343 results about "Soluble glass" patented technology

The invention discloses a formula and a method for manufacturing ceramic tile blank bodies by utilizing polished waste residues. The formula adopts ingredients by weight portions: porcelain clays account for 18 to 40 parts, clays account for 20 to 30 parts, limestone grains account for 1 to 10 parts, wollastonite grains account for 3 to 15 parts, glazed tile sludge residues account for 3 to 10 parts, ceramic polished waste residues account for 15 to 45 parts, soluble glass accounts for 1 to 2 parts, thinners account for 0.15 to 0.4 parts, sodium tripolyphosphate accounts for 0.05 to 0.2 parts, and a proper amount of water is adopted. A manufacturing method of the ceramic tile blank bodies comprises the steps as follows: a. raw materials are put in a ball grinder for ball milling after being blended so as to form sizing agents with proper fineness and screen tailings through milling, and the sizing agents are processed through deferrization, sieving and spray drying so as to form powders; and b. the powders are put in a die cavity of a press forming machine to form waterish blanks through pressing, the waterish blanks are dried in a drying kiln, the dried waterish blanks are applied with base pulp and then enter a biscuit firing kiln, biscuit firing is carried out under the temperature ranging from 1080 to 1160 DEG C, heat preservation is carried out in an area with the temperature ranging from 1040 to 1060 DEG C, the sintering time of the area is prolonged, and the sintering process for oxidizing atmosphere can be enhanced at the same time so as to obtain the ceramic tile blank bodies.

The invention discloses a reinforcing method of aluminium alloy surface fused and covered by laser, which comprises the following steps: 1. predisposing aluminium alloy base; 2. allocating laser fusing and covering material with the bulk rate of Al-Si alloy powder and SiC ceramic powder at 1:(4-2); setting the Si content in the Al-Si alloy at 10-15(wt%) with grain size at - 140-+325; setting the grain size of SiC at -200; 2. modulating evenly blended fusing and covering material into paste through soluble glass; coating on the surface of aluminium alloy with thickness at 0.8-1.2mm; drying at 100-150 deg.c for 0.5-2h; 4. adopting crossflow CO2 laser to irradiate the coated layer on the surface of aluminium alloy base; setting the output power of laser at 3-4kW and optical beam scanning velocity at 2-5mm/s and optical spot dimension at 1-4mm; protecting fusing pond through high-purity argon in the laser fusing and covering course with argon flow at 20-30L/min.

A synthetic method of Nanosized ZSM-23 zeolites belongs to the technical field of synthesis of inorganic chemistry. Firstly preparing reaction mixture from sodium metaaluminate or aluminum sulfate, silicasol or soluble glass, sodium hydroxide and isopropylamine, then hydrothermal crystallizing the reaction mixture, at last obtaining the Nanosized ZSM-23 zeolites through conventionally filtering, washing, drying and sintering the hydrothermal crystallized reaction mixture. The synthetic method has the advantages that average diameter of the cross sections of crystal grains of the synthesized ZSM-23 zeolites is not more than 100 nm, the specific surface area is comparatively high, production flow is short, the cost is low, and the method is favorable for industrial production and application.

The invention relates to a method for simultaneously preparing SiO2 aerogel and zeolite by utilizing fly ash, belonging to the technical field of the high-efficiency resource utilization of solid wastes and chemical material preparation. The method is as follows: the fly ash is firstly processed by high-temperature activation and then carries out hydro-thermal synthesis reaction with a sodium hydroxide water solution, soluble glass is catalyzed by a sulphuric acid with certain concentration, or the solution carries out cation exchange resin and is then processed by base catalysis to obtain SiO2 gel; aquagel is processed by solvent exchange/surface modification by utilizing a mixed solution of alcohols/alkanes solvent and trimethylchlorosilane, and the SiO2 aerogel is obtained under the condition of normal pressure and dryness; the fly ash is reacted with NaOH and then filtered to obtain filter residue, and the filter residue is further reacted with the NaOH so as to synthesize fly ash zeolite. The invention is not only a new way of the high-efficiency recycling of the solid wastes, but also a new technical method of the low-cost preparation of the SiO2 aerogel and the zeolite.

