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4739results about How to "No toxicity" patented technology

Super-hydrophilic and underwater-super-oleophobic oil-water separation mesh membrane, and preparation method and application thereof

The invention discloses a super-hydrophilic and underwater-super-oleophobic oil-water separation mesh membrane, and a preparation method and an application thereof. According to the method, fabric mesh with a specification of 100-300 meshes is subjected to ultrasonic cleaning, and is air-dried under normal temperature; a hydrophilic polymer water-sensitive agent and a cross-linking agent are dissolved in water according to a ratio of 1:9-9:1; the mixture is well mixed by magnetic stirring, such that a solution with a concentration of 1-99% is prepared; nano-sol is prepared with a sol-gel method; the solution and the nano-sol are prepared into a mixed solution with a concentration of 1-99%, and the solution is well dispersed through ultrasonic dispersion; the mesh is soaked in the mixed solution and is vertically lifted, or the mesh is directly sprayed by using a high-pressure spraying gun; and the mesh is bake-dried, such that the super-hydrophilic and underwater-super-oleophobic oil-water separation mesh membrane is obtained. Contact angles of the super-hydrophilic and underwater-super-oleophobic oil-water separation mesh membrane with water and oil in air are both 0 DEG, and the membrane is super-hydrophilic. Under water, the contact angle of the membrane with oil drops is larger than 150 DEG, and the membrane has an oil drop low adhesion characteristic. The mesh membrane provided by the invention can be used in oil-water mixture separation and oil-containing sewage processing.
Owner:SOUTH CHINA UNIV OF TECH

Oxidized graphene-modified super-hydrophilic super-oleophobic oil-water separation film and preparation method and application thereof

InactiveCN103623709AImproved swelling resistance and mechanical propertiesLow costSemi-permeable membranesFatty/oily/floating substances removal devicesCvd grapheneHydrophilic polymers
The invention discloses an oxidized graphene-modified super-hydrophilic super-oleophobic oil-water separation film and a preparation method and application thereof. The method comprises the following steps: mixing a hydrophilic polymer water-sensitive agent and a cross-linking film-forming agent according to a ratio of 1:9-9:1, dissolving the mixture and nano-silica sol in water according to a mass ratio of 1:9-9:1, magnetically stirring uniformly to prepare a 1-99% solution, adding 0.5-1 percent of oxidized graphen as an inorganic cross-linking agent, and ultrasonically and uniformly dispersing; ultrasonically cleaning a fabric silk screen with the particle size of 100-300 meshes, drying at normal temperature, forming a film on the silk screen in a spraying, dip-coating or spinning manner, drying and cross-linking, thus obtaining the hydrophilic and underwater super-oleophobic oil-water separation film. The oil-water separation film has excellent swelling resistance and mechanical property after graphene cross-linking modification, has a contact angle of 0 degree with both water and oil in air and has high super-hydrophilic property; the film has a contact angle of 150 degrees with oil drops under the water and has the low-adhesion characteristic to oil drops. The film can be applied to separation of oil-water mixtures and treatment of oil-containing sewage.
Owner:SOUTH CHINA UNIV OF TECH

Three-layer co-extruded EVA (ethylene-vinyl acetate copolymer) long-life fog-dissipation environment-friendly multifunctional greenhouse film

The invention discloses a nano fog-dissipation multifunctional greenhouse agricultural film, and in particular relates to a three-layer co-extruded EVA (ethylene-vinyl acetate copolymer) long-life fog-dissipation environment-friendly multifunctional greenhouse film, belonging to the field of agricultural mulching films. The raw material formula of an outer layer comprises the following components in percentage by weight: 20-50% of linear low-density polyethylene (LLDPE), 20-50% of low-density polyethylene (LDPE), 10-20% of metallocene polyethylene (mPE) and 5-10% of double-prevention masterbatch; the raw material formula of a middle layer comprises the following components in percentage by weight: 30-40% of ethylene-vinyl acetate copolymer (EVA), 20-40% of linear low-density polyethylene (LLDPE), 20-40% of low-density polyethylene (LDPE) and 5-10% of three-prevention masterbatch; the raw material formula of an inner layer comprises the following components in percentage by weight: 30-40% of ethylene-vinyl acetate copolymer (EVA), 10-20% of linear low-density polyethylene (LLDPE), 20-50% of low-density polyethylene (LDPE) and 5-10% of three-prevention masterbatch; and the formulas of the outer layer, the middle layer and the inner layer are uniformly mixed respectively, master batches are prepared by using a double-head thread screw double-screw extruding machine, a three-layer film is formed through a co-extrusion die head and is extruded out to prepare the multifunctional agricultural greenhouse film. Every quality technical index of the film reaches or exceeds a national standard, and a small part of the indexes is more than 2 times better than the national standard, so that the film is excellent in antiaging performance and cannot generate fog drops, and the service life of the film reaches more than 3 years.
Owner:HENAN YINFENG PLASTIC

Hydrophilic oleophobic polymer and preparation method thereof, and application thereof in humidity response oil and water separating membrane

The invention discloses a hydrophilic oleophobic polymer and preparation method thereof, and application thereof in humidity response oil and water separating membrane. The preparation of the hydrophilic oleophobic polymer comprises the following steps: carrying out an esterification reaction of polyvinyl alcohol and perfluorocarboxylic acid or firstly carrying out a carboxylation of polyvinyl alcohol and then a neutralization reaction of the intermediate product and perfluorotertiary amine. When the product is used, a fabric silk screen is cleaned with ultrasonic sound; 10-50 parts of hydrophilic oleophobic polymer, 50-500 parts of nanometer sol, 1-5 parts of cross-linking agents and 1-5 parts of catalysts are dispersed uniformly; the mixed liquor is dip-coated or spray-coated on the surface of the membrane, and after drying and crosslinking, the humidity response super-hydrophilic and super-oleophobic oil and water separating net membrane. According to the invention, hydrophilic groups are distributed surrounding the hydrophobic chain segment on the surface of the net membrane with humidity responsiveness, and contact angle in the air of the product to water is reduced to 0 degree from more than 90 degrees, and the contact angle in air and water of the product to oil is above 150 degrees, so the product has a low adherence characteristic of droplet. The net membrane is used for separating oil and water mixture and processing oil-containing sewage.
Owner:SOUTH CHINA UNIV OF TECH
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