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46 results about "Phase change enthalpy" patented technology

Phase-change temperature-adjustable antistatic polyester film and preparation method thereof

PendingCN120307736ASynthetic resin layered productsPhase change enthalpyPolyester
The invention discloses an antistatic polyester film capable of phase change temperature regulation and a preparation method thereof, the film provided by the invention has a double-layer structure, the bottom layer is a temperature regulation functional layer doped with a phase change material, and the surface layer is a functional layer doped with carbon black to prevent electrostatic aggregation. According to the antistatic polyester film capable of adjusting the temperature through phase change, the adjusting temperature is 27 DEG C, the phase change enthalpy is 17 j / g, the surface resistivity of the surface layer is 1.1 * 10 < 7 > omega / m < 2 >, and the antistatic polyester film is expected to be applied to the fields of intelligent wearable equipment, medical sensors, electronic packaging materials, supercapacitor protection layers and the like.
Owner:HANGZHOU HESHUN TECH CO LTD +1

Method for rapidly predicting eutectic component and melting point of multi-element eutectic molten salt

The invention discloses a multi-element eutectic molten salt eutectic component and melting point rapid prediction method, which comprises the following steps: S1, based on binary phase equilibrium data, using a Wilson model to obtain binary interaction parameters of corresponding components, and constructing a binary system database including binary system melting point, phase change enthalpy, molar ratio, biased Gibbs fusion energy and interaction parameters; and S2, based on the binary interaction parameters obtained in the step S1, calculating the eutectic components and the melting point of the multi-component molten salt by using a thermodynamic principle and a Newton-Raphson method in combination with the thermophysical property data of the single-component molten salt. According to the multi-element eutectic molten salt eutectic component and melting point rapid prediction method, the multi-element molten salt system eutectic component and the phase transition temperature can be calculated through binary molten salt system data, the dual advantages of being high in prediction speed and high in prediction precision are achieved, and the method has great significance in reducing experiment combinations, shortening experiment time and rapidly screening available formulas.
Owner:NANJING UNIV OF AERONAUTICS & ASTRONAUTICS

Two-component sweating type fiber reinforced phenolic aerogel composite material and preparation method thereof

ActiveCN121736367APhase change enthalpyPolymer science
The invention relates to the technical field of fiber reinforced resin-based composite materials, in particular to a two-component sweating type fiber reinforced phenolic aerogel composite material and a preparation method thereof. The method comprises the following steps: (1) modifying phenolic resin; (2) preparing a phenolic resin pregel solution; (3) impregnating the fiber reinforcement; (4) gel curing; (5) drying; (6) filling with an inorganic phase change agent; and (7) filling with an organic phase change agent. The phenolic aerogel is prepared by taking the phenolic resin modified by hot acid treatment as a raw material, so that the curing crosslinking degree of the phenolic resin can be effectively improved, and the skeleton and pore diameter of the aerogel can be refined. According to the invention, the inorganic phase change agent and the organic phase change agent with high phase change enthalpy values are sequentially introduced into pores of the phenolic aerogel, and the hierarchically distributed binary phase change agent can be subjected to solid-liquid-gas phase change in sequence from outside to inside in a high-temperature environment, so that the composite material has comprehensive properties such as ultrahigh temperature resistance, long-term efficient heat insulation and high mechanical strength.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI

Photo-initiated polymerization phase change microcapsule material as well as preparation method and application thereof

The invention discloses a photo-initiation polymerization phase change microcapsule material as well as a preparation method and application thereof. The method comprises the following steps: mixing a core material and a wall material, and adding a photoinitiator to obtain an oil phase; adding a surfactant into deionized water, and fully stirring to obtain a water phase; slowly pouring the oil phase into the water phase, and homogenizing at a corresponding rotating speed by using a homogenizer to obtain a stable emulsion; and cooling the emulsion to a corresponding temperature, irradiating with an ultraviolet lamp, centrifuging, washing with deionized water, and drying in a drying oven to obtain the phase change microcapsule. The phase change microcapsule disclosed by the invention shows a clear core-shell structure, is in a regular circle shape, and has relatively high phase change enthalpy, relatively high initial thermal weight loss temperature, controllable particle size and negligible leakage rate. When the phase change microcapsule is added into the resin, the composite material shows obvious delayed temperature rise when being heated, and the phase change material has no obvious leakage, so that a good application prospect is provided for being widely applied to thermal forming and thermal management based on high polymer materials.
Owner:SOUTH CHINA UNIV OF TECH

