828 results about "Ammonium persulfate" patented technology

The invention relates to the technical field of oilfield chemistry, and discloses a graft modified cellulose filtrate reducer and a preparation method thereof.The preparation method comprises the following steps that modified hydroxyethyl cellulose, 2-acrylamide-2-methyl propane sulfonic acid, dimethyl diallyl ammonium chloride, alkenylated cardanol and N, N '-methylene bisacrylamide are added into deionized water, stirring is conducted, and a mixture is obtained; the preparation method comprises the following steps: adding cellulose into a reaction kettle, stirring for 10-15 minutes at the temperature of 40-60 DEG C at the speed of 300-400 rpm, dropwise adding ammonium persulfate and sodium hydrogen sulfite into a system, and continuously reacting for 4-6 hours to obtain the grafted modified cellulose filtrate reducer. The filtrate reducer disclosed by the invention has good high temperature resistance and salt resistance.

The invention provides loofah sponge nanocellulose hydrogel and a preparation method thereof.The preparation method comprises the following steps that anhydrous citric acid, choline chloride and water are mixed to react, and a ternary eutectic solvent is obtained; dispersing loofah sponge purified cellulose in a ternary eutectic solvent, washing and filtering a product to be neutral, dispersing the product in water, and performing ultrasonic treatment to obtain loofah sponge nanocellulose turbid liquid; dissolving sodium lignin sulfonate and lithium chloride in a sodium hydroxide solution to obtain a precursor solution; mixing the loofah sponge nanocellulose suspension with water, polyacrylamide, ammonium persulfate and N, N-methylene bisacrylamide, pouring the precursor solution into the loofah sponge nanocellulose suspension, uniformly stirring the mixture, pouring the mixture into a mold, and sealing the mold; and forming to obtain the loofah sponge nanocellulose hydrogel. The invention also provides an application of the hydrogel. The hydrogel disclosed by the invention has excellent biocompatibility, mechanical property and conductivity, has a wide application prospect in the field of flexible electronics, and is simple in preparation process, low in cost, green and environment-friendly.

The invention discloses a hyperbranched water reducing agent for high-tensile wet joint UHPC (Ultra High Performance Concrete) as well as a preparation method and application of the hyperbranched water reducing agent, and belongs to the technical field of concrete admixtures. The preparation method comprises the following steps: mixing pentaerythritol and maleic anhydride, adding a catalyst p-toluenesulfonic acid, and carrying out an esterification reaction to prepare an esterification product; carrying out amidation reaction on the esterification product, diethanol amine and a catalyst sodium ethoxide to obtain a prepolymer; acrylic acid, maleic anhydride and the prepolymer are dissolved in deionized water, an initiator ammonium persulfate is added for a free radical copolymerization reaction, and a main chain polymer is obtained; carrying out phosphorylation reaction on the main chain polymer and phosphorus pentoxide to obtain a phosphorylated main chain polymer; the phosphorylated main chain polymer, methoxypolyethylene glycol and a catalyst p-toluenesulfonic acid are subjected to an etherification reaction, a hyperbranched comb-shaped polymer water reducing agent solution is obtained and then subjected to aftertreatment, and the water reducing agent is prepared. According to the hyperbranched comb-shaped polymer water reducing agent prepared by the preparation method disclosed by the invention, the problems of poor flowability and high viscosity of ultra-high performance concrete (UHPC) are solved by combining a linear side chain of a comb-shaped structure and a three-dimensional branch of hyperbranched topology.

The invention relates to the technical field of functional polymer composite materials, and provides diatomite modified composite super absorbent and rapid absorbent resin and a preparation method thereof. The preparation raw materials of the diatomite modified composite high-water-absorption and rapid-water-absorption resin provided by the invention comprise acrylic acid, acrylamide, sodium hydroxide, N, N '-methylene bisacrylamide, ammonium persulfate and modified diatomite. The diatomite is modified by the silane coupling agent, the agglomeration problem of the diatomite is solved, the compatibility with organic monomers is improved, and the modified diatomite, acrylic acid and acrylamide are utilized to construct an organic-inorganic synergistic three-dimensional porous network structure, so that the resin has ultrahigh water absorption rate, rapid water absorption performance and good water retention stability. Meanwhile, the preparation method disclosed by the invention does not need nitrogen protection, has the advantages of simple process, controllable raw material cost and easiness in industrial mass production, and is suitable for multiple fields such as water-saving agriculture, soil moisturizing, landscaping and the like.

