2348 results about "Ammonium sulfate" patented technology

The invention relates to the technical field, and particularly discloses a nano-modified epoxy building thermal insulation material and a preparation method thereof. The nano modified epoxy building thermal insulation material is prepared from the following raw materials in parts by mass: 80 to 120 parts of Portland cement, 20 to 40 parts of slag powder, 5 to 10 parts of hollow mesoporous silicon dioxide, 0.1 to 1 part of pyrrole, 0.1 to 0.2 part of ammonium persulfate, 5 to 10 parts of nano silicon dioxide, 10 to 15 parts of bisphenol S epoxy resin, 1 to 5 parts of acrylic acid, 1 to 2 parts of polylysine, 0.01 to 0.1 part of catalyst and 1 to 2 parts of curing agent. The concrete is prepared from the following raw materials in parts by weight: 20-30 parts of epoxy resin, 4-8 parts of loaded aerogel, 0.1-1 part of polycarboxylate superplasticizer, 1-4 parts of composite fiber and 0.2-1.25 parts of hydrogen peroxide. The fireproof building material has excellent toughness, can better resist cracking and absorb energy, effectively avoids cracking and damage under the action of thermal stress, and ensures that the building material has a fireproof effect.

The invention relates to the technical field of oilfield chemistry, and discloses a graft modified cellulose filtrate reducer and a preparation method thereof.The preparation method comprises the following steps that modified hydroxyethyl cellulose, 2-acrylamide-2-methyl propane sulfonic acid, dimethyl diallyl ammonium chloride, alkenylated cardanol and N, N '-methylene bisacrylamide are added into deionized water, stirring is conducted, and a mixture is obtained; the preparation method comprises the following steps: adding cellulose into a reaction kettle, stirring for 10-15 minutes at the temperature of 40-60 DEG C at the speed of 300-400 rpm, dropwise adding ammonium persulfate and sodium hydrogen sulfite into a system, and continuously reacting for 4-6 hours to obtain the grafted modified cellulose filtrate reducer. The filtrate reducer disclosed by the invention has good high temperature resistance and salt resistance.

The invention provides a polyaniline / modified graphene oxide composite material and a preparation method thereof. The preparation method comprises the following steps: dispersing purified graphene oxide, performing ultrasonic treatment, heating, adding a modifier for modification, centrifuging, taking precipitate, freezing, drying and grinding to obtain modified graphene oxide powder; mixing the powder with an aniline solution in doped acid to form a modified graphene oxide / aniline acid solution; dissolving ammonium persulfate in the doped acid to prepare an ammonium persulfate acid solution; and slowly dropwise adding the solution into the solution, carrying out in-situ polymerization, and carrying out suction filtration, washing and drying to obtain the composite material. According to the method, through chemical modification and in-situ polymerization processes, the problems that a single filler is poor in dispersity, a conductive network is discontinuous, and anti-corrosion and anti-static performance is difficult to synergistically improve are solved, and the process is simple and convenient and suitable for industrialization.

The invention discloses a preparation method of a novel industrial rare earth ammonium sulfate saline-alkali soil conditioner, and relates to the technical field of wastewater treatment.The preparation method specifically comprises the following steps that S1, a KOH solution is added into rare earth smelting ammonium sulfate waste liquid, supernate is taken, and a superior rare earth ammonium sulfate material is obtained; s2, adding a humic acid solution into the superior rare earth ammonium sulfate material to obtain a solution I; s3, adding a mineral source potassium fulvate solution into the solution I to obtain a solution II; s4, adding a wood vinegar solution into the solution II, and uniformly mixing to obtain a solution III; and S5, carrying out freeze drying treatment on the solution III to obtain the novel industrial rare earth ammonium sulfate saline-alkali soil conditioner material. Treated superior rare earth ammonium sulfate is used as a main raw material, humic acid, mineral source potassium fulvate, wood vinegar and other components are added to carry out directional modification treatment on the superior rare earth ammonium sulfate, and the novel saline-alkali soil conditioner material is obtained.

