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662 results about "Platinum Metal" patented technology

Method for improving catalyst reacting activity in the propylene producing through propane dehydrogenation

A method to promote the activity of a catalyst for dehydrogenation of propane to propylene is as follows: (1) an inorganic oxide bonding agent, a promoter and an acid solvent are added into a heat-resistant oxide; then after the oxide bonding agent, the promoter, the acid solvent and the oxide are kneaded evenly, the oxide is molded by rolling or band-extruding; (2) the catalyst carrier prepared is dried for 2 to 10 hours under the temperature of 60 centigrade degrees, and calcined under the temperature of 400 to 800 degrees; (3) the calcined carrier is immersed in a rare earth metal water solution under the temperature of 60 to 100 centigrade degrees for 2 to 10 hours; (4) the catalyst carrier modified by the rare earth is immersed in a water solution comprising platinum metal elementsand the fourteenth metal elements under the temperature of 400 to 600 centigrade degrees for 2 to 10 hours, and then the carrier is filtered, washed with distilled water, dried under the temperature of 60 to 180 centigrade degrees for 2 to 10 hours, and calcined under the temperature of 400 to 600 centigrade degrees for 2 to 10 hours; (5) the catalyst prepared is activated in the air under the temperature of 400 to 600 centigrade degrees for 3 to 10 hours, and reduced in a hydrogen flow under the temperature of 400 to 600 centigrade degrees for 2 to 10 hours; the reduced catalyst is used for catalytic reaction for dehydrogenation of propane to propylene.
Owner:SOUTHEAST UNIV

Platinum-based selective hydrogenation catalyst as well as preparation method and use thereof

The invention relates to a platinum-based selective hydrogenation catalyst. The catalyst uses active carbon as a carrier; and based on the total mass of the catalyst, in terms of mass content, the content of active component platinum metal is 0.5 to 5 percent, and the grain diameter of the platinum metal is less than 30 nanometers. The invention also relates to a preparation method for the catalyst: after the active carbon is subjected to ultrasonic treatment by nitric acid solution with a certain concentration, the active carbon is repeatedly washed by deionized water to be neutral and then added into PtCl2 aqueous solution with a certain pH value to carry out ultrasonic immersion, the solution is filtered, a filer cake is pulped and then reduced by using a chemical reduction method and filtered and washed until no chloride ion exist, and the filter cake is transferred into an oven to be dried to form a nano Pt/active carbon catalyst. The invention further relates to application of the catalyst. The catalytic hydrogenation activity of the catalyst is good, the selectivity is high, the catalyst can effectively inhibit dechlorination without adding dehalogenation inhibitor, the preparation process is simple to operate, and the platinum metal is easy to recover.
Owner:XIAN CATALYST NEW MATERIALS CO LTD

Anti-sintering catalyst for preparing low-carbon olefin by low-carbon alkane dehydrogenation and preparation method thereof

The invention relates to a platinum-tin catalyst of low-carbon alkane dehydrogenation and a preparation method thereof, and mainly solves the problem that in the prior art, in high temperature and carbon burning processes of a catalyst, metal platinum particles are easy to coalesce to grow up to affect the stability of the catalyst. According to the platinum-tin catalyst of low-carbon alkane dehydrogenation and the preparation method thereof, a technical scheme is adopted to well solve the problem, the technical scheme is shown as follows: first introducing assistants of alkalinous metals such as calcium, magnesium and the like into an alumina carrier by a coprecipitation method to get a compound metal oxide carrier, then using a dipping method to load tin and platinum components, namely dipping an aqueous solution of soluble salts of the platinum and tin components, and thus obtaining the platinum-tin catalyst by drying, roasting and water vapor treatment. The platinum-tin catalyst of low-carbon alkane dehydrogenation and the preparation method thereof can be used in industrial preparation of the catalyst for preparing low-carbon olefin by low-carbon alkane dehydrogenation.
Owner:CHINA PETROLEUM & CHEM CORP +1

