The invention discloses a producing process of quaternary ammonium type cation modifying starch, comprising the following steps of: mixing, modifying, neutralizing, physically synergizing, screening, weighing and packing. The invention ensures that the common starch has cation characteristics and higher substitution values, reduces pasting temperature and precipitability of starch, has the advantages of reasonable producing process, high heating efficiency, thorough modification, good film forming property, high binding rate, high retention, low cost, small investment, low energy consumption, low pollution, simple producing process, high production efficiency, stable and reliable quality and wide application range and is suitable for large-scale production.