The present application discloses a method for recycling and preparing lithium iron phosphate from waste lithium iron phosphate batteries, which comprises the following steps: oxidizing and acid-leaching the recycled lithium iron phosphate battery powder to obtain acid-leached lithium solution and iron-phosphorus filter residue; adjusting the pH of the acid-leached lithium solution for purification and concentration, adding a phosphorus source and adjusting the pH to 9.5 - 10.5 to obtain solution A; subjecting the iron-phosphorus filter residue to secondary acid-leaching, iron dissolution, adding a phosphorus source and adjusting the pH to 6.5 - 7.5 to obtain solution B; mixing solution A and solution B for coprecipitation reaction, and filtering to obtain lithium iron phosphate precursor and reaction mother liquor; subjecting the lithium iron phosphate precursor to anaerobic drying, mixing with a carbon source and sintering to prepare a carbon-coated lithium iron phosphate cathode material. The method provided by the present application has the advantages of short recycling path, few reaction by-products and environmental friendliness, and can recycle all components of lithium, iron and phosphorus in the waste lithium iron phosphate battery powder. At the same time, the by-product is ammonium sulfate, a high-quality fertilizer raw material, which has great application prospects.

The invention discloses a resourceful treatment method for wastewater containing magnesium and manganese ammonium sulfate, and belongs to the technical field of wastewater resourceful treatment. The method comprises the following steps: neutralizing the ammonium sulfate wastewater containing magnesium and manganese to remove heavy substances, deeply removing calcium from the neutralized and precipitated filtrate by adopting oxalic acid and a crystal inducer through crystallization, leaching the calcium-removed and precipitated filter residue by adopting sulfuric acid, recycling the leachate which is an oxalic acid solution, and removing manganese from the calcium-removed and precipitated filtrate through catalytic oxidation and decomposing residual oxalic acid to obtain manganese residues and catalytic oxidation filtrate; according to the method, the magnesium-manganese-containing ammonium sulfate wastewater can be subjected to resourceful treatment to obtain the magnesium ammonium sulfate product and the ammonium sulfate product with relatively high additional value, and the problems of difficulty in impurity removal, low cost and the like in the existing magnesium-manganese-containing ammonium sulfate wastewater treatment process are solved. The purity of by-products is low, and the like.

The invention provides loofah sponge nanocellulose hydrogel and a preparation method thereof.The preparation method comprises the following steps that anhydrous citric acid, choline chloride and water are mixed to react, and a ternary eutectic solvent is obtained; dispersing loofah sponge purified cellulose in a ternary eutectic solvent, washing and filtering a product to be neutral, dispersing the product in water, and performing ultrasonic treatment to obtain loofah sponge nanocellulose turbid liquid; dissolving sodium lignin sulfonate and lithium chloride in a sodium hydroxide solution to obtain a precursor solution; mixing the loofah sponge nanocellulose suspension with water, polyacrylamide, ammonium persulfate and N, N-methylene bisacrylamide, pouring the precursor solution into the loofah sponge nanocellulose suspension, uniformly stirring the mixture, pouring the mixture into a mold, and sealing the mold; and forming to obtain the loofah sponge nanocellulose hydrogel. The invention also provides an application of the hydrogel. The hydrogel disclosed by the invention has excellent biocompatibility, mechanical property and conductivity, has a wide application prospect in the field of flexible electronics, and is simple in preparation process, low in cost, green and environment-friendly.

