1434 results about "Methyl acrylate" patented technology

The invention discloses a repulpable and degradable PHA heat-seal barrier coating and a composition thereof, and belongs to the field of water-based functional coatings and cellulose-based packaging materials. The coating composition is prepared from the following components in percentage by non-volatile solids: 30 to 85 weight percent of polyhydroxyalkanoate emulsion, 5 to 60 weight percent of flaky natural inorganic matters, a water-based cross-linking agent and an auxiliary agent, and 1 to 20 weight percent of ethylene-acrylic acid or ethylene-methyl acrylate dispersion can be selected. The pH value of the composition is 6.5-9.0, and organic fluorine is not artificially added. When the dry weight is 6-20 g / m, the coating meets at least one of the following four items: the water vapor transmission rate (38 DEG C, 90% RH) is less than or equal to 80 g / m.d, Cobb60 is less than or equal to 15 g / m, the oil resistance grade is greater than or equal to 11, and the laboratory repulping rate is greater than or equal to 98%; and the heat-sealing peel strength is greater than or equal to 2.5 N / 15mm under the conditions of 150 DEG C, 0.2 MPa and 0.5 s. And the coating and the stripping film thereof meet the industrial composting standard.

The invention relates to the technical field of textiles, and discloses a cool and washable bio-based nylon 56 fabric and a preparation method thereof. The preparation method of the cool and washable bio-based nylon 56 fabric comprises the following steps: loading modified nano aluminum oxide on modified aluminum nitride microchips to obtain a composite cool material; nylon 56, an ethylene-methyl acrylate-glycidyl methacrylate terpolymer, polypentamethylene guanidine hydrochloride and a composite cool feeling material are subjected to blending extrusion and melt spinning, and then the bio-based nylon 56 fabric is woven. Mixing the composite modified boron nitride and ethanol to obtain finishing liquid; spraying the finishing liquid on one side of the bio-based nylon 56 fabric, and drying to obtain the cool washable bio-based nylon 56 fabric. The cool and washable bio-based nylon 56 fabric disclosed by the invention has excellent cool feeling, antibacterial property, washable property, moisture absorption property and unidirectional perspiration property.

The invention discloses a thiazolinone acrylic acid silane ester self-polishing antifouling resin and a preparation method and application of the thiazolinone acrylic acid silane ester self-polishing antifouling resin. The preparation method of the thiazolinone acrylic acid silane ester self-polishing antifouling resin mainly comprises the following steps: in a nitrogen environment, adding an initiator, the preparation method comprises the following steps: carrying out random free radical polymerization reaction on thiazolinone methacrylate, methyl methacrylate, ethyl acrylate, triisopropyl silicon-based methacrylate and phenyl dimethyl silicon-based methacrylate by taking azodiisobutyronitrile and benzoyl peroxide as initiators to synthesize the photoinitiator. Wherein the thiazolinone methacrylate monomer is prepared by grafting double bonds on 5-chloro-2-benzothiazolinone and methacryloyl chloride through a substitution reaction, then grafting hydroxyl on the 5-chloro-2-benzothiazolinone and mercaptoethanol through a mercapto-alkene click reaction and finally carrying out a substitution reaction on the 5-chloro-2-benzothiazolinone and methacryloyl chloride. According to the invention, the coating still has good surface self-renewal capability even in a static environment so as to inhibit the adhesion of large fouling organisms.

The invention relates to the technical field of blocking medicine bottles, and particularly discloses a blocking medicine bottle and a preparation method thereof, aiming at the problems that the upper limit of the blocking performance of the existing blocking medicine bottle is low and the blocking performance is difficult to break through due to the fact that the blocking performance of the existing blocking medicine bottle is mostly realized through structural design. A bottle body of the blocking medicine bottle comprises an inner layer, a secondary inner layer, a middle layer, a secondary outer layer and an outer layer which are sequentially arranged in a covering mode. The inner layer comprises polyethylene; the secondary inner layer comprises an ethylene-methyl acrylate copolymer; the middle layer comprises an ethylene-vinyl alcohol copolymer, cyclic polyolefin and modified montmorillonite; the secondary outer layer comprises an ethylene-methyl acrylate copolymer; the outer layer comprises polyethylene, cyclic polyolefin and modified montmorillonite. The barrier medicine bottle is formed by compositing five layers of materials, the oxygen and water transmittance is low, the barrier property is high, and the barrier medicine bottle has great application value in packaging of medicine or food and the like.