The invention relates to a method for preparing nanometer level white carbon black by rice husk ash. The method is characterized in that the process method comprises the following steps: the rice husk ash is treated by an alkaline method to prepare soluble glass; and a soluble glass solution is subjected to condensation, heat insulation, acidic reaction, aging, rinsing, filtering, preparing, homogenizing, spraying and drying, and airflow pulverization. The method has the technical effects that the method reduces cost, improves corrosion resistance, high hardness and high toughness of the material, and has simple preparation process flow, low production cost and good stability.

The invention discloses a preparation method of organic resin, in particular to a preparation method of a methyl vinyl MQ resin used for LED encapsulation and reinforcement. The method is that a soluble glass aqueous solution is added into concentrated hydrochloric acid (36.5 percent); after the reaction, the anhydrous ethanol solution of phenyl alkoxy silicane, vinyl alkoxy silicane and methyl alkoxy silicane is added; an extraction is carried out after cohydrolysis; the upper oil layer is removed; the reactants are washed to be neutral and dried; the low-boiling substances are removed; the colorless and transparent product of MQ resin is obtained. The preparation method of the invention has the advantages of accessible and cheap raw materials, simple and easy operation, and is convenient to industrialized with good effect. The products of the invention are especially suitable to be used as reinforcement materials in the LED encapsulation materials, also be expected as a reinforcing agent for other organosilicon materials and used in aspects of anchoring agent, surface treating agent, mold discharging agent, anti-blowing agent, adhesion preventives, brightening agent and other additives, etc.

The invention discloses a core making method by gas-blowing hardening, which is characterized in that the mass percentage of mixing materials of the making core sand is as follows: 0.9-7.0 percent of soluble glass, 0.1-1.0 percent of moisture absorption resistant agent and raw sand for the rest; the used moisture absorption resistant agent can be triacetyl glycerine, diacetin, glycerol mono acetate bulk, diethylene glycol acetic ester, propylene glycol acetic ester, other polylol organic acid ester or the mixture thereof; the volume percentage of the blowing gas for hardening is as follows: 25-100 percent of C2-C4 organic ester and 0-75 percent of C1-C2 alcohols. The method of the invention has no toxicity and odor in production process, and the produced cores have better stripping strength.

The present invention relates to the technical field of a zeolite molecular sieve synthesis, concretely speaking, relating to a preparation method of a zeolite molecular sieve of a nano heteroatom. A sodium silicate or a soluble glass, an inorganic acid, an inorganic ferric salt, an organic amine and deionized water serve as the material. After the steps of liquor preparation, two variable temperature crystallizations, washing-up centrifugalization, drying and roasting, the zeolite molecular sieve of nano Fe-ZSM-5 is produced with a grain size less than 100nm. The present invention can be used in the petrochemical industry, fine chemical industry and the environmental protection field.

The present invention provides a resin composition having excellent dispersibility, discoloration resistance and antimicrobial properties by blending a resin (A) with an antimicrobial agent (B) in which at least one kind of metal ion selected from the group consisting of silver, copper, zinc, and tin is supported on zeolite, and an antimicrobial agent (C) that includes a silver ion-containing phosphate as an active ingredient, or an antimicrobial agent (D) made of a soluble glass powder containing silver ion.

The invention discloses a high polymer composite coagulant for disposing oily wastewater and preparing method, which comprises the following steps: setting ingredient and weight ratio of high polymer composite coagulant with polymeric aluminium chloride : polymeric ferric sulfate : soluble glass : polydiene propyl dimethyl amchlor : water = 39.00:(1.90-2.10):(0.26-0.31):(1.04-1.52):(57.80-57.10); setting 0.02% basic ion polyacrylamide in polydiene propyl dimethyl amchlor; preparing finite density water solution with raw material as first step; preparing flocculant intermediate with polyaluminium chloride, polymeric ferric persulfate and sodium silicate as second step; proceeding mixed reaction with flocculating agent intermediate of the second step and polydiene propyl dimethyl amchlor of 0.02% positive ion polyacrylamide; controlling condition as temperature at 70-90 deg.c, pH value at 4-7; stirring intensity at 50-70r/min and ripening time at 6-24h.

In the invention, meta-aluminate and soluble glass are used as raw materials to preparate aluminum oxide with high-temp. resistant and high specific surface by techonlogy that using sol-gel process to prepare aluminium oxide humidity gel and using supercritical fluid drying method to prepare aluminum oxide xerogel. The aluminum oxide contains silicon oxide (wt% is 0.1-10), the aluminum oxide xerogel is processed for 4h on 500 deg.c temp., its specific superficial area is more than 365 m2/g, then it is processed for 4h, its specific superfical area is more than 165 m2/g.

