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Low-gloss polyolefin elastomer composite material and preparation method thereof

A technology of polyolefin elastomer and composite material, which is applied in the field of low-gloss polyolefin elastomer composite material and its preparation, can solve the problems of secondary pollution, high price of polyolefin elastomer, complicated preparation process, etc., and achieve good toughness, The effect of eliminating gloss and simple preparation process

Inactive Publication Date: 2013-05-22
HEFEI GENIUS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] The present invention aims at the problems of high price, complicated preparation process and secondary pollution of polyolefin elastomer existing in the prior art, and provides a low-gloss polyolefin elastomer composite material suitable for industrialized continuous production and high cost performance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Weigh respectively 65.0 parts of dry copolymerized polypropylene, 10.0 parts of low-density polyethylene, 23 parts of ethylene octene copolymer, 0.5 part of matting agent EPDM-g-MAH, and 0.5 part of PP-g-MAH by weight. 0.3 part of antioxidant 1010, 0.1 part of antioxidant DSTDP, 0.1 part of lubricant ethylene bisstearamide, 0.3 part of silicone powder, and 0.2 part of hindered amine light stabilizer are mixed, and the uniformly mixed material is added to the double In the screw extruder, after being melted and extruded, and then water-cooled, it is cut into particles with a length of 1-5mm by a pelletizer to obtain the final product. Among them, the processing temperature of the extruder is 180°C, 195°C, 200°C, 200°C, 205°C from the feeding port to the die port, the main engine speed is 60-80rpm, and the vacuum degree is 0.3MPa.

[0036]

Embodiment 2

[0038] Weigh respectively 70.0 parts of dry copolymerized polypropylene, 18.5 parts of low density polyethylene, 10. parts of EPDM rubber, 0.2 part of matting agent PP-g-MAH, 0.3 part of antioxidant 1010, and 0.3 part of anti-oxidant 1010 by weight. Oxygen agent 168 is 0.1 part, lubricant ethylene bis stearamide is 0.1 part, hindered amine light stabilizer is 0.1 part, benzophenone light stabilizer is 0.2 part, white oil is 0.2 part, calcium stearate is 0.1 part 0.1 part of amide antistatic agent is mixed, and the uniformly mixed material is added to a twin-screw extruder, melted and extruded, and then water-cooled, and cut into particles with a length of 1-5mm by a pelletizer , to get the final product. Among them, the processing temperature of the extruder is 180°C, 195°C, 200°C, 200°C, 205°C from the feeding port to the die port, the main engine speed is 60-80rpm, and the vacuum degree is 0.3MPa.

[0039]

Embodiment 3

[0041] Weigh 50.0 parts of dry copolymerized polypropylene, 18.0 parts of low-density polyethylene, 30 parts of block copolymer of styrene and butadiene, 1.0 parts of matting agent POE-g-MAH, and 1010 parts of antioxidant 0.1 part of lubricant, 0.2 part of ethylene bis stearamide, 0.2 part of white oil, 0.1 part of calcium stearate, 0.1 part of hindered amine light stabilizer, 0.2 part of benzophenone light stabilizer, amide The antistatic agent is mixed at 0.1 part, and the uniformly mixed material is added to a twin-screw extruder, melted and extruded, and then water-cooled, and cut into particles with a length of 1-5mm by a pelletizer to obtain the final product. Among them, the processing temperature of the extruder is 180°C, 195°C, 200°C, 200°C, 205°C from the feeding port to the die port, the main engine speed is 60-80rpm, and the vacuum degree is 0.3MPa.

[0042]

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PUM

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Abstract

The invention discloses a low-gloss polyolefin elastomer composite material and a preparation method thereof. The low-gloss polyolefin elastomer composite material is composed of polypropylene, polyethylene, a delustering agent, a toughening agent, an antioxidant, a lubricant, a light stabilizer and an aid. The composite material disclosed by the invention has the characteristics of low surface gloss, good toughness, excellent heat resistance and the like, the raw materials are easily available, and the cost is low; and moreover, toxic and harmful substances such as vulcanizing agent and a vulcanizing aid are not added, secondary pollution is avoided, the preparation technology is simple, and the production cost is low.

Description

technical field [0001] The invention belongs to the technical field of polymer composite materials, and in particular relates to a low gloss polyolefin elastomer composite material and a preparation method thereof. [0002] technical background [0003] Polypropylene (PP) material has excellent heat resistance, good bending fatigue resistance, low price and wide application, but PP has poor low temperature toughness. In order to improve the toughness of polypropylene, copolymerized polypropylene is prepared by copolymerizing ethylene and propylene. Copolymerized polypropylene generally contains 1%-7% by weight of ethylene molecules and 99%-93% by weight of propylene molecules. On the polymer chain, ethylene molecules are inserted in the middle of propylene molecules in a random and block manner, which improves the toughness of polypropylene. However, the toughness of copolymerized polypropylene is much worse than that of elastomers. For special application environments, ...

Claims

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Application Information

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IPC IPC(8): C08L23/16C08L23/08C08L23/06C08L51/06C08L53/02
Inventor 杨桂生汪海
Owner HEFEI GENIUS NEW MATERIALS
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