2736results about "Flotation" patented technology

The invention is suitable for the technical field of quartz sand flotation, and particularly relates to a quartz sand flotation froth characteristic and dosage linkage control method which comprises the following steps: acquiring real-time process parameters and real-time image data; benchmark foam feature recognition is carried out based on the first image data, and the stable state and particle load characteristics of the foam under the current working condition can be accurately established; motion feature recognition is conducted on the second image data based on the reference foam features, and the dynamic evolution rule of the foam in the flotation tank can be captured in real time; real-time process parameters, moving foam characteristics and reference foam characteristics are combined to determine process adjustment parameters, and the residual state of chemicals in the system and the deviation condition of the flotation working condition can be quantitatively reflected; and the dosing control quantity is determined according to the process adjustment parameters, so that concentrate quality fluctuation and long-term potential quality hazards caused by excess or insufficiency are avoided, and the risk of secondary pollution is reduced.

The invention belongs to the technical field of quartz sand preparation, and provides a flotation synergistic process for high-purity quartz sand preparation, which comprises the following steps: crushing raw ore to obtain ore pulp, detecting the dispersity of the ore pulp after the concentration is adjusted, acquiring ore pulp state parameter data in real time in the detection process, and performing fluctuation analysis to obtain a flotation result; extracting ore pulp state parameters with fluctuation as pre-analysis risk parameters; and in combination with a historical detection database, identifying whether the pre-analysis risk parameter is associated with the occurrence of pseudo uniformity. A parameter association network is constructed based on Granger causality test, an adjustment sequence is determined by integrating an influence quantity coefficient and an intensity coefficient, influence paths and intensity among parameters are defined, adjustment blindness is reduced, quantitative sorting of optimization strategies is realized, parameters having significant influence on the system are preferentially processed, adjustment efficiency and pertinence are improved, and the method is suitable for large-scale popularization and application. The stability and the control precision of the detection system are guaranteed, the false uniformity risk is effectively reduced, and the accuracy of ore pulp dispersion uniformity detection is ensured.

The invention provides a composite reagent system and a chalcopyrite and sphalerite collecting method, and belongs to the technical field of mineral processing. The composite reagent system comprises a histidine derived functional group collecting agent and a black agent, and the histidine derived functional group collecting agent (containing a total sulfur ester group, a sulfydryl functional group and a side chain imidazole ring) serves as a core and is compounded with the black agent according to a specific proportion to form a target combination-synergistic interaction flotation mechanism. The histidine derivative collecting agent derives high-activity functional groups under the alkaline condition, and after sulfydryl is dissociated, stable chemical bonds are formed by the dissociated sulfydryl and metal ions on the surfaces of the chalcopyrite and the zinc sulfide. The black powder serves as an auxiliary collecting agent, and the collecting capacity of fine-grain or low-activity sulfide minerals is enhanced through chemical adsorption of dithiophosphate radicals and metal ions on the surfaces of the chalcopyrite and the sphalerite. After the two components are compounded, the selective enrichment efficiency of copper-zinc minerals in the flotation process is remarkably improved.

The invention belongs to the field of photovoltaic module recovery, and particularly relates to a method for recovering glass and silicon powder from a waste photovoltaic module. The method comprises the following steps: (S1) crushing the waste photovoltaic module, and mixing the obtained powder with water to form slurry; (S2) adjusting the pH value of the slurry to be alkaline to obtain alkaline slurry; (S3) the alkaline slurry is mixed with a collecting agent, an inhibitor and a foaming agent, then flotation separation is conducted, and coarse silicon powder and a glass foam layer are obtained; (S4) cleaning the coarse silicon powder to obtain a silicon powder product; and (S5) sequentially carrying out defoaming, solid-liquid separation and washing on the glass foam layer to obtain a glass product. By optimizing the slurry pH, flotation reagent combination, washing and other process conditions, the separation effect of the silicon powder and the glass powder is improved, the problem that separation is not thorough due to similar surface properties in a traditional physical separation method is solved, the reagent residual quantity on the surface of the silicon powder is reduced, and the subsequent purification cost is reduced.