The invention discloses a concrete composite tackifier and a preparation method thereof, and relates to the technical field of concrete. When the concrete composite tackifier is prepared, firstly, polyacrylic resin obtained by polymerizing acrylic acid, methyl methacrylate, acrylamide and vinyl diphenylphosphine reacts with modified porphyrin, and then sulfonation is performed to obtain modified polyacrylic resin; the preparation method comprises the following steps: firstly, pre-treating silica fume with vinyltrimethoxysilane, then carrying out a reaction on the silica fume pre-treated with vinyltrimethoxysilane, tetravinyltetramethylcyclotetrasiloxane and vinylboronic acid pinacol ester to obtain modified silica fume, and finally, mixing polyacrylic resin and the modified silica fume to obtain the concrete composite tackifier. The concrete composite tackifier prepared by the invention has good working performance and antibacterial property.

The invention discloses a super-hydrophobic anti-icing coating for a power transmission line and a preparation method, and belongs to the technical field of preparation of anti-icing coatings. The super-hydrophobic anti-icing coating for the power transmission line is composed of a coating wrapping the surface of the power transmission line, and the coating is composed of the following components in parts by weight: 34-45 parts of composite resin, 8-14 parts of a composite ice melting agent, 10-18 parts of deionized water, 1-3 parts of hexadecyl trimethoxy silane and 50-58 parts of tetrahydrofuran, the composite resin is prepared from carboxyl multi-walled carbon nanotubes, isopropanol, tetraethoxysilane, a silane coupling agent KH-550, perfluorodecyl trimethoxysilane, butyl acrylate, methyl methacrylate and dodecafluoroheptyl methacrylate, and the composite ice melting agent is prepared from pyridine-2, 6-dicarboxylic acid, thionyl chloride and nicotinic acid hydrazide. The coating prepared by the method has excellent hydrophobicity, wear resistance and anti-icing effect.

The invention discloses a preparation method of an antibacterial self-repairing organic silicon coating, and belongs to the technical field of organic silicon resin preparation, octamethylcyclotetrasiloxane, siloxane and / or amino silane and a catalyst are sequentially added into a four-neck flask filled with nitrogen, after stirring and heating, acid treatment is performed to obtain amino polysiloxane with a quaternary ammonium salt modified side chain, and then the amino polysiloxane with the quaternary ammonium salt modified side chain is added into the four-neck flask to obtain the antibacterial self-repairing organic silicon coating. Adding carbon tetrachloride and methyl acrylate, adding sodium hydroxide after the reaction is finished, heating and refluxing, filtering to obtain a liquid product, carrying out rotary evaporation to obtain amino acid modified polysiloxane, uniformly stirring the amino acid modified polysiloxane and a solvent to obtain a component A, uniformly stirring an antibacterial cross-linking agent and a solvent to obtain a component B, stirring the component A and the component B, coating, and drying to obtain a finished product. And curing to obtain the amino acid modified polysiloxane for self-repairing the antibacterial coating. Through synthesis of amino acid modified polysiloxane, reversible crosslinking of polysiloxane is realized through chelation of amino and carboxyl on metal ions, the reversible crosslinking can be repeated for multiple times, and the metal ions have an antibacterial effect, so that the service life of the coating is prolonged.

The invention discloses a flame-retardant PMMA (polymethyl methacrylate) plate and a preparation method thereof, and belongs to the technical field of acrylic plates. Comprising the following raw materials in parts by weight: 70-80 parts of methyl methacrylate, 8-12 parts of methyl acrylate, 5-15 parts of a synergistic flame retardant, 10-18 parts of modified nano silicon dioxide, 0.2-0.4 part of an initiator and 3-5 parts of a release agent. Wherein the modified nano silicon dioxide is high in surface hydrophobicity and better in compatibility with a PMMA matrix, so that the wear resistance and the mechanical property of the PMMA plate are greatly enhanced; wherein the synergistic flame retardant can enhance the mechanical property of the PMMA plate, in addition, molecules contain three elements of silicon, nitrogen and phosphorus, and the three elements can achieve a synergistic effect, so that the flame retardance of the plate is remarkably improved, and the stability is good; therefore, the PMMA plate prepared by the invention is good in wear resistance and excellent in mechanical property, also has stable and efficient flame retardance, and has important application value in the technical field of acrylic plates.