The invention belongs to the technical field of lithium battery positive electrode materials, and provides high-compaction-density lithium iron phosphate and a preparation method thereof.The preparation method comprises the following steps that 1, pretreated polyvinyl alcohol is added into deionized water, the temperature is increased to 80-85 DEG C, stirring is conducted, the pH value is adjusted to 10.5-11.0, epichlorohydrin is added for a reaction, aniline is added for a continuous reaction, cooling is conducted, and a product is obtained; adjusting the pH value to 1-2, adding ammonium persulfate for reaction, and dialyzing to remove impurities to obtain modified polyvinyl alcohol; step 2, adding a lithium source, an iron source and a phosphorus source into deionized water for mixing, and performing ball milling and drying to obtain a lithium iron phosphate precursor; step 3, putting the lithium iron phosphate precursor into a tubular furnace, adding an inorganic carbon source, heating for reaction, cooling and crushing to obtain primary sintered lithium iron phosphate; and step 4, mixing the primarily sintered lithium iron phosphate and the modified polyvinyl alcohol, placing the mixture in a tubular furnace, carrying out heating reaction, cooling and crushing to obtain the lithium iron phosphate.

The invention relates to the technical field of polymer photoelectric materials, in particular to a preparation method of a supramolecular gel electrolyte. The method comprises the following steps: esterifying tetraphenylethylene alcohol and methacryloyl chloride to form tetraphenylethylene methacrylate, and performing staged linear heating polymerization on the tetraphenylethylene methacrylate, 3-(methacrylamido) propyl dimethyl 3-thiopropyl ammonium oxide inner salt, acrylic acid, tetraphenylethylene methacrylate and 4-vinylpyridine under the action of ammonium persulfate to obtain a tetraphenylethylene copolymer. And finally, soaking in a lithium chloride aqueous solution to obtain the supramolecular hydrogel electrolyte. The hydrogel obtained by the invention has high mechanical strength and high ionic conductivity, and is suitable for energy storage devices such as flexible supercapacitors and the like.

The invention discloses a preparation method for regulating and controlling the growth of a hydrophobic Cu2S nanowire material on the surface of a copper foil, and relates to the technical field of solid surface, and the preparation method comprises the following specific steps: 1) reacting the treated copper foil in a NaOH solution and an ammonium persulfate solution for 10-30 minutes, taking out the copper foil, washing the copper foil with absolute ethyl alcohol, and drying the copper foil in a drying oven for 10-30 minutes; and soaking the obtained sample in a silane coupling agent KH-570 (gamma-methacryloxy propyl trimethoxy silane) of which the concentration is 2.5% to 10% for 20 to 60 minutes. (2) reacting the sample obtained in the step (1) in a 0.1-1mol / L Na2S solution for 10-30 minutes, then taking out the sample, and continuously soaking the sample in a silane coupling agent for 20-60 minutes to obtain a hydrophobic Cu2S nanowire on the surface of a copper foil; according to the preparation method for regulating and controlling the growth of the hydrophobic Cu2S nanowire material on the surface of the copper foil, the regulation and control of the hydrophobicity of the Cu2S nanowire on the surface of the copper foil are realized by regulating and controlling the proportion of a silane coupling agent and the like; when the modified hydrophobic Cu2S nanowire is soaked in a silane coupling agent KH-570 with the mass concentration of 2.5%-10%, the contact angle of the modified hydrophobic Cu2S nanowire can reach 91.46 degrees to 129.46 degrees.

