16914results about How to "No secondary pollution" patented technology

The invention discloses a compound flocculant taking natural minerals as main components. The compound flocculant is mainly prepared from the following components by weight percent: 60%-85% of natural minerals, 8%-38% traditional inorganic flocculant and 3%-10% of organic polymer flocculant. According to the invention, key points are as follows: in the compound flocculant taking natural minerals as main components, the weight of the natural minerals, the inorganic flocculant and the organic polymer flocculant is dry weight; and the compound flocculant is implemented to purification of civil engineering wastewater, natural water, industrial wastewater, oily wastewater, fluoride wastewater, food processing wastewater, auto parts processing wastewater, colored wastewater, clean wastewater, semiconductor processing wastewater, restaurant waste water, mine water, slaughter wastewater, grinding wastewater, sewage effluent and the like.

The invention provides a method for processing de-nitration on the boiler smoke, belonging to the environmental protective technique. The method comprises: ejecting ozone O3 into the low-temperature section of smoke channel of boiler whose temperature ranges from 110-150Deg. C; oxygenizing the nitric oxide NO into high-state nitrogen oxide as NO2, NO3 or N2O5; washing the smoke with alkali liquor to remove the nitrogen oxide in the smoke. Compared to other de-nitration method, said invention has higher efficiency, lower cost, and non-secondary pollution, while the absorption effect combined with alkali liquor can reach more than 80%. In addition, the invention can apply variable boiler devices, which is not relative to the burning condition of boiler.

The invention discloses a super-hydrophilic and underwater-super-oleophobic oil-water separation mesh membrane, and a preparation method and an application thereof. According to the method, fabric mesh with a specification of 100-300 meshes is subjected to ultrasonic cleaning, and is air-dried under normal temperature; a hydrophilic polymer water-sensitive agent and a cross-linking agent are dissolved in water according to a ratio of 1:9-9:1; the mixture is well mixed by magnetic stirring, such that a solution with a concentration of 1-99% is prepared; nano-sol is prepared with a sol-gel method; the solution and the nano-sol are prepared into a mixed solution with a concentration of 1-99%, and the solution is well dispersed through ultrasonic dispersion; the mesh is soaked in the mixed solution and is vertically lifted, or the mesh is directly sprayed by using a high-pressure spraying gun; and the mesh is bake-dried, such that the super-hydrophilic and underwater-super-oleophobic oil-water separation mesh membrane is obtained. Contact angles of the super-hydrophilic and underwater-super-oleophobic oil-water separation mesh membrane with water and oil in air are both 0 DEG, and the membrane is super-hydrophilic. Under water, the contact angle of the membrane with oil drops is larger than 150 DEG, and the membrane has an oil drop low adhesion characteristic. The mesh membrane provided by the invention can be used in oil-water mixture separation and oil-containing sewage processing.

The invention relates to a synthesized recovery method for waste positive plates of iron phosphate lithium batteries. The method comprises the following steps: collected waste positive plate material is mechanically crashed into fragments; the fragments are positioned in a welding furnace which is protected by vacuum atmosphere, inert gases and/or reducing gases and/or nitrogen and are heat processed in the temperature of 150-750 DEG C; aluminum foil basal bodies are separated from the fragments after heat process by adopting mechanical separation or ultrasonic concussion to obtain a mixture of iron phosphate lithium positive material, conduction agent and caking agent giblets; the mixture of iron phosphate lithium anode material, conduction agent and caking agent giblets is roasted for 8-24 hrs in 80-150 DRG C; the mixture after roasting is classified to control the grain diameter of the powder material to be not more than 20 microns, and the D50 is controlled to be 3-10 microns so as to obtain iron phosphate lithium positive recovery material. The method has simple technique, takes effect fast and reduces the material consumption and production cost of a manufacturer.

The invention relates to a sludge drying and burning technique and its system devices, applying to the handling of active sludge in urban sewage treatment plants, its process flows through: wet sludge stock house, measuring bin, sludge mixer, sludge dryer, granular splitter, cooler, drying products storage bin, incinerator, smoke gas cleaning devices, which is characterized by: said incinerator is bubbling fluid bed incinerator with coal economizer, air heater fixed in its end part, high-heat smoke gas generated by burning is used to heat heat-conducting oil and cool air individually, and heat-conducting oil after being heated is transferred to sludge dryer through the circulating pump to dry wet-sludge. The invention is characterized by: take heat-conducting oil as heating medium, use the heat generated by burning dry sludge to heat heat-conducting oil and then dry wet-sludge to make full use of resources; the volume-reducing quantity after drying and burning could reach over 90%; the percentage of desulphurization in incinerator could reach 75% as a result of adopting two stage technology of sulfur removal, and the gross percentage of desulphurization meets national environmental legislation requirements. The invention accomplishes the resources, volume reduction, and innocence of sludge.

