The invention provides a low-temperature phase-change heat storage material and a preparation method thereof. The low-temperature phase-change heat storage material comprises the following components in percentage by weight: 90%-92% of sodium acetate trihydrate, 3%-5% of tetrasodium pyrophosphate decahydrate, 2%-3% of anhydrous sodium carbonate and 1%-2% of polyacrylamide. The preparation method comprises the following steps of: grinding the four components until the granularity is 30-50 meshes respectively, mixing uniformly, and heating the mixture in a water bath at the temperature of 74-79 DEG C, so as to completely melt all the components to form a colloidal liquid; after stirring uniformly, injecting the colloidal liquid into a container, wherein the injected volume is 88%-90% of the volume of the container; and after the colloidal liquid is cooled to room temperature, sealing the container. According to the invention, the adding ratio of an additive is low, the stability of the material is high, the phase-change latent heat is large, the crystallization temperature is moderate, and the supercooling degree is not more than 2 DEG C; and the phase-change heat storage material is the colloidal liquid in melting, so that the phase separation phenomenon is avoided, the preparation process is simple, the packaging is easy and the production is convenient.