The utility model belongs to the technical field of flotation machines, and particularly relates to a flotation machine scraper cleaning device which comprises a flotation machine main shell, first fixing rings are symmetrically arranged on one side of the upper side of the flotation machine main shell, a first shaft rod is rotationally arranged between the first fixing rings, and scraper mechanisms are arranged on the outer side of the first shaft rod at equal intervals. The scraping plate mechanism comprises a sleeve, connecting rods and scraping plates, the sleeve is fixedly connected to the outer side of the first shaft rod in a sleeving mode, the connecting rods are symmetrically arranged on the outer side of the sleeve in a surrounding mode, and the scraping plates are arranged at the ends, away from the sleeve, of the connecting rods. The bristles can brush the upper side face of the arc-shaped blanking plate and the upper side face of the scraping plate about to rotate away from the arc-shaped blanking plate, the scraping plate can be cleaned in time in the separation process, ore grain foam scraped by the scraping plate can be rapidly cleaned out of the arc-shaped blanking plate, the ore grain foam is prevented from rotating back to the surface of ore pulp along with the scraping plate, and the ore pulp quality is improved. Therefore, the effect of scraping ore grain foam next time is prevented from being affected, and the overall efficiency of ore grain separation is guaranteed.

The invention relates to a waste photovoltaic panel recycling method which comprises the following steps: crushing a waste photovoltaic panel until the size of the waste photovoltaic panel is 80-160 meshes, and preparing powder; carrying out acid leaching treatment on the powder, and respectively collecting a leaching solution and a solid material; an acid leaching solution adopted in the acid leaching treatment is a mixed acid aqueous solution of hydrochloric acid and sulfuric acid; the pH of the leachate is adjusted to be neutral with an alkaline agent, then the leachate is mixed with metal iron to be subjected to a replacement reaction, and metal copper is prepared; the solid material is mixed with water, hydrofluoric acid and a flotation agent are added into the obtained mixture for flotation treatment, floats and precipitates are collected respectively, the floats comprise silicon powder, the precipitates comprise glass powder, and the flotation agent comprises one or two of hexadecyl potassium hydrogen phosphate and sodium dodecyl sulfate. According to the recycling method, the silicon powder, the glass powder and the metal copper can be comprehensively recycled from the waste photovoltaic panel.

The invention discloses a semi-supervised flotation working condition recognition method based on spatial-temporal feature fusion, and belongs to the field of industrial process monitoring. The method comprises the steps that flotation froth videos are collected and preprocessed to obtain a data set of a preset proportion; constructing a student model fused with spatial-temporal characteristics to predict each working condition category; a teacher model is constructed, and index moving average of student model parameters is used for updating so as to maintain stability and guide learning of the student model; and calculating supervision loss based on the labeled training set, calculating consistency loss based on the unlabeled training set, and performing semi-supervised training on the model by minimizing the total loss. According to the method, a spatial-temporal characteristic representation model is embedded into a semi-supervised learning framework, foam state evolution characteristics are fully represented, and high-precision working condition recognition is realized by using limited labeled samples; through the spatio-temporal feature fusion method of the cross additive attention mechanism, mutual enhancement of spatio-temporal features is realized, the time complexity is reduced, and the calculation efficiency is improved.

The invention provides a dosage prediction method and system based on multi-mode flotation froth digital characterization, and relates to the technical field of froth flotation. The method comprises the following steps: collecting multi-modal data of a foam state in a metal ore flotation process, wherein the multi-modal data comprises an RGB image, a video sequence and a three-dimensional point cloud; constructing three foam feature extraction networks, and respectively extracting RGB features, video dynamic features and three-dimensional point cloud features of the multi-modal data; fusing the extracted RGB features, the video dynamic features and the three-dimensional point cloud features based on a cross-modal attention mechanism to generate multi-modal features; constructing an expert knowledge base, wherein the expert knowledge base comprises structured rules and historical cases; and constructing a dosage decision model based on an expert knowledge base and a large language model, converting the multi-modal features into standardized vector representation, retrieving the expert knowledge base by utilizing similarity matching, and generating a dosage adjustment strategy. According to the invention, accurate prediction from foam multi-mode characteristics to dosage adjustment can be realized.