A centrifugal cleaning apparatus for the air or fume, such as treating oil soot, exchanging air, and desulfurizing fume, features that at least one rotary netted filter disc is arranged to the axle of a motor in an air guiding cylinder. Said rotary netted filter disc is composed of a disc skeleton and a radiant filtering net wound uniformly on said disc skeleton. A method for preparing said rotary netted filter disc is also disclosed.

The invention discloses a novel method of the harmless treatment and utilization of livestock and poultry which died of disease according to the steps as follows: firstly, various kinds of the animal bodies of the livestock and the poultry which died of disease are collected; secondly, the animal bodies are crushed; thirdly, the crushed animal bodies are sterilized under high temperature and highpressure and separated for filtering, the material of oil and fat flows into a cooling pool, and the material of hair and bone is dried; fourthly, the material of hair and bone after drying is carbonized; fifthly, the material of oil and fat after cooling is added with catalyst, high-efficiency compound microorganism, trash, organic wastewater and sludge; sixthly, the mixed organic material is put into an anaerobic tower to be fermented, and then biogas, biogas slurry and biogas slag are processed for three-phase separation; seventhly, the biogas is used for burning and generating electricity; eighthly, the biogas slurry inside a fertilizer storing pool is used as farmland fertilizer; ninthly, the biogas slag is added with the high-efficiency compound microorganism and the catalyst for secondary ferment; tenthly, the material after the secondary ferment is made into agricultural high-efficiency organic fertilizer. The invention solves the problem of the environmental pollution caused by the livestock and poultry which died of disease and change the waste livestock and poultry which died of disease into valuables.

The invention relates to a kieselguhr-based porous ceramics, a preparation method thereof and a method for loading Ag doped with nano TiO2 on the same, belonging to the technical field of a kieselguhr inorganic material. The kieselguhr-based porous ceramics is made from kieselguhr, a sintering auxiliary agent, a dispersing agent, a binder and water in the weight ratio of 60-92:8-40:0.01-2:0:001-1:100-450. The kieselguhr-based porous ceramics has functions of absorption and filtration, and can absorb granules in fluid when the fluid passes through the lieselguhr-based porous ceramics. Ag doped with nano TiO2 is loaded on the kieselguhr-based porous ceramics to generate kieselguhr-based porous ceramics loading the Ag doped with TiO2. The laden anatase-type nano TiO2 has large specific surface area. The effects of filtration, photochemical catalysis and sterilization of the kieselguhr-based porous ceramics loading the Ag doped with nano TiO2 are greatly increased.

The invention relates to an ammonia process flue gas treatment method for acidic tail gas. The method includes the steps of: 1) controlling the sulfur dioxide concentration of tail gas entering an absorption tower at a level of less than or equal to 30000mg/Nm<3>; 2) arranging process water in an absorption tower entrance flue or in the absorption tower or cooperating with a ammonium sulphate solution to perform spray cooling; 3) disposing an oxidation section in the absorption tower, setting an oxidation distributor at the oxidation section to achieve oxidation of a desulfurized absorption liquid; 4) arranging an absorption section in the absorption tower, utilizing an absorption liquid distributor in the absorption section to realize desulfurization spray absorption by an ammonia-containing absorption liquid, which is fed through an ammonia storage groove; 5) arranging a water washing layer at an absorption section upper part in the absorption tower, washing the absorption liquid in the tail gas by the water washing layer and reducing the absorption liquid escape; and 6) setting a demister at the upper part of the water washing layer in the absorption tower to control the mist drop content in the purified tail gas. Employment of the Claus sulfur recovery and ammonia process desulfurization integrated desulfurization technology in the coal chemical industry can reduce the investment cost of after-treatment, the process can be simpler, and factory environmental protection treatment can form an intensive advantage.

