123results about How to "Small specific surface area" patented technology

The invention discloses a heat exchange structure design method based on three-period minimal curved surface space subdivision. The invention provides a heat exchange structure design method based on a three-period minimal curved surface (TPMS) structure, and aims to improve the performance of efficient heat dissipation equipment. According to the method, by generating the Gyandroid structure and conducting multi-layer subdivision, the fluid flowing path is optimized, and the heat exchange efficiency is improved. Meanwhile, by adopting the lightweight composite material for construction, the structural weight is remarkably reduced, and the composite material is suitable for high-efficiency heat dissipation application in the fields of new energy automobile battery heat management, electronic equipment, aerospace and the like. Through finite element simulation analysis, the heat dissipation performance and mechanical strength of the structure are verified, efficient heat dissipation can be achieved in a limited space, and the service life of equipment is prolonged.

The invention belongs to the technical field of energy and petrochemical engineering catalysts, and particularly discloses a preparation method and application of a copper-zinc-aluminum spinel solid solution catalyst. The Cu-Zn-Al spinel solid solution catalyst is prepared by ball-milling copper, zinc and aluminum precursors and then roasting at 800-1200 DEG C in the air atmosphere, and the preparation method is simple, does not need a large amount of solvent, is less in wastewater and avoids the influence of other impurity ions. The Cu-Zn-Al spinel solid solution catalyst prepared by the invention is used for methanol reforming hydrogen production reaction, the methanol conversion rate is as high as 95.5%, the H2 selectivity in the product is 74.8%, and the CO selectivity is 0.76%, so that the Cu-Zn-Al spinel solid solution catalyst has high activity, high selectivity and good reaction stability.

The invention provides a silicon carbon material with a multilayer coating structure and a preparation method and application thereof, and relates to the technical field of battery materials. The silicon-carbon material with the multi-layer coating structure comprises a porous carbon core body, and a first carbon layer and a second carbon layer which sequentially coat the porous carbon core body from inside to outside, and the porous carbon core body comprises porous carbon and nano silicon particles deposited on the surface and in pore channels of the porous carbon; and a conductive nano carbon filler is dispersed in the second carbon layer. The silicon carbon material with the multilayer coating structure provided by the invention is used as a lithium ion battery negative electrode material, and has excellent specific capacity, coulombic efficiency and cycle performance. The result of the embodiment shows that when the silicon carbon material with the multi-layer coating structure is applied to the lithium ion battery, the first reversible capacity is 1882-2071 mAh / g, the first coulombic efficiency is 92.6-94.1%, and the capacity retention ratio of 100 cycles is 95.3-97.7%.

The invention belongs to but not limited to the technical field of electrode materials, and particularly relates to a preparation method of a bamboo-based hard carbon sodium battery negative electrode material, which comprises the following specific steps: S1, cleaning and drying natural bamboo, scraping surface bamboo green with a knife, and cutting into small blocks; s2, a dilute acid solution is prepared, the bamboos are soaked in the dilute acid solution in a vacuum mode, then the bamboos and the dilute acid solution are transferred into a hydrothermal kettle together, a solvothermal acidolysis reaction is conducted under the high-temperature and high-pressure condition, ash removal and impurity removal are conducted, and meanwhile the bamboos are softened; s3, the bamboo wood subjected to solvothermal acidolysis is washed with water and dried, and a tubular furnace is used for pre-carbonization treatment; after pre-carbonization, a sample is subjected to ball milling, grinding and screening, then is transferred into a graphite mold, and is put into a discharge plasma sintering furnace for high-temperature sintering carbonization; and S4, carrying out ultrasonic oscillation on the carbon powder subjected to discharge plasma treatment, re-screening, and carrying out chemical vapor deposition carbon coating to obtain the bamboo-based hard carbon sodium battery negative electrode material.