The invention discloses a method for comprehensively recovering lithium beryllium resources in spodumene tailings, and belongs to the technical field of mineral separation. The method comprises the steps that after spodumene tailings are subjected to size mixing, amine and fatty acid serve as a combined collecting agent, flotation I is conducted, and mica concentrate and tailings I are obtained; after size mixing is conducted on the tailings I, sodium sulfide and phosphate serve as a combined inhibitor, a metal-hydroximic acid organic complex and fatty acid serve as a combined collecting agent, flotation II is conducted, and lithium beryllium bulk concentrate and tailings II are obtained; and after size mixing is conducted on the lithium beryllium bulk concentrate, flotation III is conducted with phosphate and EDTA as a combined inhibitor and fatty acid as a collecting agent, and beryllium concentrate and lithium-containing tailings are obtained. By means of the method, the beryllium concentrate with the BeO grade being 4.448% and the recovery rate being 64% can be obtained, meanwhile, the lithium concentrate with the Li2O grade being 4.8% and the recovery rate being 57.6% can be produced, deep comprehensive recovery of the lithium beryllium resources in the spodumene tailings is effectively achieved, and the economic benefit capacity is large.

The utility model discloses an SF type flotation machine for phosphoric acid beneficiation. The SF type flotation machine comprises a groove body, a power system, a center cylinder, a stirring system and a scraper system. The air distributor is arranged to uniformly distribute the sucked air, so that a large amount of fine bubbles can be formed, and the generation of the bubbles is further facilitated; the slurry on the dispersing cover can be sucked into an upper impeller cavity through the through holes, so that slurry upper circulation is formed; the backward-inclined lower blade and the backward-inclined upper blade are arranged, so that slurry in the tank is subjected to upper and lower double circulation, and the suspension of coarse-grain minerals is facilitated; a large gap between the impeller and the dispersion cover is arranged, and the air suction amount is large. The ore pulp and air are self-sucked, the air suction amount is large, the number of auxiliary devices is small, and operation and maintenance are easy.

The invention discloses a composite collecting agent and a preparation method and application thereof, and relates to the technical field of solid waste recycling. The composite collecting agent comprises a main agent, an auxiliary agent and a synergist, and the mass ratio of the main agent to the auxiliary agent is (3-1): (1-2). The mass of the synergist is 0.1%-2.5% of the total mass of the composite collecting agent; the structural formula of the main agent is as shown in formula (I): R-O-C (= S)-NH-R '(I); in the formula (I), R is alkyl, and R'is 3-chloro-1, 2-epoxypropane; the auxiliary agent is a mercaptobenzothiazole derivative. The thiocarbamate and the mercaptobenzothiazole derivative are compounded according to a specific proportion for the first time, a Zn-S shielding layer is destroyed through an intermolecular synergistic effect, and the silver recovery rate is increased; the preparation method is simple and easy to operate, facilitates reduction of the dosage of a single agent and reduces environmental pollution. The foam stability is improved, the flotation efficiency is improved, the selective collection efficiency of the silver-zinc ore is remarkably improved, and the flotation index is improved.

The invention relates to the technical field of mineralogy, and provides a prediction method for mineral flotation yield. According to the method, the content and dissociation degree of the target minerals under different size fractions are accurately obtained through the technologies of ore grinding, system screening and automatic mineralogy analysis, the yield prediction method based on the mineral selectability physical model is established, the crossing from elements to minerals and from the whole to the size fractions can be achieved, and the yield prediction accuracy is improved. And a brand-new, scientific and reliable technical reference is provided for precise prediction and process optimization of the sulfide ore flotation yield.

