1241 results about "Ammonium sulfate" patented technology

The invention relates to the technical field of oilfield chemistry, and discloses a graft modified cellulose filtrate reducer and a preparation method thereof.The preparation method comprises the following steps that modified hydroxyethyl cellulose, 2-acrylamide-2-methyl propane sulfonic acid, dimethyl diallyl ammonium chloride, alkenylated cardanol and N, N '-methylene bisacrylamide are added into deionized water, stirring is conducted, and a mixture is obtained; the preparation method comprises the following steps: adding cellulose into a reaction kettle, stirring for 10-15 minutes at the temperature of 40-60 DEG C at the speed of 300-400 rpm, dropwise adding ammonium persulfate and sodium hydrogen sulfite into a system, and continuously reacting for 4-6 hours to obtain the grafted modified cellulose filtrate reducer. The filtrate reducer disclosed by the invention has good high temperature resistance and salt resistance.

The invention relates to the technical field of functional polymer composite materials, and provides diatomite modified composite super absorbent and rapid absorbent resin and a preparation method thereof. The preparation raw materials of the diatomite modified composite high-water-absorption and rapid-water-absorption resin provided by the invention comprise acrylic acid, acrylamide, sodium hydroxide, N, N '-methylene bisacrylamide, ammonium persulfate and modified diatomite. The diatomite is modified by the silane coupling agent, the agglomeration problem of the diatomite is solved, the compatibility with organic monomers is improved, and the modified diatomite, acrylic acid and acrylamide are utilized to construct an organic-inorganic synergistic three-dimensional porous network structure, so that the resin has ultrahigh water absorption rate, rapid water absorption performance and good water retention stability. Meanwhile, the preparation method disclosed by the invention does not need nitrogen protection, has the advantages of simple process, controllable raw material cost and easiness in industrial mass production, and is suitable for multiple fields such as water-saving agriculture, soil moisturizing, landscaping and the like.

The invention relates to the field of caprolactam production, and discloses a green and efficient production process and device. The process comprises the following steps: continuously oximating cyclohexanone and hydroxylamine in a microreactor under the catalysis of mesoporous silica solid acid; carrying out gas phase rearrangement on cyclohexanone-oxime in the presence of a ZSM-5 molecular sieve under the assistance of microwaves; coupling, rectifying and purifying the crude product through a four-stage molecular sieve membrane; and performing catalytic cracking on the by-product to obtain N2 / H2O and recycling. The device comprises a micro-reaction unit, a microwave-radial reactor, a membrane coupling rectifying tower group and a tail gas cracking unit. Zero emission of ammonium sulfate is achieved, the product purity is larger than or equal to 99.95%, and energy consumption is reduced by 45%.

The invention relates to the technical field of polymer photoelectric materials, in particular to a preparation method of a supramolecular gel electrolyte. The method comprises the following steps: esterifying tetraphenylethylene alcohol and methacryloyl chloride to form tetraphenylethylene methacrylate, and performing staged linear heating polymerization on the tetraphenylethylene methacrylate, 3-(methacrylamido) propyl dimethyl 3-thiopropyl ammonium oxide inner salt, acrylic acid, tetraphenylethylene methacrylate and 4-vinylpyridine under the action of ammonium persulfate to obtain a tetraphenylethylene copolymer. And finally, soaking in a lithium chloride aqueous solution to obtain the supramolecular hydrogel electrolyte. The hydrogel obtained by the invention has high mechanical strength and high ionic conductivity, and is suitable for energy storage devices such as flexible supercapacitors and the like.