The invention discloses a sulfur-doped composite hard carbon material as well as a preparation method and application thereof. Sulfonated resin is used as a carbon source and a sulfur source, and non-metal sulfur atoms with the atomic radius larger than that of carbon are doped in situ, so that the carbon layer spacing of hard carbon is increased, and the rate capability of the hard carbon is improved; and the sulfonated resin is subjected to surface pre-coating modification by using a cheap biomass carbon source, so that the specific surface area and defect sites of hard carbon are reduced, the number of closed pores is increased, and the specific capacity and the first coulombic efficiency of the hard carbon are improved.

The invention discloses low-impurity biomass hard carbon as well as a preparation method and application thereof. The low-impurity biomass hard carbon is prepared from biomass raw material powder through impurity removal and carbonization; the invention discloses a preparation method of low-impurity biomass hard carbon. The preparation method comprises the following steps: mixing biomass raw material powder with a strain of macro fungi, and culturing until the macro fungi grow sporocarp; the application of the low-impurity biomass hard carbon is that the low-impurity biomass hard carbon is used for preparing a sodium ion battery negative electrode material. According to the method provided by the invention, impurities such as inorganic salts and metal elements in the biomass raw material for preparing the biomass hard carbon can be effectively removed, and meanwhile, the microporous structure of the biomass hard carbon material is maintained, so that the sodium storage performance and the cycling stability of the biomass hard carbon material serving as a sodium-ion battery negative electrode material are improved.

The invention discloses a bimetallic Ag and Pd loaded WO3 material and a preparation method thereof, and relates to the technical field of sensor material preparation, and the preparation method comprises the following steps: 1, dissolving a tungsten source in an ethanol solution, mixing, hydrolyzing, aging, precipitating, washing, drying, calcining and cooling; 2, adding deionized water, adding a silver source solution and a palladium source, adding ascorbic acid, and stirring; 3, centrifuging, washing with ethanol and deionized water, and drying; 4, selecting a gold interdigital electrode with aluminum oxide ceramic as a substrate as a base electrode material, dipping the WO3 nano-particle dispersion liquid by using a line drawing pen, and uniformly coating the WO3 nano-particle dispersion liquid on the surface of the interdigital electrode; and 5, electrode drying and heat treatment. The efficient gas sensing material is prepared through the preparation method which is easy to operate, environmentally friendly and economical, and the gas sensing material has the advantages of being high in sensitivity, rapid in response, good in selectivity and the like at the low working temperature.

The invention provides porous aluminum oxide for a lithium ion battery, a battery component, a battery and electric equipment, and relates to the technical field of battery materials, the pore size of particles in porous aluminum oxide powder is 16-50nm, the BET specific surface area is not more than 25m < 2 > / g, the crystal forms of the particles comprise 30-60% of theta phase, 0-50% of delta phase and 0-50% of alpha phase, the alpha phase is 0-50% of the theta phase, the beta phase is 0-50% of the beta phase, and the beta phase is 0-50% of the alpha phase. And the ratio of the alpha phase is 10%-50%. The invention further provides a battery component, a battery and electric equipment based on the porous aluminum oxide. The porous alumina powder provided by the invention has a relatively low specific surface area, relatively low activity and a reasonable pore channel structure, and is beneficial to improving the thermal stability of a diaphragm and the affinity and wettability of the diaphragm to an electrolyte when being applied to a diaphragm coating of a lithium ion battery, improving the liquid retention level and prolonging the service life of the diaphragm. And more ion transmission channels can be provided for ion conduction, so that the cycling stability of the battery is improved, and the service life of the battery is prolonged.

The invention discloses a method for reducing pores formed among particles during sintering of composite ferric sodium pyrophosphate, which comprises the following steps: step 1, preparation of precursor slurry: mixing, stirring and grinding an iron source, a phosphorus source, a sodium source, a carbon source and deionized water to obtain the precursor slurry; wherein the stoichiometric ratio of the iron source to the phosphorus source to the sodium source is 3: 4: 4, and the chemical formula of the synthesized composite ferric sodium pyrophosphate is Na4Fe3 (PO4) 2P2O7; 2, carrying out spray drying on the precursor slurry to obtain a dried precursor; and step 3, loading the dried precursor in a graphite sagger, and then feeding the dried precursor into a roller kiln for sintering to obtain the composite ferric sodium pyrophosphate material. According to the invention, the solid content of the slurry is reduced to realize that the spray-dried composite phosphoric acid ferric pyrophosphate precursor forms thin-wall secondary spherical particles, and then through a unique sintering process curve, volatile components of the precursor are smoothly discharged in the sintering process, so that the composite phosphoric acid ferric pyrophosphate product without pores among particles is obtained.

