3814 results about "Ore concentrate" patented technology

The invention belongs to the technical field of ironmaking, and particularly discloses a method for producing titanium-rich direct reduction iron and high-titanium slag by using vanadium titano-magnetite, which comprises the following steps: preparing vanadium titano-magnetite raw ore into vanadium-titanium-iron concentrate powder and titanium concentrate powder, mixing the vanadium-titanium-iron concentrate powder and the titanium concentrate powder with a binder to prepare iron-titanium concentrate composite green pellets, and oxidizing and roasting to obtain the titanium-rich direct reduction iron and high-titanium slag with the compressive strength of more than 2000N / pellet and the compressive strength of more than 2000N / pellet. The reduction expansion rate of the iron-titanium concentrate composite high-titanium pellets is smaller than 20%; the iron-titanium concentrate composite high-titanium pellets are subjected to a direct reduction reaction in a shaft furnace, and titanium-rich direct reduced iron with the metallization ratio larger than or equal to 85% is obtained; and molten iron and high-titanium slag are obtained after the obtained titanium-rich direct reduced iron is subjected to melting separation through a melting separation electric furnace. According to the method, the iron-titanium concentrate composite high-titanium pellets meeting the direct reduction smelting requirement of the gas-based shaft furnace are prepared and applied to the gas-based shaft furnace for direct reduction production of the titanium-rich direct reduction iron, high-quality titanium-rich raw materials can be provided for smelting titanium slag in a melting electric furnace, and the problem that the recovery rate of titanium resources in existing vanadium titano-magnetite is low is effectively solved.

The invention discloses an improved efficient turbulent flow microbubble flotation device for feeding and discharging materials. Comprising an outer cylinder, an inner cylinder arranged in the outer cylinder, a stirring mechanism arranged in the outer cylinder, a feeding mechanism used for conveying raw materials into the inner cylinder, a concentrate tank located on the upper portion of the outer cylinder, a countercurrent mineralization mechanism arranged in the inner cylinder and a tailing separation mechanism connected to the bottom of the inner cylinder. Through cooperation of the sawtooth disc self-suction dispersion impeller and the false bottom structure, local area circulation can be formed, the elution effect on the surfaces of coarse particles can be enhanced, meanwhile, dispersion of heterogeneous fine silt is facilitated, and the purity of tailings is further ensured; according to the method, the flotation efficiency can be improved, and the energy consumption is greatly reduced; due to the design of the sawtooth disc self-suction dispersion impeller, gas is allowed to enter in a self-suction mode, and energy consumption of traditional air compression equipment is avoided. According to the sawtooth disc self-suction dispersion impeller, suction force brought by the vacuum effect generated by rotation of the impeller can be improved, and suction of more air is promoted.

The invention discloses a method for synchronously improving the recovery rate of copper and cobalt in high-oxidation-rate copper-cobalt ore and low-grade copper oxide-cobalt concentrate, which comprises the following steps: (1) carrying out copper sulfide flotation on the high-oxidation-rate copper-cobalt ore to obtain high-copper tailings; (2) the low-grade copper-cobalt concentrate and the high-copper tailings are mixed according to the mass ratio of 1: (1-2), and mixed ore is obtained; (3) the obtained mixed ore and a sulfuric acid solution system leaching agent are stirred and mixed, and slurry is obtained; (4) leaching the obtained slurry at normal temperature, and carrying out solid-liquid separation to obtain leached residues and leached liquid; (5) carrying out washing, extraction, reverse extraction and electrodeposition on the obtained leaching residues to obtain metal copper; and removing iron from the raffinate, and adding magnesium oxide into the iron-removed liquid for precipitation to obtain crude cobalt hydroxide. According to the method, the high-copper tailings and the low-grade copper oxide cobalt concentrate are subjected to the processes of ore blending, size mixing, normal-temperature sulfuric acid leaching and the like, the final copper leaching rate is 95% or above, and the cobalt leaching rate is 70% or above.