The utility model discloses an ammonium sulfate wastewater treatment system which comprises an ammonium sulfate wastewater storage pool used for collecting ammonium sulfate wastewater, the calcium hydroxide preparation system is used for preparing a calcium hydroxide solution, an evaporator and a first circulating heater and is used for reacting ammonium sulfate wastewater and calcium hydroxide and heating and evaporating; the first crystallizer and the second circulating heater as well as the second crystallizer and the third circulating heater are used for two times of evaporative crystallization, a final concentrated solution is filtered by the filter and then flows into the mother liquor collecting tank to facilitate wastewater treatment, and evaporated ammonia gas is absorbed by the cooling absorption tower and the condensate collecting tank to form ammonia water; and condensate water of the second heat exchanger, the first circulating heater, the second circulating heater and the third circulating heater also flows back to the condensate collecting pool. According to the wastewater treatment system, ammonium sulfate wastewater and a calcium hydroxide solution are distilled and crystallized, so that calcium sulfate and ammonia water can be recovered, and waste utilization is realized.

The invention belongs to the technical field of solar-driven interface evaporation, and particularly relates to a solar-driven interface evaporation aerogel material based on gradient modification and a preparation method and application thereof. The preparation method specifically comprises the following steps: performing cross-linking reaction on chitosan and a cross-linking agent in an organic acid aqueous solution, and performing freeze drying to obtain a chitosan matrix with a three-dimensional network structure; a pyrrole monomer is uniformly dispersed in a network structure of a chitosan matrix, then the chitosan matrix is immersed in an ammonium persulfate solution, and by controlling the oxidative polymerization degree of ammonium persulfate to the pyrrole monomer, concentration gradient distribution gradually decreasing from the surface to the inside of polypyrrole is formed in the chitosan matrix, so that the polypyrrole / chitosan composite material is obtained. The solar-driven interface evaporation aerogel material based on gradient modification is obtained. The aerogel material provided by the invention combines a photothermal effect with interface evaporation, and achieves the purpose of reasonably and efficiently utilizing solar energy resources to carry out seawater desalination.

The invention relates to an ultrasonic vibration assisted large-width copper plate strip continuous extrusion short-process technology, and belongs to the technical field of metal processing. A copper raw material is subjected to mechanical cleaning and then ultrasonic cleaning, and the surface cleanliness of the raw material is guaranteed; the cleaned copper raw materials are fed into continuous extrusion equipment, and ultrasonic vibration is adopted for assisting continuous extrusion; after the extruded copper plate strip is cooled, spraying a suspension containing cerium (IV)-sodium dodecyl benzene sulfonate-pyrrolidone nano aluminum oxide additive on the surface of the copper plate strip, and drying; straightening by using a multi-roll straightening machine to obtain a large-width copper plate strip; the cerium (IV)-sodium dodecyl benzene sulfonate-pyrrolidone nanometer aluminum oxide auxiliary agent is prepared from nanometer aluminum oxide, DMF (Dimethyl Formamide), sodium dodecyl benzene sulfonate, N-vinyl pyrrolidone, ammonium persulfate and cerous sulfate (IV); the copper plate strip prepared by the invention has relatively high density, relatively high tensile strength and ductility, and the mechanical property of the copper plate strip is remarkably improved.

The invention discloses a preparation process of a rare earth precipitation resistant electrophoretic coating for an automobile body. The preparation process comprises the following steps: S1, preparing a stable solution; s2, preparing a rare earth chelating solution; adding lanthanum lactate into the stable solution for multiple times, and adding ammonium ceric sulfate for multiple times after the lanthanum lactate is completely dissolved; s3, preparing a resin base solution; s4, preparing mixed slurry; s5, adding a solvent and an auxiliary agent; a five-membered ring chelate with thermodynamic stability is formed by carboxyl, hydroxyl and rare earth elements in sodium citrate, rare earth ions can be tightly wrapped through strong coordination bonds, namely, empty orbits of the rare earth ions and lone pair electrons of a chelating agent form coordination bonds, so that the rare earth ions cannot be dissociated in a system, and the rare earth ions are prevented from being dissociated in the system. And a path of generating hydroxide precipitates by free rare earth ions is thoroughly blocked, so that rare earth elements are effectively ensured to be uniformly distributed in the electrophoretic paint, and the surface of a raw material treated by a subsequent electrophoresis process is more uniform.