The invention discloses a high-RAP-doping-amount cold-mixed asphalt regenerant, and particularly relates to the technical field of asphalt regenerant, the high-RAP-doping-amount cold-mixed asphalt regenerant comprises the following raw materials: hydrogenated extract oil, acetyl tributyl citrate, a low-temperature penetrant, pre-swelling SEBS master batch, a crosslinking catalyst and a microcapsule antioxidant. Molecular-level branched-chain alkyl sodium sulfonate can be wedged into aged asphalt microcracks at the temperature of 65 DEG C, lost light components are balanced and supplemented through hydrogenated extract oil, an SEBS micro-crosslinking network forms an in-situ reinforcement effect at the temperature of 90 DEG C, the triple regeneration effect of regenerated asphalt is achieved, and the service life of the regenerated asphalt is prolonged. Nano-zinc oxide is treated by a silane coupling agent and then is modified by using methyl methacrylate and potassium persulfate, so that the nano-zinc oxide is coated with polymethyl methacrylate, the compatibility of the microcapsule antioxidant and the recycled asphalt can be improved, and the anti-aging performance of the recycled asphalt is improved.

The invention provides transparent high-impact-resistance heat-resistant MBS (methyl methacrylate-butadiene-styrene) resin and a preparation method thereof, and relates to the field of high polymer material preparation methods, the transparent high-impact-resistance heat-resistant MBS resin is prepared from the following raw materials: water, ethanol, maleic anhydride, an emulsifier, MBS resin grafted latex, potassium persulfate and an antioxidant; the MBS resin grafted latex is prepared from the following raw materials: water, modified styrene-butadiene latex, sodium hydrogen sulfite, potassium persulfate, methyl methacrylate and styrene, the modified styrene-butadiene latex is prepared from the following raw materials: a pre-emulsion, glycidyl methacrylate, ammonium persulfate, divinyl benzene and potassium persulfate; the pre-emulsion is prepared from the following raw materials: water, an emulsifier, butadiene and styrene. The product is good in heat resistance and good in PVC modification effect, and the modified PVC composite material is high in light transmittance, high in cantilever beam impact strength and resistant to aging.

The invention discloses a hydrogel dressing with a double-slow-release effect as well as a preparation method and application of the hydrogel dressing. The preparation method of the hydrogel dressing comprises the following steps: firstly, preparing methyl acrylate modified hyaluronic acid capable of being photo-crosslinked, then preparing carboxymethyl chitosan nanoparticles loaded with chlorogenic acid, and finally, mixing the methyl acrylate modified hyaluronic acid and the carboxymethyl chitosan nanoparticles loaded with chlorogenic acid to obtain the hydrogel dressing. The hydrogel dressing embedded with the nanoparticles is obtained in a photo-crosslinking mode. The hydrogel dressing provided by the invention not only has good biocompatibility and mechanical properties, but also plays an anti-oxidation role by removing free radicals in a body, and can effectively kill bacteria such as escherichia coli and staphylococcus aureus to play an antibacterial role. The hydrogel dressing can also reduce excessive inflammatory response in the wound healing process by influencing macrophage polarization, promote chronic wound healing and relieve pain of patients.

The invention relates to the technical field of cables, and provides a tensile new energy charging pile cable which comprises a conductor, an insulating layer, a shielding layer and a sheath layer which are sequentially arranged from inside to outside. The sheath layer comprises the following components in parts by weight: 60-70 parts of chlorinated polyethylene, 15-20 parts of polyisoprene, 5-10 parts of an ethylene-methyl methacrylate copolymer, 8-18 parts of an acrylonitrile-butadiene-styrene copolymer, 20-30 parts of modified hydroxyapatite, 1-5 parts of a lubricant, 3-6 parts of a plasticizer, 30-40 parts of a flame retardant and 1-3 parts of an antioxidant; the raw materials of the modified hydroxyapatite comprise hydroxyapatite and a modifier; the modifier comprises maleic acid-acrylic acid copolymer sodium salt; the weight ratio of the hydroxyapatite to the modifier is 45: (1-7). According to the technical scheme, the problem that the cable sheath layer of the new energy charging pile is poor in tensile property and corrosion resistance in the prior art is solved.

