990 results about "Photogenerated electron" patented technology

A bias-free driven ion-based photoelectrochemical wastewater treatment system and method is disclosed. Through an ion-coupled photogenerated electron-assisted photocatalytic oxidation-reduction pathway, the system achieves efficient treatment of high-salinity wastewater. The system employs electron-ion receptor materials as the counter electrode, providing reaction sites to drive the coupling of photogenerated electrons and cation transfer. Additionally, the voltage generated by the system directly drives hole oxidation to produce strong oxidizing free radicals. Furthermore, this ion-based photoelectrochemical system demonstrates excellent degradation performance in high-concentration chloride media. This indicates that, in addition to cations (such as Na+) helping to accelerate the electron transfer rate, the presence of Cl− further enables efficient and sustainable wastewater treatment. The concept proposed in this invention emphasizes the potential for using abundant sodium chloride in seawater as an inexpensive additive for wastewater treatment.

The invention discloses a magnetic visible light photocatalyst ZnFe2O4 / MXene as well as a preparation method and application thereof, and belongs to the technical field of photocatalytic materials. According to the specific technical scheme, the preparation method comprises the following steps: fully dissolving a zinc source and an iron source in a solvent under the ultrasonic action, adding a morphology regulator, and preparing magnetic ZnFe2O4 through a hydrothermal method; then a two-dimensional material MXene with high conductivity is introduced to promote separation and migration of ZnFe2O4 photo-induced electrons and holes and inhibit compounding of the ZnFe2O4 photo-induced electrons and holes, so that the photocatalytic efficiency is improved, and the magnetic visible light photocatalyst ZnFe2O4 / MXene is prepared. The prepared photocatalyst is easy to recover, has the advantage of rapidly degrading organic pollutants, and has a good application prospect in the aspect of treatment of organic wastewater such as dyeing wastewater and medical wastewater.

The invention discloses a novel photocatalyst for producing hydrogen from organic matter wastewater and a preparation method of the novel photocatalyst, and relates to the technical field of photocatalysis. The photocatalyst disclosed by the invention is combined with oxidation-reduction capability, and can effectively degrade and produce hydrogen under the irradiation of sunlight. Through combination of quaternized porous tungsten oxide and vanadate radicals, silver vanadate load growth is promoted, the sunlight utilization rate is increased, and the electron-hole recombination rate is reduced. Reduced graphene oxide is used for pretreatment, active groups are introduced, the reduced graphene oxide is compounded with tungsten oxide / silver vanadate, the binding force is enhanced through heat treatment, photo-induced electron-hole pair compounding is inhibited through the conductivity, and the visible light catalytic performance is improved. The adsorption effect of porous tungsten trioxide and reduced graphene oxide can accelerate the degradation of organic matters. By optimizing the proportion of silver vanadate, tungsten oxide and reduced graphene oxide, the visible light response and charge separation efficiency are enhanced, the degradation and hydrogen production performance is improved, and light corrosion is reduced.

The invention relates to the technical field of photocatalysis, in particular to a defect-state titanium dioxide supported catalyst, a preparation method and application of the defect-state titanium dioxide supported catalyst in a reaction for co-converting methane and carbon dioxide. The defect-state titanium dioxide supported catalyst comprises a carrier and metal Au supported on the surface of the carrier; the carrier is a defect-state titanium dioxide nanosheet with oxygen vacancies. According to the invention, the defect-state titanium dioxide nanosheet is used as a carrier, and after metal particles (Au) are loaded, the metal particles are used as capture centers of photo-induced electrons to promote spatial separation of photo-induced electron-hole pairs. In addition, the formed metal-carrier interface site effectively enhances the adsorption and activation of CH4 and CO2 by the photocatalyst. Moreover, the loaded high-electronegativity metal Au can also be used as a coupling site of methyl, so that high-yield C2H6 is obtained, and meanwhile, a corresponding CO product is obtained.