The embodiments of the present application relate to the field of photovoltaic technology, and in particular to a sliced ​​cell and a method for forming the same, and a photovoltaic module. The sliced ​​cell comprises: the sliced ​​cell is formed by slicing a whole cell, and the sliced ​​cell has a cutting surface formed by the slicing process; wherein at least part of the cutting surface has a first texture structure, and the first texture structure includes at least a plurality of rectangular portions, and at least one of the rectangular portions partially overlaps with at least one adjacent rectangular portion. The embodiments of the present application are at least conducive to improving the performance of the sliced ​​cell and the photovoltaic module.

The invention relates to the technical field of lithium ion battery negative electrode materials, in particular to a graphite negative electrode material and a preparation method thereof, a negative electrode plate and a lithium ion battery. The graphite negative electrode material comprises composite particles, the composite particles comprise graphite particles and polymer films coating the surfaces of the graphite particles, and the materials of the polymer films comprise polyolefin and / or polyurethane; the weight loss ratio of a TG curve obtained by carrying out a thermal weight loss test on the graphite negative electrode material in an air atmosphere at 200-600 DEG C is 1%-5%. The surfaces of the graphite particles are coated with a small amount of polyolefin and / or polyurethane, so that the specific surface area can be remarkably reduced, and the compaction density can be improved.

The invention provides a graphite composite negative electrode material and a preparation method thereof, and a lithium ion battery, the graphite composite negative electrode material has a core-shell structure, and comprises a graphite core, a mesh conductive intermediate layer and a surface soft carbon coating layer; the raw materials of the net-shaped conductive middle layer comprise polyhydroxy benzene and metal salt, the raw material of the graphite inner core comprises natural graphite, and the raw material of the surface soft carbon coating layer comprises high-temperature coating asphalt; the mass ratio of the natural graphite to the polyhydroxy benzene to the metal salt to the high-temperature coated asphalt is 1000: (20-80): (20-80): (20-60). According to the invention, the natural graphite negative electrode material with high first-cycle coulombic efficiency, high rate capability and excellent long cycle performance can be prepared.

The invention relates to the technical field of lithium ion battery negative electrode materials, in particular to a silicon-carbon negative electrode material, a preparation method thereof, a negative electrode plate and a lithium ion battery. The silicon-carbon negative electrode material comprises a composite fiber, wherein the composite fiber comprises a core layer and a carbon coating layer; the core layer has a pore structure and comprises a carbon skeleton and a silicon material; in the cross section of the composite fiber, the area of the pore structure is S pore, the area of the silicon element is S silicon, the area of the carbon element is S carbon, and 0.5 < = S pore / (S silicon + S carbon) < = 2. The silicon material in the core layer can provide higher gram volume, and the carbon skeleton can provide mechanical strength and enhance the conductivity of the material; the core layer has a pore structure and can provide a buffer space when the silicon material is charged, so that the cycle performance is improved; the carbon coating layer can effectively reduce the specific surface area of the material, avoids direct contact between the silicon material and an electrolyte, and improves the initial coulombic efficiency; the silicon material can be ensured to have enough buffer space by meeting the relational expression, and the cycle performance can be further improved.

The invention discloses a high-conductivity sodium ion battery positive electrode material / organic conductive polymer composite material and a preparation method thereof, and the preparation method comprises the following steps: S1, preparation of a chain product: adding water into an organic conductive polymer monomer for dissolving, adjusting the pH value of the solution to be acidic, adding an oxidizing agent, and stirring to obtain the chain product; inducing an organic conductive polymer monomer to generate a polymerization reaction to form a chain product; s2, preparation of precursor slurry: adding a sodium source, an iron source and a sulfur source into the solution for forming the chain product, and fully dissolving to form uniform precursor slurry; s3, preparation of precursor powder: drying the precursor slurry to realize solid-liquid separation so as to obtain dried precursor powder; and S4, high-temperature sintering: calcining the precursor powder in a protective atmosphere, and naturally cooling to obtain the Na < 2 + x > Fe < 2-x > (SO4) 3 / organic conductive polymer composite positive electrode material. The preparation method has the characteristics of high electronic conductivity, low specific surface area, high compaction density and excellent electrochemical performance.