The invention relates to a method for preparing high-quality ammonium sulfate by using sodium-ammonium-containing sulfate solid waste, which comprises the following steps: partially dissolving the sodium-ammonium-containing sulfate solid waste and carrying out solid-liquid separation to obtain a first dissolved solution and a first solid phase; the first dissolving solution is subjected to first evaporative crystallization and solid-liquid separation, and an ammonium sulfate product and a first mother solution are obtained; wherein the temperature of partial dissolution is 5-10 DEG C; efficient separation and recovery of ammonium sulfate and sodium sulfate resources in sulfate solid waste containing sodium and ammonium are achieved, the purity of an ammonium sulfate product obtained after first evaporative crystallization is preferably as high as 98.6% or above, the appearance color is white, the water content is preferably as low as 1.3% or below, and the recovery rate is high. The recovery rate is preferably up to 98.00% or above, the purity of the sodium sulfate product is up to 98.5% or above, the amount of sodium hydroxide required to be consumed is as low as 0.93% or below, and the method is simple in technological process, mild in condition and easy to industrialize.

The invention provides an ammonium sulfate production process control method based on model prediction, which comprises the following steps: acquiring real-time data of flue gas flow, sulfur dioxide concentration, slurry PH value and ammonia water concentration, analyzing dynamic change characteristics of the flue gas flow, the sulfur dioxide concentration, the slurry PH value and the ammonia water concentration under different coal types and load working conditions, and constructing a flue gas component mutation characteristic library; transmitting an ammonia water adding amount and / or material transfer pump rotating speed control instruction to a desulfurization tower control system, executing dynamic adjustment of an absorption circulating tank, updating real-time monitoring data, comparing output prediction results, calculating deviation, and generating an optimized future prediction sequence; and judging whether the pH value and the ammonium sulfate concentration of the absorption circulating tank can continuously meet the preset upper and lower limit range conditions in the future preset time or not by comparing the prediction result sequences before and after optimization, if so, completing a dynamic adjustment period, and if not, recalculating the adjustment value of the ammonia water addition amount and / or the rotating speed of the material transfer pump.

The invention relates to the technical field of ton bag lining materials, and particularly discloses a shielding antistatic ton bag lining bag and a preparation method thereof. The invention relates to a shielding antistatic ton bag lining bag, which is prepared by processing a multi-layer composite film with a structure of PET / antistatic layer / PA / PE, and the antistatic layer is prepared from the following raw materials by weight: 40-75 parts of a resin material; 20 to 40 parts of filler; 5-10 parts of a color master batch; 1-3 parts of an antistatic agent; 2-5 parts of a dispersant; 0.2 to 0.4 part of an antioxidant; 4 to 6 parts of polyimide nanofiber; 1-3 parts of a modified carbon nanotube; the modified carbon nanotube is prepared by the following method: S1, pretreating a carbon nanotube raw material with a concentrated nitric acid solution to obtain a pretreated carbon nanotube; and S2, dispersing the pretreated carbon nanotubes in xylene, then adding deionized water and p-toluenesulfonic acid, then adding an aniline monomer, then adding ammonium persulfate, and carrying out a reaction to obtain the composite material after the reaction is finished. The shielding anti-static ton bag lining bag can keep stable anti-static performance under the influence of a severe temperature change environment.

The invention discloses a BOE waste liquid treatment method and device. The method comprises the following steps: replacing hydrogen fluoride in BOE waste liquid with sulfuric acid, evaporating, fractionating and recovering hydrofluoric acid, neutralizing evaporated residual liquid with ammonia to obtain a fluorine-containing ammonium sulfate solution, defluorinating with fluorgypsum slurry to obtain a low-fluorine ammonium sulfate solution, and concentrating and crystallizing to obtain an ammonium sulfate product. The BOE waste liquid is treated by adopting the scheme, the bottleneck of the market capacity of ammonium bifluoride is avoided, the hydrofluoric acid product and the ammonium sulfate product with huge market capacity are produced, the value orientation of turning waste into wealth, circular economy and environmental protection is really realized, and the method is suitable for industrial popularization and application.