The invention belongs to the technical field of sewage treatment, and particularly relates to an anaerobic ammonia oxidation-photoelectric denitrification deep nitrogen removal method. The method comprises the following steps: firstly, adopting a double-chamber reactor; introducing part of sewage into the cathode chamber, carrying out Anammox reaction under a dark state condition to remove ammonia nitrogen and part of nitrite nitrogen, and synchronously generating nitrate nitrogen; turning on a light source to irradiate the anode chamber, exciting photo-induced electrons by a photosensitizer, transmitting the photo-induced electrons to the cathode chamber through an external circuit, and driving the sulfur autotrophic denitrification sludge to reduce residual nitrite nitrogen and nitrate nitrogen generated by Anammox; the total nitrogen removal rate is close to 100%. According to the invention, photo-induced electrons are used as the only denitrification electron donor, so that the addition of a carbon source / sulfide is thoroughly avoided, and the risk of secondary pollution is eliminated. The method is suitable for green low-carbon deep treatment of sludge digestion liquid and pharmaceutical wastewater high-ammonia-nitrogen low-carbon-nitrogen-ratio sewage.

The invention relates to a K / O co-doped and cyano-grafted graphite phase carbon nitride material as well as a preparation method and application thereof. The material comprises three defect types, namely a C-O-C bond formed by a C-N = C bond in an oxygen substituted triazine skeleton, potassium ions existing between layers and cyano groups generated by protonation of amino groups at the edge. According to the material disclosed by the invention, K ions are doped into the g-C3N4 layer to form K-N bridge connection between layers, the material can be used as an electron channel to effectively accelerate electron migration, cyano groups at the edge have relatively strong electron-withdrawing capability and can be used as sites for adsorbing hydrogen ions, and introduced oxygen can be used as active sites for producing H2O2. The three components cooperate with each other to effectively promote transmission of photo-induced electrons and separation of photo-induced electron hole pairs, so that the photocatalytic effect is remarkably improved, and the photocatalyst is an efficient photocatalyst with excellent performance.

The invention belongs to the technical field of photocatalysis, and particularly discloses a diatomic metal complex / CdS nanorod composite photocatalyst as well as a preparation method and application thereof. The specific preparation method comprises the following steps: synthesizing a pure CdS nanorod by using an EDA assisted solvothermal reaction; then carrying out Schiff base reaction, heating in an oil bath, and condensing and refluxing to synthesize a diatomic metal complex; and putting the diatomic metal complex and the CdS nanorod into a beaker, adding ethanol, uniformly stirring and drying to obtain the diatomic metal complex and CdS nanorod photocatalytic composite material, namely the target product. The CdS nanorod is of a rod-shaped hexagonal crystal structure, the diatomic metal complex is blocky and is loaded on the wall of the CdS nanorod after being compounded with the CdS nanorod, and the main morphology of the CdS nanorod is not changed. According to the invention, the diatomic metal complex is compounded with the CdS nanorod, so that photo-induced electrons and holes can be effectively separated, and the activity of photocatalytic formic acid decomposition to prepare synthesis gas (H2 + CO) is improved.

The invention belongs to the field of polymer modification and processing, and particularly relates to a nano photocatalytic self-cleaning composite material, a fresh-keeping cover and a preparation method of the fresh-keeping cover. The composite material comprises aliphatic nylon, a maleic anhydride grafted copolymer, nano titanium dioxide, carbon nanotubes, boron nitride, a coupling agent, a release agent and an antioxidant. The nano photocatalytic self-cleaning composite material is prepared by taking nano titanium dioxide as an antibacterial active agent and adding a certain amount of carbon nanotubes and boron nitride powder. The carbon nanotubes can conduct electrons, have high surface area and high adsorption capacity, and are good dopants and carriers for titanium dioxide as photocatalysts. Hexagonal boron nitride can effectively improve separation and transfer of photo-induced electron-hole pairs of the material, so that the visible light response photocatalytic activity is enhanced. And by adding the carbon nanotubes and boron nitride, the dispersing performance of nano titanium dioxide can be physically improved, titanium dioxide agglomeration is prevented, and the photocatalytic self-cleaning performance of the nano titanium dioxide is improved.

The invention provides a Cu2O-based heterogeneous composite material as well as a preparation method and application thereof. The preparation method comprises the following steps: coating the surface of a Cu2O hollow sphere substrate with a carbon layer, and depositing layered double hydroxides (LDHs) and metal palladium (Pd) nanoparticles on the carbon layer. According to the material, through a Cu2O-carbon layer-LDHs-Pd multistage heterostructure design, space optimization of light absorption, charge transfer and catalytic sites is realized; cu2O-carbon layer-LDHs interface coupling promotes directed migration of photo-induced electron-hole pairs, and the surface plasmon resonance effect of Pd nanoparticles enhances the charge separation efficiency; the LDHs optimizes a charge transfer path through surface oxygen vacancy or metal valence cycle, so that synergistic oxidation of non-free radicals and free radicals is realized, the organic matter degradation efficiency is remarkably improved, the oxidation path is widened, and the performance bottleneck of a single material is broken through.