Preparation and application of inorganic eutectic form-stable phase change material with heat preservation function

ActiveCN116606634BHeat-exchange elementsPhase change enthalpyGas phase
The application relates to preparation and application of inorganic eutectic shaped phase change materials with heat preservation function, belonging to the technical field of phase change energy storage. The inorganic eutectic shaped phase change material takes sodium carbonate decahydrate and disodium hydrogen phosphate dodecahydrate as phase change main body materials, and takes sodium silicate nonahydrate as a nucleating agent, so that the supercooling degree is reduced, and the inorganic eutectic phase change material with low supercooling and no phase separation is prepared. Further, the inorganic eutectic shaped phase change material is prepared by using gaseous SiO2 as supporting material. The material prepared by the application has suitable phase change temperature, higher phase change enthalpy and very low supercooling degree, and has no phase separation phenomenon. Moreover, the synthesis process is simple, and the raw material is low in price. Simulation application test shows that the material has excellent building heat buffering performance, and has wide application prospect in the field of building energy saving.
Owner:DALIAN UNIV OF TECH

High energy density phase change composite materials, their preparation methods and applications

PendingCN122302832APhase change enthalpyHigh energy
This invention relates to high-energy-density phase change composite materials, their preparation methods, and applications, belonging to the field of phase change composite material technology. To address the problems of low energy density, insufficient mechanical properties, and poor processability of current phase change materials, this invention provides a high-energy-density phase change composite material, specifically a lightweight porous cellulose phase change composite aerogel. Internally, it consists of a three-dimensional network framework formed by the cross-linking of vinyl-functionalized cellulose nanocrystals and cellulose nanofibers. The phase change material is uniformly loaded within the pores of this three-dimensional network, with a loading amount of 65.53~91.02 wt%. The phase change temperature range of the composite material is 20~80℃. This invention's phase change composite material, relying on a hierarchical confinement structure, achieves efficient encapsulation and high loading of the phase change material, with a phase change enthalpy as high as 133.2 J / g. It also possesses excellent mechanical and thermal cycling stability and 3D printing performance, making it suitable for scenarios with wide temperature fluctuations and applicable to the field of intelligent thermal management.
Owner:ZHEJIANG FORESTRY UNIVERSITY

A high thermal conductivity and high phase change enthalpy carbon nanocomposite phase change microcapsule and its preparation method

ActiveCN119775972BHeat-exchange elementsAlkanePhase change enthalpy
The present invention belongs to the field related to phase change materials, and specifically relates to a high thermal conductivity and high phase change enthalpy carbon nanocomposite phase change microcapsule and its preparation method. The present invention uses flaky graphene oxide as a dispersant to form a water-in-oil Pickering emulsion with graphene oxide as the interface, and adds an initiator to the aqueous phase to polymerize the aniline monomer and the cross-linking monomer in the oil phase at the interface of the Pickering emulsion to form a network polymer layer to fix the capsule thermal conductive particle shell. The microcapsule shell is composed of thermal conductive polymer cross-linked polyaniline and thermal conductive particle graphene oxide. The diameter of the thermal conductive carbon nanoparticles first dispersed in the alkane phase change material is equivalent to the diameter of the capsule, and a thermal conductive path supporting the skeleton structure is formed in the confined space inside the microcapsule, thereby improving the thermal conductivity of the microcapsule. It has the characteristics of high thermal conductivity and high phase change heat storage capacity, and can be applied to renewable energy storage, new energy vehicle thermal management, industrial waste heat utilization, aerospace engineering and other fields.
Owner:HEFEI INSTITUTE OF PHYSICAL SCIENCE CHINESE ACADEMY OF SCIENCES

Low-thermal-conductivity phase-change aerogel material as well as preparation method and application thereof