The invention discloses a rapid method for determining the grade of target elements in concentrate based on mineral dissociation degree, and the grade of the target elements in the concentrate under a certain fineness condition is calculated according to the dissociation degree of target minerals in a raw ore sample under the certain fineness condition and the content of the target elements in the target minerals in the raw ore sample. By means of the method, the grade of the target element in the concentrate under the specified fineness condition can be calculated more quickly and more effectively, the beneficiation effect under the fineness condition can be predicted in advance when beneficiation operation is not conducted, and powerful data support is provided for formulation of the beneficiation technological process.

The invention discloses a method for recovering iron and titanium in vanadium titano-magnetite, and relates to the technical field of vanadium titano-magnetite beneficiation. Raw ore is crushed, and then is subjected to roller milling and screening to obtain oversize and undersize products; undersize products are subjected to weak magnetic pre-selection, tailings obtained after weak magnetic pre-selection and strong magnetic pre-selection are subjected to strong magnetic pre-selection, concentrate obtained after weak magnetic pre-selection and strong magnetic pre-selection are sequentially subjected to first-stage grinding, first-stage weak magnetic separation, second-stage grinding, second-stage weak magnetic separation and second-stage weak magnetic concentration, final iron ore concentrate is obtained, the obtained tailings are combined into iron separation tailings, then the iron separation tailings are subjected to titanium separation grinding, medium magnetic iron removal and strong magnetic roughing, and iron separation tailings are obtained. And tailings obtained after strong magnetic roughing are subjected to strong magnetic scavenging, concentrates obtained after strong magnetic roughing and strong magnetic scavenging are subjected to gravity roughing and gravity concentration, and final titanium concentrates are obtained. By adopting conventional crushing, high-pressure roller grinding, magnetic separation, pre-selection and tailing discarding, the subsequent ore grinding and selecting cost can be effectively reduced, the iron and titanium grades of the ore entering the grinding process are improved, high efficiency and energy conservation are achieved, and the ore dressing efficiency is improved.

The invention provides a treatment method of copper-nickel concentrate rich in platinum group metals, which comprises the following steps: feeding the copper-nickel concentrate rich in platinum group metals and a first flux into a smelting furnace, and introducing first oxygen-enriched gas for smelting; copper matte and a second flux are continuously fed into a first converting furnace, and second oxygen-enriched gas is continuously introduced for first converting; raw copper and a third flux are fed into the oxygen inclined blowing rotary converter, and oxygen is introduced for second blowing; the crude copper is fed into an anode refining furnace, and air and a first reducing agent are introduced for fire refining; casting the copper liquid into an anode plate, and carrying out electrolytic refining on the anode plate; feeding the first converting slag, the second converting slag, a second reducing agent and a vulcanizing agent into a dilution electric furnace for slag dilution to obtain low-nickel matte and dilution slag; and the low-nickel matte is fed into a third converting furnace, air or oxygen-enriched air is introduced for third converting, and the problem that the recovery rate of nickel metal elements and platinum group metals in the copper-nickel concentrate rich in the platinum group metals is low is solved.

The invention discloses a method for separating niobium from niobium-containing ore, which comprises the following steps: mixing niobium rough concentrate with a vulcanizing agent to obtain a mixture, carrying out reduction smelting on the mixture to obtain reduced ore, and directly obtaining a niobium-rich product from the reduced ore, or carrying out post-treatment on the reduced ore to obtain the niobium-rich product. Compared with a traditional reduction smelting process, the method for separating the niobium from the niobium-containing ore has the advantages that separation of the slag and the iron is achieved, separation of the niobium and the slag can be achieved, the niobium is enriched, a high-grade niobium-rich product is obtained, purification can be carried out through a further metallurgy process, the process method is high in operability, and the method is suitable for industrial production. And the process is simple, has low requirements on bearing smelting equipment and is easy to industrially popularize and apply.

The invention discloses a method for low-carbon preparation of a high-reactivity blast furnace burden from magnetite concentrate and the blast furnace burden, and belongs to the technical field of ferrous metallurgy. According to the method, an iron-containing raw material, an organic-inorganic composite binder, a multifunctional additive and water are sequentially subjected to uniform mixing, high-pressure double-roller forming and consolidation, and the finished product cold pressing block is obtained. According to the method, the strength and reducibility of the cold pressing block can be remarkably improved by optimizing the particle size composition of the raw materials and adding the multifunctional additive, the technological process is simple, a high-temperature process is not needed, and carbon emission is low.