The invention relates to the technical field of photocatalytic carbon dioxide reduction, in particular to a Ti < 3 > C < 2 > T < x > MXene / CuInSnS4 composite photocatalyst for photocatalytic carbon dioxide methanation. The reaction yield of photocatalytic reduction of carbon dioxide into methane by using a single CuInSnS4 catalyst is poor. In order to solve the problems, the invention provides the Ti3C2TxMXene / CuInSnS4 composite photocatalyst for photocatalytic carbon dioxide methanation, the Ti3C2TxMXene / CuInSnS4 composite photocatalyst is obtained by compounding Ti3C2TxMXene and CuInSnS4, and the addition of the Ti3C2TxMXene enhances the conductivity of the composite material, inhibits the compounding of photo-induced electrons and holes to a certain extent, and is more beneficial to the proceeding of photocatalytic carbon dioxide reductive methanation reaction.

The invention discloses preparation of a phenanthroline-based covalent organic framework photocatalyst and application of the phenanthroline-based covalent organic framework photocatalyst in photocatalytic production of hydrogen peroxide. According to the method, a hydrogen peroxide production experiment is carried out in a water-oxygen system or a benzyl alcohol-water-oxygen system by taking phenanthroline-based COF as a photocatalyst. According to the invention, through regulation and control of molecular flatness engineering, an electron-rich phenanthroline unit (Phen) anchored by a pyridine expansion plane and electron-deficient triazine (TTA) are integrated into a COF skeleton, and a novel electron donor-acceptor (D-A) type COF is synthesized. The COF has the advantages of proper energy band structure, excellent photo-induced electron and hole separation efficiency, strong D-A interaction, good hydrophilicity and the like, and the efficiency of photocatalytic hydrogen peroxide production reaction within a short time is greatly improved. The invention provides a use method of the COF photocatalyst which is cheap, convenient, rapid, efficient and environment-friendly, and has a potential application prospect.

The invention belongs to the technical field of photoelectric catalytic materials, and particularly relates to an experimental method for rapidly preparing a copper oxide nanowire and application of the copper oxide nanowire. The preparation method comprises the following steps: adopting a copper net as a substrate, rapidly preparing a Cu (OH) 2 nanowire array on the surface of the copper net through a constant-voltage anodic oxidation method, rapidly dehydrating Cu (OH) 2 through high-temperature heat treatment, and preparing the CuxO nanowire array in situ. Compared with the existing P-type semiconductor material, the material has a wider visible light absorption range as a photoelectric catalytic material, and has better performance in the fields of hydrogen production through photoelectric water decomposition and photo-assisted Li-CO2 batteries. The problem of low light energy utilization rate is solved, and the copper oxide nanowire material is beneficial to separation of photo-induced electrons and hole pairs, so that the charge-discharge voltage close to a theoretical value can be measured when the copper oxide nanowire material is used as the positive electrode material of the Li-CO2 battery.

The invention discloses a preparation method and application of a molybdenum monatomic photocatalyst for producing ammonia through nitrogen reduction, and belongs to the technical field of photocatalytic material preparation. According to the preparation method, molybdenum hexacarbonyl is taken as a metal precursor, and molybdenum single atoms are introduced into a covalent organic framework material sp2c-COF by adopting a solvothermal synthesis method, so that the covalent organic framework photocatalyst is obtained; according to the covalent organic framework photocatalyst, molybdenum single atoms are anchored, the local coordination environment of a covalent organic framework is finely controlled, the unique electronic structure and catalytic activity of the molybdenum single atoms can effectively optimize electron cloud distribution of COFs, the adsorption and activation capacity on nitrogen molecules is enhanced, and the covalent organic framework photocatalyst has the advantages that the covalent organic framework photocatalyst is high in catalytic activity and high in catalytic activity; the covalent organic framework photocatalyst can effectively inhibit the compounding of photo-induced electron-hole pairs so as to prolong the service life of photo-induced electrons, so that the covalent organic framework photocatalyst has excellent ammonia production performance, and the ammonia production activity can reach 372.6 [mu] mol.g <-1 >. H <-1 > under the conditions of visible light and pure water.