PendingCN122011767AIncrease enthalpylow thermal conductivityPhase change enthalpyTemperature control
The invention discloses a low-thermal-conductivity phase change aerogel material as well as a preparation method and application thereof. The phase change enthalpy value of the material is 50J / g to 110J / g; the phase change temperature is 0-60 DEG C; and the heat conductivity coefficient is 0.08 W / (m.K)-0.1 W / (m.K). The novel low-thermal-conductivity phase-change material is generated by curing polydimethylsiloxane (PDMS) and the phase-change microcapsules. The phase change aerogel material is simple in synthesis process, relatively high in phase change enthalpy value and good in phase change cycle stability. The method has important application prospects in the two aspects of heat energy collection and heat insulation temperature control.
Owner:DALIAN INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES

Medium temperature zone phase change material and preparation method thereof

PendingCN120137601AHeat-exchange elementsPhase change enthalpyTemperature control
The invention discloses a medium-temperature zone phase change material and a preparation method thereof, and the preparation method comprises the following steps: stirring a mixed solution containing stearic acid, zinc salt, triethylamine and ethanol, reacting, centrifuging, and drying to obtain the medium-temperature zone phase change material. The stearic acid reacts with the zinc salt to generate the novel medium-temperature zone phase change material, the phase change temperature is 117.49 DEG C, and the phase change enthalpy value is 184.16 J / g. The phase change material is simple in synthesis process, relatively high in phase change enthalpy value and good in phase change cycle stability. The method has important application prospects in the two aspects of heat energy collection and temperature control in a medium-temperature area.
Owner:DALIAN INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES

A composition for preparing phase change composite materials, the phase change composite material, the preparation method, and its application.

PendingCN122080653AImprove phase change enthalpy yieldImprove thermal conductivityHeat-exchange elementsPhase change enthalpyMolten state
This disclosure relates to a composition for preparing phase change composite materials, the phase change composite material itself, a preparation method thereon, and its applications. Based on the total weight of the composition, it comprises: 80-90% by weight of a phase change material, 5-17% by weight of a thermally conductive filler, and 3-15% by weight of a thickener. The phase change composite material has a phase change enthalpy of 80-250 J / g, a phase change enthalpy yield of 80-90%, a thermal conductivity of 1-10 W / m·K, and a melt index of 15-150 g / min. Using the composition of this disclosure to prepare the phase change composite material can improve the phase change enthalpy yield, while also exhibiting high thermal conductivity and a certain degree of plasticity in the molten state. Furthermore, the mixing and molding processes are simplified by using only a heated stirring pan or kneading pan, reducing production costs.
Owner:CHINA ENERGY INVESTMENT CORP LTD +1

Quantitative design method for functional mix proportion of phase change material for SAC

PendingCN122088122AGeometric CADChemical processes analysis/designAluminatePhase change enthalpy
The invention relates to a method for quantitatively designing the functional mix proportion of a phase-change material for SAC. The method comprises the following steps: acquiring a characteristic initial temperature T, a peak temperature T and a characteristic final temperature T of sulphoaluminate cement through an adiabatic temperature rise test; [T, T] is used as a functional targeted phase change interval of the phase change material, and based on the total hydration heat release amount Qcem in the temperature interval and the phase change enthalpy delta Hpcm of the phase change material, the functional mixing amount Mpcm of the phase change material in unit volume of concrete is calculated, then the aggregate dosage is calculated through an absolute volume method, and finally the concrete mix proportion is determined. According to the invention, accurate matching of the phase-change material and sulphoaluminate cement hydration characteristics is realized, and an effective temperature control solution is provided for sulphoaluminate cement concrete construction.
Owner:CHINA CONSTRUCTION SIXTH ENGINEERING DIVISION CO LTD +1

Preparation method of lignin-based organic phase change material

PendingCN121991641AHeat-exchange elementsPhase change enthalpyHexagonal boron nitride
The invention belongs to the field of phase change energy storage temperature control materials of an organic system, and provides a preparation method of a lignin-based organic phase change material, the lignin-based organic phase change material comprises the following raw materials by weight: 86%-97% of erythritol, 2%-5% of hexagonal boron nitride, 0.5%-2% of a lignin compatibilizer and 0.5%-10% of expanded graphite, and the sum of the mass percentages of the raw materials is 100%. By adding the lignin compatibilizer, the compatibility of the phase change material and other components is improved, and the stability of the whole material is improved by regulating and controlling the formula. The energy storage and temperature control phase change material provided by the invention has the advantages of proper phase change temperature, high phase change enthalpy value, low supercooling degree, good cycle stability and no obvious phase separation phenomenon, and is a proper thermal physical energy storage technology.
Owner:QILU UNIVERSITY OF TECHNOLOGY (SHANDONG ACADEMY OF SCIENCES)