The invention discloses an environment-friendly deformation-resistant reed wood composite shaving board and a preparation method thereof, and belongs to the technical field of boards. The reed wood composite shaving board is prepared from wood chips, reed fibers, basalt fibers, lignin fibers, plant extracts, nano silicon dioxide, acetylated distarch phosphate, a C30-45 alkyl cetearyl polydimethylsiloxane cross-linked polymer and a PEG-10 polydimethylsiloxane-vinyl polydimethylsiloxane cross-linked polymer according to a specific proportion. The adhesive is prepared from a methyl methacrylate cross-linked polymer, an MDI adhesive and an organic silicon waterproof agent. All the components are matched for use, the shaving board is prepared in a directional mode, the shaving board has excellent mechanical performance, crack resistance and deformation resistance, the environment-friendly performance is improved, and the use amount of glue is reduced. The novel formaldehyde-free adhesive and the plant extract are adopted to replace traditional formaldehyde-containing glue and a mildew-proof and insect-resistant agent, formaldehyde release is effectively avoided, and a healthier home decoration plate choice is provided for consumers.

The invention relates to an epoxy core-shell polymer particle and resin, a preparation method of the epoxy core-shell polymer particle and resin and application of the epoxy core-shell polymer particle and resin to epoxy resin. The preparation method of the epoxy core-shell polymer particle comprises the following steps: heating and mixing a polybutadiene seed emulsion, a reducing agent, an emulsifier and the like; adding methyl methacrylate and an initiator, and glycidyl methacrylate and an initiator, and heating to react; compared with the prior art, the core-shell particle with the outer layer of the synthesized shell containing the epoxy group can be used for toughening the epoxy resin, so that the toughness of the epoxy resin is effectively improved while the excellent heat resistance and mechanical properties of the epoxy resin are maintained.

The invention relates to a biodegradable composite material as well as a preparation method and application thereof, and belongs to the technical field of compositions of high-molecular compounds. The biodegradable composite material is prepared from the following components in parts by weight: 46 to 87 parts of PBAT resin, 2 to 10 parts of PLA resin, 10 to 40 parts of calcium carbonate, 0.5 to 2 parts of a slipping aid and 0.5 to 2 parts of an edge sealing aid, the molar content of D-lactic acid in the PLA resin is greater than or equal to 2%; the particle size D50 of the calcium carbonate is less than 1.8 microns; the edge sealing auxiliary agent is an ethylene-acrylic acid copolymer, an ethylene-vinyl acetate copolymer, an ethylene-methyl acrylate copolymer, an ethylene-methyl acrylate-glycidyl methacrylate terpolymer, an ethylene-butyl acrylate copolymer, an ethylene-butyl acrylate-glycidyl methacrylate terpolymer, an ethylene-vinyl acetate copolymer, an ethylene-vinyl acetate copolymer, an ethylene-vinyl acetate copolymer, an ethylene-vinyl acetate copolymer, an ethylene-vinyl acetate copolymer, an ethylene-vinyl acetate copolymer, an ethylene-vinyl acetate copolymer and an ethylene-vinyl acetate copolymer. And at least one of epoxy resin. The biodegradable composite material has excellent long-acting edge sealing performance.

The invention discloses a biodegradable polylactic acid composite material and a preparation method thereof, and relates to the technical field of polylactic acid materials. The method comprises the steps that firstly, chitosan activated through hydrochloric acid is subjected to graft modification through a KH550 silane coupling agent, meanwhile, nano-zinc oxide is subjected to surface modification through stearic acid, the chitosan and the nano-zinc oxide are mixed, spray drying is conducted, and antibacterial composite powder is prepared; the preparation method comprises the following steps: performing hydrochloric acid activation and KH570 silane coupling agent modification on nano silicon dioxide, performing hydroxypropylation modification on alkali lignin, and performing reflux crosslinking reaction on the modified alkali lignin, KH570 modified nano silicon dioxide, polycaprolactone, methyl methacrylate and azodiisobutyronitrile to prepare a heat-resistant reinforcer; uniformly mixing polylactic acid, poly (butylene succinate), the antibacterial composite powder, the heat-resistant reinforcer, tributyl citrate, polyethylene glycol and talcum powder, and extruding and granulating by using a twin-screw extruder to obtain the heat-resistant antibacterial material. The composite material prepared by the invention has excellent antibacterial property, heat resistance and biodegradability.