The invention discloses a papermaking filling method based on calcium carbonate wrapping, and relates to the technical field of papermaking filling, and the papermaking filling method comprises the following steps: S1, mixing heavy calcium carbonate and precipitated calcium carbonate according to a ratio, and conveying the mixture into mixing equipment; s2, two drugs DEV310 and DEV210 are selected as filler wrapping agents, the papermaking filling method based on calcium carbonate wrapping comprises the steps that ground calcium carbonate and precipitated calcium carbonate are mixed in proportion and then enter filler wrapping agent mixing equipment, then dissolved DEV210 and DEV210 absolute dry filler are input into the mixing equipment according to needs, calcium carbonate filler is subjected to wrapping treatment, and the calcium carbonate filler is filled with the filler wrapping agent. Compared with a conventional filler adding method, the specific surface area of the treated filler is reduced, and bonding points between fibers are increased, so that filler retention and paper strength are improved, filler retention can be improved by 2-3%, paper quality is improved, paper cost can be reduced, and economic benefits are considerable.

The invention belongs to the technical field of lithium ion battery negative electrode materials, and particularly relates to a high-temperature self-healing composite silicon carbon electrode and a preparation method thereof.The high-temperature self-healing composite silicon carbon electrode comprises a copper foil, the two faces of the copper foil are coated with negative electrode active layers, and liquid metal layers are applied to the negative electrode active layers through supersonic spraying; the liquid metal is condensed and rolled in a gap of the negative electrode active layer; the negative electrode active layer is prepared by coating negative electrode slurry, the negative electrode slurry is prepared by mixing small-particle-size graphite, graphite, a silicon material, a binder and deionized water, the mass ratio of the small-particle-size graphite to the graphite to the silicon material is (0.5-1): (1.5-3): (6-8), and the viscosity of the negative electrode slurry is 3000-6000 mPa.s. Graphite with different particle sizes and a silicon material are used as negative electrode active substances for mixing, so that the compaction of an electrode material is effectively improved, the specific surface area of an electrode is reduced, and the first coulombic efficiency of a negative plate is facilitated.

The invention relates to the technical field of battery material preparation, and provides a coal-based hard carbon negative electrode material, a preparation method thereof and a sodium ion battery. The preparation method of the coal-based hard carbon negative electrode material comprises the following steps: (I) synchronously purifying and pre-oxidizing pulverized coal and mixed acid in a solvent to obtain modified pulverized coal, wherein the mixed acid comprises hydrochloric acid, hydrofluoric acid and nitric acid; (II) the modified coal powder and starch are subjected to solid-phase mixing to obtain a first precursor, the content of amylose in the starch is 50% or above, and the mass ratio of the modified coal powder to the starch is (6-9): (1-4); (III) sequentially esterifying and pre-carbonizing the first precursor to obtain a second precursor; and (IV) carbonizing the second precursor to obtain the coal-based hard carbon negative electrode material. The coal-based hard carbon prepared by the preparation method has expanded interlayer spacing, increased pseudo graphite phase proportion and reduced specific surface area, shows high specific capacity and first coulombic efficiency when being used as a sodium ion battery negative electrode material, and can improve the carbon yield.