The invention relates to a flotation method for niobium-containing minerals, and belongs to the technical field of mineral separation. The method comprises the steps that niobium-containing ore is subjected to crushing, ore grinding and size mixing, obtained ore pulp is subjected to weak magnetic treatment to remove strong magnetic minerals, after the pH of magnetic separation tailings is adjusted, a flotation reagent containing an iron mineral inhibitor and an amine collecting agent is added for silicon-niobium bulk flotation, and after the pH of obtained silicon-niobium bulk concentrate is adjusted, the obtained silicon-niobium bulk concentrate is subjected to flotation separation. And a flotation reagent containing a hydroximic acid metal organic complex collecting agent and a siliceous mineral inhibitor is added for silicon-niobium separation flotation, and niobium concentrate is obtained. According to the method, iron gangue mineral removal is achieved through step-by-step flotation by means of the amine collecting agent, silicon separation is achieved by means of the hydroximic acid metal organic complex collecting agent, efficient enrichment of the niobium mineral is achieved, the step of strong magnetic iron removal is avoided, the process is simplified, and the loss rate of the niobium mineral is reduced.

The invention provides a treatment method for low-grade multi-metal gold concentrate, and relates to the technical field of comprehensive utilization of minerals. According to the treatment method of the low-grade multi-metal gold concentrate, most of iron and copper form iron-copper matte through pyrogenic smelting, meanwhile, gold is captured into the iron-copper matte, then iron-copper matte powder is obtained after water quenching and ball milling, the iron-copper matte powder is subjected to oxidation ammonia leaching, copper in the iron-copper matte is extracted, and the iron-copper matte powder is subjected to oxidation ammonia leaching to obtain the low-grade multi-metal gold concentrate. The obtained copper-containing ammonia leaching liquid is subjected to a traditional extraction-reverse extraction-electrodeposition process to obtain an electrodeposited copper product, ammonia leaching residues obtained after copper extraction are subjected to cyanidation leaching, gold in the ammonia leaching residues is extracted, cyanidation liquid is subjected to a traditional gold extraction process to obtain a gold product, the cyanidation tailings mainly comprise iron sulfide, the content of iron and sulfur in the tailings is high, and the content of sulfur in the tailings is high. And the subsequent cinder can be directly sold as an iron-making raw material. The amount of iron-silicon slag generated by the method is extremely low, and compared with a traditional molten pool smelting method, the comprehensive utilization rate of iron in the multi-metal gold concentrate is greatly increased.

The invention relates to the technical field of rare earth ore concentrate treatment, in particular to a rare earth ore concentrate treatment method. The treatment method of the rare earth concentrate comprises the following steps that the rare earth concentrate, a calcium-containing compound, silicon dioxide and carbon powder are mixed and roasted, and roasted ore is obtained; water is added into the roasted ore for size mixing, and size is obtained; and acid is added into the slurry for reaction, solid-liquid separation is carried out, and acid leaching residues and rare earth chloride feed liquid are obtained. The method has the advantages of being simple in technological process, high in rare earth recovery rate, short in reaction time, environmentally friendly, low in cost and diversified in rare earth grade applicability. The silicon dioxide can increase the decomposition activity of bastnaesite and monazite in the rare earth ore, rare earth compounds easy to leach can be generated, and therefore the decomposition rate of the rare earth ore concentrate is increased, and calcium can also play a role in fixing fluorine. According to the method, the rare earth decomposition rate is 98% or above, and the rare earth leaching rate is 96% or above.