The invention belongs to the field of flotation, and particularly relates to a method for flotation of copper cobalt oxide ore by using magnesium-containing tailing water, the magnesium-containing tailing water is used as flotation water to carry out five-stage roughing on the copper cobalt oxide ore, the first-stage roughing is carried out under a vulcanizing agent and a xanthate-thionocarbamate collecting agent, and the second-stage roughing is carried out under the action of a flotation agent; and the second-stage roughing is carried out under the condition of containing a compound additive, a vulcanizing agent and xanthate-hydroximic acid. The third-stage roughing is carried out under the action of a vulcanizing agent and xanthate-hydroximic acid; and the fourth-section roughing process and the fifth-section roughing process are carried out under the action of a hydroximic acid collecting agent. The compound additive comprises a component A and a component B with a structure shown in a formula 1 (# imgabs0 #); the component A comprises at least one of ammonium carbonate, ammonium bicarbonate, ammonium nitrate, ammonium acetate, ammonium sulfate and ammonium chloride; and the composite collecting agent comprises a xanthate collecting agent and a hydroximic acid collecting agent. By means of the method, the problem of flotation degradation caused by magnesium-containing tailing water recycling can be solved, and the excellent flotation effect can be achieved.

The invention provides a method for preparing sodium carbonate and co-producing ammonium sulfate from sodium sulfate waste salt, and relates to the technical field of chemical engineering. The method comprises the following steps: mixing sodium sulfate waste salt with water for dissolution, mixing the obtained sodium sulfate waste salt solution with an impurity removal agent for impurity removal, and mixing the obtained impurity removal solution with ammonium bicarbonate for double decomposition reaction to obtain a reaction feed liquid; carrying out primary cold separation on the reaction feed liquid to obtain first filtrate and primary sodium bicarbonate; sequentially washing, drying and roasting the primary sodium bicarbonate to obtain a sodium carbonate product; carrying out secondary cold separation on the first filtrate, carrying out solid-liquid separation to obtain a second filtrate and mixed salt, and reusing the mixed salt in the metathesis reaction; and mixing the second filtrate with an acid adjusting agent to adjust the acid, and carrying out evaporative crystallization on the obtained solution to obtain an ammonium sulfate product and an evaporation mother solution. Industrial-grade sodium carbonate and ammonium sulfate are co-produced by using sodium sulfate waste salt, sodium carbonate and ammonium sulfate meet national standard requirements, and the recovery rate of sodium sulfate is greater than or equal to 90%.

The invention belongs to the technical field of lithium-containing waste treatment, and particularly discloses a method for preparing lithium carbonate by recycling lithium through cooperative treatment of lithium-containing waste. The method specifically comprises the following steps: mixing a lithium amide waste material, a lithium sulfide waste material and water, then mixing with a hydrogen peroxide solution and a sulfuric acid solution, and carrying out an acid dissolution reaction to obtain a lithium-containing acid solution and an insoluble substance; mixing the lithium-containing acid solution with alkali liquor, and carrying out alkalization reaction to obtain insoluble impurities and alkalized feed liquid; concentrating the alkalized feed liquid to obtain concentrated alkalized feed liquid, and mixing the concentrated alkalized feed liquid with a sodium carbonate solution for lithium precipitation reaction to obtain lithium precipitation mother liquor and lithium carbonate; extracting the lithium element in the lithium precipitation mother liquor, and evaporating and concentrating the raffinate to separate out sodium sulfate and ammonium sulfate; ammonium sulfate and the lithium iron phosphate waste are mixed and then sequentially subjected to roasting and leaching, and a leaching solution and a lithium-containing acid solution are mixed for alkalization. The method has the characteristics of high process integration level, high economic value and less environmental pollution, and conforms to the new concept of chemical green atom economy.