A gel-based composite phase change energy storage material and its preparation method

PendingCN122278442ACold chainPhase change enthalpy
This invention discloses a gel-based composite phase change energy storage material and its preparation method. The material comprises the following components in the indicated mass fractions: 70%–80% phase change matrix; 5%–10% temperature regulator; 1%–3% nucleating agent; 0.5%–1.5% thermal conductivity enhancer; 10%–15% gel skeleton; and 0.5%–2% thickener. This invention precisely controls the phase change temperature to -25°C to -20°C using the temperature regulator, meeting the requirements for frozen product transportation; it utilizes synergistic nucleating agents and functionalized multi-walled carbon nanotubes to control the supercooling to within 2°C; the carbon aerogel skeleton and surface gel protective layer achieve dual leak prevention, exhibiting excellent cycle stability, with a phase change enthalpy decay rate of less than 5% after 500 cycles; simultaneously, the thermal conductivity is significantly improved, and the raw materials are environmentally friendly and biodegradable, showing broad application prospects in the cold chain logistics field.
Owner:ZHEJIANG VOCATIONAL COLLEGE OF COMMERCE

Pure-phase vanadium dioxide powder, preparation method and application thereof

PendingCN122627462AVanadium dioxidePhase change enthalpy
The application belongs to the technical field of inorganic functional material preparation, and particularly relates to pure-phase vanadium dioxide powder and a preparation method and application thereof. The application makes the precursor system simultaneously contain pentavalent vanadium species and tetravalent vanadium species through partial reduction treatment, so that the average valence of vanadium gradually approaches the target valence of vanadium in VO2, and meanwhile, reaction space for further reduction, hydrolysis, condensation and crystal growth in a subsequent hydrothermal process is reserved. The partial reduction mode can avoid excessive complexation, rapid nucleation and organic residue caused by excessive citric acid, relieve the reduction and hydrolysis process, and reduce the risk of local excessive reduction and out-of-control oxygen content in a subsequent vacuum annealing process. The obtained VO2(M) powder has obvious heat-induced phase change endothermic and exothermic peaks and high phase change enthalpy, indicating that the crystal phase purity is high and the phase change process is sufficient, and the powder is suitable for the fields of thermochromic, infrared regulation, intelligent window and infrared camouflage.
Owner:UNIV OF ELECTRONICS SCI & TECH OF CHINA

Novel phase change energy module and preparation method therefor

PCT designated stageWO2026129612A1Heat-exchange elementsPhase change enthalpyThermal energy storage
Disclosed in the present invention are a novel phase change energy module and a preparation method therefor, belonging to the technical field of phase change energy storage materials. The energy module product consists of a shape-stabilized phase change system having thermal energy storage properties and an encapsulating bag. The preparation method comprises: using a support framework material to realize shape stabilization and adsorption of a phase change matrix and an additive, and performing secondary encapsulation with an aluminum foil bag, so as to solve the problem of liquid leakage during long-term recycling. The present invention involves a simple synthesis process, and is convenient to use. The material exhibits no significant liquid leakage during operation, a high phase change enthalpy value and a low price, and therefore has wide application prospects.
Owner:DALIAN UNIV OF TECH