The invention provides a gel composite adsorbent with a foaming structure as well as a preparation method and application thereof, and the preparation method comprises the following steps: S1, dissolving acrylamide powder in deionized water, and stirring to obtain a solution A; s2, dissolving sodium alginate in the solution A for thickening to obtain a solution B; s3, transferring the solution B into an ice-water bath; s4, adding N, N-methylene bisacrylamide into the solution B, stirring until the N, N-methylene bisacrylamide is completely dissolved, then adding N, N, N ', N'-tetramethylethylenediamine, and stirring until the N, N, N ', N'-tetramethylethylenediamine is uniform to obtain a solution C; s5, adding ammonium persulfate into the solution C, and stirring until the ammonium persulfate is completely dissolved to obtain a solution D; s6, the solution D is poured into a mold and then vacuumized to form gel, and a hydrogel sample is obtained after gel forming; s7, drying the hydrogel sample, and then soaking the dried hydrogel sample in a salt solution to obtain a soaked gel material; and S8, drying the soaked gel material to obtain the finished product composite adsorbent.

The invention relates to conductive silk fibroin loaded methacrylated gelatin hydrogel and a preparation method thereof, and belongs to the technical field of biomedical materials. The preparation method comprises the following steps: S1, adding silk fibroin fibers into a dopamine hydrochloride solution, stirring, standing, then adjusting the pH value to 8-9, and carrying out a heating reaction to obtain polydopamine grafted silk fibroin fibers; s2, sequentially dipping the polydopamine grafted silk fibroin fibers in an ammonium persulfate solution and a pyrrole solution to obtain conductive silk fibroin fibers; and S3, adding the conductive silk fibroin fibers into the methacrylated gelatin solution, carrying out ultraviolet light cross-linking curing, and then soaking the conductive silk fibroin fibers in a glycerol solution to obtain the conductive silk fibroin loaded methacrylated gelatin hydrogel. The method not only can ensure the structural integrity and conductive continuity of a conductive network in the hydrogel, but also breaks through the dependence of in-situ polymerization on the permeability of a matrix.

The invention belongs to the technical field of solar-driven interface evaporation, and particularly relates to a solar-driven interface evaporation aerogel material based on gradient modification and a preparation method and application thereof. The preparation method specifically comprises the following steps: performing cross-linking reaction on chitosan and a cross-linking agent in an organic acid aqueous solution, and performing freeze drying to obtain a chitosan matrix with a three-dimensional network structure; a pyrrole monomer is uniformly dispersed in a network structure of a chitosan matrix, then the chitosan matrix is immersed in an ammonium persulfate solution, and by controlling the oxidative polymerization degree of ammonium persulfate to the pyrrole monomer, concentration gradient distribution gradually decreasing from the surface to the inside of polypyrrole is formed in the chitosan matrix, so that the polypyrrole / chitosan composite material is obtained. The solar-driven interface evaporation aerogel material based on gradient modification is obtained. The aerogel material provided by the invention combines a photothermal effect with interface evaporation, and achieves the purpose of reasonably and efficiently utilizing solar energy resources to carry out seawater desalination.

The present invention relates to a monovalent selective cation exchange membrane and a preparation method thereof, belonging to the technical field of cation exchange membranes. The specific steps are: weighing DA and ammonium persulfate and adding them to a buffer solution to obtain a PDA coating solution, pouring the PDA coating solution on the surface of a base membrane for soaking, depositing a PDA coating on the surface of the activated base membrane to obtain membrane I; dissolving zirconium tetrachloride and 2-aminoterephthalic acid in DMF, then solvent-thermally synthesizing an amino-functionalized MOF (UIO-66-NH2) under acidic conditions, weighing PEI and MOF (UIO-66-NH2) powders and adding them to a buffer solution, then pouring them on the surface of membrane I, depositing a PEI-MOF composite coating to obtain membrane II, and air-drying membrane II to obtain a monovalent selective cation exchange membrane. It can be seen that the present invention can prepare a low-cost, highly selective, and stable-performance monovalent selective cation exchange membrane by modifying the cation exchange membrane through a simple and easy-to-operate method.