The invention relates to the technical field of fluorite ore beneficiation, discloses a fluorite ore flotation composite collecting agent and a preparation method and application thereof, and aims to solve the problems that an existing collecting agent is limited in applicability, insufficient in selectivity, poor in environmental stability and the like and is difficult to deal with separation of fluorite ore containing various impurities or under complex working conditions. The composite collecting agent is composed of dehydroabietylamine, sodium oleoyl sarcosinate, sodium silicate-citric acid composite salt, ethylene glycol butyl ether and a sodium carbonate-sodium bicarbonate buffer pair, all the components have a synergistic effect, dehydroabietylamine provides selective collecting and fine particle agglomeration functions, sodium oleoyl sarcosinate enhances adsorption stability, the composite salt inhibits gangue in a targeted mode, and therefore the adsorption efficiency is improved. Buffer pairs and ethylene glycol butyl ether guarantee the environmental adaptability of a system. The collecting agent can adapt to various fluorite ores with high sulfur, high silicon, low temperature and the like, can stably play a role under different water quality and working conditions, realizes efficient separation of fluorite and impurities, improves the separation efficiency and the concentrate quality, and is flexible in preparation process and convenient for industrial application.

The invention discloses a normal-temperature efficient recovery method for low-grade tungsten in gold, antimony and tungsten multi-metal symbiotic ore. The method comprises the steps that raw ore is ground and then subjected to shaking table reselection, reselected concentrate, reselected middling and reselected tailings are obtained, foam flotation is conducted on the reselected middling, sulfide ore is floated out, coarse-grain tungsten minerals are recycled through reselection of the flotation tailings, ore grinding is conducted on the reselected tailings, gold and antimony bulk flotation is conducted, then scheelite flotation and tungsten concentrate flotation are conducted under the action of a combined collecting agent, and finally tungsten concentrate is obtained. According to the method, aiming at the characteristic that the granularity of the tungsten mineral in the gold-antimony-tungsten symbiotic ore is uneven in thickness distribution, a proper ore grinding separation process and proper ore grinding fineness are selected, the tungsten mineral is prevented from being over-crushed, and underground wastewater is reasonably utilized, so that the use amount of clear water is effectively reduced, and meanwhile, the underground wastewater is recycled; furthermore, an ore pulp heating process is omitted in the tungsten ore concentration stage, the fuel cost is greatly reduced, and therefore the production cost is greatly reduced on the premise that the tungsten concentrate recovery rate is guaranteed.

The invention belongs to the technical field of mineral flotation, and particularly discloses a method for recovering whole-fraction iron lepidolite through combination of multi-stage magnetic separation and synergistic flotation. Comprising a matched compound collecting agent which is composed of sodium dodecenesulfonate, amino acid methyl thiohydracrylate, an amphoteric polyacrylamide polymer, carboxyethylidene diphosphonic acid and polyethylene glycol, and efficient recovery of whole-size-fraction iron lepidolite is achieved by matching with a corresponding magnetic separation-flotation combined process. The compound collecting agent generates static electricity and physical and chemical adsorption on the iron lepidolite through specific groups such as sulfonic acid groups, carboxyl groups, amino groups, acylamino groups and phosphate groups, exerts excellent selectivity and collecting functions, generates a dispersion effect and a chelating flocculation effect on micro-fine-particle iron lepidolite, and well cooperates with multi-stage magnetic separation to recover whole-particle-size iron lepidolite, so that the recovery rate of the whole-particle-size iron lepidolite is increased, and the recovery rate of the whole-particle-size iron lepidolite is increased. And the existing combined beneficiation process of the iron lepidolite is optimized, the cost and the environmental influence are reduced, and technical support is provided for sustainable development of lithium resources.