Composite phase change material, and preparation method and application thereof

ActiveCN120665571BHeat-exchange elementsPhase change enthalpyPlasma technology
The application belongs to the technical field of energy storage, and relates to a composite phase change material and a preparation method and application thereof.The composite phase change material comprises a paraffin base body and a heat-conducting phase change material dispersed in the paraffin base body; the heat-conducting phase change material comprises at least one of biomass-based graphene, copper nanowire foam and Fe3O4 modified biomass-based graphene. Bamboo powder is converted into few-layer graphene through sandwich microwave plasma technology, then is modified by Fe3O4 nanoparticles, is compounded with paraffin, and finally is packaged with copper nanowire foam to construct a synergistic structure of 'two-dimensional heat-conducting network-three-dimensional metal skeleton-nano light absorber'. The prepared composite phase change material has a photo-thermal conversion efficiency of 73.47%, a heat conductivity of 3.157 W·m ‑1 ·K ‑1 , a phase change enthalpy retention rate of >98% and no leakage. The composite phase change material is suitable for solar heat storage, intelligent building and electronic device heat management, and is produced in a green and low-cost manner through biomass waste resource utilization.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

A phase change microcapsule design system and method based on artificial intelligence

The application provides a phase change microcapsule design system and method based on artificial intelligence, which comprises a machine learning module, a data establishing module, a target input module, a machine screening module and a target output module, the machine learning module is used for collecting raw material composition, synthesis process and performance data of existing phase change microcapsules, the data establishing module is used for collecting types of organic materials and inorganic materials and material preparation processes, the target input module is used for inputting phase change temperature, phase change enthalpy value, coating rate and type of core material of the phase change microcapsule to be designed, the machine screening module is used for screening suitable wall materials and emulsifiers from the data establishing module according to machine learning results and data of the target input module, and the target output module is used for outputting the designed phase change microcapsule.
Owner:WUHAN INSTITUTES OF ADVANCED TECHNOLOGY CHINESE ACADEMY OF SCIENCES

Long-chain ethylenediamine bis-n-alkanoic acid diammonium salt single crystal phase change material and preparation method thereof

The invention discloses a long-chain ethylenediamine bis-n-alkanoic acid diammonium salt single-crystal phase change material and a preparation method thereof, ethylenediamine is used as an alkaline ligand, long-chain n-alkanoic acid is used as an acidic ligand, and the long-chain n-alkanoic acid is introduced to amino groups at two ends of ethylenediamine through a salt forming reaction to form the long-chain single-crystal phase change material with a sandwich layered structure. The structural formula of the material is [NH3 (CH2) 2NH3] < 2 + >. 2 [RCOO] <->, wherein R represents C11-C15 linear alkyl; the single crystal is regular in structure and belongs to a triclinic system and a P1 space group, and Z is equal to 1. The narrow phase change temperature zone and the phase change enthalpy of the material are averagely improved by more than 30% and can be maximally improved by more than 80% compared with corresponding long-chain n-alkanoic acid, and the material has good thermodynamic properties and is expected to be applied to the fields of industrial waste heat recovery, solar heat storage, aerospace thermal control systems and the like as an efficient phase change energy storage material.
Owner:SHANGLUO UNIV

A method for preparing and applying a shaped organic / inorganic composite phase change material

A method for preparing and applying a shaped organic / inorganic composite phase change material (CPCM) is disclosed, belonging to the field of phase change energy storage technology. The CPCM comprises 50-70 wt% inorganic solid-liquid CPCM, 5-30 wt% organic solid-liquid CPCM, 5-15 wt% emulsifier and thickener, and 10-30 wt% porous support material. The inorganic solid-liquid CPCM is a hydrated inorganic salt-based CPCM, the organic solid-liquid CPCM is an organic acid ester or long-chain alkane-based CPCM, and the emulsifier and thickener are ionic cellulose gums. These three components are assembled under supramolecular forces and uniformly composited with the porous adsorbent material. The prepared CPCM exhibits a high phase change enthalpy and good cycling stability. Furthermore, the CPCM demonstrates excellent building thermal management performance, making it highly suitable for large-scale application in future building thermal management.
Owner:DALIAN UNIV OF TECH

Solid-solid composite phase change heat storage material and preparation method thereof