The invention provides a production process for reducing the nitrogen content in reagent-grade sulfuric acid, and relates to the technical field of sulfuric acid. Comprising the following steps: adding urea solid powder into sulfuric acid at 55-65 DEG C according to the mass ratio of urea to sulfuric acid of (0.001-0.01): 100, and stirring until the urea solid powder is completely dissolved; s100, heating the mixture in the step S100 to 83-87 DEG C in a gradient manner, adding ammonium sulfate powder according to the mass ratio of ammonium sulfate to sulfuric acid of (0.05-0.1): 100 in the heating process, and stirring to react for 0.8-1.2 hours; performing reduced pressure distillation on the sulfuric acid after the reaction in the step S200 at 80-150 DEG C, introducing inert gas in a synchronous pulse manner for purging in the heating process, repeating for 2-3 times, and collecting a main fraction; treating tail gas. According to the method, the total nitrogen content and the content of NH4 < + > ions and NO3 <-> ions in the reagent-grade sulfuric acid are effectively reduced, the electronic-grade sulfuric acid is obtained, and the yield of the sulfuric acid can reach 97.5%.

The invention relates to the technical field of functional polymer composite materials, and provides diatomite modified composite super absorbent and rapid absorbent resin and a preparation method thereof. The preparation raw materials of the diatomite modified composite high-water-absorption and rapid-water-absorption resin provided by the invention comprise acrylic acid, acrylamide, sodium hydroxide, N, N '-methylene bisacrylamide, ammonium persulfate and modified diatomite. The diatomite is modified by the silane coupling agent, the agglomeration problem of the diatomite is solved, the compatibility with organic monomers is improved, and the modified diatomite, acrylic acid and acrylamide are utilized to construct an organic-inorganic synergistic three-dimensional porous network structure, so that the resin has ultrahigh water absorption rate, rapid water absorption performance and good water retention stability. Meanwhile, the preparation method disclosed by the invention does not need nitrogen protection, has the advantages of simple process, controllable raw material cost and easiness in industrial mass production, and is suitable for multiple fields such as water-saving agriculture, soil moisturizing, landscaping and the like.

The invention relates to the field of caprolactam production, and discloses a green and efficient production process and device. The process comprises the following steps: continuously oximating cyclohexanone and hydroxylamine in a microreactor under the catalysis of mesoporous silica solid acid; carrying out gas phase rearrangement on cyclohexanone-oxime in the presence of a ZSM-5 molecular sieve under the assistance of microwaves; coupling, rectifying and purifying the crude product through a four-stage molecular sieve membrane; and performing catalytic cracking on the by-product to obtain N2 / H2O and recycling. The device comprises a micro-reaction unit, a microwave-radial reactor, a membrane coupling rectifying tower group and a tail gas cracking unit. Zero emission of ammonium sulfate is achieved, the product purity is larger than or equal to 99.95%, and energy consumption is reduced by 45%.

The invention belongs to the technical field of lithium battery positive electrode materials, and provides high-compaction-density lithium iron phosphate and a preparation method thereof.The preparation method comprises the following steps that 1, pretreated polyvinyl alcohol is added into deionized water, the temperature is increased to 80-85 DEG C, stirring is conducted, the pH value is adjusted to 10.5-11.0, epichlorohydrin is added for a reaction, aniline is added for a continuous reaction, cooling is conducted, and a product is obtained; adjusting the pH value to 1-2, adding ammonium persulfate for reaction, and dialyzing to remove impurities to obtain modified polyvinyl alcohol; step 2, adding a lithium source, an iron source and a phosphorus source into deionized water for mixing, and performing ball milling and drying to obtain a lithium iron phosphate precursor; step 3, putting the lithium iron phosphate precursor into a tubular furnace, adding an inorganic carbon source, heating for reaction, cooling and crushing to obtain primary sintered lithium iron phosphate; and step 4, mixing the primarily sintered lithium iron phosphate and the modified polyvinyl alcohol, placing the mixture in a tubular furnace, carrying out heating reaction, cooling and crushing to obtain the lithium iron phosphate.