The invention provides a poly-like flocculation flotation method for micro-fine particle galena and micro-fine particle sphalerite. The method comprises the following steps: firstly, mixing to-be-treated ore samples containing micro-fine particle galena and micro-fine particle sphalerite with the particle sizes of less than or equal to 20 microns with water to obtain to-be-treated ore pulp, then sequentially adding zinc sulfate, diethyldithiocarbamate, polyoxyethylene, polyaluminum chloride and a foaming agent, and carrying out air inflation flotation and foam scraping to obtain galena concentrate and tailings. ZnSO4 is adsorbed on the surface of the micro-fine-particle sphalerite in advance and generates a synergistic effect with polyaluminum chloride added subsequently, and N, N '-diethyldithiocarbamate is adsorbed on the surface of the micro-fine-particle galena in advance and generates a synergistic effect with polyoxyethylene added subsequently, so that galena hydrophobic floccules and sphalerite hydrophilic floccules with proper apparent particle sizes are formed; on one hand, the flotation recovery rate of the micro-fine particle galena can be increased, and on the other hand, mechanical entrainment of the micro-fine particle sphalerite can be reduced, so that the flotation separation efficiency of the micro-fine particle lead zinc ore can be effectively improved.

The invention discloses a combined inhibitor for high-mud-content scheelite flotation and application, belongs to the technical field of scheelite flotation, and aims to solve the technical problems that in the high-mud-content scheelite flotation process, argillaceous particle adsorption agents and gangue inhibition are not thorough, and an existing inhibitor is poor in selectivity, large in dosage and the like. The combined inhibitor comprises tannic acid / sodium humate and metal ions and is matched with the pH regulator to form a flotation reagent system, the collecting agent is prepared by compounding sodium oleate, oxidized paraffin soap and sodium dodecyl benzene sulfonate according to the mass ratio of 3: 1: 1, and the foaming agent is MIBC or terpenic oil. Through the synergistic effect of tannic acid / sodium humate-metal ions, mud dispersion and inhibition of fluorite and calcite can be synchronously achieved, and flotation of scheelite with the high mud content is enhanced; through one-stage roughing, three-stage scavenging and three-stage heating concentration, the grade and the recovery rate of WO in scheelite concentrate are improved, and the method is low in reagent dosage, environmentally friendly and suitable for industrial production.

The invention provides a low-molecular soluble chelating collector as well as a preparation method and application thereof, and belongs to the technical field of mineral processing. According to the collecting agent, low-molecular-weight ethylene glycol terephthalate serves as a precursor, and isosorbide is introduced for a copolymerization reaction; glutamic acid is introduced as a branched chain unit, and the branching degree and reaction active site density of the molecular structure are remarkably improved by utilizing the polyfunctional group characteristic of glutamic acid. A rigid ring structure and an ether bond of the isosorbide endow the medicament with good water solubility and dispersity, and invalid curling of a macromolecular chain is avoided; the introduction of glutamic acid branched chains greatly increases the number of hydroxyl groups and amino groups capable of reacting with carbon disulfide, so that each molecule carries more xanthate groups, and the adsorption stability and coverage density of the molecule on the surface of arsenopyrite are enhanced. By means of the structure, xanthate functional groups are fully exposed, multi-tooth chelation is easily conducted on the xanthate functional groups and iron and arsenic ions on the surface of arsenopyrite, a strong hydrophobic surface layer is formed, and therefore the collecting selectivity is remarkably improved.

The invention relates to the technical field of mineral processing, and particularly provides a combined reagent system for flotation and magnesium reduction of talc-containing copper-molybdenum ore and application of the combined reagent system. The combined reagent system comprises a flotation collecting agent (faint yellow to orange transparent liquid, 40%-50% of active ingredients and less than or equal to 3% of free alkali) with active ingredients in the formula 1 and a flotation depressing agent (light yellow powder, extracellular polysaccharide extract of xanthomonas, the weight-average molecular weight of 1000-1500000 Daltons and rich in hydroxyl, carboxyl and pyruvic acid groups) with a structural formula in the formula 2, and the flotation depressing agent comprises extracellular polysaccharide extract of xanthomonas, the weight-average molecular weight of xanthomonas and the weight-average molecular weight of xanthomonas and is rich in hydroxyl, carboxyl and pyruvic acid groups. Through the synergistic adsorption effect of the combined reagent, the flotation grade and the recovery rate of the copper sulfide molybdenum ore are remarkably improved under the condition that the pH is 8-11. The combined reagent system has the advantages of being high in flotation efficiency, high in selectivity, low in reagent cost, environmentally friendly, high in industrial applicability and the like.