The invention relates to an ultrasonic vibration assisted large-width copper plate strip continuous extrusion short-process technology, and belongs to the technical field of metal processing. A copper raw material is subjected to mechanical cleaning and then ultrasonic cleaning, and the surface cleanliness of the raw material is guaranteed; the cleaned copper raw materials are fed into continuous extrusion equipment, and ultrasonic vibration is adopted for assisting continuous extrusion; after the extruded copper plate strip is cooled, spraying a suspension containing cerium (IV)-sodium dodecyl benzene sulfonate-pyrrolidone nano aluminum oxide additive on the surface of the copper plate strip, and drying; straightening by using a multi-roll straightening machine to obtain a large-width copper plate strip; the cerium (IV)-sodium dodecyl benzene sulfonate-pyrrolidone nanometer aluminum oxide auxiliary agent is prepared from nanometer aluminum oxide, DMF (Dimethyl Formamide), sodium dodecyl benzene sulfonate, N-vinyl pyrrolidone, ammonium persulfate and cerous sulfate (IV); the copper plate strip prepared by the invention has relatively high density, relatively high tensile strength and ductility, and the mechanical property of the copper plate strip is remarkably improved.

The invention discloses a conductive layer coated ruthenium-doped beta-manganese dioxide catalyst and a preparation method and application thereof.The preparation method comprises the following steps that a manganese source, ruthenium trichloride trihydrate, an oxidizing agent and water are mixed, an obtained precursor solution is subjected to microwave synthesis, and the conductive layer coated ruthenium-doped beta-manganese dioxide catalyst is obtained. The obtained ruthenium-doped beta-manganese dioxide composite material, hydrochloric acid A and aniline are added into water, then hydrochloric acid B and ammonium persulfate are added, the obtained polyaniline-coated ruthenium-doped beta-manganese dioxide composite material is subjected to calcination treatment, and the conductive layer-coated ruthenium-doped beta-manganese dioxide catalyst is obtained. The conductive layer coated ruthenium-doped beta-manganese dioxide catalyst prepared by the invention has excellent catalytic activity and catalytic stability, and solves the problem of insufficient stability caused by high catalytic potential and catalyst dissolution in the test process of the anode catalyst of the proton exchange membrane electrolytic cell.

The present invention discloses a conductive slurry for lithium-ion battery positive electrodes. The slurry comprises the following substances: 1-2 parts graphene, 4-5 parts modified polymer, and 90-100 parts N-methylpyrrolidone, by weight. The modified polymer is prepared by mixing modified carbon nanotubes, acrylonitrile, methyl acrylate, sodium methacrylic acid sulfonate, and deionized water, stirring at room temperature for 30-40 minutes, then introducing nitrogen to deoxygenate for 1-2 hours, then adding ammonium persulfate, and heating the mixture to 60-70°C under a protective atmosphere for 3-4 hours. The mixture is then heated to 90-100°C and allowed to react for 3-4 hours. After the reaction is complete, the mixture is filtered, washed, and dried to obtain the modified polymer. Advantages: The present invention chemically modifies the surface of carbon nanotubes, allowing them to participate in the synthesis of the modified polymer (polyacrylonitrile binder), resulting in the slurry having good electrical conductivity and stability in battery applications.

The invention belongs to the technical field of self-repairing materials, and particularly relates to a double-microcapsule self-repairing waterborne polyurethane material and a preparation method thereof. Comprising the following steps: ultrasonically dispersing cellulose nanocrystals in deionized water to form a water phase, adding drying oil and lauryl sodium sulfate, and stirring to obtain the drying oil microcapsule taking Pickering emulsion as a template. Preparing a polyvinylpyrrolidone aqueous solution, a non-polar solvent solution of thiophene monomers and an ammonium persulfate aqueous solution; and mixing and ultrasonically dispersing the two, mixing with an ammonium persulfate aqueous solution, stirring and polymerizing to obtain a polythiophene microcapsule suspension after the reaction is completed, centrifuging until the supernatant is colorless, and washing and drying the solid to obtain the polythiophene microcapsule. And finally, adding the two microcapsules into waterborne polyurethane, uniformly mixing, and drying at room temperature to form the double-microcapsule self-repairing waterborne polyurethane material. According to the invention, the self-repairing and mechanical property improvement of the double-microcapsule self-repairing waterborne polyurethane material under room-temperature natural light are realized.

