The invention relates to the technical field of preparation of rubber composite materials, in particular to a glycerin-
carbon black covalent conjugate, a rubber
composite material and a preparation method of the glycerin-
carbon black covalent conjugate. Acidifying the
carbon black to oxidize carbon atoms at the edge or defect of the carbon black to generate carboxyl so as to obtain carboxylated carbon black; under a protective
atmosphere, carrying out acylating chlorination on the carboxylated carbon black to obtain acylating chlorinated carbon black; under a protective
atmosphere,
acylation reaction is carried out by taking acylating chlorination carbon black and
glycerol as a
reaction system, and the
glycerol-carbon black covalent conjugate is obtained. The rubber
composite material is obtained by mixing and vulcanizing the
glycerol-carbon black covalent conjugate, rubber, a cross-linking agent, an activating agent and an
accelerant. According to the invention, the glycerol-carbon black covalent conjugate plays a role of'bridge-
lubrication-synergistic reinforcement ', so that the
Mooney viscosity is reduced, the fluidity is improved, the
mechanical property is improved through chemical bonds, the dynamic
heat generation is reduced, the
wear resistance is enhanced, and the rubber composition is suitable for precise rubber products and has processability and performance advantages.