The invention discloses a conductive layer coated ruthenium-doped beta-manganese dioxide catalyst and a preparation method and application thereof.The preparation method comprises the following steps that a manganese source, ruthenium trichloride trihydrate, an oxidizing agent and water are mixed, an obtained precursor solution is subjected to microwave synthesis, and the conductive layer coated ruthenium-doped beta-manganese dioxide catalyst is obtained. The obtained ruthenium-doped beta-manganese dioxide composite material, hydrochloric acid A and aniline are added into water, then hydrochloric acid B and ammonium persulfate are added, the obtained polyaniline-coated ruthenium-doped beta-manganese dioxide composite material is subjected to calcination treatment, and the conductive layer-coated ruthenium-doped beta-manganese dioxide catalyst is obtained. The conductive layer coated ruthenium-doped beta-manganese dioxide catalyst prepared by the invention has excellent catalytic activity and catalytic stability, and solves the problem of insufficient stability caused by high catalytic potential and catalyst dissolution in the test process of the anode catalyst of the proton exchange membrane electrolytic cell.

The invention relates to the technical field of evaporative crystallization control, in particular to an iron phosphate wastewater low-energy-consumption evaporative crystallization control system which comprises a preheating module, an evaporation concentration module, a steam circulation module, a steam detection module, a salt separation and recovery module and a low-energy-consumption control module. The evaporation and concentration module realizes water gradient evaporation and feed liquid concentration through evaporation units which are connected in series in multiple stages; the steam circulation module integrates a steam compressor and a steam ejector, leading equipment can be intelligently switched according to system requirements, and dual-mode operation of mechanical compression and thermal compression is achieved. The steam detection module judges the equipment state in real time by analyzing the rotating shadow and vibration waveform of the compressor and the audio waveform of the ejector; the salt separation and recovery module is used for continuously separating ammonium sulfate and monoammonium phosphate, recovering crystals and recovering condensed water for preheating; the low-energy-consumption control module dynamically adjusts the operation mode and steam parameters, and energy-saving optimization and stable control of the whole process are achieved.

The invention belongs to the technical field of chemical engineering and secondary resource utilization, and particularly discloses a collaborative utilization process of sodium sulfate and ammonium-containing waste salt. The high-value utilization method of sodium sulfate provided by the invention comprises the following steps: mixing sodium sulfate, organic ammonium salt and sulfuric acid, and adding water to prepare a mixed solution; extracting the mixed solution by using an extracting agent, and separating a water phase from an organic phase; adding a pH regulator into the water phase to regulate the pH to alkalescence, introducing carbon dioxide gas to fully react, cooling, crystallizing, and filtering to obtain filtrate and sodium bicarbonate precipitate; heating the filtrate for evaporative crystallization to obtain ammonium sulfate; and recovering the organic acid in the organic phase. The invention provides a subversive solution for sodium sulfate by-product accumulation and ammonium-containing wastewater treatment, has double values of resource circulation and carbon emission reduction, and has the advantages of full-flow closed-loop design, wide applicability, high product purity and high economical efficiency in process.

The invention discloses a trinitrile quenching purification device and process. The device comprises a quenching tower, a dust removal spraying outer circulation system and a deamination spraying outer circulation system, a process gas inlet, a gas uniform distribution plate, 2-3 stages of differential dust removal spraying layers, a liquid receiving and gas distribution assembly, 3-5 stages of deamination spraying layers and a three-stage demister are sequentially arranged in the quench tower from bottom to top; instant cooling and deep solid removal of the trinitrile gas at 210-220 DEG C are realized through subsection spraying of micro fog and large fog drops, and the solid content of circulating liquid is less than or equal to 20ppm; multi-stage deamination spraying is matched with online pH control, deep absorption of NH3 is achieved, polymerization is inhibited, high-purity dilute ammonium sulfate liquid with the solid and polymer content being smaller than or equal to 5 ppm and the concentration being 20%-28% is produced, and the total yield of trinitrile is larger than or equal to 98%; the device is compact in structure, stable in operation and convenient for industrial application.