The invention relates to the technical field of mineral processing data processing, in particular to a preparation method of a high-calcium fluorite and barite paragenic ore combined inhibitor, which comprises the following steps: collecting multi-source process mineralogy data output by an X-ray fluorescence spectrometer, an automatic mineral analyzer and the like, converting the multi-source process mineralogy data into a structured format, and constructing a process mineralogy database; based on historical data of a database, a random forest algorithm is adopted to train a correlation model, the correlation rule of mineral characteristics such as calcite content, fluorite particle size distribution and barite monomer dissociation degree and the inhibitor ratio is learned, and parameters of the optimization model are fed back through a flotation test. The combined inhibitor solves the problem of selective separation caused by similar surface properties through a synergistic effect of covering active sites of fluorite calcium by modified water glass, regulating active sites of barite barium by citric acid and assisting in enhancing inhibition by modified starch, and solves the problem of low efficiency of multi-source data integration through structured data processing and model closed-loop optimization; the flotation separation efficiency and the concentrate grade are improved.

The invention discloses a multi-element combined collecting agent and application of the multi-element combined collecting agent in low-grade lepidolite flotation, and belongs to the technical field of mineral processing. The multi-element combined collecting agent is composed of the cationic amine collecting agent, the anion accelerant and the long-chain anion collecting agent, the reaction activity of the collecting agent and the capturing behavior on mineral particles are remarkably improved in the flotation process, the foam viscosity is reduced, the fluidity is improved, and the flotation efficiency is improved. The method effectively solves the problems that foam is too stable and different silicate minerals are difficult to float and separate under the acidic condition, reduces environmental pollution and equipment corrosion, further strengthens the hydrophobic floating behavior on the surface of lepidolite, enables the grade of obtained concentrate Li2O to be high, and further realizes clean recycling of low-grade lepidolite resources.

The invention discloses a multi-metal rare earth ore sulfating roasting clinker immersion cleaning integrated method which comprises the following steps: slurrying sulfating roasting clinker of multi-metal rare earth ore concentrate powder, and carrying out a multi-stage countercurrent leaching-washing process on the obtained slurry to obtain overflow liquid containing rare earth metal. By means of the method, the concentration difference between the solution and the clinker in the leaching process can be increased, then the mass transfer driving force in the leaching process is improved, the leaching process is enhanced, and the dissolution rate of valuable metal is increased; and meanwhile, the washing purpose is synchronously achieved in the leaching process, the using amount of washing water is reduced, and the washing efficiency is improved.

The invention discloses a method for converting niobium minerals in niobium rough concentrate into pyrochlore. The method comprises the following steps: (1) mixing the niobium rough concentrate with a modifier, a fluorine-containing reagent, a reducing agent and a binder, and carrying out compression molding; and (2) roasting the mixed blank for a set time, preserving heat, and quenching to obtain pyrochlore type rough concentrate. The method comprises the following steps: (1) carrying out magnetic separation on pyrochlore type rough concentrate; (2) performing heating and acid leaching on the magnetic separation tailings; and (3) carrying out flotation to obtain niobium concentrate. According to the method, iron components in the rough concentrate are reduced into magnetic iron minerals, niobium minerals are converted into non-magnetic pyrochlore, follow-up niobium-iron separation is facilitated, and the grade of niobium in the niobium concentrate obtained through production can be effectively improved; and the method is high in adaptability to niobium rough concentrate, is also applicable to alkaline or acidic niobium rough concentrate, is relatively small in gangue mineral change and low in conversion reaction temperature, and has the advantages of energy conservation and emission reduction compared with other regulation and control processes.

The invention discloses a flash and top blowing coupled molten pool tin smelting device and method, and belongs to the technical field of pyrogenic smelting of crude tin. Tin concentrate, fuming enriched tin middling and powdery tin smoke dust are subjected to ore blending with a flux and then are smelted; adding a carbonaceous reducing agent into the molten pool, and reducing to form a CO reducing atmosphere layer at the upper part of the slag layer; and blowing fluidized bed furnace roasting dry powder to the upper part of the CO reducing atmosphere layer, carrying out flash reduction smelting on the fluidized bed furnace roasting dry powder, enabling the fluidized bed furnace roasting dry powder which is not subjected to flash reduction smelting to enter a molten pool, and continuing to carry out a reduction stage in top-blowing molten pool smelting, so that flash and top-blowing coupling is realized, and crude tin is prepared. According to the invention, flash melting pool smelting and top-blowing melting pool smelting are effectively coupled together, fuel consumption can be reduced by about 20%, and the bed capacity is obviously improved.

