benzene sulfonate, adding pyrrole with different mass ratios, filtering, washing with water, and drying to obtain the polypyrrole=graphite phase carbon nitride composite material; adjusting the pH value of the uranium-containing wastewater to 4-7, adding the composite material as a uranium removal agent into the uranium-containing wastewater, placing the uranium-containing wastewater in a dark box environment, introducing nitrogen, stirring, irradiating the stirred solid-liquid mixture with a xenon lamp, filtering the irradiated hexavalent uranium-containing wastewater, taking the filtered clear liquid, and calculating the removal rate of uranium in the uranium-containing wastewater. The polypyrrole-graphite-phase carbon nitride composite material prepared by the method is good in catalytic activity in a visible light region, low in cost, simple to operate, relatively high in uranium-containing wastewater removal rate, remarkable in adsorption effect and relatively good in economic benefit.

The invention discloses a method for producing an H-occupied BiVO4-OVs photocatalytic material and application of the H-occupied BiVO4-OVs photocatalytic material. The production method comprises thesteps of dissolving a certain molar weight of Bi(NO3)3.5 H2O in glycerin; dissolving a certain molar weight of NaVO3.2 H2O in deionized water; mixing solutions; transferring a mixed solution into a teflon-lined high-pressure kettle, and maintaining 180 DEG C for 8 h; conducting 10000-rpm centrifugal separation on a solvothermal synthesis product, washing the solvothermal synthesis product subjected to 10000-rpm centrifugal separation with deionized water and ethyl alcohol, and drying the washed solvothermal synthesis product subjected to 10000-rpm centrifugal separation at 60 DEG C for 4 h; calcining the solvothermal synthesis product, which is thoroughly washed, in a muffle furnace at 300 DEG C for 5 h; and conducting annealing on a calcined product in an Ar/H2 atmosphere at 350 DEG C for10 h to obtain the H-occupied BiVO4-OVs photocatalytic material. The H-occupied BiVO4-OVs photocatalytic material has the advantages that a photoresponse range is wide, the catalytic activity is high, the degradation rate is high, and the hydrolysis ability is high; and solar energy can be fully and effectively used.

Belonging to the technical field of photocatalysis, the invention discloses a reducing carbon nitride photocatalyst, a preparation method and application thereof. The photocatalyst is prepared by thesteps of: heating melamine to 520-550DEG C, performing roasting, and conducting grinding to obtain g-C3N4 powder; mixing NaBH4 with g-C3N4 powder, and then performing heating to 570-600DEG C in a protective atmosphere; and performing cooling, then cleaning the product with deionized water and ethanol, and conducting drying. The reducing carbon nitride catalyst does not contain metal, and has the advantages of environmental protection, stability, low cost and the like. According to the invention, reducing carbon nitride is applied to photocatalytic degradation of diclofenac sodium for the firsttime, also shows excellent photocatalytic performance, and has good stability.

The invention discloses a method for preparing a composite nano Tb/BiOCl material. The method comprises the following steps: firstly, putting potassium chloride into ethylene glycol so as to form a solution A; putting bismuth nitrate pentahydrate into ethylene glycol so as to form a solution B, and dropping the solution A into the solution B one droplet by one droplet till the ratio of n(Bi) to n(Cl) is 1:1; after dropping is completed, continuously stirring, adding terbium nitrate, and performing ultrasonic oscillation so as to obtain a mixed solution; transferring the mixed solution into a reaction kettle, sealing, and putting into an oven for reactions; after the reactions are completed, naturally cooling the reaction kettle to the room temperature, collecting solid precipitate, washing, and drying, thereby obtaining the composite nano Tb/BiOCl material. The composite nano Tb/BiOCl material prepared by using the method has relatively good catalytic degradation properties upon methylorange under visible light.

The invention relates to a method for treating hexavalent chromium-containing wastewater by photocatalytic reduction of a nickel oxide-nickel cobaltate-black titanium dioxide compound. The method comprises the following steps: preparing black titanium dioxide, dissolving cobalt nitrate hexahydrate, nickel nitrate hexahydrate and the black titanium dioxide in a proper amount of deionized water, magnetically stirring to form a uniform solution, adding a proper amount of polyvinylpyrrolidone (PVP, K30) into the solution, and stirring the suspension with a magnetic stirrer for at least 1 hour; dispersing urea into the suspension, grinding powder, and calcining the powder in a tubular furnace in air at 500 DEG C for 2 hours to obtain the nickel oxide-nickel cobaltate-black titanium dioxide compound; adding the nickel oxide-nickel cobaltate-black titanium dioxide compound into the hexavalent chromium-containing wastewater; taking out the mixture at a certain time interval, immediately filtering, measuring the concentration of the treated hexavalent chromium at 540nm by using an ultraviolet-visible spectrophotometer according to a 1, 5-diphenylcarbazide method, and calculating the removalrate. The method has the advantages of high removal rate, low treatment cost, environmental friendliness and the like.

