The invention discloses self-adsorption and self-exhaust silica gel, a self-adsorption and self-exhaust silica gel preparation method and a tempered glass protection film applying the self-adsorption and self-exhaust silica gel, and belongs to the field of polymer materials. The self-adsorption and self-exhaust silica gel comprises, by weight, 1,000-4,000 parts of methyl vinyl silicone rubber, 2,000-20,000 parts of methylbenzene, 50-300 parts of silicone resin, 8-20 parts of ethynyl cyclohexanol, 20-60 parts of vinyl silicone oil, 3-18 parts of organic silicone cross-linking agents and 5-20 parts of organic silicon catalysts. The tempered glass protection film is composed of tempered glass, an acrylic adhesive layer, a PET layer and a self-adsorption and self-exhaust silica gel layer from top to bottom, and the thickness of the tempered glass protection film is 390-650 microns. According to the tempered glass protection film applying the self-adsorption and self-exhaust silica gel, the problems that common silica gel is poor in exhaust and light transmittance, has bubbles and easily produces splay marks and other problems which are always difficult to solve in the industry are solved, and meanwhile the problems that the common silica gel will have snowflake lines, splay marks and streaks and other uneven problems during self adsorption and self exhaust can be solved.