The invention discloses a sulphide ore flotation method which comprises the following steps: (1) carrying out ore grinding operation on sulphide ore to obtain ore pulp; (2) the pH value of the ore pulp is adjusted, then a pyrite inhibitor, a collecting agent and a foaming agent are sequentially added, flotation operation is conducted, and concentrate and tailings are obtained; the chemical structural formula of the pyrite inhibitor is as shown in formula (I). The flotation method preferably selects the pyrite inhibitor, can be widely applied to inhibition of pyrite, hemite and pyrrhotite in copper-sulfur separation, lead-zinc-sulfur separation and lead-antimony, molybdenum-bismuth and sulfur separation, can generate a strong inhibition effect on the pyrite and the pyrrhotite, has the characteristic of small dosage, is non-toxic and environment-friendly, can replace sodium cyanide for use, and has a wide application prospect. Meanwhile, the problems that the pH value of ore pulp is too high and the separation efficiency is low due to the fact that a large amount of lime is used can be effectively solved, and the grade and flotation recovery rate of target mineral concentrate are improved.

The invention discloses a quality-divided treatment and recycling method for lead-zinc beneficiation wastewater, and belongs to the technical field of beneficiation wastewater treatment.The method comprises the steps that beneficiation tail water is introduced into a Fenton reaction tank, a catalyst is added firstly, then hydrogen peroxide is added, a Fenton oxidation reaction is conducted, after the Fenton oxidation reaction is finished, the beneficiation tail water is introduced into a coagulation reaction tank, caustic soda liquid is added, and the mixture is stirred and mixed uniformly; adding a precipitating agent, a flocculating agent and a stabilizing agent, and flocculating and settling the precipitate; introducing the beneficiation tail water added with the treatment agent into a honeycomb inclined tube sedimentation tank, further flocculating and settling, then returning flocculated precipitates in a bottom tank to a coagulation reaction tank, and discharging redundant bottom mud into a tailing pond; and settled clear water enters a clear water tank and is used as production water for ore grinding classification and flotation operation. According to the invention, through quality-divided treatment-quality-divided recycling of the beneficiation wastewater, it is ensured that the beneficiation tail water meets the requirements of ore grinding and flotation production indexes, the treatment cost of concentrate overflow water and filtered water is reduced, and the purpose of 100% recycling of the beneficiation wastewater after quality-divided treatment is achieved.

The invention provides a beneficiation method of micro-fine particle low-grade tin ore. The beneficiation method comprises the following steps: (1) feeding; (2) physical reselection: a centrifugal drum of the physical concentrator rotates horizontally, and ore pulp is fed to the inner surface of the drum by an ore feeding device and is driven by the centrifugal drum to rotate along with the drum; (3) thickening; (4) the flotation process comprises the following steps: S1, feeding; s2, pulp mixing, wherein a flotation reagent is added into the ore pulp; the flotation reagents comprise a desulfurization flotation reagent and a floating tin flotation reagent, the desulfurization flotation reagent is added into the ore pulp for desulfurization flotation, and then the floating tin flotation reagent is added for floating tin flotation; s3, air inflation is carried out; s4, separating; and (5) secondary concentrate upgrading is conducted, specifically, flotation concentrate enters the physical concentrating machine again, secondary upgrading is conducted, and tin concentrate is obtained. According to the beneficiation method, the tin-containing grade of a tin concentrate product reaches 50% or above, and the comprehensive recovery rate reaches 55% or above.

The invention discloses a beneficiation method for efficiently recovering barite from heat treatment drilling waste. The beneficiation method comprises the following steps that (1) the drilling waste containing the barite is subjected to wet screening classification; (2) performing magnetic separation on the undersize product to obtain a magnetic product and a non-magnetic product; (3) carrying out primary roughing and primary concentration on the non-magnetic product to obtain a barite powder product 1; and (4) the roughing tailings are subjected to scavenging for three times, scavenged concentrates are combined and then subjected to fine selection for two times, and a barite powder product 2 is obtained. According to the method, barite in the heat treatment drilling waste is efficiently recycled by adopting a beneficiation method, two different grades of barite powder products are obtained and can serve as drilling fluid raw materials to be recycled, resource utilization of the waste is achieved, and meanwhile environmental hazards are reduced.