The invention provides a collecting agent for micro-fine particle quartz ore and a preparation method and application of the collecting agent, and relates to the technical field of mineral flotation. Specifically, the preparation method of the collecting agent comprises the steps that a mixture containing the graphene and the sodium oleate is subjected to cold plasma treatment, and the graphene and the sodium oleate are grafted to obtain the collecting agent. The collecting agent can be used for mineral flotation, and high-purity quartz can be efficiently obtained; on the basis of the net capturing performance of graphene and functional groups corresponding to grafted sodium oleate, the flocculation effect on micro-fine quartz is achieved, so that the quartz is efficiently captured, the problem that the fine quartz is free in ore pulp due to large free energy in the flotation process and is difficult to capture and float is solved, the flotation separation efficiency is improved, the separation index is improved, and the flotation cost is reduced. Good application prospects are realized.

A beneficiation method for improving a grade of a magnesium-containing copper sulfide ore concentrate includes: crushing and grinding an ore to a fineness degree allowing 55% to 65% of particles to pass through a 0.074 mm sieve, adding an adjusting agent lime, collecting agents butylxanthate and kerosene, and a foaming agent methyl isobutyl carbinol (MIBC) to obtain a copper-molybdenum-sulfur mixed concentrate; re-grinding the copper-molybdenum-sulfur mixed concentrate to a fineness degree allowing 75% to 82% of particles to pass through a 0.048 mm sieve, adding lime, a magnesium-containing silicate inhibitor, a collecting agent 1, and MIBC to obtain a copper-molybdenum mixed concentrate; and adding sodium sulfide, kerosene, and MIBC to the copper-molybdenum mixed concentrate to obtain a high-grade copper concentrate. The beneficiation method adopts mixed flotation of copper-molybdenum, regrinding for separating copper and molybdenum from sulfur, and magnesium removal from a copper concentrate to allow quality improvement for the copper concentrate.

The invention discloses a method for recovering molybdenum from tungsten smelting soda boiling slag through flotation, and relates to the technical field of comprehensive utilization of tungsten smelting resources. Step 2, grading and desliming; step 3, elutriation and reagent removal; 4, potential regulation and control; and fifthly, flotation enrichment is conducted. According to the method, a pre-treatment scheme of ore grinding scrubbing and desliming elutriation is innovatively adopted, a Ca (OH) 2 passivation layer and CaCO3 colloidal precipitate adsorbed on the surface of the ore are removed, fine silt of-15 microns is removed, the inevitable ion cover effect is eliminated, and the pH value of a flotation system is reduced; through an innovative reagent combination and a progressively-decreased reagent system, the overall grade of the concentrate is remarkably improved, and the recovery rate of molybdenum is greatly increased; according to the method, a large amount of acid-base reagents are not introduced, acid-base wastewater is not generated, the process is simple, large-scale treatment can be achieved, closed-loop circulation of mineral separation water can be achieved, wastewater discharge is avoided, the process is environmentally friendly and free of pollution risks, tailings can be directly discharged after soda boiling residues are subjected to harmless treatment, and the environment-friendly treatment cost is low.

The invention discloses a beneficiation method for concentrate regrinding reinforced copper-molybdenum mixed rough concentrate magnetic levitation combined separation. The method comprises the following steps: (1) carrying out two-stage magnetic separation on the copper-molybdenum bulk concentrate to obtain a magnetic product and a non-magnetic product; (2) the magnetic products and the non-magnetic products are subjected to particle size control regrinding treatment, so that the copper minerals and the molybdenum minerals are further subjected to monomer dissociation, and agglomeration structures among the minerals are scattered; (3) preferential molybdenum flotation and copper flotation operation is conducted on reground ore pulp of magnetic separation magnetic products, after magnetic separation non-magnetic products are combined, the reground ore pulp is directly subjected to molybdenum flotation operation, an inhibitor, a collecting agent and a foaming agent are added in a segmented mode in the molybdenum flotation operation, and an adjusting agent, a dispersing agent, an activating agent, a collecting agent and a foaming agent are added in a segmented mode in the copper flotation operation; the concentrates obtained through the flotation operation are copper concentrates and molybdenum concentrates. The method improves the grade of the molybdenum concentrate, reduces the copper inclusion amount, stabilizes the product quality, and improves the copper-molybdenum separation efficiency and the recovery rate of copper and molybdenum.