The invention belongs to the technical field of catalytic degradation, and particularly relates to a bismuth cluster / CTF composite photocatalyst and a preparation method and application thereof. The bismuth cluster and CTF are compounded through a hydrothermal method, photocatalytic cracking of lignin can be achieved, efficient separation of photo-induced electrons and holes of the photocatalyst can be achieved, fine adjustment of the electron structure of the photocatalyst is achieved by adjusting the addition amount of the bismuth cluster precursor, generation of h < + > and. O < 2-> in the photocatalytic process is improved, and the photocatalytic performance of the photocatalyst is improved. Therefore, the yield of the aromatic monomer prepared by cracking the lignin is improved, the cracking conversion rate can reach 78.5%, the yield of benzoic acid can reach 65.2%, the yield of benzaldehyde can reach 81.4%, the yield of phenyl formate can reach 52.6%, and the method is green, clean and safe.

The invention relates to the technical field of preparation of catalytic materials, in particular to a preparation method of a modified BN two-dimensional catalytic material and application of the modified BN two-dimensional catalytic material in methane conversion. S2, preparing a boron nitride material; s3, modification of a boron nitride material; and S4, post-processing. The modeling modification liquid prepared from the oxygen stability enhancing liquid and the boron nitride material form a heterojunction structure, separation of photo-induced electron-hole pairs is remarkably promoted, solar driven catalytic reaction kinetics is improved, oxygen doping sites on the surface of the boron nitride material can be dynamically adjusted, oxygen elements are prevented from being lost in the reaction, and the service life of the boron nitride material is prolonged. The long-acting stability of the catalytic material is ensured. According to the method, the efficiency of solar catalytic methane conversion is improved, a large amount of carbon dioxide is generated, high-yield generation of high-value chemicals such as methanol or formaldehyde under the mild condition is achieved, and a new way is provided for green methane conversion.

The invention belongs to the technical field of optical communication, and relates to a flexible silicon-based photoelectric device, a receiving end and a visible light communication system. The flexible silicon-based photoelectric device comprises a back electrode layer, a hole transport layer, a P-type silicon light absorption layer, an electron transport layer and a front electrode layer. The valence band side energy difference between the electron transport layer and the P-type silicon light absorption layer is greater than the conduction band side energy difference; the conduction band side energy difference between the P-type silicon light absorption layer and the hole transport layer is greater than the valence band side energy difference; the forbidden bandwidth of the electron transport layer is greater than 3.0 eV. The front electrode layer comprises a plurality of grid electrodes which are separately arranged on the surface of the electron transport layer. According to the scheme provided by the invention, the heterojunction is formed on the surfaces of the two sides of the P-type silicon light absorption layer, so that the intensity of a built-in electric field is effectively enhanced, and the flowing speed of photo-generated electrons and photo-generated holes in the device is accelerated, thereby improving the response speed of the device; and meanwhile, the collection efficiency of electrons and holes is improved, so that the photoelectric conversion efficiency of a photoelectric device is improved.

The invention discloses a sewage treatment method based on ultrasonic enhanced photocatalysis cooperating with microorganisms, a Mn-TiO2 / Fe2O3 composite photocatalyst is created for the first time, meanwhile, a heterojunction structure of Fe2O3 and TiO2 can promote directed migration of photo-induced electron-hole pairs, Mn doping serves as an electron trap to further inhibit recombination, the carrier separation efficiency is improved, and the photocatalytic activity is improved. Therefore, the generation amount of active oxygen is greatly increased, and an easily degradable substrate is provided for microbial metabolism. An ultrasonic technology is introduced into a sewage treatment system of Mn-TiO2 / Fe2O3 photocatalysis and microorganisms in a breakthrough manner, so that the effective contact area of florae and pollutants / intermediate products is increased, and the decomposition capability of the microorganisms on the pollutants is enhanced; sewage treatment is carried out by innovatively adopting a three-effect synergistic effect of ultrasonic cavitation, photocatalytic oxidation and microbial metabolism; the pseudomonas is subjected to ultrasonic domestication, so that the pseudomonas has ultrasonic resistance, the normal metabolism and degradation capability of microorganisms in an ultrasonic environment is ensured, and efficient sewage treatment is performed according to the microorganisms required by wastewater culture of different pollutants.