The invention discloses a low-shrinkage acrylate gel material and a preparation method thereof. The gel material is prepared by mixing a solution A and a solution B according to an equal proportion, the liquid A comprises acrylate, a cross-linking agent, an accelerant and a retarder; the acrylate is a calcium acrylate solution, a magnesium acrylate solution or a mixed solution of calcium acrylate and magnesium acrylate; the concentration of the acrylate in the solution A is 15wt.%-35wt.%; the liquid A is also added with a modified material, and the modified material is selected from at least one of hydroxyethyl ester, chloroprene rubber, polyurethane, polyvinyl alcohol and epoxy resin; the addition amount of the modified material is 1%-5% of the total mass of the solution A; the solution B comprises an initiator and distilled water; the initiator is selected from at least one of ammonium persulfate, hydrogen peroxide and azodiisobutyronitrile; the use amount of distilled water in the solution B is determined according to initiator concentration; by optimizing an acrylate compound system, introducing an anti-shrinkage functional component and accurately controlling a preparation process, the comprehensive improvement of material performance and engineering applicability is finally realized.

The invention discloses a preparation method and application of a polymer lithium-conducting glue solution and a solid-state lithium battery, and the preparation method comprises the following steps: adding a lithium salt and a polymer monomer into a solvent according to a mass ratio of (5-10): (3-5) to form a mixed solution; adding an initiator, uniformly stirring to obtain a mixture glue solution, and carrying out heat treatment to obtain a polymer lithium-conducting glue solution; the initiator is selected from one or a mixture of two or more of azodiisobutyronitrile, benzoyl peroxide, potassium persulfate and ammonium persulfate in any proportion; the interface material which is formed in situ in the battery and has excellent mechanical property and lithium conducting capacity is used for reducing the operation pressure of the solid-state battery and improving the electrochemical performance of the solid-state battery.

The invention provides a preparation method of an insecticide synergistic responsive release delivery system, and belongs to the technical field of insecticides. Chlorantraniliprole insecticide is dissolved in an acetone solvent containing Tween 80 to form a drug-carrier complex; then polymerizing the N-isopropylacrylamide temperature-sensitive monomer under the action of an ammonium persulfate and tetramethylethylenediamine initiation system to form a temperature-responsive hydrogel matrix; four key parameters including the optimal molar ratio, the optimal embedding temperature, the optimal embedding time and the optimal phase change temperature control precision of an amido hydrophilic group and an isopropyl hydrophobic group are calculated by applying a double-layer game model, and a drug-carrier complex is embedded into a hydrogel matrix through a physical embedding effect to construct a three-layer nested delivery structure; the technical problem that the pesticide effect utilization rate is low due to the fact that the pesticide lacks an accurate temperature-responsive release control mechanism in environmental application is solved.

The invention relates to a polycarboxylic acid water reducer and a preparation method thereof, and the water reducer is prepared from the following raw materials: 45 to 55 percent of isopentenyl polyoxyethylene ether, 28 to 35 percent of acrylic acid, 1.5 to 2.5 percent of modifier, 0.3 to 0.5 percent of ammonium persulfate, 0.03 to 0.06 percent of ascorbic acid, 5 to 8 percent of hydroxyethyl methylacrylate, 0.15 to 0.25 percent of 2, 4-diphenyl-4-methyl-1-pentene and the balance of water. The modifier is prepared from the following raw materials: 1, 5-dichloronaphthalene, p-nitrostyrene, dimethyl sulfate, ceric ammonium nitrate and tetramethylpiperidine oxide. The polycarboxylate superplasticizer has excellent neat paste fluidity and fluidity retention capability, has low 1h time-dependent variable slump which is below 18mm and optimally 10mm when applied to concrete, has a water-reducing rate of more than 40% and a gas content of less than 3.8%, and also has more advantages in compressive strength ratio.