The invention belongs to the technical field of mineral flotation, and particularly relates to a nanocellulose-based coal slime collecting agent and a preparation method and application thereof. Wet-grinding the dried absorbent cotton, drying again, acidizing, filtering, washing and centrifugally drying to obtain precursor cellulose; dissolving the precursor cellulose in deionized water, adjusting the pH value to 10, adding an ethanol solution of alkyltriethoxysilane, heating, stirring for reaction, naturally cooling, centrifuging, washing and drying to obtain hydrophobic nano cellulose; and the hydrophobic nanocellulose and the non-polar hydrocarbon oil are evenly mixed, and the coal slime collecting agent is obtained. The prepared coal slime collecting agent contains the hydrophobic nanocellulose which is high in softness and has a net-shaped structure, in the flotation process, adhesion of bubbles and minerals can be promoted, diffusion of the bubbles is promoted, and the flotation efficiency and the recovery rate are improved.

The invention provides a beneficiation method of low-grade superfine silt containing lithium, rubidium and cesium, which comprises the following steps: adding sodium hexametaphosphate and a collecting agent JXL-01 into ore pulp, stirring, and roughing to obtain lepidolite rough concentrate and flotation tailings I; a collecting agent JXL-01 is added into the flotation tailings I for two times of scavenging, the flotation tailings and two scavenging middlings are obtained, and the scavenging middlings are sequentially returned to the upper layer for operation; sodium hexametaphosphate is added into the lepidolite rough concentrate for two times of concentration, lepidolite concentrate and two concentrated middlings are obtained, and the two concentrated middlings are sequentially returned to the upper layer for operation. And the collecting agent JXL-01 is obtained by mixing dodecylamine and sodium alpha-olefin sulfonate according to the mass ratio of 3: 2. According to the method, comprehensive utilization of the lithium-rubidium-cesium-containing superfine silt is achieved, the recovery effect of the lithium-rubidium-cesium-containing superfine silt is effectively improved, and the method is a novel mineral separation method which is stable, efficient, high in adaptability and high in recovery index and is suitable for application and popularization.

The invention provides a high-selectivity flotation method for micro-fine particle lepidolite containing rubidium and cesium, which comprises the following steps: levigating raw lepidolite ore, and desliming to obtain a flotation material and slime; adding sodium hexametaphosphate and a collecting agent HT8-01 into the flotation material, stirring, and roughing to obtain lepidolite rough concentrate and flotation tailings I; a collecting agent HT8-01 is added into the flotation tailings I for two times of scavenging, flotation tailings and two scavenging middlings are obtained, and the scavenging middlings are sequentially returned to the upper layer for operation; sodium hexametaphosphate is added into the lepidolite rough concentrate for two times of concentration, lepidolite concentrate and two concentrated middlings are obtained, and the concentrated middlings are sequentially returned to the upper layer for operation; the collecting agent HT8-01 is obtained by mixing octadecylamine and sodium dioctyl sulfosuccinate according to the mass ratio of 5: 3. According to the method, the separation effect of the rubidium-cesium-lithium-containing mica and gangue minerals such as quartz and feldspar is improved, the problems that foam is too stable, the viscosity is too high and the size is too large are solved, and high-selectivity separation of the micro-fine-particle rubidium-cesium-lithium-containing mica is achieved.