The invention discloses a multipurpose comprehensive utilization system for flue gas of a garbage incinerator, and relates to the technical field of solid waste treatment and resource recovery. After steam generated by a waste heat boiler drives a generator set, medium-temperature and low-temperature flue gas is sequentially guided into a sludge drying system for heat energy coupling utilization; in the purification section, a synergistic removal process is adopted, and trapped pollutants are converted into ammonium sulfate fertilizer raw materials while acid gas and dioxin are efficiently removed; finally, the fly ash rich in heavy metal is guided into a melting system, and inert building material aggregate is formed through high-temperature vitrification. According to the integrated system, the limitation of traditional quality-divided treatment is broken through, the three targets of deep recovery of flue gas waste heat, collaborative resource conversion of pollutants and safe treatment of fly ash are achieved, the operation cost is greatly reduced, additional economic values are created, and a win-win comprehensive solution of environmental benefits and economic benefits is provided for a waste incineration plant.

The invention belongs to the technical field of self-repairing materials, and particularly relates to a double-microcapsule self-repairing waterborne polyurethane material and a preparation method thereof. Comprising the following steps: ultrasonically dispersing cellulose nanocrystals in deionized water to form a water phase, adding drying oil and lauryl sodium sulfate, and stirring to obtain the drying oil microcapsule taking Pickering emulsion as a template. Preparing a polyvinylpyrrolidone aqueous solution, a non-polar solvent solution of thiophene monomers and an ammonium persulfate aqueous solution; and mixing and ultrasonically dispersing the two, mixing with an ammonium persulfate aqueous solution, stirring and polymerizing to obtain a polythiophene microcapsule suspension after the reaction is completed, centrifuging until the supernatant is colorless, and washing and drying the solid to obtain the polythiophene microcapsule. And finally, adding the two microcapsules into waterborne polyurethane, uniformly mixing, and drying at room temperature to form the double-microcapsule self-repairing waterborne polyurethane material. According to the invention, the self-repairing and mechanical property improvement of the double-microcapsule self-repairing waterborne polyurethane material under room-temperature natural light are realized.

The invention discloses a low-shrinkage acrylate gel material and a preparation method thereof. The gel material is prepared by mixing a solution A and a solution B according to an equal proportion, the liquid A comprises acrylate, a cross-linking agent, an accelerant and a retarder; the acrylate is a calcium acrylate solution, a magnesium acrylate solution or a mixed solution of calcium acrylate and magnesium acrylate; the concentration of the acrylate in the solution A is 15wt.%-35wt.%; the liquid A is also added with a modified material, and the modified material is selected from at least one of hydroxyethyl ester, chloroprene rubber, polyurethane, polyvinyl alcohol and epoxy resin; the addition amount of the modified material is 1%-5% of the total mass of the solution A; the solution B comprises an initiator and distilled water; the initiator is selected from at least one of ammonium persulfate, hydrogen peroxide and azodiisobutyronitrile; the use amount of distilled water in the solution B is determined according to initiator concentration; by optimizing an acrylate compound system, introducing an anti-shrinkage functional component and accurately controlling a preparation process, the comprehensive improvement of material performance and engineering applicability is finally realized.

The invention discloses a method for separating and recycling phosphorus, iron and lithium in battery black powder, and relates to the technical field of battery recycling. The method comprises the following steps: carrying out acid leaching on battery black powder to obtain a battery black powder leaching solution and filter residues; an oxidizing agent is added into the battery black powder leaching solution, the pH of the solution is adjusted to 1.8-2.5, solid-liquid separation is conducted after the reaction is completed, and iron phosphate sediment and a lithium-containing solution are obtained; adjusting the pH value of the lithium-containing solution to 10-12, and carrying out solid-liquid separation after the reaction is completed to obtain a metal precipitate and a lithium sulfate solution; dissolving the iron phosphate precipitate in a sulfuric acid solution, adding a reducing agent to reduce ferric iron into ferrous iron, separating out ferrous sulfate by adopting an alcohol precipitation method or an ammonium sulfate crystallization method, and performing solid-liquid separation after the reaction is completed to obtain ferrous sulfate precipitate or ammonium ferrous sulfate crystals and mother liquor; and evaporating and concentrating the mother liquor, and extracting to obtain a phosphoric acid solution. According to the method, the three elements of phosphorus, iron and lithium in the battery black powder can be recycled, and the environmental problem caused by stacking of the lithium extraction slag can be avoided.