PendingCN120098608AHeat-exchange elementsPhase change enthalpyHeat management
The invention relates to the technical field of heat management materials, in particular to a solid-solid composite phase change heat storage material and a preparation method thereof.The 1, 10-decanediol is selected as a main phase change material, and the synergistic effect of expanded graphite and flake graphene is combined, so that the high phase change enthalpy is kept, and meanwhile the solid-solid composite phase change heat storage material is obtained; the phase change temperature of the material is adjusted to a more ideal range; the heat storage capacity of the material is improved, the expanded graphite and the flake graphene are introduced, particularly 12-15% of expanded graphite and 2-5% of flake graphene are matched, so that the heat conduction performance of the material is greatly enhanced, the heat absorption and release process is accelerated, and the selected 1, 3-propylene glycol has the advantages that the heat storage capacity of the material is improved; the 1, 10-decanediol, the expanded graphite and the flake graphene are all environment-friendly materials, are non-toxic and harmless, are easy to recycle and process, and accord with the current green and low-carbon development trend, so that the technical problem that a solid-solid phase change heat storage material in the prior art is difficult to meet the requirements of phase change temperature and phase change enthalpy at the same time is solved.
Owner:CHONGQING HFC ELECTRONIC NEW MATERIAL CO LTD

A double-shell high-thermal-conductivity phase-change heat storage microcapsule for ultra-deep drilling fluid and a preparation method and application thereof

ActiveCN119193120BHeat-exchange elementsDrilling compositionPhase change enthalpyLatent heat
The present application relates to a kind of double-shell high-thermal-conductivity phase change heat storage microcapsules for ultra-deep drilling fluid and its preparation method and application, belong to the drilling fluid chemistry field of petroleum industry.The present application respectively with two high-melting-point phase change materials and two eutectic compounds of phase change material as core material, by twice the coating of outer shell, a kind of double-shell high-thermal-conductivity phase change heat storage microcapsules for ultra-deep drilling fluid is prepared, the material has high phase change temperature, phase change temperature is between 173.3-230.7 DEG C, phase change enthalpy is as high as 211.4J / g, when in phase change temperature range, a large number of heat will be absorbed, play the role of " phase change latent heat", the material is applied to drilling fluid can significantly reduce the temperature of drilling fluid, improve the tolerance of drilling fluid to high temperature formation.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

Method for testing supercooling degree of nano-liter liquid drops by differential scanning calorimetry

PendingCN120294059AMaterial crystallisationMaterial heat developmentPhase change enthalpyFreezing Point Temperature
The invention discloses a method for testing the supercooling degree of nano-liter liquid drops by a differential scanning calorimetry. The method comprises the following steps: taking a liquid sample with the mass of more than 0.2 mg or the volume of more than 0.2 mu L, then placing the liquid sample in a crucible to form a plurality of sub-droplets, then carrying out DSC test to obtain the phase change enthalpy of the plurality of sub-droplets, and calculating to obtain the degree of supercooling of the plurality of sub-droplets; wherein the volume of at least one sub-droplet is less than 0.1 mu L. The method provided by the invention can accurately measure the freezing point temperature of the liquid drop below 50 nanoliters and even 5 nanoliters, widens the measurement range of the quantitative relationship between the liquid drop size and the supercooling behavior, and lays a technical foundation for researching the liquid coating dominated liquid drop phase change behavior.
Owner:QINGHAI INST OF SALT LAKES OF CHINESE ACAD OF SCI

Composite phase change material as well as preparation method and application thereof

ActiveCN120665571AHeat-exchange elementsPhase change enthalpyPlasma technology
The invention belongs to the technical field of energy storage, and relates to a composite phase change material and a preparation method and application thereof. The composite phase-change material comprises a paraffin base body and a heat-conducting phase-change material dispersed in the paraffin base body. The heat-conducting phase-change material comprises at least one of biomass-based graphene, copper nanowire foam and Fe3O4 modified biomass-based graphene. Bamboo powder is converted into few-layer graphene through an interlayer type microwave plasma technology, the few-layer graphene is modified by Fe3O4 nanoparticles and then compounded with paraffin, and finally, a two-dimensional heat conduction network-three-dimensional metal framework-nanometer light absorber synergistic structure is constructed through copper nanowire foam packaging. The photothermal conversion efficiency of the prepared composite phase change material reaches 73.47%, the thermal conductivity is improved to 3.157 W.m <-1 >. K <-1 >, the phase change enthalpy retention rate is larger than 98%, and leakage is avoided. The method is suitable for solar heat storage, intelligent building and electronic device heat management, and green and low-cost production is achieved through biomass waste recycling.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