The invention relates to the technical field of polymer photoelectric materials, in particular to a preparation method of a supramolecular gel electrolyte. The method comprises the following steps: esterifying tetraphenylethylene alcohol and methacryloyl chloride to form tetraphenylethylene methacrylate, and performing staged linear heating polymerization on the tetraphenylethylene methacrylate, 3-(methacrylamido) propyl dimethyl 3-thiopropyl ammonium oxide inner salt, acrylic acid, tetraphenylethylene methacrylate and 4-vinylpyridine under the action of ammonium persulfate to obtain a tetraphenylethylene copolymer. And finally, soaking in a lithium chloride aqueous solution to obtain the supramolecular hydrogel electrolyte. The hydrogel obtained by the invention has high mechanical strength and high ionic conductivity, and is suitable for energy storage devices such as flexible supercapacitors and the like.

The invention discloses a preparation method of ammonium sulfate spherical crystals and ammonium sulfate. The preparation method of the ammonium sulfate spherical crystal comprises the following steps: (1) under the condition of 500-800r / min, cooling an ammonium sulfate solution at 70-80 DEG C to 65-68 DEG C, adding a seed crystal, and continuously cooling to 1-15 DEG C; and (2) after cooling is finished, heating to 20-25 DEG C under a stirring condition to dissolve edges and corners on the surfaces of the crystals, and continuously stirring for 0.5-5 hours to obtain the ammonium sulfate spherical particles. The preparation process is single in raw material, only water is involved in the solvent, environmental protection is achieved, and the process is simple; the product particles are round, the average particle size is 900-1100 microns, the fluidity is high, the angle of repose is 15-20 degrees, the caking resistance is better, and the economic and equipment cost of industrial subsequent treatment is greatly reduced.

The invention discloses a device for recovering ammonium sulfate through electrocatalytic reduction and a using method thereof.The device comprises a wastewater pool and an outer shell, a physical filtering bin is fixedly installed in the outer shell, a water inlet of the physical filtering bin is communicated with the wastewater pool, and a water outlet of the physical filtering bin is fixedly connected with a closed electrolytic tank; the upper end of the closed electrolytic tank is fixedly connected with an electrochemical workstation, the lower end surface of the closed electrolytic tank is fixedly provided with a lead-out port, the lead-out port is fixedly connected with a product recovery device, the product recovery device comprises a first chamber and a second chamber, and a gas diffusion port is formed between the first chamber and the second chamber; a gas diffusion film is fixedly installed in the gas diffusion opening, a product discharging opening is fixedly formed in the second cavity, a product discharging valve is fixedly installed at the product discharging opening, and the nitrate reduction device is simple in structure and convenient to use, and the nitrate reduction efficiency is greatly improved.

The invention provides a gel composite adsorbent with a foaming structure as well as a preparation method and application thereof, and the preparation method comprises the following steps: S1, dissolving acrylamide powder in deionized water, and stirring to obtain a solution A; s2, dissolving sodium alginate in the solution A for thickening to obtain a solution B; s3, transferring the solution B into an ice-water bath; s4, adding N, N-methylene bisacrylamide into the solution B, stirring until the N, N-methylene bisacrylamide is completely dissolved, then adding N, N, N ', N'-tetramethylethylenediamine, and stirring until the N, N, N ', N'-tetramethylethylenediamine is uniform to obtain a solution C; s5, adding ammonium persulfate into the solution C, and stirring until the ammonium persulfate is completely dissolved to obtain a solution D; s6, the solution D is poured into a mold and then vacuumized to form gel, and a hydrogel sample is obtained after gel forming; s7, drying the hydrogel sample, and then soaking the dried hydrogel sample in a salt solution to obtain a soaked gel material; and S8, drying the soaked gel material to obtain the finished product composite adsorbent.