The invention discloses a preparation method of a halloysite nanotube adsorption material with sulfonic groups polymerized on the surface, and belongs to the technical field of wastewater treatment materials, the preparation method comprises the following steps: S1, adding 5.0 g of halloysite nanotubes and 5 mL of gamma-methacryloxypropyltrimethoxysilane into 100 mL of toluene; s2, in a magnetic stirrer, condensing and refluxing at 120 DEG C for 10 hours, cooling, filtering, washing with toluene and ethanol for multiple times to remove unreacted KF570, and drying a product in a vacuum drying oven at 60 DEG C for 8 hours to obtain a KH570 modified halloysite nanotube; s3, weighing 1.0 g of HNTs-KH570 as a raw material, dispersing the HNTs-KH570 in 80 mL of distilled water, adding 5.0 g of 2-acrylamide-2-methylpropanesulfonic acid, performing uniform ultrasonic dispersion, and continuously stirring at the temperature of 70 DEG C; and S4, adding 0.15 g of ammonium persulfate into 20 mL of distilled water, and fully stirring to completely dissolve the ammonium persulfate. The adsorption performance of the halloysite nanotube to methylene blue is remarkably improved through sulfonic acid group modification, and the adsorption capacity is improved by 270%.

The invention belongs to the technical field of scale inhibitors, and particularly relates to a slow-release scale inhibitor and a preparation method thereof.The preparation method comprises the steps that 3, 4, 5-allyl trihydroxybenzoate, itaconic acid, sodium hydrogen sulfite, methacryloyloxyethyl-n-hexadecyl-dimethyl ammonium bromide and deionized water are mixed, after water bath heating, an ammonium persulfate aqueous solution is slowly added, and the scale inhibitor is obtained after reaction; the preparation method comprises the following steps: dissolving agar in deionized water, adding polyethylene glycol modified sodium alginate and a scale inhibitor into the deionized water, stirring, dropwise adding into edible oil to obtain gel microspheres, adding the gel microspheres into a calcium chloride aqueous solution, slowly stirring, cross-linking, cleaning and drying to obtain the slow-release scale inhibitor. The hydrogel microspheres swell to slowly release the scale inhibitor, meanwhile, the released scale inhibitor is hydrolyzed in water, ester groups are slowly broken, polycarboxylic acid, 3, 4, 5-trihydroxybenzoic acid and hydroxyethyl-n-hexadecyl-dimethyl ammonium bromide are slowly released, and good scale inhibition and corrosion inhibition effects are achieved.

The invention belongs to the technical field of petroleum drilling engineering, and discloses a chitosan-quaternary ammonium salt modified composite shale inhibitor and a preparation method thereof. According to the inhibitor, natural chitosan is used as a main chain, dimethyl diallyl ammonium chloride (DMDAAC) is adopted for free radical grafting modification, glycine is combined as a synergistic auxiliary agent, and a composite structure with high cation density is constructed. The preparation method comprises the following steps: dissolving 15-25 parts of chitosan in 1000 parts of 1% glacial acetic acid, and stirring at room temperature; dropwise adding 2 to 4 parts of DMDAAC, reacting at 65 to 75 DEG C, and then adding 0.1 to 1 part of ammonium persulfate for grafting for 3.5 to 4.5 hours; and cooling, filtering and drying to obtain powder. And dissolving 10-20 parts of the solution in deionized water, adding 1.5-2.5 parts of glycine, and uniformly mixing to obtain the composite inhibition liquid. The inhibitor has good water solubility and thermal stability, can significantly inhibit shale hydration expansion and particle dispersion, and experiments show that the inhibitor can be suitable for well wall stability control of complex stratums such as high-temperature deep wells and the like, and has good field adaptability and industrial popularization value.

The invention discloses a method for synthesizing a NiFeCu array catalyst through a template method and the NiFeCu array catalyst, and relates to the technical field of catalysts.The method comprises the following steps that foamy copper is cleaned, and surface oxides and pollutants are removed; uniformly mixing an ammonium persulfate solution with the concentration of 0.1-0.2 mol / L and a NaOH solution with the concentration of 1 mol / L according to the volume ratio of 1: 1 to obtain a mixed solution I, and putting the cleaned foamy copper into the mixed solution I to react for 20-60 minutes to obtain a Cu (OH) 2 / CuF array template; the Cu (OH) 2 / CuF array template is placed in a second mixed solution containing oxalic acid, a nickel source and an iron source to react for 30-120 min, and a NiFeCu array catalyst of a nanorod array structure is obtained; when applied to an OER working electrode, the NiFeCuOX array catalyst is formed through activation, a nafion binder needed by a similar powder catalyst is not needed, effective contact between an electrolyte and the catalyst and rapid release of oxygen can be guaranteed, and the electrochemical performance is greatly improved.