The invention discloses a mineral separation magnetic separator for muddy tungsten polymetallic ore and a recovery system for recovering black tungsten, and relates to the technical field of mineral separation of the muddy tungsten polymetallic ore. The blending box is used for blending raw material ore pulp with the concentration of 30%; the bottom of the blending box is transmitted to the permanent magnet separator through a transmission pump connecting pipeline, and a return pipeline I and a circulating pump I are mounted on the permanent magnet separator; magnetically separating the raw ore pulp by a permanent magnetic separator to obtain weak magnetic concentrate pulp; the bottom of the permanent magnetic separator is provided with a transmission pipeline and connected with the high-intensity magnetic separator, and the transmission pipeline is connected with a transmission pump; the concentrate thickener is used for blending and concentrating to obtain concentrated ore pulp with the concentration of 25-35%; a centrifugal concentrator; a return pipeline II and a circulating pump II are arranged on the centrifugal separator, and the number of cycles is three; and the frequencies of the centrifugal separator are respectively 50HZ, 40HZ and 30HZ. The technical problems that argillization tungsten ore cannot be recycled, and materials with proper tungsten concentration cannot be selected through magnetic separation and gravity separation, and the recycling difficulty is large are solved.

The invention provides a beneficiation and enrichment method for high-molybdenum oxide ore, which comprises the following steps of: performing fraction magnetic separation on a product after ore grinding, regrinding magnetic separation coarse particle tailings, mixing the reground product with magnetic separation fine fraction tailings to perform low-potential sulphide ore flotation, performing oxidized ore flotation on sulphide ore flotation tailings, and the like. And finally, the molybdenum concentrate with the high recovery rate and grade is obtained, the molybdenum ore separation and enrichment effect is achieved, and the fine disseminated-particle-size refractory molybdenum oxide ore resources in the high-oxidation-type molybdenum ore are effectively and comprehensively recycled. In order to quickly optimize and obtain the optimal condition of oxidized ore flotation, the flotation inhibitor with the good inhibition effect is determined through the pure ore flotation test, the flotation collecting agent with the high selectivity is selected through the molecular simulation calculation method, and the flotation efficiency and selectivity are improved. The method provided by the invention can be widely applied to the fields of development of high-oxidation molybdenum ore mines and recycling of fine-fraction refractory molybdenum oxide ore resources in tailings after sulfuration flotation.

The invention belongs to the technical field of mine ore washing equipment, and relates to improvement of the production efficiency of an elutriation machine, in particular to an elutriation system for efficient iron ore washing and separation and a control method thereof.The elutriation system comprises a concentrate pulp mixer, an overflow groove, an elutriation barrel, a supporting platform, an ore washing water path and a control system; the concentrate pulp mixer is arranged above the elutriation barrel, the overflow groove is formed in the lower portion outside the concentrate pulp mixer and is in an inclined table shape, the tailing outlet is formed in the bottom of the inclined table, the middle of the interior of the overflow groove is connected with the elutriation barrel, a middle barrel body of the elutriation barrel is divided into an inner barrel body and an outer barrel body, and multiple sets of magnet exciting coils are arranged between the inner barrel body and the outer barrel body. The lower part of the inner cylinder is connected with an inverted-cone cylinder; a stirring impeller is arranged below the concentrate pulp mixer; the lower part of the elutriation barrel is filled with direct-flow water and rotational flow water through an ore washing water path; the system automatically recognizes working condition changes according to the ore feeding property, the material amount, field data and database set values, the optimal operation mode is selected, a magnetic field, an ore removal valve, a water supply valve and the like are controlled, efficient and intelligent separation of iron ore powder is achieved, and the optimal ore washing effect is achieved.