The invention relates to an antistatic film and a preparation method thereof, and belongs to the technical field of polymer film materials. The antistatic film is prepared from the following components in parts by weight: 100 parts of PP resin, 5 to 8 parts of hydrogenated petroleum resin, 4.5 to 5.5 parts of conductive filler, 1.2 to 1.6 parts of antistatic additive, 0.1 to 0.12 part of antioxidant, 0.08 to 0.1 part of light stabilizer and 2.5 to 3 parts of lubricant, the preparation method comprises the following steps: carrying out amine ester exchange on methyl acrylate and diethylenetriamine under the catalysis of sodium hydride to prepare a double-bond-terminated amide compound, namely an amidated matrix, carrying out addition on mercaptopropyltrimethoxysilane and the amidated matrix under the initiation of ultraviolet radiation, and introducing a methoxysilane structure to the end part of the amidated matrix for modification, so as to obtain the antistatic additive. Finally, bromopropane and residual amido of the silanization intermediate are subjected to quaternization treatment, and the antistatic auxiliary is obtained. The film material is endowed with good antistatic performance and packaging performance through the interaction of the antistatic auxiliaries.

The utility model discloses a high-purity methyl 3-methoxypropionate filtering device which is provided with a product tank for conveying materials, and a conveying pipe is mounted on the right side of the outer surface of the product tank; comprising a molecular sieve device installed on the upper side of the outer surface of the conveying pipe, a first feeding pipe is installed on the upper side of the molecular sieve device, and an ion exchange device is installed at the other end of the first feeding pipe. According to the high-purity methyl 3-methoxypropionate filtering device, the conveying pipe with the conveying pump is arranged, materials in the product tank are stably pumped into the filtering device, and the molecular sieve device is matched, so that methyl alcohol, methyl acrylate, acrylic acid, sodium methoxide and other impurities in industrial methyl 3-methoxypropionate can be effectively adsorbed and removed; and ion-state metal, anions, organic pigment free alkali and the like are removed by gradually matching with an ion exchange device, and finally, the material is filtered by matching with a filter element filter, and the purity of the product is kept.

The present invention relates to the technical field of modification of lithium battery current collector materials, and provides a coating material and a preparation method for preventing PET film degradation. The coating material is a film-forming substance made of vinyl pyrrolidone / methyl acrylate / fluorinated ethylene copolymer and a graphene nanosheet as a filler. The main component of the film-forming substance is a polyvinyl pyrrolidone segment, and the relative content of the methyl acrylate segment and the fluorinated ethylene segment is small. In addition, the vinyl pyrrolidone / methyl acrylate / fluorinated ethylene copolymer forms a three-dimensional network structure through cross-linking, and the graphene nanosheet forms a chemical connection with the polymer network through a surface active group. The coating can effectively prevent the lithium battery electrolyte and the catalyst alkoxy lithium from contacting with the PET substrate, thereby preventing the PET substrate from degrading.

The invention relates to an in-situ curing gel structure electrolyte as well as a preparation method and application thereof. The preparation method comprises the following steps: (1) mixing a resin matrix with a pore-forming agent, then adding a curing agent for mixing to obtain a mixed solution, and pouring the mixed solution into a closed mold for curing to obtain a resin film; soaking and drying the resin film to obtain porous resin; and (2) mixing 4-styrene sulfonyl (phenylsulfonyl) imide lithium salt, polyethylene glycol methyl ether acrylate, polyethylene glycol dimethacrylate, ethylene carbonate and azodiisobutyronitrile to prepare a mixed solution, and soaking the porous resin in the mixed solution to react and cure, thereby obtaining the in-situ curing gel structure electrolyte. The preparation method is simple, and the prepared in-situ curing gel structure electrolyte can improve the mechanical property, the battery capacity and the cycle performance of the in-situ curing gel structure electrolyte.