The invention discloses a formaldehyde-free composite board for a cabinet and a preparation method of the formaldehyde-free composite board, and relates to the technical field of artificial board manufacturing. The preparation method of the formaldehyde-free composite board for the cabinet comprises the following steps: mixing high amylose with a choline chloride / urea deep eutectic solution, stirring, adding concentrated hydrochloric acid for reaction, adjusting the pH value, and adding ammonium persulfate to obtain pretreated oxidized starch; methacrylic acid dehydrated glyceride is added into the pretreated oxidized starch for a grafting reaction, then modified polyvinyl alcohol is added for blending, sodium metaphosphate is added for crosslinking, finally, heating and curing are conducted, modified titanium dioxide nanoparticles are added, and the formaldehyde-free starch adhesive is obtained. The wood shavings and the formaldehyde-free starch adhesive are mixed, and a core material is obtained; and arranging the core material between the formaldehyde-free veneers, and carrying out hot press molding to obtain the formaldehyde-free composite board. The formaldehyde-free composite board for the cabinet has excellent mechanical strength, bonding performance and water resistance.

The invention discloses a functional and recoverable vegetable protein adhesive with high strength and toughness and a preparation method of the functional and recoverable vegetable protein adhesive. The adhesive is prepared from the following components in parts by mass: 30 parts of soybean protein, 4 to 7.5 parts of acrylamide, 0.5 to 4 parts of methacryloyloxyethyl trimethyl ammonium chloride, 1 to 3 parts of a peptide self-assembly cross-linking agent, 1.6 parts of ammonium persulfate, 5 parts of a metal-polyphenol catalyst and 65 parts of a dispersion medium. The preparation method comprises the following steps: weighing the components in proportion, dispersing the acrylamide, the methacryloyloxyethyl trimethyl ammonium chloride, the peptide self-assembly cross-linking agent and the ammonium persulfate in a medium, uniformly stirring, adding the soybean protein, finally adding the metal-polyphenol catalyst, and uniformly dispersing. The self-assembled amphiphilic peptide fiber is introduced as a dynamic cross-linking agent, and a multi-stage energy dissipation structure is constructed in the adhesive, so that the mechanical strength, the toughness and the function customizability of the adhesive are remarkably improved, and meanwhile, room-temperature polymerizability, recoverability and reprocessing are realized.

The invention relates to the technical field of polymer composite materials, and provides a composite water-retaining agent based on charcoal and bentonite as well as a preparation method and application of the composite water-retaining agent. The composite water-retaining agent provided by the invention is prepared from the following raw materials: acrylic acid, 2-acrylamido-2-methyl-1-propanesulfonic acid, acrylamide, sodium hydroxide, N, N '-methylene bisacrylamide, ammonium persulfate, modified bentonite and corn straw biochar. The composite water-retaining agent provided by the invention has excellent salt resistance, water holding capacity and structural stability, and the water absorbency in pure water and a 0.9% NaCl solution respectively reaches 2547.30 g / g and 164.45 g / g; when the soil conditioner is applied to saline-alkali soil, the maximum water holding capacity of the soil can be remarkably improved. The preparation process is simple, the cost is low, and the method has important practical significance on promoting ecological environment restoration of the arid mining area and realizing coordinated development of mineral resource development and environmental protection.

