The invention provides low-temperature polymer conductive paste and a preparation method thereof. The low-temperature polymer conductive paste comprises conductive filler and carrier adhesives for carrying the conductive filler, wherein the carrier adhesives comprise functional resin including phenoxy resin and fluorine resin. The low-temperature polymer conductive paste has the advantages that a mixed resin system is adopted, wherein the phenoxy resin has excellent carrying capacity for the conductive filler and is good in adhesion force, and the fluorine resin is excellent in conductive filler dispersing performance, has low surface energy and is good in base material wetting performance and high in flexibility, therefore, high filling for conductive powder can be achieved, wetting and dispersing the conductive powder are also benefited, and further, achievement of high conductivity, low wire resistance, low contact resistance, good adhesion force and high weatherability after the paste is cured are facilitated.