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45results about How to "Wide phase transition temperature range" patented technology

Polyalcohol solid-solid phase-change composite material and preparation method thereof

The invention provides a polyalcohol solid-solid phase-change composite material. The polyalcohol solid-solid phase-change composite material comprises a polyalcohol solid-solid phase-change material and a resin base material, is capable of avoiding the problems of melt flow and osmotic migration, and has wide phase-change temperature range, big phase-change latent heat, and adjustable phase-change temperature and phase-change latent heat. The invention further provides a method for preparing the polyalcohol solid-solid phase-change composite material. The method can be used for preparing the polyalcohol solid-solid phase-change composite materials with all profiles and good constancy and in all sizes. The preparation technology is simple and free from environment pollution. The polyalcohol solid-solid phase-change composite material of the invention has wide application value in the fields, such as the heat protection of aircrafts, the constant-temperature temperature control of precise instruments, meters and electronic devices, heat barrier coating, solar utilization, recovery of industrial residual heat and waste heat, the energy source of electric peak load shifting and valley filling, material, aerospace, textile, electric power, medical instrument, building and the like.
Owner:海鹰空天材料研究院(苏州)有限责任公司

Preparation method of paraffin/polyurethane solid-solid composite double-phase change energy storage material

The invention discloses a preparation method of a paraffin / polyurethane solid-solid composite double-phase change energy storage material, comprising the following steps: selecting raw materials which comprises the following components: by weight, 40-90 parts of polyethylene glycol, 4-20 parts of isocyanate, 0-10 parts of a chain extender, 0-50 parts of paraffin, 0-5 parts of a surfactant and 0-1 part of a catalyst; melting glycol and carrying out vacuum-pumping processing, mixing the molten glycol with the surfactant and paraffin, adding isocyanate, the chain extender and the catalyst to react at a temperature of 60-90 DEG C to obtain a performed polymer, carrying out deaeration on the performed polymer, injecting the deaerated performed polymer into a mould, solidifying, cooling and demoulding. According to the composite double-phase change energy storage material provided by the invention, a paraffin hydrocarbon compound with large latent heat of phase change is used as a filling material, and a polyurethane material with a phase change function is used as a matrix. Latent heat of phase change of the prepared paraffin / polyurethane solid-solid composite double-phase change energy storage material reaches 154J / g, phase-change temperature ranges from 15 DEG C to 70 DEG C, and the material is a composite phase change material having a double-phase change character.
Owner:INST OF CHEM MATERIAL CHINA ACADEMY OF ENG PHYSICS

Preparation method for phase-M vanadium dioxide nanometre powder

The invention discloses a preparation method for phase-M vanadium dioxide nanometre powder. The preparation method comprises the following steps: mixing polyhydric alcohol with a carbon chain length of 3 to 10 with monohydric alcohol with a carbon chain length of 1 to 5 in a volume ratio of 1: (6 to 15), so as to obtain a mixed alcohol solution; then adding quaternary ammonium salt with a carbon chain length of 1 to 16 in the mixed alcohol solution, so as to obtain electrolyte, wherein the concentration of quaternary ammonium salt in the electrolyte is 1-5 g/L; then using a vanadium metal block as an anode, using a platinum metal block or a vanadium metal block as a cathode, keeping a distance between the anode and the cathode to be 2 mm to 5 cm, placing the anode and the cathode in the electrolyte, and electrolysing for 1 to 3 hours under a voltage of 2 to 30 V, so as to obtain a reaction solution containing precipitates; then performing a solid-liquid treatment and a washing treatment on the reaction solution, so as to obtain an intermediate product; and after that, annealing the intermediate product for 1 to 3 hours at a temperature of 350 to 450 DEG C and under a pressure of 10 to 100 Pa, so as to prepare the target product with a particle size of 50 to 100 nm. The preparation method has the characteristics of being time-saving, energy-saving, environment-friendly, low in preparation cost, and easy to realize large-scale industrialized production.
Owner:HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI

Thermodiffusion method for manufacturing wide temperature range phase transition nickel titanium alloy

InactiveCN101245438AHas a fastening effectWide phase transition temperature rangeQuenchingNickel titanium
The invention relates to a thermal diffusion method for manufacturing a nitinol with wide temperature phase transition, pertaining to the filed of metallic functional materials. The invention is characterized in that the composition range of the nitinol with wide temperature phase transition is: Ni50.5-Ti to Ni52-Ti, and the manufacturing method comprises: (1) the nitinol with wide temperature phase transition is obtained by adopting a plurality of short-term heating and quenching; (2) the heating temperature for the quenching of the nitinol with wide temperature phase transition ranges from 300-900 DEG C; (3) the heating time for the quenching of the nitinol with wide temperature phase transition is 1-600s; (4) the treatment times for the quenching of the nitinol with wide temperature phase transition are 1-30. From the beginning of the phase transition to the end of the phase transition Ms-Mf, the temperature range is more than 50 DEG C. The temperature range of the martensitic phase transformation of the invention is wide, high damping temperature range is wide, good damping effect is performed under poor strain condition; the austenite phase always kept in the interior of the nitinol can ensure good hyperelasticity, thus leading an oscillating damper to have tightening effect to improve the damping effect; the thermal diffusion method requires simple equipment and is easily operated.
Owner:UNIV OF SCI & TECH BEIJING

Thin-film material with double-effect functions of heat absorption and wave absorption and preparation method thereof