The invention relates to a composite heat-insulating material, comprising the following ingredients: 0.4-10 wt% of sepiolite, 0-5 wt% of brucite, 0-15 wt% of alumina silicate fiber, 5-10 wt% of asbestos fiber, 0.5-8 wt% of aerogel, 0-12 wt% of diatomite, 0-3 wt% of bentonite, 1-5 wt% of perlite, 0.5-5 wt% of dispersant, 0.1-1 wt% of polyvinyl alcohol, 0-1 wt% of soluble glass, 0-0.015 wt% of sodium cetanesulfonate, and the balance consisting of clear water. The invention also discloses a preparation method of the composite heat-insulating material. The composite heat-insulating material disclosed herein has low heat-insulating coefficient, good flexibility, and high tensile strength, and is difficult to pulverization. In addition, the method has the advantages of simple process, high production efficiency, and low energy consumption.

The invention relates to a hard surfacing sintered flux and a manufacturing method thereof. The sintered flux comprises MgO of 30 percent to 50 precent, CaO of 2 percent to 10 percent, Al2O3 of 10 percent to 20 percent, CaF2 of 18 percent to 28 percent, SiO2 of 10 percent to 20 percent, SiC of 0 percent to 1.5 percent and other components of 0 percent to 5 percent such as ferroalloy mainly playing a role of desoxidation and the like. Material preparation, dry mixing and wet mixing by adding soluble glass into a blender are conducted until granules which have the required sizes are formed, then the granules are dried in a rotary drying way at the low temperature of 200 DEG C to 250 DEG C, and then finished products are obtained by high-temperature sintering in a rotary drying oven at the high temperature of 700 DEG C to 750 DEG C, sieving and packaging. The invention has low flux cost so as to meet the requirements of different hardness, excellent technique and good high-temperature slag detachability; the deposited metal has no gas hole, no crackle but adjustable hardness; and the high-temperature wear-resistance, oxide etch resistance and cold and thermal fatigue resistance of a hot roll are greatly improved.

The invention discloses a benefication method for concentrating fine tungsten ore in tailings by warming scheelite, which is characterized by comprising the following steps in turn: performing desliming and reagent removal; condensing concentrate after desliming and reagent removal, which is added with water, into 26 to 44 percent of pulp density, and controlling the pH of pulp at about 8.5; performing floatation on the fine tungsten ore; adding regulators of sodium fluosilicate, soluble glass, aluminium sulphate and lead nitrate; and adding collecting agents of benzohydroxamic acid and sulfated oleate soap, and performing rough concentration, concentration and scavenging to obtain the fine tungsten ore concentration and fine tungsten tailings. The method has simple recovery process flow, stable benefication process, high tungsten recovery rate, and low cost of reagents; the used benefication reagents do not pollute environment; and tailing water can meet the emission requirement. The method is suitable for the fine tungsten ore, of which the WO3 content is 0.95 to 5.10 percent, the ratio of peanut ore to the scheelite is between 1:9 to 9:1, and the occupancy rate of WO3 metal smaller than 30 microns is more than or equal to 60 percent, and which is subjected to concentration of the tailings by warming the scheelite and then reconcentration of the tailings by a shaker.

The invention relates to a method for synthesizing ZSM-5/ZSM-5 core-shell type zeolite molecular sieve, mainly solving the technical problems of expensive used raw materials, great environment pollution of template agent, high difficulty of industrial amplification and synthesis, difficult industrial production and the like of the core-shell type zeolite molecular sieve in the prior art. The invention adopts the following technical scheme: the core-shell zeolite molecular sieve is prepared by adopting ZSM-5 core phase molecular sieve with a relatively low silica alumina ratio as a seed crystal, using at least one of soluble glass, silica solution, sodium silicate, white carbon black or atlapulgite which are cheap and easily obtained as a silicon source, and taking at least one organic amine from ethylamine, ethanediamine, propylamine and butylamine or the mixture of the organic amine and inorganic amine as a template agent so as to better solve the above technical problems. The invention can be used in industrialized synthetic production of core-shell type molecular sieve.