The invention discloses a method for promoting synthesis of microbial oil based on a light-operated gene and a photocatalyst, and belongs to the technical field of microbial oil. According to the invention, the oleaginous yeast Po1f-OptoZWF1 containing a light-operated gene expression system is constructed by adopting a molecular biological technology, and meanwhile, the oleaginous yeast is cultured by adopting a two-stage method (darkness and illumination). In the dark stage, sufficient nutrition is provided, and rapid proliferation of the oleaginous yeast is promoted; in the grease accumulation stage, illumination culture is converted, a photocatalyst is added, a photocatalyst-oleaginous yeast hybrid system and a light-operated gene expression system are constructed to inhibit the ZWF1 gene and a corresponding pentose phosphate pathway, and a photocatalytic material provides photo-induced electrons to promote regeneration of reducing power NADPH, so that grease synthesis is efficiently promoted. According to the method, through gene modification and a two-stage culture strategy, the yield of oil synthesis is remarkably increased, and the problems that existing oil-producing microorganisms are slow in proliferation and low in oil yield are solved.

The invention relates to a manganese cadmium sulfur and manganese sulfide heterojunction composite photocatalytic material, which is composed of Mn < 0.7 > Cd < 0.3 > S and MnS. The invention also discloses a preparation method of the manganese-cadmium-sulfur-coated manganese sulfide heterojunction composite photocatalytic material. The preparation method specifically comprises the following steps: preparing the manganese-cadmium-sulfur-coated manganese sulfide heterojunction photocatalytic material through a one-step hydrothermal method; (CH3COO) 2Mn. 4H2O and (CH3COO) 2Cd. 2H2O are added, and the mixture is stirred and dissolved in water; adding the mixture into TAA and stirring for 30 minutes to obtain a fully mixed solution; and carrying out a hydrothermal reaction to obtain the final manganese-cadmium-sulfur-coated manganese sulfide heterojunction photocatalytic material. According to the invention, the photoresponse range is widened through the construction of the heterojunction, the transfer and separation efficiency of photo-induced electron holes is obviously improved, the compounding of photo-induced electron hole pairs is inhibited, and the efficiency of photocatalytic uranium reduction is improved.

The invention relates to the technical field of catalytic materials, and particularly discloses a visible light photocatalyst and a preparation method thereof.The visible light photocatalyst comprises a core layer-shell layer-dynamic regulation and control layer three-stage structure; the core layer is heterojunction nano-particles formed by bismuth vanadate and bismuth oxyiodide, and the bismuth vanadate particles are uniformly dispersed on the surface of the bismuth oxyiodide to form a p-n heterojunction; the molar ratio of bismuth vanadate to bismuth oxyiodide in the core layer is 1: (0.5-2), and the particle size range is 30-80 nm; through an elaborately designed three-level structure and a dynamic regulation and control mechanism, the response efficiency and environmental adaptability of the photocatalyst to visible light are remarkably improved. A built-in electric field is formed by utilizing the energy band matching characteristic of bismuth vanadate and bismuth oxyiodide, so that the separation of photo-induced electron-hole pairs is effectively promoted, and the absorption boundary of visible light is expanded to 650nm.

The invention relates to a cadmium telluride solar cell and a preparation method thereof, the cadmium telluride solar cell comprises a TCO layer, a buffer layer, a window layer, a light absorption layer, a back electrode layer and a back contact layer, the back contact layer is located between the light absorption layer and the back electrode layer, and the back contact layer is made of boron or carbon doped transition metal nitride. The back contact layer made of boron or carbon doped transition metal nitride is introduced between the light absorption layer and the back electrode layer, and transition gold elements in the back contact layer can be compatible with the cadmium telluride absorption layer, so that the obstruction of a contact barrier to hole transport is reduced, the interface characteristic between the CdTe absorption layer and the back contact layer is optimized, and the light emitting efficiency is improved. According to the present invention, the cadmium telluride absorption layer can form the good ohmic contact with the cadmium telluride absorption layer, such that the effect of the back field buffer layer can be provided so as to reflect the photo-induced electrons on the back surface in the cadmium telluride to the PN junction, such that the recombination of the electrons on the back surface can be substantially reduced, and the carrier collection efficiency of the cell can be improved so as to improve the open-circuit voltage and the conversion efficiency of the cell;