The invention discloses a method for separating and recycling phosphorus, iron and lithium in battery black powder, and relates to the technical field of battery recycling. The method comprises the following steps: mixing and leaching battery black powder and sulfuric acid, and filtering to obtain a leaching solution; the pH of the leachate is controlled, ferrous sulfate in the solution is separated out through alcohol substances or ammonium sulfate, and ferrous sulfate precipitates or ammonium ferrous sulfate crystals and mother liquor are obtained after filtration; evaporating and concentrating the mother liquor, adding an impurity removing agent into the mother liquor, and extracting to obtain a phosphoric acid solution and a lithium-containing solution; after phosphoric acid is supplemented into the lithium-containing solution, the pH is adjusted to be 8-10, and battery-grade lithium phosphate precipitates are obtained. According to the method, iron in the leachate is separated out firstly, and the subsequent impurity removal difficulty is greatly reduced, so that recycling of three elements including phosphorus, iron and lithium in the battery black powder is facilitated, and the environmental problem caused by stacking of lithium extraction residues can be avoided.

The present application belongs to the technical field of waste lithium ion battery recycling, and discloses a method for preferentially extracting lithium from waste ternary lithium ion battery powder: waste ternary lithium ion battery powder is mixed with water, ammonium sulfate and concentrated sulfuric acid to form a slurry; the slurry is subjected to ripening treatment; the ripened material is ground and then water immersed to obtain a lithium-containing solution and a water immersion residue. The method for preferentially extracting lithium from waste ternary lithium ion battery powder combines pyrometallurgical and hydrometallurgical means, not only has low energy consumption, but also has a reaction system temperature far lower than the high temperature required by conventional pyrometallurgical processes; moreover, the method exhibits significant selectivity in the process of recovering lithium, which not only improves the recovery efficiency of lithium and reduces the interference of other metals, but also reduces the types and amount of required reagents. In addition, the method does not require complicated impurity removal means, and is a method for treating waste ternary lithium ion battery powder with low industrial cost and high return rate.

The application discloses a polishing liquid and a polishing method for a laser gyroscope cavity, and the polishing liquid comprises a polishing liquid and acid-resistant soft abrasive particles, the polishing liquid comprises the following components in mass fraction: HF 5-20%, H2SO4 5-10%, CH3COOH 10-20%, NH4HF 10-20%, disodium ethylenediaminetetraacetate 2-5%, ammonium sulfate 2-5%, and the balance is water; the mass of the acid-resistant soft abrasive particles is 10-20% of the mass of the polishing liquid. The polishing method comprises circulating jet polishing of the polishing liquid at a flow rate of 500-600 mL / min through the laser gyroscope cavity. The polishing liquid can realize one-time polishing of the laser gyroscope cavity during polishing, not only has good polishing effect, but also greatly improves polishing efficiency and greatly reduces polishing cost, and can also avoid the uneven corrosion caused by the traditional polishing method of fixing the cavity.

The invention relates to a method for improving fermentation production efficiency of bacillus subtilis lipopeptide sodium by controlling threonine flow acceleration rate based on fermentation process oxygen uptake rate curve feedback. Bacillus subtilis is used as a production strain, and lipopeptide sodium is produced through deep liquid state fermentation. In the fermentation process, the oxygen uptake rate of the process is detected, a threonine and ammonium sulfate continuous feeding control process based on oxygen uptake rate curve parameters is implemented, the oxygen uptake rate in the fermentation process is stably maintained to be 60-65 mmo1 / L / h, the ammonium ion concentration is maintained to be 15-20 mmol / L, and rapid growth of hyphae and rapid increase of the lipopeptide sodium synthesis rate can be achieved. The threonine and ammonium sulfate fed-batch control process based on oxygen uptake rate feedback control is established, the production period is shortened, and the fermentation production level is stably improved.