According to the inorganic passivation layer modified perovskite solar cell and the preparation method thereof, the compact lead sulfate-lead oxide inorganic layer is further formed through surplus lead iodide on the surface of calcium perovskite with strong oxidizing property to passivate the perovskite thin film, and the efficient and stable perovskite cell is prepared. According to the invention, the perovskite thin film is processed by using the passivator solution, and the photoelectric conversion efficiency of the prepared device can reach 24.98% at most. Meanwhile, the perovskite thin film treated by the passivator has excellent photo-thermal stability. According to the perovskite device prepared by the method, the passivation effect is remarkable, the waterproof performance of the perovskite material is remarkably improved, and the method has important significance in performance improvement and commercialized production of perovskite.

The invention discloses a method for recovering valuable metals from a waste hydrogenation catalyst, and relates to the technical field of waste catalyst recovery, and the method comprises the following steps: carrying out oxidizing roasting and oxygen pressure alkaline leaching on the waste hydrogenation catalyst to obtain an alkaline leaching solution and alkaline leaching residues; aluminum, vanadium and molybdenum are recycled from the alkaline leaching solution, wherein carbon dioxide is introduced into the alkaline leaching solution for aluminum precipitation; ammonium sulfate and magnesium sulfate are added into the filtrate subjected to aluminum precipitation to remove phosphorus, silicon and arsenic, molybdenum and vanadium are adsorbed through resin, and vanadium precipitation and molybdenum precipitation are carried out; and aluminum and nickel are recycled from alkaline leaching residues, specifically, aluminum is precipitated through oxygen pressure acid leaching, then alkali is added into filtrate to further recycle aluminum, and then sodium carbonate is added for nickel precipitation. By means of the method, molybdenum, vanadium, nickel, aluminum and other elements in the waste catalyst can be effectively recycled, the recycling rate is high, the molybdenum recycling rate can reach 97%, the vanadium recycling rate can reach 95%, the nickel recycling rate can reach 92%, comprehensive utilization of the waste catalyst is achieved, and good social value and economic value are achieved.

The invention provides a preparation method and application of coating enhanced nano silver powder. The preparation method comprises the following steps: S1, preparing nano silver by taking silver nitrate as a silver source and polyethyleneimine as a reducing agent; s2, carrying out coating modification on the nano-silver by adopting aniline and ammonium persulfate under an acidic condition; s3, modifying the polyaniline coated nano-silver by adopting chloroacetic acid to obtain chloroacetic acid modified polyaniline coated nano-silver; s4, preparing a modified graphene oxide dispersion liquid; s5, partially reducing the graphene oxide; s6, partially reduced graphene oxide is adopted to load the chloroacetic acid modified polyaniline coated nano-silver, polyaniline coating and reduced graphene oxide compounding are carried out, and the dispersity and stability of nano-silver particles are effectively improved. The oxidation state of polyaniline promotes the release of silver ions through an electron transfer effect, so that the antibacterial effect is enhanced; and the partially reduced graphene oxide synergistically accelerates the release of silver ions, so that the antibacterial property is further improved.

The invention provides a composite synergistic system for a shale gas old well and an immovable string production increasing process. The composite synergistic system mainly comprises the following substances: 10-12% of a wetting improver; 4%-6% of a scale remover; 2%-3% of a scale inhibition dispersant; 5%-10% of a resistance-reducing discharge aiding agent; 15%-20% of a synergistic accelerant; the wetting improver is a mixture of alkyl polyglucoside, an anionic surfactant sodium dodecyl benzene sulfonate and deionized water, the content of the alkyl polyglucoside in the wetting improver is 5%-10%, and the content of the anionic surfactant sodium dodecyl benzene sulfonate is 15%-18%; the descaling agent is a mixture of sodium alpha-olefin sulfonate and nonylphenol polyoxyethylene ether ammonium sulfate, and the mass ratio of the sodium alpha-olefin sulfonate to the nonylphenol polyoxyethylene ether ammonium sulfate in the descaling agent is (2: 1)-(3: 1). According to the composite synergistic system, through combination and reuse of different materials and different doses, the multifunctional composite synergistic system integrating vibration, permeation and dispersion effects is researched and developed, and therefore immovable tubular column yield increase construction of a shale gas old well is achieved.