The invention discloses composite hydrogel for adsorption of metal ions and a preparation method thereof. The hydrogel comprises, by weight, 5-95 parts of polyvinyl alcohol, 5-95 parts of chitosan, 0.1-20 parts of modified graphene oxide and 2-6 parts of sodium alginate, the weight ratio between the polyvinyl alcohol and the chitosan is (5: 95)-(95: 5), modified graphite oxide includes modified graphene oxide modified by dopamine and/or modified graphene oxide modified by ferroferric oxide, all components are uniformly mixed in a certain sequence, and the composite hydrogel is obtained under special conditions. The composite hydrogel for adsorption of the heavy metal ions and the preparation method thereof have the advantages that high speed, high efficiency, high adsorption capacity and high selectivity are achieved, the adsorption effect on the heavy metal ions is remarkable, meanwhile, the preparation process is simple, and the operability is high.

The invention relates to the chemical technology field, and concretely relates to a formaldehyde scavenging agent with oil solubility and a preparation method and a usage method. The formaldehyde scavenging agent with oil solubility can be prepared to paint, and can be used for coating on the furniture, floor or other decoration sheet materials, and has good purification efficiency on indoor free formaldehyde, and no secondary pollution can be generated. On the premise of no change of the sheet material application and construction technology in the prior art, and the release of indoor formaldehyde can be fundamentally controlled. The preparation method is simple, the usage is convenient, and the formaldehyde scavenging agent is suitable for large-scale production and business application for enterprises, has good application prospect, and has obvious economy and social benefit.

The invention which relates to a culture method of short-cut nitrification and denitrification granular sludge belongs to the technical field of water processing. The culture method is characterized in that: hydroxylamine with the concentration of 5-15mg/L is regularly added to gradually improve COD, ammonia nitrogen, and the phosphorous load in water to culture aerobic granular sludge. The effect of the culture method of the invention is the selective inhibition of hydroxylamine to NOB, so AOB and denitrifying bacteria are enriched. High waterpower shearing force (completed in an aeration mode) is needed to form the granular sludge, so an over-high aeration level allows DO in water to be improved, but low DO is needed by the short-cut nitrification, thereby above problem is solved through the intermit hydroxylamine addition. Hydroxylamine is an intermediate product of a nitration reaction, so the addition of a small amount of hydroxylamine generates no secondary pollution, thereby the culture method of the short-cut nitrification and denitrification granular sludge has a wide market application prospect.

The invention discloses a photochemical advanced oxygenation-based simultaneous desulfuration and denitration system. The system is provided with a burning and exhausting system consisting of a burner, an electrostatic dust collector, a heat exchanger, a spray tower, a liquid adding tower and a chimney, wherein fume generated by the burner enters the electrostatic dust collector, fume particles are removed from the fume by the electrostatic dust collector, the fume enters the heat exchanger and is cooled by the heat exchanger, and then the fume enters the spray tower; an UV light tube is arranged in the spray tower; hydrogen peroxide solution from the liquid adding tower is pumped by a circulating pump, sprayed into the spray tower through an atomizing nozzle and is activated by ultraviolet light to decompose hydrogen peroxide and then generate hydroxyl radicals (.OH) with strong oxidizing property; after being contacted with the fume in the spray tower, the hydroxyl radicals undergoes a gas-liquid absorption reaction with the fume to oxidize and remove NOx and SO2 in the fume; the fume, after being absorbed and washed, enters the chimney from the top of the spray tower and is exhausted; and sulfuric acid solution and salpeter solution generated in the spray tower are pumped into the separating column by the circulating pump and are reacted with added ammonia water to generate agricultural fertilizers including ammonium sulfate and ammonium nitrate.

The invention relates to the field of environmental protection and restoration and in particular relates to an environmental-friendly heavy metal stabilizer used for soil restoration of an industrial pollution site and an application method thereof. The environmental-friendly heavy metal stabilizer is prepared from the following material components in parts by weight: 40-50 parts of clay mineral, 17-24 parts of adsorbing material, 10-18 parts of heavy metal chelating agent, 4-8 parts of heavy metal precipitating agent and 10-15 parts of alkaline modifier. Main ingredients of the adopted stabilizer are natural materials, heavy metal pollutant in soil can be rapidly and effectively stabilized through composite action such as chelating, precipitation and adsorption; the heavy metal pollutant is stabilized for a long time, toxicity and biological availability of the heavy metal pollutant can be reduced, risk of the heavy metal polluted soil to the environment and human health is reduced, and the heavy metal polluted soil is restored; besides, a soil texture improving ingredient is contained, so that soil is restored while tillability of the soil is improved.

The chain-net type solid-liquid separating mechanical apparatus for cutting aquatic weed and cleaning river includes one aquatic weed cutting mechanism, one aquatic weed and waste fishing mechanism, one compressing and conveying mechanism, one flow forming mechanism, one anchor locating mechanism, one intercepting and driving mechanism and one control system. It is used to cut, collect, solid-liquid separate, pile, etc for maintaining clean river.