The invention belongs to the technical field of petroleum drilling engineering, and discloses a chitosan-quaternary ammonium salt modified composite shale inhibitor and a preparation method thereof. According to the inhibitor, natural chitosan is used as a main chain, dimethyl diallyl ammonium chloride (DMDAAC) is adopted for free radical grafting modification, glycine is combined as a synergistic auxiliary agent, and a composite structure with high cation density is constructed. The preparation method comprises the following steps: dissolving 15-25 parts of chitosan in 1000 parts of 1% glacial acetic acid, and stirring at room temperature; dropwise adding 2 to 4 parts of DMDAAC, reacting at 65 to 75 DEG C, and then adding 0.1 to 1 part of ammonium persulfate for grafting for 3.5 to 4.5 hours; and cooling, filtering and drying to obtain powder. And dissolving 10-20 parts of the solution in deionized water, adding 1.5-2.5 parts of glycine, and uniformly mixing to obtain the composite inhibition liquid. The inhibitor has good water solubility and thermal stability, can significantly inhibit shale hydration expansion and particle dispersion, and experiments show that the inhibitor can be suitable for well wall stability control of complex stratums such as high-temperature deep wells and the like, and has good field adaptability and industrial popularization value.

The invention belongs to the technical field of microbial culture, and particularly relates to a culture medium composition and application thereof in PDRN recombinant escherichia coli fermentation. The culture medium composition comprises a fermentation culture medium and a fed-batch culture medium, the fermentation culture medium consists of disodium hydrogen phosphate, monopotassium phosphate, ammonium sulfate, magnesium chloride, calcium nitrate tetrahydrate, glycerol and water; the supplemented culture medium is composed of dipotassium phosphate, sodium dihydrogen phosphate, sodium sulfate, ammonium sulfate, ammonium chloride, diammonium hydrogen citrate, glycerin and water, and the metabolic requirements of PDRN recombinant escherichia coli are accurately matched. Meanwhile, the invention provides a fermentation method using the composition, and the problems of unbalanced nutrition, low fermentation efficiency and the like of an existing culture medium are solved. Stable proliferation of thalli can be remarkably promoted, the yield of PDRN products is increased, the culture medium is easy and convenient to prepare, fermentation conditions are easy to control, and the culture medium is suitable for industrial large-scale production and has important application value.

The invention discloses a formaldehyde-free composite board for a cabinet and a preparation method of the formaldehyde-free composite board, and relates to the technical field of artificial board manufacturing. The preparation method of the formaldehyde-free composite board for the cabinet comprises the following steps: mixing high amylose with a choline chloride / urea deep eutectic solution, stirring, adding concentrated hydrochloric acid for reaction, adjusting the pH value, and adding ammonium persulfate to obtain pretreated oxidized starch; methacrylic acid dehydrated glyceride is added into the pretreated oxidized starch for a grafting reaction, then modified polyvinyl alcohol is added for blending, sodium metaphosphate is added for crosslinking, finally, heating and curing are conducted, modified titanium dioxide nanoparticles are added, and the formaldehyde-free starch adhesive is obtained. The wood shavings and the formaldehyde-free starch adhesive are mixed, and a core material is obtained; and arranging the core material between the formaldehyde-free veneers, and carrying out hot press molding to obtain the formaldehyde-free composite board. The formaldehyde-free composite board for the cabinet has excellent mechanical strength, bonding performance and water resistance.