The invention discloses a preparation method of a flexible electronic device with specific wet adhesion capability, which comprises the following steps: dissolving acrylamide Am, methacrylic acid esterified gelatin GelMA and chitosan powder in an acetic acid solution, uniformly stirring, adding carboxylated multi-walled carbon nanotubes (MWCNTs) into the mixed solution, stirring uniformly, and drying to obtain the flexible electronic device with specific wet adhesion capability. Performing ultrasonic treatment, water bath treatment and degassing treatment to obtain a precursor solution; the preparation method comprises the following steps: mixing sodium monohydrogen phosphate and sodium dihydrogen phosphate, adding sodium bicarbonate, adding ammonium persulfate as an initiator, fully stirring, and degassing to obtain a gelling solution for inducing physical crosslinking of chitosan; selecting a material with carboxyl, amino and hydroxyl groups to manufacture a mold for polymer cross-linking molding; and mixing and stirring the precursor solution and the gelling solution, injecting into a prepared mold, placing at room temperature, and integrally forming to manufacture the flexible electronic device. The invention further discloses application of the flexible electronic device in preparation of a bioelectric sensor sensitive element and tissue repair.

The invention belongs to the technical field of high-molecular polymers, and particularly relates to glyoxal modified polyacrylamide and a synthesis method thereof. Comprising the following steps: adding sulphaguanidine and 4-vinyl benzaldehyde into a solvent for reflux to obtain a compound 1; the preparation method comprises the following steps: adding acrylamide and methacryloyloxyethyl trimethyl ammonium chloride into water, adding into the hydrolysate of 1, 3-dimethoxy-1, 3-dimethyl-1, 3-divinyl disiloxane, and adding an ammonium persulfate solution for reaction to obtain a mixed solution; adding an acetone solution of a compound 1 into the mixed solution, and adding an ammonium persulfate solution to react to obtain cationic polyacrylamide; the cationic polyacrylamide and glyoxal are stored separately, and are mixed and reacted during use to obtain glyoxal modified polyacrylamide. According to the invention, early crosslinking of glyoxal and a polymer is avoided, the paper strength can be obviously improved, and the product can show excellent stability in the storage process.

The preparation method comprises the following steps: (1) dissolving a zinc salt in a mixed solvent of ethanol, DMF (Dimethyl Formamide), ammonia water and water, dropwise adding triazole, carrying out stirring reaction at room temperature for 5-10 hours, then carrying out aging treatment for 20-30 hours, obtaining a solid product, washing the solid product, and drying the solid product to obtain zinc-triazole MOF; (2) heating the zinc-triazole MOF to 800-850 DEG C under the protection of inert gas, calcining for 2-4 hours, cooling, washing to remove metal ions, and drying to obtain MOF-derived porous carbon; and (3) adding the MOF-derived porous carbon into an aniline hydrochloride solution, uniformly dispersing, adding an ammonium persulfate solution, stirring and reacting for 5-10 hours, and washing and drying a product to obtain the MOF-derived porous carbon composite electrode material. The MOF-derived porous carbon composite electrode material is used as a negative electrode material to prepare the supercapacitor, and the supercapacitor has very excellent electrochemical performance and cycling stability.

The invention discloses a subtractive etching micro-nano multistage rough structure copper surface for strengthening boiling heat transfer and a preparation method thereof, and relates to the technical field of micro-nano composite structure strengthening phase change heat transfer. The etched micro-nano multistage coarse structure completely covers the surface of the copper substrate, the micro-nano multistage coarse structure comprises micron-scale concave cavities, nano-scale concave cavities / holes and nano-scale granular bulges, and the micron-scale concave cavities, the nano-scale concave cavities / holes and the nano-scale granular bulges jointly form a multistage structure; performing ultrasonic cleaning on the target metal substrate by using a cleaning solution; and a mixed aqueous solution of ammonium persulfate and chlorate is used as an etching solution, and the cleaned target metal substrate is left to stand in the etching solution for etching. And after the etching is finished, cleaning to obtain the etched micro-nano composite rough structure surface. Ammonium persulfate and chlorate are used as solutes, and the mass ratio of the solutes to the solvent is 1: 3. The mass ratio of the ammonium persulfate to the chlorate in the solute is (1: 9)-(3: 7). The method has high production efficiency, shows good thermal stability in a boiling test, and is beneficial to industrial large-scale application and production.