The invention relates to a coal-fired power plant coal dust prepared activated coke flue gas comprehensive purification system and a technology. The technology provided by the invention comprises the following steps of: using coal dust in a coal-fired power plant as a raw material, simultaneously carrying out carbonization and activation on coal dust in an activated coke preparation reactor to obtain powdered activated coke, using pyrolysis gas obtained during the preparation process as reburning fuel and sending it into a boiler so as to remove part of NOx; sending the powdered activated coke into a flue gas adsorption tower, adsorbing pollutants such as sulfur dioxide, mercury and the like at an appropriate temperature, injecting ammonia gas and nitrogen oxide to perform a catalytic reduction reaction so as to remove nitrogen oxide; reusing the adsorbed activated coke after regeneration; sending the activated coke into the boiler for combustion after multiple adsorption/regeneration; regenerating the activated coke after adsorbing sulfur dioxide to obtain high-density sulfur dioxide gas to realize resource utilization. By the utilization of coal resources in a coal-fired power plant, the comprehensive purification of flue gas and the resource utilization of sulfur dioxide are realized without discharge of waste water, exhaust gas and solid waste.

The invention relates to a set of electrocatalytic strong oxidizer materials, comprising a nano-function anode material which compounds nano oxide particles and catalyzes metal nano particles on a titanium substrate, and a nano-function cathode material which takes titanium or stainless steel as a substrate and introduces transition metal nano-particles on the surface thereof. By the electro-catalytic advanced oxidation technology, under the catalytic action of electrocatalytic strong oxidizer materials, water body can generate a hydroxyl radical with strong oxidizing performance and an oxygen radical; and if a chloride ion exists in water, hypochlorite can be generated. Under the joint action of a plurality of types of strong oxidizers, the algae cells in the water body and various harmful bacteria can be killed; and simultaneously the ammonia in water and the water-soluble organic matters can be degraded, so the goal of purifying water is achieved. According to the electrocatalytic advanced oxidation theory, the electrocatalytic strong oxidizer materials does not need to add any chemical agent when in application, does not have secondary pollution, and has good safety, high efficiency and low energy consumption.

A method for recycling waste lithium iron phosphate batteries relates to a battery recycling method. The method provided by the invention aims to provide a battery recycling method which is simple in process and low in cost. The method comprises the following steps of: removing residual electric quantity of a waste lithium iron phosphate battery, taking out the cell of the battery and crashing the cell into fragments, soaking the cell fragments in sodium hydroxide solution and stirring; and then performing filtering, washing, drying and vibratory screening so as to obtain pure alumium, pure copper and a diaphragm on a screen, recycling alumium and copper through smelting so as to obtain mixed powder under the screen, cleaning the mixed powder by using acidic solution, performing drying and thermal treatment, adjusting the mol ratio of lithium to iron to phosphorus to carbon, and then performing ball milling, drying and roasting, thereby obtaining a lithium iron phosphate anode material. The method for efficiently recycling the waste lithium iron phosphate batteries provided by the invention is simple in process, low in production cost and quick in taking effect.

The invention relates to a preparation method of an organic exhaust gas micro-emulsion absorption liquid, and a method for applying the micro-emulsion absorption liquid for cleaning industrial organic exhaust gas comprising benzene, toluene, xylene, and the like. The invention belongs to the technical field of atmosphere pollution control. The absorption liquid is prepared from the components of, by mass, 80-90% of water, 0.5-3% of a surfactant, 7-19.5% of a coupling agent, and 0.02-0.06% of an auxiliary agent. The surfactant is sufficiently mixed with water, such that a surfactant solution is obtained; the auxiliary agent is dissolved in water, such that an auxiliary agent solution is obtained; the two solutions are combined and uniformly mixed; and the coupling agent is added, and the obtained solution is stirred, such that the organic exhaust gas micro-emulsion absorption liquid is obtained. The organic exhaust gas micro-emulsion absorption liquid is suitable to be used for controlling exhaust gas containing benzene-series volatiles, and has the advantages of convenient raw material source, low cost, mild and stable property, low toxicity, environment-friendliness, no absorption tower corrosion or blocking phenomena, no severe influence to human health, high removal rate to organic exhaust gas, no need of pretreatment upon exhaust gas, and low investment and running cost. Saturated absorption liquid and absorbed organics can be recycled, such that waste can be turned useful.