The invention relates to the technical field of polymer composite materials, and provides a composite water-retaining agent based on charcoal and bentonite as well as a preparation method and application of the composite water-retaining agent. The composite water-retaining agent provided by the invention is prepared from the following raw materials: acrylic acid, 2-acrylamido-2-methyl-1-propanesulfonic acid, acrylamide, sodium hydroxide, N, N '-methylene bisacrylamide, ammonium persulfate, modified bentonite and corn straw biochar. The composite water-retaining agent provided by the invention has excellent salt resistance, water holding capacity and structural stability, and the water absorbency in pure water and a 0.9% NaCl solution respectively reaches 2547.30 g / g and 164.45 g / g; when the soil conditioner is applied to saline-alkali soil, the maximum water holding capacity of the soil can be remarkably improved. The preparation process is simple, the cost is low, and the method has important practical significance on promoting ecological environment restoration of the arid mining area and realizing coordinated development of mineral resource development and environmental protection.

The invention discloses a preparation method of a flexible electronic device with specific wet adhesion capability, which comprises the following steps: dissolving acrylamide Am, methacrylic acid esterified gelatin GelMA and chitosan powder in an acetic acid solution, uniformly stirring, adding carboxylated multi-walled carbon nanotubes (MWCNTs) into the mixed solution, stirring uniformly, and drying to obtain the flexible electronic device with specific wet adhesion capability. Performing ultrasonic treatment, water bath treatment and degassing treatment to obtain a precursor solution; the preparation method comprises the following steps: mixing sodium monohydrogen phosphate and sodium dihydrogen phosphate, adding sodium bicarbonate, adding ammonium persulfate as an initiator, fully stirring, and degassing to obtain a gelling solution for inducing physical crosslinking of chitosan; selecting a material with carboxyl, amino and hydroxyl groups to manufacture a mold for polymer cross-linking molding; and mixing and stirring the precursor solution and the gelling solution, injecting into a prepared mold, placing at room temperature, and integrally forming to manufacture the flexible electronic device. The invention further discloses application of the flexible electronic device in preparation of a bioelectric sensor sensitive element and tissue repair.

The invention discloses a water-soluble fertilizer containing humic acid. The water-soluble fertilizer comprises the following components in parts by weight: 5-8 parts of ammonium sulfate, 28-32 parts of calcium ammonium nitrate, 18-22 parts of monoammonium phosphate, 32-38 parts of potassium sulfate and 10-15 parts of modified potassium humate. The preparation method comprises the following steps: carrying out alkali extraction on modified humic acid obtained by modifying lignite to prepare modified potassium humate, adding the modified potassium humate into a fertilizer raw material, and granulating to prepare the humic acid-containing water-soluble fertilizer. The preparation process comprises the following steps: S1, crushing and sieving the ammonium sulfate, the calcium ammonium nitrate, the monoammonium phosphate and the potassium sulfate, adding the modified potassium humate into a granulator in proportion, and uniformly stirring to obtain a mixture; s2, urea and water are prepared into a solution according to the mass ratio of 1: 3; and S3, uniformly spraying the urea guniting solution prepared in S2 into the raw material layer, and stirring until liquid drops and powder are in full contact to form particles to prepare the fertilizer. The humic acid-containing water-soluble fertilizer produced by the invention has the advantages of high nutrient content, soil structure improvement, crop root growth promotion and yield increase.

The preparation method comprises the following steps: (1) dissolving a zinc salt in a mixed solvent of ethanol, DMF (Dimethyl Formamide), ammonia water and water, dropwise adding triazole, carrying out stirring reaction at room temperature for 5-10 hours, then carrying out aging treatment for 20-30 hours, obtaining a solid product, washing the solid product, and drying the solid product to obtain zinc-triazole MOF; (2) heating the zinc-triazole MOF to 800-850 DEG C under the protection of inert gas, calcining for 2-4 hours, cooling, washing to remove metal ions, and drying to obtain MOF-derived porous carbon; and (3) adding the MOF-derived porous carbon into an aniline hydrochloride solution, uniformly dispersing, adding an ammonium persulfate solution, stirring and reacting for 5-10 hours, and washing and drying a product to obtain the MOF-derived porous carbon composite electrode material. The MOF-derived porous carbon composite electrode material is used as a negative electrode material to prepare the supercapacitor, and the supercapacitor has very excellent electrochemical performance and cycling stability.