The invention relates to a photovoltaic cell and a preparation method, and the preparation method enables a doped conductive layer of the prepared photovoltaic cell to have a high-low junction, and the high-low junction facilitates the promotion of electron or hole migration, and facilitates the reduction of Auger recombination rate. According to the preparation method disclosed by the invention, the thickness size of the first doped conductive layer in the doped conductive layers of the prepared photovoltaic cell is smaller than that of the second doped conductive layer, so that most of light reflected by the environment can enter the silicon substrate through the first doped conductive layer; therefore, the silicon substrate can generate more photo-generated holes and photo-generated electrons after absorbing more light. In addition, the area of the contact surface between the second doped conductive layer and the metal electrode is large, and the contact resistance between the second doped conductive layer and the metal electrode is small. Therefore, the photovoltaic cell prepared by the preparation method is relatively high in photoelectric conversion efficiency.

The invention discloses a preparation method of a bamboo charcoal-based high-dispersion composite photocatalyst for indoor formaldehyde adsorption-photocatalytic decomposition, and belongs to the technical field of indoor air purification materials. The preparation method comprises the following steps: respectively preparing a g-C3N4 or N-TiO2 main component by using an inorganic or organic precursor, loading metal onto the main component, finally adding pretreated bamboo charcoal, mixing, and activating at high temperature to obtain the bamboo charcoal-based composite photocatalyst. According to the invention, high-dispersion metal monatomic or nanocluster components are utilized to accelerate the separation efficiency of photo-induced electrons-holes, and meanwhile, the introduction of bamboo charcoal can effectively adsorb formaldehyde molecules, so that the photocatalytic decomposition reaction of formaldehyde is further accelerated; the material can be repeatedly used and does not need to be regenerated repeatedly, and a green method for efficiently decomposing formaldehyde for a long time is provided.

The invention belongs to the technical field of photocatalytic hydrogen evolution, and particularly relates to application of a g-C3N4 / Al-SrMoO4 heterojunction photocatalyst in hydrogen evolution through photocatalytic decomposition of water. The preparation method comprises the following steps: uniformly dispersing a g-C3N4 / Al-SrMoO4 heterojunction photocatalyst prepared by using a high-temperature molten salt method and a high-temperature calcination method in a mixed solution of simulated seawater, triethanolamine and chloroplatinic acid, continuously introducing argon into a reactor to obtain a relatively vacuum environment, and carrying out photocatalytic decomposition of water to produce hydrogen under the irradiation of simulated sunlight. The g-C3N4 / Al-SrMoO4 heterojunction photocatalyst disclosed by the invention has better stability and light absorption characteristic, can effectively reduce the recombination of photo-induced electrons and holes and improve the photocatalytic activity, is low in raw material cost, mild in reaction condition and environment-friendly and pollution-free, and conforms to the currently advocated green and environment-friendly concept.

The invention provides a covalent organic framework material as well as a preparation method and application thereof, 1, 3, 6, 8-tetra (4-aminophenyl) pyrene is selected as a central construction unit, and a trap state is realized in a covalent organic framework (COFs) by regulating and controlling the symmetry of active sites (benzothiadiazole, BT). Compared with a centrosymmetric counterpart in the COFs, by breaking the symmetry of the center BT core, the trap state density in the COFs can be remarkably reduced, and the service life of the shallow trap state can be prolonged to 1160.02 picoseconds. Therefore, more photo-induced electrons can participate in the photocatalytic reaction, and the remarkable performance (greater than 99%) of photocatalytic reduction of uranium (VI) is finally realized. According to the invention, the key effect of symmetric breaking in inhibition of excited state decay of COFs is clarified for the first time, and a profound solution is provided for understanding how to improve the photocatalytic performance of COFs in environmental restoration.

The invention provides a photocatalyst based on sulfide homogeneous heterojunction and a preparation method and application thereof, and belongs to the technical field of photocatalysts. The photocatalyst based on the sulfide homogeneous heterojunction provided by the invention is a heterojunction formed by twin-crystal sulfur-cadmium-manganese and transition metal sulfide, has excellent structural stability, and can provide more photo-induced electrons. Therefore, when the photocatalyst provided by the invention is used for degrading H2S to produce hydrogen, the Schottky junction of the photocatalyst can reduce the hydrogen production overpotential, H2S is effectively decomposed to produce hydrogen, and meanwhile, a product Na2S2O3 with a high additional value is produced. The result of the embodiment shows that the photocatalyst based on the sulfide homogeneous heterojunction has excellent catalytic activity when being used for degrading H2S to produce hydrogen.