The invention relates to a method for preparing metallic titanium through two-step electrolysis in halide molten salt, and belongs to the technical field of metallurgy. The method comprises the following steps: by taking fluorine-chloride mixed molten salt as primary electrolytic molten salt, adding TiO2 into the fluorine-chloride mixed molten salt, uniformly mixing, heating the fluorine-chloride mixed molten salt containing TiO2 to the electrolytic temperature of 650-850 DEG C in an inert atmosphere, inserting a cathode and an anode, carrying out primary molten salt electrolysis, taking out a cathode product, and carrying out secondary electrolytic treatment on the cathode product to obtain the TiO2 / TiO2 composite material. Performing vacuum distillation or washing on the cathode product to remove impurities, and drying to remove attached electrolyte to obtain a primary electrolytic product crude titanium; the method comprises the following steps: by taking primary electrolysis product crude titanium as a soluble anode, high-purity metal titanium as a cathode and chloride molten salt as secondary electrolysis molten salt, heating the chloride molten salt to the electrolysis temperature of 550-750 DEG C in an inert atmosphere, inserting the cathode and the anode, performing electrolytic refining, and washing the electrolysis product with diluted hydrochloric acid and deionized water to remove impurities, thereby obtaining the low-oxygen metal titanium powder. A low-melting-point molten salt system is adopted in two-step electrolysis, and energy consumption can be effectively reduced.

The invention discloses a preparation method of silicon dioxide for a powder coating, and belongs to the technical field of precipitation method silicon dioxide preparation, a sodium silicate solution with a specific modulus is selected to be prepared into a proper concentration, and a large amount of silicic acid is generated in the solution in combination with a specific proportion, temperature and early-stage rapid acid adding mode; a large number of uniform primary silicon dioxide particles can be quickly formed, the silicon dioxide particles with high specific surface area and high surface energy are finally separated out, and the growth and aggregation of the silicon dioxide particles are effectively controlled in a manner of slowly adding acid according to a specific proportion and temperature subsequently, so that the silicon dioxide aggregate with uniform particle size is formed; the water-soluble amino acid is added into the silicon dioxide slurry, so that the silicon dioxide particles are endowed with charge property, the finally dried silicon dioxide powder can be directly used in the powder coating, mechanical crushing is not needed again, the energy consumption is reduced, a surfactant is not needed, the influence on the environment in the production process can be avoided, and the method is energy-saving and environment-friendly.

The invention relates to a uniform carbon-coated mesoporous silicon carbon negative electrode material and a preparation method and application thereof.The preparation method comprises the steps that a product obtained after pyrolysis and carbonization of a biomass carbon source is subjected to alkali activation treatment, acid pickling, drying, smashing, passivation, water washing and drying are conducted to obtain a mesoporous carbon matrix, nanometer silicon particles are deposited in pores of the mesoporous carbon matrix, and the uniform carbon-coated mesoporous silicon carbon negative electrode material is obtained. Then selecting a low-temperature carbonization material and polyethylene glycol to perform pre-carbonization and complete carbonization treatment on the mesoporous silicon carbon material to obtain a carbon coating layer, and finally obtaining the uniform carbon-coated mesoporous silicon carbon negative electrode material. When the uniform carbon-coated mesoporous silicon carbon negative electrode material is applied to a lithium battery, the mesoporous skeleton can effectively inhibit volume expansion of silicon in a battery circulation process, and the uniform carbon-coated layer can effectively reduce the risk of direct contact between the negative electrode material and an electrolyte, so that a stable SE I film is formed to reduce the occurrence of side reactions; and the first coulombic efficiency and the cycle performance of the battery are further improved.

The invention belongs to the field of sodium-ion batteries, and particularly relates to a preparation method of lotus petiole derived hard carbon as a negative electrode of a sodium-ion battery. Firstly, lotus petiole is subjected to pretreatment such as washing and drying to remove surface impurities, then a pretreated material is obtained by adopting a microwave-assisted and chemical treatment method, and finally, the hard carbon material with good stability is obtained by high-temperature carbonization in a nitrogen atmosphere. The half-cell assembled by the biomass derived hard carbon prepared by the invention has excellent electrochemical performance. In the preparation process, raw materials are cheap and easy to obtain, the cost is low, the method is simple and easy to implement, the preparation efficiency is high, and no template or surfactant exists. A half battery assembled by the prepared hard carbon material has relatively high specific capacity, has the reversible capacity of 342.4 mAh g <-1 > under the current density of 20 mA g <-1 >, and still has the capacity retention rate of 90.2% after 2000 cycles under the current density of 1 A g <-1 >. In addition, the natural lotus petiole is used as the raw material, the material is easy to obtain and low in cost, and comprehensive utilization of biomass waste is achieved.