The invention discloses a flotation machine, particularly relates to the technical field of flotation machines, and comprises a flotation bin, a flotation mechanism, an adjusting assembly and a detection assembly. Through the arrangement of the detection assembly and the adjusting assembly, the flotation mechanism can dynamically adjust the bubble generation size according to the ore pulp concentration, the differential requirements of different ore pulp viscosities for bubble separation can be met, full coverage of the particle size of slag is automatically achieved, and on one hand, the number of generated small bubbles can be reduced when the ore pulp concentration is high; on the other hand, when the ore pulp concentration is low, the number of generated small bubbles can be increased, the number of generated large bubbles can be reduced, inflation waste is avoided, inflation energy consumption is reduced, excessive adsorption of impurities is avoided, and the concentrate purity is remarkably improved; and meanwhile, manual intervention is replaced by full-mechanical electric closed-loop control, the operation process is simplified, and the method can adapt to ore pulp fluctuation scenes.

The invention relates to the technical field of ore flotation, and discloses a preparation process of a foaming agent. The foaming agent is obtained by mixing fluorine-containing pyridine modified carboxyl betaine, sulfonic group modified polyoxyethylene ether and methyl isobutyl carbinol. Fluorine atoms can enhance the stability of the foaming agent and improve the flotation effect; sulfur atoms and metal ions form a stable chelate, and mineral separation and purification are achieved; pyridyl can generate electrostatic attraction with the surface of the mineral to form a hydrophobic membrane, so that the adhesive force of bubbles and the mineral is improved, and the flotation effect is enhanced; polar groups in the carboxyl betaine are adsorbed on the surfaces of the minerals, and non-polar groups face outwards, so that the surfaces of the minerals are hydrophobic, and a flotation effect is achieved; sulfonic groups can be adsorbed on the surfaces of minerals, so that the original hydrophilic surfaces of the minerals are changed into hydrophobic surfaces, and the floatability of the minerals is improved; the polyoxyethylene ether has good dispersing performance, so that the foaming agent is more uniformly distributed in ore pulp, and minerals can be better captured by bubbles and float upwards.

The invention belongs to the technical field of mineral flotation separation, and particularly relates to a complexing inhibitor and application thereof in mineral flotation separation of smithsonite and calcium-containing gangue. The complexing inhibitor provided by the invention is prepared by complexing a flavonoid organic compound and aluminum ions, is used for flotation separation of smithsonite and calcium-containing gangue minerals, can be selectively adsorbed on the surface of the calcium-containing gangue, effectively inhibits the floatability of the calcium-containing gangue, and has the advantages that compared with a traditional agent, the complexing inhibitor is simple in preparation method and low in cost; the method has the advantages of being high in separation efficiency, small in reagent dosage, environmentally friendly and the like, the grade and the recovery rate of smithsonite can be remarkably improved, and the method has important significance on efficient recycling of zinc oxide resources.

The invention discloses a beneficiation method for tin-silver symbiotic polymetallic ore and application of the beneficiation method, and relates to the technical field of mineral separation. Comprising the steps that after tin-silver symbiotic polymetallic ore is ground, undersize minerals are obtained through a high-frequency screen, silver-copper flotation is conducted on the undersize minerals, and silver-copper concentrate and silver-copper tailings are obtained; the silver-copper tailings are subjected to lead-zinc-sulfur flotation, and lead concentrate and zinc-sulfur tailings are obtained; and the zinc-sulfur tailings are subjected to zinc-sulfur flotation, and zinc-sulfur concentrate and tin-sulfur tailings are obtained. The concentration of ore pulp in the ore grinding process is controlled, it is guaranteed that cassiterite and sulfide minerals are fully dissociated, then a first inhibitor is added in the lead-zinc-sulfur flotation process, the valuable metal recovery efficiency can be enhanced by optimizing the flotation process and collaboratively innovating a reagent formula according to the complex characteristics of tin-silver symbiotic polymetallic ore, and the recovery rate of the tin-silver symbiotic polymetallic ore is increased. The contents of silver, copper and tin in the tailings are obviously reduced, and efficient utilization of resources and reduction of solid wastes are realized.