The invention belongs to the technical field of mineral separation processes, and particularly relates to a magnetic separation process for low-grade potassium feldspar ore, which comprises the following steps: (1) crushing: crushing low-grade potassium feldspar raw ore; (2) ore grinding: grinding the fine particle raw materials to obtain ore pulp; (3) desliming: desliming the ore pulp to obtain a material containing magnetite and other weakly magnetic minerals; (4) removing strong magnetic magnetite through weak magnetic separation; (5) superconducting magnetic separation: carrying out superconducting magnetic separation on the magnetite-removed material to obtain potassium feldspar concentrate; (6) concentration is conducted, specifically, concentrate is subjected to concentration, and residual impurities are removed; and (7) dewatering and drying: dewatering and drying the concentrated concentrate to obtain a final product. According to the method, a two-step magnetic separation process is adopted for the low-grade potassium feldspar raw ore, weakly magnetic iron-containing impurities in the potassium feldspar raw ore are effectively removed, the impurity removing and whitening effects are achieved, the potassium feldspar powder with high purity and high whiteness is obtained, and the method is free of pollution and suitable for large-area application and popularization.

The present invention discloses a method for separating niobium from niobium-containing ore, wherein the niobium coarse concentrate is mixed with a sulfiding agent to obtain a mixture, and the mixture is subjected to reduction smelting to obtain a reduced ore, and a niobium-rich product is directly obtained from the reduced ore, or the niobium-rich product is obtained after post-processing the reduced ore. Compared with the traditional reduction smelting process, the method for separating niobium from niobium-containing ore of the present invention can achieve separation of niobium from slag while achieving separation of slag and iron, and enrich niobium to obtain a high-grade niobium-rich product, which can be purified through further metallurgical processes. The process method of the present invention has strong operability, simple process, low requirements on load-bearing smelting equipment, and is easy to promote and apply industrially.

The invention discloses a comprehensive utilization process for kaolin tailings. The comprehensive utilization process comprises the following steps: scrubbing the kaolin tailings; the scrubbed kaolin slurry is sieved by a 5mm linear sieve, waste rocks of + 5mm are used as sand-gravel materials, and the waste rocks of-5mm are classified into 2-5mm, 0.1-2mm and-0.1 mm; the method comprises the following steps: grinding and grading ore with the particle size of 2-5mm, returning and regrinding the ore with the particle size of + 0.6 mm, removing tail mud with the particle size of-0.045 mm by grading the ore with the particle size of-0.6 mm, carrying out magnetic separation on the ore with the particle size of 0.045-0.6 mm, carrying out 1-2 sections of strong magnetic separation on the obtained magnetic separation concentrate to obtain strong magnetic concentrate, heating, adding chemicals, scrubbing, and carrying out chemical removal, desliming and washing to obtain primary photovoltaic glass sand and graded fine sand; the method comprises the following steps of: grinding and screening the ore with the particle size of 0.1-2mm, grinding and screening the ore with the particle size of + 0.6 mm until the ore with the particle size of-0.6 mm is completely ground, carrying out spiral chute reselection on the ore with the particle size of-0.6 mm to obtain heavy ore and light ore, carrying out 2-3 sections of magnetic separation on the light ore to obtain magnetic concentrate, carrying out flotation to obtain mica, carrying out graded desliming on the product in a flotation tank, and carrying out graded fine sand with the particle size of-0.1 mm; carrying out heating, chemical adding and scrubbing at the particle size of 0.1-0.6 mm, and then carrying out chemical removal, desliming and washing to obtain secondary photovoltaic glass sand; the yield of the obtained product is higher, and the product index is better.

The invention belongs to the field of flotation, and particularly relates to a lithium-containing china clay ore flotation method which comprises the following steps: carrying out flotation on to-be-separated minerals of lithium-containing china clay ore in a flotation reagent containing a collecting agent to obtain lithium china clay ore concentrate; the collecting agent is characterized in that the collecting agent is a compound shown in the formula 1 # imgabs0 #; and / or a product obtained by carrying out an addition reaction on a formula 2 (R-NH2) and a formula 3 # imgabs1 # in advance and then carrying out a saponification reaction with an alkali. According to the collecting agent for the lithium china clay ore, the component shown in the formula 1 is innovatively adopted as the collecting agent for the lithium china clay ore, in this way, on the basis of intermolecular coupling of beta-NH-and-COOM, the collecting agent can accidentally adapt to the surface characteristics of target minerals of the lithium china clay ore, high-selectivity collecting can be achieved, and effective collecting under the low-temperature and mild conditions can be achieved.

