The invention relates to a
urea bond modified bismaleimide resin-based
elastomer and a synthesis method thereof, and belongs to the field of
elastomer composites.The synthesis method comprises the following steps that S1, raw materials are dehydrated; s2, preparing an
isocyanate solution from
isocyanate and a
solvent, and adding polyether amine into the
isocyanate solution; s3, heating and pre-polymerizing the reaction solution to obtain a
prepolymer; s4, an amino-terminated chain
extender is added for a chain extension reaction; and S5, mixing the
diamine compound containing carbamido and bismaleimide for reaction, and cooling to obtain the
urea bond modified bismaleimide resin-based
elastomer. When the carbamido-containing
diamine compound reacts with bismaleimide, the amino group of the carbamido-containing
diamine attacks the
double bond of the bismaleimide to form a carbamido-containing intermediate, and then the carbamido-containing intermediate is cyclized to generate a stable
imide structure. The reaction not only can effectively enhance the mechanical properties such as tensile strength and
impact toughness of the resin, but also obviously improves the key properties such as
heat resistance,
chemical corrosion resistance,
water resistance and dimensional stability of the resin.