The invention relates to a normal temperature methane high-efficiency adsorption material and a preparation method thereof. The material is characterized in that a metal organic skeleton composite material containing transition metals Fe III, Zn II, Cu II, Ni II and Co III grows on an active carbon ceramic mainly prepared from active carbon and molecular sieve in an in situ manner. The preparation method of the normal temperature methane high-efficiency adsorption material comprises the following steps: carrying out dry mixing and ball milling on one or more of chlorides and sulfates of Fe<3+>, Zn<2+>, Cu<2+>, Ni<2+> and Co<3+>, high-specific surface area coconut shell active carbon, Y molecular sieve, attapulgite, kaolin and methyl cellulose in proportion, adding a certain amount of water, carrying out wet mixing, kneading, carrying out vacuum pugging, ageing, carrying out extrusion molding, drying in the shade, carrying out microwave irradiation sizing to obtain an active carbon ceramic molding material containing transition metals, immersing the molding material in a mixed solution containing an organic solvent, an deprotonated alkali and an organic carboxylic acid ligand according to a certain ratio, reacting at 120-180DEG C for 6-24h, carrying out solid-liquid separation, washing, and carrying out microwave vacuum drying to obtain a metal organic skeleton-active carbon ceramic composite material. The material has the characteristics of large specific surface area, developed aperture, high compressive strength, large methane adsorption capacity and high CH4/N2 and CH4/CO2 separation coefficients, and can be widely used in the fields of methane pressure swing adsorption separation and low-concentration methane recovery.