The invention discloses a pre-concentration and tailing discarding process for vanadium titano-magnetite, and relates to the technical field of vanadium titano-magnetite beneficiation, and the pre-concentration and tailing discarding process comprises the following steps: raw ore is subjected to crushing operation to obtain a crushed product, and the crushed product is fed into high-pressure roller grinding operation to obtain a high-pressure roller grinding product; the high-pressure roller-milled product is subjected to screening operation, and an oversize product with the large particle size and an undersize product with the small particle size are obtained; the undersize products are subjected to first weak magnetic pre-concentration operation, tailings obtained through the first weak magnetic pre-concentration operation are subjected to first strong magnetic pre-concentration operation, concentrate obtained through the first weak magnetic pre-concentration operation and concentrate obtained through the first strong magnetic pre-concentration operation are combined into final pre-concentration concentrate, and the tailings obtained through the first strong magnetic pre-concentration operation serve as one part of final tailings; the oversize products are subjected to second weak magnetic pre-concentration operation, tailings obtained through the second weak magnetic pre-concentration operation are subjected to second strong magnetic pre-concentration operation, and concentrate obtained through the second weak magnetic pre-concentration operation and concentrate obtained through the second strong magnetic pre-concentration operation are combined and then returned to the high-pressure roller grinding operation; tailings obtained by the second strong magnetic pre-separation operation are used as one part of final tailings. According to the method, crushing, high-pressure roller grinding and screening are adopted, oversize and undersize products obtained through screening are subjected to magnetic separation, pre-concentration and tailing discarding, oversize product pre-concentration concentrate is returned to the high-pressure roller grinding, the subsequent ore grinding and selecting cost is effectively reduced, the iron and titanium grades of subsequent ore entering the grinding process are improved, the load capacity of the high-pressure roller grinding machine can be reduced, and energy consumption and production cost are reduced.

The invention relates to the technical field of jigging magnetic flotation columns, and discloses a jigging magnetic flotation column which comprises an inner cylinder, a magnet exciting coil is fixedly connected to the periphery of the inner cylinder, and an outer cylinder is arranged on the periphery of the magnet exciting coil; a conical concentrator is fixedly connected to the bottom of the inner cylinder, and a pulsation mechanism is arranged on one side of the conical concentrator; and the inner cylinder is connected with a feeding mechanism. The technical problems that a large amount of washing water needs to be used for elutriating the magnetic separator, and the concentration of reagents is affected by adding water into a flotation column are solved, the magnetic separation method for magnetite by applying magnetic levitation is possible, the magnetic separation magnetic field intensity is synchronously and reversely adjusted, and the problems of overflow tailing black running and magnetic ore concentrate magnetic inclusion caused by jigging pulsation are solved; the accidents that the ore pulp of the flotation column runs out of the groove and overflows and the elutriation magnetic separator runs out of the groove and overflows are prevented, and the product recovery rate and the concentrate index are also improved.

The invention discloses an environment-friendly flotation separation method for copper-lead bulk concentrate. The method comprises the following steps: (1) preparing copper-lead mixed ore pulp; (2) flotation pretreatment of copper-lead mixed ore pulp; (3) carrying out flotation on the copper-lead mixed ore pulp; and (4) performing solid-liquid separation to obtain concentrate. The flotation method has the advantages that the novel flotation method capable of efficiently and environmentally separating complex and difficult-to-separate copper-lead bulk concentrate is provided, and the copper grade and the copper recovery rate can be effectively improved; meanwhile, the selected chemicals are environment-friendly and nontoxic chemicals, so that the chemicals are wide in source, low in price and very friendly in environmental protection requirement; the method is not only a key for solving the current technical bottleneck, but also an inevitable requirement for promoting green and sustainable development of the mining industry.