Single metal/multi-wall carbon nano tube type composite material, preparation method and application thereof

The invention provides a single metal/multi-wall carbon nano tube type composite material, a preparation method and application thereof. According to the composite material, the single metal is uniformly loaded on the carbon nano tube, wherein the mass percentage of the carbon nano tube is 63 to 95 percent, the particle diameter of the single metal is 15 to 28 nanometers, and the diameter of the carbon nano tube is 10 to 30 nanometers. The preparation method comprises the following steps of: preparing a laminated plate containing LDH of Co, Cu and Mg activity or activity-aid species by using the micro adjustable characteristics of the composition and the structure of the LDH laminated plate, growing a carbon composite material by roasting and a chemical vapor deposition method, and meanwhile reducing mixed metal oxide into the single metal so as to obtain the single metal/multi-wall carbon nano tube type composite material. A noble platinum metal is loaded on the composite material to prepare an anode catalyst of a direct methanol fuel cell, the peak current density of the catalyst on methanol electro-catalysis oxidation is 21 to 36mA.cm<2>, and the specific activity can reach 235 to 451 mA/mg. The preparation method has the advantages of simple preparation flow, low cost, environment friendliness and the like, and is suitable for industrialized application.
Owner:BEIJING UNIV OF CHEM TECH

Platinum supported nitrogen-doped molybdenum disulfide photocatalyst and preparation method thereof

ActiveCN105618098AGood hydrogen production capacityAnd stable hydrogen production capacityHydrogen productionHydrogen/synthetic gas productionElectrochemistryHydrogen production
The invention provides a platinum supported nitrogen-doped molybdenum disulfide photocatalyst and a preparation method thereof. The method comprises the following steps: with sodium molybdate and thioacetamide as raw materials, preparing molybdenum disulfide nanoplates via a hydrothermal method; performing thermal treatment on the molybdenum disulfide nanoplates in an ammonia atmosphere to obtain nitrogen-doped molybdenum disulfide nanoplates; and finally, loading precious metal platinum on the nitrogen-doped molybdenum disulfide nanoplates via a photo reduction method to obtain the platinum supported nitrogen-doped molybdenum disulfide photocatalyst. With the platinum supported nitrogen-doped molybdenum disulfide photocatalyst, molybdenum disulfide is taken as a photocatalyst to produce hydrogen from water by visible light catalytic decomposition for the first time. The platinum supported nitrogen-doped molybdenum disulfide photocatalyst has excellent visible light catalytic hydrogen production capability and excellent stability. The preparation method is simple to operate, the photocatalyst is good in repeatability, and the application of molybdenum disulfide in the aspects of photocatalysis and electrochemistry is expanded.
Owner:XI AN JIAOTONG UNIV

Graphene dye sensitized solar cell and production method thereof

The invention discloses a graphene dye sensitized solar cell and a production method thereof. The solar cell comprises a light anode comprising transparent upper base material and graphene conducting layer, a porous nano semiconductor film and a dye sensitizer, oxidation reduction electrolyte solution, a counter electrode comprising a lower base and graphene conducting layer and a composite catalytic layer as well as a film shell. The production method comprises the steps of preparing the light anode, preparing the counter electrode, encapsulating and injecting the electrolyte solution. In the invention, graphene with an available raw material, low cost, good conductive performance, extremely high flexibility and good ductibility is adopted as the conducting layer, the flexible transparent material is adopted as a substrate, and platinum metal particles are embedded on the graphene conducting layer of the counter electrode by adopting adsorption instead of magnetron sputtering to form the composite catalytic layer. Thus, the invention has the characteristics that the raw material is available, the production cost is low, the production process is simple and reliable, the flexible solar cell can be produced and applied to the flexible field, and the application range is effectively expanded.
Owner:UNIV OF ELECTRONICS SCI & TECH OF CHINA
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