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Vanadium(IV) oxide or vanadium dioxide is an inorganic compound with the formula VO 2. It is a dark blue solid. Vanadium (IV) dioxide is amphoteric, dissolving in non-oxidising acids to give the blue vanadyl ion, [VO] 2+ and in alkali to give the brown [V 4 O 9] 2− ion, or at high pH [VO 4] 4−.