The invention discloses an organic light-emitting material with a bithiophene pentalene derivative structure and an organic light-emitting device of the organic light-emitting material, and belongs to the technical field of organic photoelectric materials. According to the organic light-emitting material with the bithiophene pentalene derivative structure and the organic light-emitting device of the organic light-emitting material, 4-H-cyclopentadiene bithiophene-1,1,7,7-tetroxide is adopted as a body structure, and through connection of ligand genes with different polarities, the obtained derivative has strong eletrophilicity, charge transferring capacity and light-emitting performance. In the organic light-emitting device prepared through the bithiophene pentalene derivative, the light-emitting efficiency is high, the pohotochromism is uniform, and the organic light-emitting device has good film stability and thermal stability, and the problem that a unipolarity transmission material in the organic light-emitting device is unbalanced in current carrier can be effectively solved.

A one-step method for preparing a GQDs modified flaky TiO2/g-C3N4 heterojunction composite material comprises the following steps: (1) sequentially adding acetylacetone and tetrabutyl titanate into absolute ethyl alcohol to obtain a solution A; (2) adding polyvinyl pyrrolidone into the solution A to obtain a solution B after complete dissolution; (3) adding a proper amount of melamine powder intothe solution B to obtain a solution C after complete dissolution; (4) adding graphene quantum dot powder into the solution C, and ultrasonically dispersing for 24 hours to obtain a mixed solution D; (5) filling the mixed solution D into a syringe, performing electrostatic spinning under certain conditions, and collecting a spinning product by using a stainless steel disc; AND (6) after the spinning product is dried, roasting the spinning product for 4 hours at 550 DEG C in an air atmosphere. The one-step method has the characteristics of simple and quick method, low cost, improved spectral response range, reduced photogenerated electron-hole recombination rate, large specific surface area and the like, and is widely applied to photocatalytic degradation of pollutants.

The invention discloses preparation and application of an Ag-doped CdSe nanosheet photocatalytic material for uranium reduction separation. The preparation method comprises the steps of mixing mixed powder of CdCl2. 5H2O and AgNO3 with a first mixed solvent of octylamine and oleylamine, carrying out heating reaction, and cooling to room temperature to obtain a reaction solution; mixing Se powder with a second mixed solvent of octylamine and oleylamine at room temperature to obtain a Se precursor solution; and adding the Se precursor solution into the reaction solution, carrying out heating reaction, cooling, cleaning the obtained precipitate with a trichloromethane solution for multiple times, uniformly mixing the precipitate with a cetyltrimethylammonium bromide solution, and carrying out ultrasonic treatment, ethanol washing and drying to obtain the Ag-doped CdSe nanosheet photocatalytic material for uranium reduction separation. According to the Ag-doped CdSe nanosheet photocatalytic material disclosed by the invention, photocatalytic reduction of U (VI) is met while the light absorption capacity is improved, and generation and use of photon-generated carriers are facilitated.

The invention discloses a preparation method of tubular g-C<3>N<4> with a visible-light response function and belongs to the field of photocatalytic semiconductor material preparation technologies. The preparation method comprises the steps that (1) melamine and cyanuric acid are mixed and dissolved in ultrapure water according to an arbitrary proportion, magnetic stirring is performed, and a uniform mixed solution is formed; (2) then, the solution is transferred to a stainless steel autoclave for a reaction, and a precursor of a synthetic product is obtained; (3) the obtained precursor is dried after being washed with ultrapure water; and (4) after the dried precursor is calcined in nitrogen, the tubular g-C<3>N<4> with the visible-light response function is obtained. According to the preparation method, the one-dimensional tubular g-C<3>N<4> is prepared through high-temperature calcination, band gap width of the tubular g-C<3>N<4> is remarkably reduced, visible-light response of thetubular g-C<3>N<4> is improved, and the charge transport capability of the tubular g-C<3>N<4> is enhanced through a tube separation mode; and application of the tubular g-C<3>N<4> with the visible-light response function in the photocatalytic field comprises degradation, hydrogen production, nitrogen fixation, bacterial resistance and the like.