The invention belongs to the technical field of processing equipment of battery materials, and discloses discharging equipment and a discharging method of an Acheson graphitization furnace, the discharging equipment comprises a plurality of protective cover plates and a protective gas supply mechanism, the protective cover plates are sequentially erected above a furnace body, and a cooling chamber is formed by the protective cover plates and the furnace body; any two protective cover plates are provided with an air inlet channel and an air outlet channel respectively. The protective gas supply mechanism communicates with the gas inlet channel and is used for guiding gas into the cooling cavity, and the gas outlet channel is used for communicating the outside with the cooling cavity. Due to the existence of the discharging equipment, the negative electrode material is not easy to oxidize in the cooling process, and the specific surface area is reduced; and the flowing of the protective gas can take away part of heat in the graphitization furnace, the cooling period is shortened, the protective cover plates covering the graphitization furnace can better isolate external dust and prevent external pollution in the material suction process, and the quality of the negative electrode material is ensured.

The invention relates to a catalyst for preparing allyl acetate through acetylation of propylene and a preparation method of the catalyst. The catalyst comprises a carrier, active components and an auxiliary agent, the average pore size of the carrier is 20-100 nm, the active components are bimetallic palladium Pd and antimony Sb, and the auxiliary agent is potassium acetate. The invention mainly solves the problems of low conversion rate, low selectivity, short service life and the like of the catalyst used in the current acryl acetylation reaction. Compared with the prior art, the catalyst provided by the invention has the advantages of high conversion rate and high selectivity on the acetylation reaction of the propylene, and solves the problem of poor stability of the existing catalyst.

The application discloses a preparation method of a sodium ion battery hard carbon negative electrode material based on step-by-step synergistic regulation, and comprises the following steps: S1, biomass pretreatment; S2, low-temperature pre-carbonization to obtain biomass pre-carbonized carbon; S3, physical activation: the pre-carbonized carbon is placed in an activation atmosphere to perform medium-temperature activation, and biomass activated carbon is obtained; S4, high-temperature carbonization: the biomass activated carbon is placed in an inert atmosphere to perform high-temperature carbonization, and a hard carbon intermediate is obtained; S5, chemical vapor deposition coating: the hard carbon intermediate is placed in a mixed atmosphere of a coating carbon source and an inert gas to perform chemical vapor deposition coating, and a surface-coated biomass hard carbon negative electrode material is obtained. The application can realize a higher closed pore volume at a milder temperature, and the synergistic regulation pore forming mode of activating and forming pores first and then high-temperature closing pores also avoids the insufficient closed pores caused by single high-temperature treatment.

The application relates to the technical field of batteries, in particular to a hard carbon negative electrode material and a preparation method and application thereof. A preparation method of a negative electrode hard carbon material comprises the following steps: carrying out first heat treatment on a mixture of an organic metal catalyst and biomass activated carbon, introducing a gas-phase carbon source and carrying out second heat treatment to obtain first material, and carrying out carbonization treatment and acid pickling treatment on the first material. The method can improve the capacity and initial efficiency of the hard carbon negative electrode material through cooperation of various steps; the method is simple in process and easy to realize large-scale production.

The present invention relates to a pellet for an organic electroluminescent element and an organic electroluminescent element using the same, the pellet for an organic electroluminescent element being obtained by crimping two or more kinds of organic compound powder containing a first organic compound powder and a second organic compound powder, and has the same maximum emission wavelength as the maximum emission wavelength of an organic compound having a longer emission wavelength among the first organic compound and the second organic compound.