The invention discloses a thin-film material with double-effect functions of heat absorption and wave absorption and a preparation method thereof. The composite thin-film material takes water-soluble macromolecules such as polyvinyl alcohol (PVA), sodium cellulose and gelatin as a shell layer, takes a phase change material polyethylene glycol (PEG) as a core layer, takes magnetic nanoparticles such as metals (Fe, Co and Ni), metal alloys (FeCo) and metal oxides (Fe3O4, NiO and CoFe2O4) as wave-absorbing fillers, and the composite thin-film material is prepared by a coaxial electrostatic spinning method. The thin-film material with the double-effect functions of heat absorption and wave absorption has the advantages that water is used as a spinning solvent, the prepared fiber is of a core-shell structure, the problem that leakage is prone to occurring when the phase change core layer is subjected to solid-liquid phase transition is solved, and the content of the phase change core layer is high. In addition, magnetic nanoparticles have high magnetic loss tangent angles and can be used for absorption and attenuation of electromagnetic waves. Therefore, the prepared composite film material has the advantages of green and environment-friendly preparation process, high phase change latent heat, good electromagnetic wave absorption performance, stable recycling performance and the like, and can simultaneously meet the multifunctional application requirements of heat absorption / wave absorption of the thin-film material.
Owner:WUHAN UNIV OF TECH

Temperature-control flame-retardant phase-change material for power lithium ion battery, preparation method of temperature-control flame-retardant phase-change material and lithium ion battery

The invention provides a flame-retardant phase change material, which is prepared from the following raw materials in parts by mass: 1 to 90 parts by weight of polyhydric alcohol, 1 to 90 parts by weight of resin, 1 to 10 parts by weight of solid porous material, 0.1 to 7 parts by weight of flame retardant, 0.1 to 5 parts by weight of heat conduction agent and 0.01 to 2 parts by weight of coupling agent and/or curing agent. The temperature-control heat-conduction phase-change material is obtained by taking polyhydric alcohol and the like as a phase-change agent, taking resin as a support body of the phase-change material, taking a solid porous material as an auxiliary setting agent, combining with a specific heat-conduction agent and a flame retardant, uniformly mixing the phase-change agent, the support body, the auxiliary setting agent, the heat-conduction agent and the flame retardant, and polymerizing or curing. The solid-solid phase change composite material provided by the invention is wide in phase change temperature range, large in phase change latent heat and adjustable in phase change temperature and phase change latent heat, does not need complex use devices and packaging containers with good sealing performance, and is wider in application occasion and lower in system cost.
Owner:HAIKE GRP RES INST OF INNOVATION & TECH

Preparation method of m-phase vanadium dioxide nanopowder

ActiveCN103409768BGood dispersionInfrared transmittance changeElectrolysis componentsVanadium dioxideElectrolysis
The invention discloses a preparation method for phase-M vanadium dioxide nanometre powder. The preparation method comprises the following steps: mixing polyhydric alcohol with a carbon chain length of 3 to 10 with monohydric alcohol with a carbon chain length of 1 to 5 in a volume ratio of 1: (6 to 15), so as to obtain a mixed alcohol solution; then adding quaternary ammonium salt with a carbon chain length of 1 to 16 in the mixed alcohol solution, so as to obtain electrolyte, wherein the concentration of quaternary ammonium salt in the electrolyte is 1-5 g / L; then using a vanadium metal block as an anode, using a platinum metal block or a vanadium metal block as a cathode, keeping a distance between the anode and the cathode to be 2 mm to 5 cm, placing the anode and the cathode in the electrolyte, and electrolysing for 1 to 3 hours under a voltage of 2 to 30 V, so as to obtain a reaction solution containing precipitates; then performing a solid-liquid treatment and a washing treatment on the reaction solution, so as to obtain an intermediate product; and after that, annealing the intermediate product for 1 to 3 hours at a temperature of 350 to 450 DEG C and under a pressure of 10 to 100 Pa, so as to prepare the target product with a particle size of 50 to 100 nm. The preparation method has the characteristics of being time-saving, energy-saving, environment-friendly, low in preparation cost, and easy to realize large-scale industrialized production.
Owner:HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI

Preparation method and application of a shape-fixed phase change heat insulation and cooling pavement material suitable for high temperature areas

The invention discloses a preparation method and an application of a shape-stabilized phase change heat insulation and cooling pavement material applicable to high-temperature regions. The method comprises steps as follows: silica sol is prepared with tetraethoxysilane as a precursor with a sol-gel technology; a proper amount of expanded perlite is modified with an organic modifier, and modified perlite is obtained; molten calcium chloride hexahydrate is subjected to emulsification dispersion under the ultrasonic condition under the emulsification dispersion effect of laurinol, and a stable emulsion is formed; modified perlite is added to silica sol and dispersed uniformly, an obtained mixed solution is placed in a vacuum oven, proper amounts of stearic acid, cellulose diacetate and the obtained emulsion are added, the obtained mixture is vacuumized, left to stand at the room temperature for 30 min and reacts at 70-80 DEG C under the normal pressure for 5 h, drying is performed at the normal temperature, and the pavement material is obtained. The obtained material is stable in structure, has better heat storage, cooling and heat insulation performance and has wide phase change temperature range, and the asphalt pavement rut problem in the high-temperature regions can be effectively solved.
Owner:NANCHANG INST OF TECH
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