The invention relates to the technical field of oilfield chemistry, in particular to an aminoethanesulfonic acid type surfactant and a preparation method and application thereof.The preparation method of the aminoethanesulfonic acid type surfactant comprises the steps that firstly, fatty amine is dissolved in a first solvent, a sodium chloroethanesulfonate aqueous solution is added, and N-long-chain alkyl-2-sodium aminoethanesulfonate is obtained through a reaction; and 2, dissolving a required amount of N-long-chain alkyl-2-sodium aminoethanesulfonate in a second solvent, adding a required amount of methyl acrylate, and reacting to obtain the aminoethanesulfonic acid type surfactant. The aminoethanesulfonic acid type surfactant disclosed by the invention contains long-chain alkyl, amino, ester groups and sulfonic acid groups, so that the aminoethanesulfonic acid type surfactant has good surface activity and can meet the development requirements of oil and gas fields. The microemulsion cleanup additive prepared from the aminoethanesulfonic acid type surfactant can effectively reduce the surface tension and the interfacial tension of an aqueous solution, and the preparation method is easy and convenient to operate, mild in condition and suitable for industrial production.

The invention discloses an OCA (Optical Clear Adhesive) solution for a folding screen protective film, the OCA solution comprises an optical raw adhesive, a curing agent and a first solvent, the raw adhesive is prepared from the following raw materials in parts by mass: 270-283 parts of 2-ethylhexyl acrylate, 50-62 parts of butyl acrylate, 318-330 parts of methyl acrylate, 40-55 parts of acrylic acid, 1-2 parts of gamma-acryloyloxypropyltrimethoxysilane, 2.1-2.3 parts of an initiator and 1250-1350 parts of a second solvent; the second solvent comprises methylbenzene and ethyl acetate. According to the OCA optical glue solution for the folding screen protection film, raw glue is prepared from the isooctyl acrylate, the butyl acrylate, the methyl acrylate, the acrylic acid, the gamma-acryloyloxy propyl trimethoxy silane and the initiator in a toluene and ethyl acetate compounded solvent system, and an OCA glue layer with excellent stripping force, light transmittance, holding power and bending resistance is obtained after curing; and the cost of the raw materials is optimized, and the method is more economical.

The invention discloses a high-toughness biaxially oriented nylon film and a production method thereof. Comprising the following raw materials in parts by weight: 40-50 parts of copolymerized nylon resin, 10-20 parts of nylon 12, 15-25 parts of thermoplastic polyamide elastomer, 3-6 parts of nanofiller, 1-3 parts of coupling agent, 10-20 parts of reinforced fiber, 5-8 parts of additive, 3-7 parts of ethylene-methyl acrylate-glycidyl methacrylate terpolymer and 6-10 parts of modified cellulose nanocrystal. The invention relates to a flame-retardant polyamide resin, which is prepared from the following components in parts by weight: 2-4 parts of amino-terminated hyperbranched polyamide and 1-3 parts of 3, 3 '-diamino-4, 4'-difluorodiphenyl sulfone. The film is high in tensile strength, good in tear resistance and excellent in barrier property and low-temperature impact resistance.

The invention relates to the technical field of coatings, in particular to an associative emulsion thickener for latex paint and a preparation method of the associative emulsion thickener. The associative emulsion thickener for the latex paint is formed by polymerizing a monomer A, a monomer B and a monomer C, the monomer A is prepared from tridecyl methacrylate, diethyl itaconate and isobornyl acrylate; the monomer B comprises methyl acrylate, acrylic acid and acrylic acid-2-hydroxyethyl ester; the monomer C is prepared from diacetone acrylamide, N-isopropyl acrylamide, N-dodecyl acrylamide and ethylene glycol dimethacrylate. The thickening agent has the advantages of environmental protection, high biocompatibility and good thickening effect, solves the problem of poor stability of latex paint at low temperature and high temperature, and improves the glossiness.

The invention relates to a perovskite solar cell and a preparation method thereof, a photovoltaic module, a system and an electric device. The perovskite solar cell comprises a transparent electrode layer, and a perovskite layer, an electron transport layer and a metal electrode which are sequentially arranged on the transparent electrode layer; the electron transport layer comprises an organic electron transport material, a first additive and a second additive; the first additive is prepared from one or more of polymethyl methacrylate, a methacrylic acid-methyl methacrylate copolymer, a 4-vinylpyridine-styrene copolymer, polyacrylonitrile and poly (4-vinylpyridine); the second additive comprises one or more of a compound shown as a formula I and a compound shown as a formula II. The perovskite solar cell provided by the invention has relatively high photoelectric conversion efficiency and relatively good stability.