Recyclable flexible composite phase change material as well as preparation method and application thereof

PendingCN121825506ASecondary cellsHeat-exchange elementsElastomerPhase change enthalpy
The invention discloses a recyclable flexible composite phase change material as well as a preparation method and application thereof, and relates to the technical field of battery thermal management. The lauric acid, the thermoplastic polyester elastomer and the hexagonal boron nitride are simply blended to prepare the recyclable flexible composite phase-change material with wide-temperature flexibility and excellent electrical insulating property, the phase-change material keeps flexibility in a wide temperature range of-15-60 DEG C, can be tightly attached to a battery, is extremely small in temperature fluctuation under continuous vibration, and can be widely applied to the field of lithium ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries and lithium ion batteries. And the short circuit risk is reduced through high insulativity. In addition, the high phase change enthalpy can significantly reduce the working temperature of the battery. And the material also has excellent recoverability, the performance is not attenuated after 10 times of remodeling, and excellent practicability and reliability are shown.
Owner:ZHEJIANG SCI-TECH UNIV

Preparation method of high-thermal-conductivity phase change energy storage material based on bubble jet oriented graphene nanosheet layer

ActiveCN119143121BCarbon compoundsHeat-exchange elementsPhase change enthalpyMicrosphere
The application relates to a preparation method of a high-thermal-conductivity phase change energy storage material based on bubble jet orientation of graphene nanosheet layers. By introducing high-pressure expanded microspheres into graphene, air jets are generated when the microspheres break, the graphene sheet layers are deflected, a highly oriented graphene skeleton is prepared, high-thermal-conductivity graphene skeletons are obtained through high-temperature graphitization treatment, the phase change energy storage material is filled multiple times through a vacuum-assisted filling method, and a high-thermal-conductivity graphene phase change energy storage composite material is obtained. The high-thermal-conductivity graphene phase change energy storage material has the characteristics of fast response and high heat storage, the response time is shortened by 1 / 2 compared with traditional commercial materials, the thermal conductivity is up to 152 W / (m*K), the bulk phase change enthalpy value is up to 249 kJ / L, and the thermal conductivity and the phase change enthalpy value can be adjusted according to different requirements. Therefore, the novel graphene phase change energy storage material has great application prospect.
Owner:BEIHANG UNIV

Preparation method of oriented graphene-carbon nano tube aerogel synergistic heat conduction enhanced sizing composite phase change material

PendingCN120248838AHeat-exchange elementsPhase change enthalpyFreeze-drying
The invention discloses a shaped composite phase change material with high thermal conductivity and anisotropy as well as a preparation method and application thereof. The invention belongs to the field of composite phase change materials. The problems that in the prior art, a phase change material is low in heat conductivity coefficient, unstable in phase change form and prone to leakage are solved. According to the preparation method, docosane, chitosan, nano graphene and carbon nanotubes are taken as raw materials, and the shaped composite phase change material with high thermal conductivity and anisotropy is prepared through freeze drying and an impregnation method. The phase change enthalpy of the prepared phase change material is 234.2-251.9 J / g, the heat conductivity is 0.431-0.606 W / (m.K), the phase change material has a high heat conductivity coefficient and high heat conductivity, keeps stable form in a leakage experiment, the leakage rate is smaller than 2%, the phase change material is good in insulativity, high in safety, high in mechanical strength, small in density, capable of keeping stable working state and temperature output, good in plasticity and formability, capable of meeting complex engineering requirements and suitable for industrial production. A new material is provided for the energy storage field.
Owner:HARBIN INST OF TECH

Graphene@polymer microsphere / alkane composite phase change material and preparation method thereof

ActiveCN118995144BPhase change enthalpyAlkane
The application belongs to the technical field of phase change materials, and particularly relates to a mixed graphene / polymer microsphere / alkane composite phase change material and a preparation method thereof. The preparation method comprises the following steps: heating and melting an alkane base to obtain an alkane fluid, adding two kinds of graphene with the same sheet diameter and different thicknesses and a dispersing aid into the alkane fluid, adding polymer microspheres, sealing and placing in a heat treatment device at 50-80 DEG C, and then performing ultrasonic crushing to obtain the graphene / polymer microsphere / alkane composite phase change material. The two kinds of graphene with the same sheet diameter and different thicknesses and the microsphere-assisted heat conduction framework significantly improve the heat conductivity of the alkane phase change material, significantly reduce the viscosity, and minimize the influence of the phase change enthalpy, so that the efficient heat conduction and energy storage efficiency are realized. The preparation process is simple, and the mass production and application can be realized.
Owner:HEFEI INSTITUTE OF PHYSICAL SCIENCE CHINESE ACADEMY OF SCIENCES