The invention relates to an energy storage type photo-generated cathode protection coating material and a preparation method thereof, and belongs to the technical field of chemical materials. The coating material is a binary composite material which is composed of nanometer MoO3 and BiVO4. The preparation method comprises the following steps: firstly, preparing nano MoO3 by a precipitation method, and then preparing a nano MoO3 and BiVO4 binary composite material in situ by a low-temperature hydrothermal method, namely the coating material disclosed by the invention. In the coating material, nano MoO3 and BiVO4 are adopted to form a heterojunction material, so that the photoresponse range of BiVO4 is widened, and the photoelectron-hole separation efficiency is effectively improved; meanwhile, nano MoO3 is used as an energy storage material with high theoretical specific capacity, part of photo-induced electrons generated by BiVO4 can be stored in the form of a compound, and in a dark state environment, the electrons stored in MoO3 are released and quickly transferred to the surface of metal or a film-forming substrate, so that cathode protection of the metal in the dark environment is realized; the technical problems that in the prior art, nano BiVO4 is low in electron-hole separation efficiency and poor in metal surface adhesive force, and the cathode protection effect cannot be continued in the dark state are solved.

The invention discloses a carbon nitride loaded metal diatom photocatalytic material as well as a preparation method and application thereof. The invention belongs to the field of photocatalytic materials. The invention aims to solve the technical problems of complex preparation process and low photocatalytic efficiency of the existing metal diatom photocatalyst. The method comprises the following steps: dissolving a nitrogen source and a phosphorus source in deionized water, and carrying out hydrothermal reaction to obtain a precursor; dissolving the precursor in a mixed solvent of alcohol, and then refluxing at constant temperature for a certain time to obtain a pre-product; and adding a metal compound solution capable of forming a conjugated system into the pre-product, carrying out ultrasonic treatment, heating in a constant-temperature water bath kettle, and calcining to obtain the carbon nitride loaded metal diatom photocatalytic material. The obtained photocatalytic material has the advantages of high visible light utilization rate, low photo-induced electron-hole recombination rate and high electron transfer rate. The method is used in the fields of photocatalytic hydrogen production, carbon dioxide reduction and organic matter oxidation.

The invention provides an MXene-derived bimetallic composite material as well as a preparation method and application thereof, and relates to the technical field of catalysts. In the MXene-derived bimetallic composite material provided by the invention, a 3D ordered pore structure provides a channel for organic pollutant molecules and H2O2 to transfer mass to a catalytic active center in the material; tiO2 and the MCuFe-MOF generate photo-induced electrons, a TiO2 / Ti3C2Tx Schottky junction and a MCuFe-MOF / Ti3C2Tx Schottky junction promote separation and transfer of charges, and Fe < 3 + > / Fe < 2 + > circulation is accelerated; the synergistic effect of a redox pair between iron and copper in the MCuFe-MOF is shown as a copper-iron bimetal oxide or a copper-iron bimetal organic framework and the like, interface electron transfer can be accelerated, rapid reduction of Fe < 3 + > and Cu < 2 + > is promoted, the Fenton reaction efficiency is improved, and the photo-Fenton catalytic activity is excellent.

The invention discloses a mid-infrared light detector and a preparation method thereof, and belongs to the technical field of light detection.The light detector comprises a piezoelectric substrate, and a Van der Waals heterojunction, an input interdigital transducer and an output interdigital transducer are arranged on the piezoelectric substrate; the input interdigital transducer and the output interdigital transducer are symmetrically arranged on two sides of the Van der Waals heterojunction; the input interdigital transducer is used for generating a surface acoustic wave according to the alternating current signal; and the output interdigital transducer is used for receiving the surface acoustic wave signal passing through the Van der Waals heterojunction and outputting the signal. According to the device, a periodic strain field and a piezoelectric field are formed on the surface of a substrate through surface acoustic waves, graphene plasmons are excited, mid-infrared light absorption is enhanced, photo-generated electron-hole space separation is promoted, photo-generated carrier recombination is inhibited, a photoelectric response signal is converted into an acoustoelectric signal, and the photoelectric response signal is converted into an acousto-electric signal. And high-performance mid-infrared light detection is realized by using the high-sensitivity response characteristic of the surface acoustic wave device to acoustoelectric interaction.