The invention relates to a method for preparing soluble glass by using waste residues with aluminum extracted by coal gangue. The method comprises firstly mixing and grinding the waste residue with aluminum extracted by coal gangue and sodium carbonate to be 1-50mu m particles, then conducting temperature programming in a muffle furnace, conducting low temperature congruent melting reaction for 1-5 hours at the temperature of 500-850 DEG C, and conducting water quenching to obtain coarse sodium silicate solid; and placing the coarse sodium silicate solid in a high pressure reactor, adding distilled water, heating to be 150 DEG C, stirring and dissolving for 5 hours, cooling to be room temperature, filtering and separating to obtain a colorless and transparent sodium silicate solution, and crystallizing to be the soluble glass. The method lowers the temperature for preparing sodium silicate by using a traditional soda ash method by about 600 DEG C, greatly reduces energy consumption, and simultaneously avoids highly corrosive of a traditional caustic soda alkali-dissolution method on production facilities and alkali pollution on the environment.

The invention discloses a Fischer-Tropsch synthesis iron-based catalyst and a preparation method thereof. The preparation method comprises the following steps: 1, carrying out a coprecipitation reaction on an aqueous solution of an iron salt, a copper salt and a cobalt salt, and an aqueous solution of potash to obtain a precipitation slurry; 2, ageing the precipitation slurry, adding water, uniformly stirring, and concentrating to remove partial water; 3, adding potassium silicate soluble glass or a silicon sol to the concentrated precipitation slurry, uniformly stirring, and allowing the obtained mixture to stand for 0-180min; and 4, carrying out spray drying and roasting on the slurry obtained in step 3 to obtain the Fischer-Tropsch synthesis iron-based catalyst. The preparation method of the Fischer-Tropsch synthesis iron-based catalyst of the invention selects potash as a precipitating agent, and potassium is one component for composing the catalyst, so no impurity ions are introduced, the washing process is omitted, and a large amount of a water resource is saved; the preparation technology is simplified, so interference factors in the catalyst preparation process are reduced; and the atomic utilization rate of raw materials in the catalyst preparation process is improved.

The invention discloses a fly ash/bentonite ceramsite concrete hollow insulation block and a preparation method thereof. The block is prepared from the following raw materials by weight: 100 to 150 parts of ordinary Portland cement grade 42.5, 500 to 600 parts of stone chippings, 30 to 40 parts of fly ash, 10 to 15 parts of bentonite, 5 to 10 parts of paper pulp waste liquid, 2 to 4 parts of nanometer alumina, 3 to 6 parts of light calcium carbonate, 20 to 30 parts of soluble glass, 10 to 15 parts of straw powder, 4 to 6 parts of a foaming agent, 1 to 2 parts of foots, 2 to 3 parts of a glass fiber, 0.5 to 1.5 parts of a redispersible latex powder and 150 to 210 parts of water. The boron fly ash/bentonite ceramsite concrete hollow insulation block produced in the invention has the advantages of high strength, low density, good heat insulation performance, good impact resistance, small possibility of water absorption, fire resistance, flame retardation, good weatherability, environment-friendliness, energy conservation and the like and has great market space and development prospects in the application field of building energy conservation in China.

The invention relates to a fracturing proppant used for oil and gas wells, which is prepared with the following materials by weight: 80 to 88 portions of low content bauxite, 1 to 4 portions of manganese ore, 2 to 3 portions of potash feldspar, 2 to 4 portions of solid soluble glass, 1 to 5 portions of calcium mountain meal, and 1 to 5 portions of French chalk. The quality of the fracturing proppant is stable; the break resistance is high; the acid corrosion resistance is high; the volume density is low; the fracturing proppant can effectively prop up fracture, and significantly improve the permeability in the fracture so that oil and gas flow smoothly, and the oil productivity is improved. In addition, the raw materials and the preparation method are simple, and low requirements are proposed about the raw materials, and the fracturing proppant is prepared simply.

Disclosed is a steel slag-metakaolin compound gel material which comprises steel slag, metakaolin, soluble glass solution, sodium sulfate, and sodium fluoride by the mass proportion of steel slag : metakaolin : soluble glass solution : Na2SO4 : NaF = 1:0.1-9:0.66-8:0.033-0.3:0.022-0.2.

The invention provides a high temperature far infrared insulation energy-saving coating material and its preparing process, wherein the coating material comprises zircon sand, aluminium oxide, porcelain clay, rare-earth oxide, boron nitride, silicasol, phosphoric acid, soluble glass, cellulose methyl or cellulose glycolate. The preparing process consists of batching, immersing, agitating, mixing, filtering and loading.