The invention discloses a method and a system for recovering rare earth elements from china clay ore resources, the recovery process comprises the following steps: stirring petuntse into slurry through a stirring barrel, and then carrying out filter pressing on the petuntse through a first filter press, ammonium sulfate, washing water and compressed air are sequentially pumped into the petuntse at high pressure, so that tail liquid and petuntse waste materials can be blown out in a high-pressure state, then the tail liquid and the petuntse waste materials sequentially pass through a clarification tank, an impurity removal tank and a sedimentation tank and are subjected to solid-liquid layering, obtained solid parts are subjected to filter pressing through a second filter press, and rare earth products are obtained. The method is efficient and rapid, operation is simplified and programmed, the overall production cost is reduced, and the overall technological method is reliable and practical.

The invention relates to the technical field of agricultural fertilizers, in particular to a functional sustained and controlled release fertilizer for regulating and controlling productivity of salinized soil and a preparation method thereof. The slow / controlled-release fertilizer is prepared by compounding a fertilizer matrix, a soil conditioner, a water-retaining agent and humic acid, wherein the fertilizer base body comprises a core material, and the surface of the core material is sequentially coated with a chelating layer and a wall material layer from inside to outside; the core material comprises the following components in parts by weight: ammonium sulfate, monoammonium phosphate, potassium sulfate and trace elements; the chelating layer is sodium ethylene diamine tetracetate; and the wall material layer is sodium alginate. The sodium alginate coating material adopted by the fertilizer can control the fertilizer to be slowly released in soil, and after the fertilizer is completely released in the soil, the adopted coated fertilizer is non-toxic and harmless in the soil and is easy to degrade. The chelating layer is arranged between the core material and the wall material and can be chelated to form a connecting structure of the inner layer and the outer layer, so that the strength of the fertilizer matrix particles is improved, the particles have stability, and the slow release effect is favorably exerted.

The utility model discloses an ammonium sulfate wastewater treatment system which comprises an ammonium sulfate wastewater storage pool used for collecting ammonium sulfate wastewater, the calcium hydroxide preparation system is used for preparing a calcium hydroxide solution, an evaporator and a first circulating heater and is used for reacting ammonium sulfate wastewater and calcium hydroxide and heating and evaporating; the first crystallizer and the second circulating heater as well as the second crystallizer and the third circulating heater are used for two times of evaporative crystallization, a final concentrated solution is filtered by the filter and then flows into the mother liquor collecting tank to facilitate wastewater treatment, and evaporated ammonia gas is absorbed by the cooling absorption tower and the condensate collecting tank to form ammonia water; and condensate water of the second heat exchanger, the first circulating heater, the second circulating heater and the third circulating heater also flows back to the condensate collecting pool. According to the wastewater treatment system, ammonium sulfate wastewater and a calcium hydroxide solution are distilled and crystallized, so that calcium sulfate and ammonia water can be recovered, and waste utilization is realized.

The invention relates to a water-resistant magnesium phosphate cement-based material which comprises the following components: magnesium oxide, a composite phosphate compound, borax, a sodium silicate solution, water, a polyethylene glycol derivative, polyacrylamide and an ammonium sulfate solution. According to the water-resistant magnesium phosphate cement-based material, precipitation of water can be controlled in the preparation process, so that the speed of a hydration reaction is conveniently controlled, and the situation that phosphate is fixed in a matrix and cannot continue to participate in the reaction due to the fact that the hydration reaction is too fast is avoided; according to the water-resistant magnesium phosphate cement-based material, the fluidity of a mixture can be better in the preparation process, so that the mixture can be stirred and mixed more sufficiently, and the polyethylene glycol derivative can introduce bubbles to block capillary pore channels in concrete; therefore, permeation of external water can be reduced in the using process of the water-resistant magnesium phosphate cement-based material.