The invention relates to the technical field of oilfield chemistry, in particular to a diester single-tail cationic surfactant, a preparation method and application thereof and a discharge aiding agent for acid fracturing. The diester single-tail cationic surface active agent is prepared from raw materials such as N, N-dimethyl-1, 3amine, methyl acrylate and halogenated alkane. The invention provides a low-cost, green and environment-friendly diester single-tail cationic surface active agent, and the preparation method of the diester single-tail cationic surface active agent is simple and convenient to operate, safe, reliable and beneficial to industrial production, popularization and application, and has a wide market prospect. The acid fracturing discharge aiding agent using the diester single-tailed surfactant as a raw material can effectively reduce the surface and interfacial tension of an aqueous solution, and meets the technical specification of the acid fracturing discharge aiding agent.

The invention discloses a preparation process of an early-warning anti-loosening bolt, and relates to the technical field of bolts, the outer side of a bolt base body is coated with a layer of anti-corrosion sheath containing a polyamide composite material through an injection molding process, so that the effect of improving the corrosion resistance of the bolt is achieved. Furan-2, 5-diketone is used for modifying aminated graphene oxide, maleimide modified graphene oxide is obtained, maleimide has the characteristic of being sensitive to ultraviolet light, and can react with styrene and methyl methacrylate under ultraviolet irradiation, so that vinyl graphene oxide is obtained; and then polyamide modified glass fibers are added, so that the corrosion resistance of the bolt is further improved.

The invention provides an ash-free antirust agent and a preparation method thereof. The preparation method comprises the following steps: in a non-polar solvent, mixing dinonyl naphthalene sulfonic acid and dodecenylsuccinic acid to obtain a mixed acid A; the preparation method comprises the following steps: mixing polyethylene polyamine and mixed acid A according to a molar ratio of (0.5-2.0): 1, and adding deionized water and methanol to react until the pH value of the solution is neutral; and adding methyl methacrylate and base oil into the reacted system, heating and distilling, and then carrying out reduced pressure distillation until no obvious distillate is generated, thereby obtaining the ash-free antirust agent. The invention also provides the ash-free antirust agent prepared by the method. The ashless antirust agent integrates the advantages of the dinonyl naphthalene sulfonic acid group and the dodecenyl succinic acid group on the molecular level, the antirust property is better, and the ashless antirust agent and the anti-wear reagent at extreme pressure have a very good synergistic effect.

The invention discloses an artificial SEI film coated graphite negative electrode material and a preparation method and application thereof, and belongs to the technical field of lithium ion battery negative electrode materials. The preparation method comprises the following steps: heating and oxidizing graphite in mixed gas of air and nitrogen, and cooling to obtain oxidized and etched graphite; then dispersing the oxidized and etched graphite in a solvent, adding methyl methacrylate and graphene, stirring and initiating an in-situ polymerization reaction, and forming a doped coating layer on the oxidized and etched graphite; and finally, carrying out vacuum drying on the coated oxidized and etched graphite, and cooling to obtain the artificial SEI film coated graphite negative electrode material. The specific surface area of graphite is increased through oxidation etching, the ion diffusivity is improved, the combination effect of the organic polymer is improved, the first efficiency of the negative electrode material is remarkably improved by combining the synergistic effect of the conductive polymerized organic matter and graphene, and the conductivity, the structural stability and the interface compatibility are enhanced.

The invention discloses an anti-aging and anti-corrosion coating and a preparation method thereof, and relates to the technical field of coatings. When the anti-aging and anti-corrosion coating is prepared, firstly, tetramethyl tetravinyl cyclotetrasiloxane, n-butyllithium and dimethyl-3-chloropropyl chlorosilane react to obtain modified polysiloxane, then 4-vinylpyridine, methyl methacrylate and n-butyl acrylate are copolymerized and then react with the modified polysiloxane, and then bis (4-chlorphenyl) phosphine is grafted to obtain the anti-aging and anti-corrosion coating. Finally, reacting with p-aminodiphenylamine to obtain modified acrylic resin; secondly, enabling the titanium dioxide nanosheet pretreated by 3-aminopropyltrimethoxysilane to react with ester phthalocyanine, and then hydrolyzing to obtain a modified titanium dioxide nanosheet; finally, mixing the modified acrylic resin, the modified titanium dioxide nanosheet, a solvent, a dispersing agent and a defoaming agent to obtain the anti-aging and anti-corrosion coating. The anti-aging and anti-corrosion coating prepared by the invention has excellent anti-aging, anti-corrosion, flame-retardant and antibacterial properties.