Preparation method and application of phase-change nanocapsule-based latent heat type functional hot fluid

PendingCN120098611ASolar heating energySolar heat collector detailsPhase change enthalpyPolystyrene
According to the preparation method and application of the phase-change nanocapsule-based latent heat type functional hot fluid, a nuclear material with the phase-change temperature of 20-80 DEG C is packaged in polystyrene or silicon dioxide to form a phase-change nanocapsule, and the phase-change nanocapsule has the characteristics of being controllable in size, large in phase-change enthalpy, high in encapsulation efficiency and excellent in thermal stability and cycling stability. Dispersing the phase-change nanocapsules in deionized water containing the modified multi-walled carbon nanotubes; and finally, forming the uniformly mixed latent heat type functional thermal fluid under the action of an emulsifier and magnetic stirring. The phase change nanocapsule prepared by the invention has the characteristics of controllable size, larger phase change enthalpy, higher encapsulation efficiency and excellent thermal stability and cycling stability, is prepared into latent heat type functional thermal fluid with better dispersion stability, larger heat storage capacity and excellent photothermal conversion performance, and can be popularized and applied in the field of solar photothermal.
Owner:ZHENGZHOU UNIVERSITY OF LIGHT INDUSTRY

A phase change refrigeration material performance prediction method and related device

ActiveCN119851827BDesign optimisation/simulationConstraint-based CADPhase change enthalpyData set
The application discloses the data phase change material information field, disclose a kind of oriented phase change refrigeration material performance prediction method and related device, construct about phase change refrigeration material component, process condition, temperature induced martensitic phase change enthalpy change data and adiabatic temperature change shape memory alloy database;Utilize database and machine learning model, establish component process-adiabatic temperature change generation model;Utilize component process-adiabatic temperature change generation model to obtain phase change enthalpy change dataset;Extract DSC curve feature in phase change enthalpy change dataset, obtain low-dimensional phase change feature;Based on low-dimensional phase change feature, combine process parameter, utilize artificial neural network model to construct elastic-thermal performance prediction model;Under the condition of given DSC data, utilize elastic-thermal performance prediction model, obtain corresponding adiabatic temperature change under the condition of given DSC data.The application can combine generation model and prediction model under small sample condition, with temperature induced martensitic phase change feature as bridge, and predict shape memory alloy elastic-thermal performance.
Owner:XI AN JIAOTONG UNIV

Medium-high temperature eutectic phase change energy storage material and preparation method thereof

The invention discloses an adipic acid-sebacic acid binary eutectic phase change material and a preparation method thereof, and belongs to the field of phase change energy storage materials. The eutectic phase change material is composed of two compounds which are respectively adipic acid and sebacic acid. The eutectic phase change material with the melting point of 124.1 DEG C and the phase change enthalpy of 216.1 J / g is provided by adjusting the molar percentage of adipic acid and sebacic acid in a binary system, and the eutectic phase change material has potential application in the scenes of medium-high temperature electronic device heat management, mold temperature control, solar energy and industrial waste heat energy storage and the like. The adipic acid / sebacic acid eutectic phase-change material has the advantages that (1) the phase-change temperature of the prepared adipic acid / sebacic acid eutectic phase-change material is 124.1 DEG C, and the adipic acid / sebacic acid eutectic phase-change material is suitable for a thermal management scene of medium-high temperature electronic equipment; (2) the adipic acid / sebacic acid eutectic phase change material prepared by the method is homogeneous, free of phase separation and high in phase change enthalpy value; and (3) the preparation method provided by the invention is simple, green, environment-friendly and pollution-free.
Owner:UNIV OF ELECTRONICS SCI & TECH OF CHINA