The invention discloses a silicon heterojunction solar cell and a manufacturing method thereof, and relates to the technical field of solar cells. The invention aims to inhibit epitaxial growth of a silicon substrate interface by using an intrinsic amorphous silicon germanium layer and improve the passivation effect of the silicon substrate interface by using an intrinsic amorphous silicon layer.The silicon heterojunction solar cell comprises: an N-type silicon substrate; an intrinsic amorphous silicon germanium layer formed on one surface of the N-type silicon substrate; a first intrinsic amorphous silicon layer formed on the intrinsic amorphous silicon germanium layer; and a P-type doped amorphous silicon layer formed on the first intrinsic amorphous silicon layer. The manufacturing method of the silicon heterojunction solar cell is used for manufacturing the silicon heterojunction solar cell.

The invention relates to an yttrium oxide-ferric oxide composite nano antibacterial material. The preparation method comprises the following steps: uniformly dispersing nano ferric oxide obtained by hydrothermal synthesis into a yttrium oxide synthetic system, carrying out reaction in a high-pressure reaction kettle, carrying out centrifugal separation to obtain a precipitate, and drying over night to obtain a yttrium oxide-ferric oxide composite; sterilizing the nano material by anhydrous ethanol, centrifugating, removing the supernate, adding water, and sufficiently mixing uniformly; adding the yttrium oxide-ferric oxide composite material with unequal concentrations into test tubes with a certain concentration of Escherichia coli and staphylococci, and respectively carrying out shake culture in the light and dark for some time; and analyzing the inhibition efficiency of the nano material for Gram-negative bacteria and Gram-positive bacteria by a plate counting process. The yttrium oxide-ferric oxide composite material has favorable inhibition effects on both Gram-negative bacteria and Gram-positive bacteria, and especially has very high inhibition efficiency for Gram-negative bacteria. The yttrium oxide-ferric oxide composite material is environment-friendly, and can not cause the problem of bacterial drug resistance and the like.

The invention relates to a photocatalytic material and a preparation method and a fabric thereof. The preparation method for the photocatalytic material comprises the following steps: a graphene oxidesolution is provided; thermal reduction treatment is carried out for the graphene oxide solution, so that a graphene solution is obtained, the concentration of graphene in the graphene solution is 10mg/mL to 20mg/mL, and the oxygen content of the graphene is 5 to 10 percentage by weight; the graphene solution is added with hydrated titanium dioxide and is subjected to homogenization treatment, sothat mixed liquid is obtained; and a spray dryer is adopted to carry out spray-drying for the mixed liquid, so that the photocatalytic material is obtained. The graphene and the titanium dioxide nanoparticles are combined to form the photocatalytic material, and voids exist between the graphene and the titanium dioxide nanoparticles. Because the photocatalytic material which is formed by combining the graphene and the titanium dioxide nanoparticles can be obtained by the preparation method, the photocatalytic effect of the titanium dioxide nanoparticles can be effectively improved, and thereby the photocatalytic material can effectively degrade polluting gas in the environment when being applied to fabrics.

The invention relates to a defect-state TiO2/Fe3O4 composite nanofiber material and a preparation method thereof, and belongs to the technical field of materials. The preparation method of the material comprises the following steps: firstly, dispersing a titanium source, an iron source and a high-molecular polymer in a solvent to prepare a stable and uniform solution; then preparing the solution into a nanofiber membrane through an electrostatic spinning technology; and calcining the nanofiber membrane, grinding the calcined material and sodium borohydride, and reducing in a nitrogen atmosphere to obtain the defect-state TiO2/Fe3O4 composite nanofiber material. The method is simple to operate, easy to control, environment-friendly and capable of realizing continuous production, and the obtained defect-state TiO2/Fe3O4 composite nanofiber material has good crystallinity and photoresponsiveness and has excellent degradation performance on organic pollutants in a water environment.

The invention relates to preparation and application of an yttrium oxide-ferroferric oxide composite nanometer antibacterial material. Preparation of the yttrium oxide-ferroferric oxide composite nanometer antibacterial material includes the following steps that nanometer iron oxide obtained through hydro-thermal synthesis is uniformly dispersed into an yttrium oxide synthesis system, a reaction is conducted in a high-pressure reaction kettle, precipitate is subjected to centrifugal separation and dried and stays overnight, and an yttrium oxide-ferroferric oxide compound is obtained; a nanometer material is subjected to sterilization with absolute ethyl alcohol, then supernatant is removed through centrifugation, then water is added, and the mixture is fully and uniformly mixed; yttrium oxide-ferroferric oxide compound materials of different concentrations are added into a test tube of escherichia coli and staphylococcus of a certain concentration and subjected to shake cultivation under the light or in dark for certain time; and then inhabitation efficiency of the nanometer material to the gram-negative bacterium and the gram-positive bacterium is analyzed through a plate count method. The compound material has a good inhabitation effect on both the gram-negative bacterium and the gram-positive bacterium, particularly on the gram-negative bacterium, is environmentally friendly and cannot cause antibiotic resistance in bacteria and other problems.