This invention belongs to the field of battery materials technology, and discloses a single-crystal lithium nickel manganese oxide material, its preparation method, and a lithium-ion battery. The single-crystal lithium nickel manganese oxide material contains Li... x Ni 2‑x The percentage content of O2 is C≤1.6%, C=(I LixNi2‑xO2 / (I LixNi2‑xO2 +I LiNi0.5Mn1.5O4 ))×100%, I LixNi2‑xO2 For Li in the XRD refinement results x Ni 2‑x The diffraction peak intensity corresponding to O2, I LixNi2‑xO2 +I LiNi0.5Mn1.5O4 To add LiNi to the XRD refinement results 0.5 Mn 1.5 O4 and Li x Ni 2‑x The diffraction peak intensity of the O2 two-phase model indicates a grain size of 5–11 μm. The aforementioned single-crystal lithium nickel manganese oxide material was prepared via a lithium-deficient high-temperature sintering and lithium-replenished low-temperature sintering process. Li x Ni 2‑x Large-particle monocrystalline lithium nickel manganese oxide materials with low O2 content avoid electrolyte decomposition under high voltage, thus preventing the generation of HF and Li. x Ni 2‑x The O2 reaction can effectively improve the cycle stability of the battery. Simultaneously, the high compaction density of monocrystalline lithium nickel manganese oxide material can enhance the battery's energy density, thermal stability, mechanical properties, and durability. The method for preparing monocrystalline lithium nickel manganese oxide material in this invention is relatively simple, reliable, and effective, and can utilize existing production lines.

The present invention relates to a preparation method and application of titanium dioxide coated hollow glass microspheres, belonging to the technical field of hollow glass microspheres. 0.1 to 1 parts by weight of a titanate coupling agent is added to 80 to 90 parts by weight of an organic solvent, stirred for 1 to 3 hours, and a titanium solution is obtained; 10 to 20 parts by weight of hollow glass microspheres are added to the titanium solution prepared by S1, stirred for 1 to 3 hours, and a glass microsphere titanium solution is obtained; the organic solvent in the glass microsphere titanium solution prepared in S2 is evaporated by a low-temperature reduced pressure distillation method, and a freeze dryer or a vacuum oven is used for drying to obtain a pre-coated material; the pre-coated material prepared by S3 is sieved and calcined at 400 to 600°C for 2 to 6 hours, and cooled to obtain a titanium dioxide coated hollow glass microsphere product. The present invention has a simple process, is easy to mass produce, and can ensure coating uniformity and performance stability; in addition, the thermal insulation coating to which the titanium dioxide coated hollow glass microspheres of the present invention are added has significant thermal insulation performance, and good water resistance, stain resistance, and corrosion resistance.

The application discloses a kind of composite heat-conducting fillers, the composite heat-conducting filler is graphene oxide wraps aluminium oxide composite heat-conducting filler, wherein aluminium oxide is in situ grown on the surface of graphene oxide, then through special drying technique to form the microsphere structure of graphene oxide wrapping on the surface of aluminium oxide.The application also discloses a kind of graphene in-situ modified heat-conducting gel, containing the composite heat-conducting filler described above.The application also discloses its preparation and application.In the product prepared in the embodiment of the application, graphene is wrapped on the surface of aluminium oxide, and the two are mutually overlapped, mutually synergistic, form the special compounding effect of two-dimensional and zero-dimensional spherical, construct three-dimensional, extensive heat-conducting network structure, realize high thermal conductivity and high extrusion rate under lower filling amount.

This invention discloses a hard carbon material with ultra-high platform capacity, its preparation method, and its applications. The hard carbon material is prepared by hydrothermal reaction and high-temperature carbonization, with a particle size of 2-4 μm, a pore size of 0.4-200 nm, and a specific surface area of ​​no more than 15 m². 2 / g, with a platform capacity ratio of not less than 40%; the preparation method of hard carbon material is as follows: S1: Add surfactant to pectin aqueous solution for hydrothermal reaction, and obtain hard carbon microspheres after filtration and drying; S2: Carbonize the hard carbon microspheres of S1 at high temperature under an inert atmosphere, and obtain hard carbon material with ultra-high platform capacity after cooling. The hard carbon material of the present invention can be used as a negative electrode material for lithium-ion batteries, which can significantly improve the platform capacity ratio.