The invention provides a water-soluble fertilizer and a compound fertilizer for promoting growth of oats in saline-alkali soil as well as a preparation method and application of the water-soluble fertilizer and the compound fertilizer, and belongs to the technical field of fertilizers and preparation thereof. The water-soluble fertilizer comprises the following components in parts by weight: 20-30 parts of urea, 25-35 parts of ammonium sulfate, 10-20 parts of ammonium polyphosphate, 40-50 parts of potassium sulfate and 5-15 parts of humic acid. The compound fertilizer comprises the water-soluble fertilizer and a seed embedding agent, the seed embedding medium is prepared from the following components in parts by weight: 0.5 to 1.5 parts of bacillus subtilis, 1 to 3 parts of plant lactobacillus, 3 to 5 parts of basophilic halomonas and 10 to 15 parts of kaolin. The components and contents of the water-soluble fertilizer meet the nutritional requirements of the oats in the growth and development period, and the growth of the oats in the saline-alkali soil is promoted. By adding the microbial agent, the pH and salt content of the saline-alkali soil are reduced, the salinization of the saline-alkali soil is improved, and the oat plant height, the overground plant quantity and the seed yield of the saline-alkali soil are obviously increased.

The invention provides a special fiber material and a preparation method thereof, and belongs to the technical field of polymer composites.The preparation method comprises the following steps that cellulose and an ethanol solution are mixed, polyvinyl alcohol and a 3-glycidoxypropyltrimethoxysilane solution are added, the pH is adjusted to be acidic, heating, suction filtration and drying are conducted, and modified cellulose is obtained; mixing expanded graphite, deionized water, ammonium persulfate and dilute sulphuric acid, heating, cooling, dropwise adding amino polyethylene glycol silane, heating, washing and drying to obtain modified expanded graphite; the preparation method comprises the following steps: mixing modified cellulose, modified expanded graphite, phosphate montmorillonite, 3-(methacryloyloxy) propyltrimethoxysilane, bisphenol A diglycidyl ether and 2-methylimidazole, stirring, heating, defoaming, and carrying out two-stage constant-temperature treatment to obtain the special fiber material. The special fiber material disclosed by the invention has good flame retardance, mechanical strength, water resistance and filtering performance, and can be applied to various organic composite boards, filter membranes and the like with high quality requirements.

The invention discloses zwitterionic concrete internal curing hydrogel based on humidity-pH dual responsiveness and a preparation method of the zwitterionic concrete internal curing hydrogel, and belongs to the technical field of building materials. The water-based cleaning agent is prepared from the following raw material components in percentage by weight: 6%-8% of N-vinyl imidazole, 8%-12% of 2-methylimidazole, 6%-8% of 2-acrylamido-2-methylpropanesulfonic acid, 2%-4% of sodium p-styrenesulfonate, 26%-30% of acrylic acid, 18%-21% of N-vinyl pyrrolidone, 15%-18% of glycidyl methacrylate, 2%-5% of nano montmorillonite powder, 0.05%-0.1% of divinyl benzene, 0.05%-0.15% of N, N-dimethylformamide and the balance of water. The invention discloses an anti-freezing agent which is prepared from the following components in percentage by weight: 0.1%-0.3% of N, N-methylene bisacrylamide, 0.1%-0.3% of 1-[4-(2-hydroxyethoxy)-phenyl]-2-hydroxy-2-methyl-1-propane-1-ketone, 0.5%-0.8% of ammonium persulfate and 0.5%-0.8% of sodium hydrogen sulfite. Double response to the internal humidity and pH value of the concrete can be achieved, and the requirement for precise internal curing of modern high-performance concrete is met.