The invention discloses a gating tube with a superlattice-like structure and a preparation method of the gating tube, and belongs to the technical field of micro-nano electronics. The gate tube comprises a substrate, and a first metal electrode layer, a superlattice-like layer and a second metal electrode layer which are sequentially stacked on the substrate; the superlattice-like layer comprisesn + 1 first sub-layers and n second sub-layers which are periodically and alternately stacked, the material of the first sub-layers comprises GeS or GeSe, and the material of the second sub-layers comprises one of GeTe, ZnTe, AlTe, SiTe, BTe or CTe. Due to the fact that the GeS material and the GeSe material have high stability, diffusion separation of Te in the second sub-layer material caused byhigh temperature can be prevented. Meanwhile, each sub-layer of the superlattice-like structure is very thin, the coupling between adjacent wells is very strong, periodic quantum potential wells areformed in the superlattice-like layer, and the original discrete energy levels in the quantum wells are expanded into energy bands, so the band gap width can be reduced, the power consumption is reduced, and the superlattice-like structure can be better integrated with a memory device unit.

The invention relates to the technical field of photocatalyst spray, and discloses photocatalyst spray for air purification, which is prepared from the following raw materials in parts by weight: 1 to10 parts of I-TiO2, 1 to 5 parts of nano titanium dioxide, 5 to 15 parts of polyethylene glycol, 5 to 20 parts of glycerol, 1 to 5 parts of tourmaline powder, 5 to 10 parts of nano silicon dioxide and 1 to 8 parts of nano silver. According to the photocatalyst spray, effects of the spray after iodine doping is superior to that of a pure TiO2 photocatalyst; the main reason is that on one hand, a new energy level can be introduced into a TiO2 energy band gap by an iodine element so that the band gap width of TiO2 is reduced and TiO2 surface properties and effects of enhancing photo-induced electron hole pair separation are achieved; on the other hand, impurity replacement is carried out after iodine enters TiO2 crystal lattices, so that oxygen vacancies and defects of photo-induced electroncenters capable of generating strong-oxidation active particles on the surface of TiO2 are increased, and the active effect of the photocatalyst is enhanced.

The invention provides a high-In-composition InGaN/GaN quantum well structure solar cell based on a self-supporting GaN substrate and a preparation method thereof. The solar cell is composed of the self-supporting GaN substrate, a GaN buffer layer, an n-type doped GaN layer, a high-In-composition InGaN/GaN quantum well layer, a p-type doped GaN layer and a P-type electrode which are laminated in turn. An epitaxial layer is grown by adopting the self-supporting GaN substrate, and high In composition is adopted in the quantum well layer; an n-type doped GaN layer mesa is manufactured by adopting a dry etching method, and an N-type electrode is formed on the mesa; and the P-type electrode is formed on the p-type doped GaN layer by adopting the methods of photoetching and film coating. Performance of the solar cell can be greatly enhanced; and crystal lattice mismatching can be effectively reduced by adopting the self-supporting GaN substrate, and high-quality high-In-composition InGaN is grown by adopting an RF-MBE technology so that light absorption range of the solar cell can be greatly enhanced.

The invention provides an iron oxide doped mixed crystal form titanium dioxide nano-net photocatalytic composite material. A preparation method comprises the steps of placing a titanium mesh as an anode and a platinum sheet as a cathode in an electrolyte for an anodic oxidation reaction so that a titanium dioxide nano-mesh array of a titanium mesh substrate is obtained, placing the titanium dioxide nano-net array of the titanium net substrate in an ethanol solution dissolved with ferric chloride for dipping treatment, taking out the titanium dioxide nano-net array, drying the titanium dioxidenano-net array, and then carrying out heat treatment to obtain the ferric oxide doped mixed crystal form titanium dioxide nano-net photocatalytic composite material. An ethanol solution of ferric chloride is used as an iron source for doping, amorphous titanium dioxide does not fall off in ethanol, and ferric oxide is generated after a thermal reaction of ferric chloride. Iron oxide is deposited on the titanium dioxide nano-net, a part of crystal lattices are occupied, the band gap width of TiO2 can be changed, and the photocatalytic activity is improved, and meanwhile, the product is of a net-shaped thin film structure, so that the use is convenient and secondary pollution is avoided.