564 results about "Catalytic decomposition" patented technology

The invention provides an efficient and stable ship hybrid power generation system which comprises a hydrogen production unit and an ammonia supply system, and the hydrogen production unit comprises an ammonia decomposer, a hydrogen separator, a high-pressure hydrogen storage tank, a fuel cell and an ammonia-hydrogen internal combustion engine. The ammonia decomposer enables the ammonia flow to enter the ammonia decomposer in a segmented constant mode for catalytic decomposition through four set working conditions; the hydrogen separator is used for separating and purifying the generated mixed gas, and the separated and purified hydrogen is respectively fed into the fuel cell and the ammonia-hydrogen internal combustion engine through valves for power generation; the molten salt system recycles high-temperature tail gas of the ammonia-hydrogen internal combustion engine through the heat exchanger for heat energy storage and power generation through the steam Rankine cycle system. The regulation and control method is used for stabilizing the system and prolonging the service life of equipment by limiting the dynamic loading rate and start-stop times of the fuel cell and the ammonia-hydrogen internal combustion engine, and is used for waste heat recovery power generation through the molten salt and the steam expansion machine, so that the efficiency of the system is improved.

The invention discloses a self-cleaning photovoltaic super-hydrophobic coating based on a nano-porous structure and a preparation method of the self-cleaning photovoltaic super-hydrophobic coating, and belongs to the technical field of photovoltaic panel coatings. The coating comprises the following components in percentage by mass: 15-25% of nano porous silicon dioxide particles, 5-10% of a low surface energy modifier, 3-8% of photocatalytic nano titanium dioxide, 30-40% of organic silicon resin and the balance of deionized water. The coating has super-hydrophobicity, photocatalytic decomposition of organic matters and wear resistance, can solve the problems of photovoltaic panel dust accumulation, bird droppings, organic matter pollution and the like, and improves the power generation efficiency of a photovoltaic system.

The invention discloses a Fe-Beta molecular sieve for N2O catalytic decomposition and a preparation method of the Fe-Beta molecular sieve. According to the method, chitosan and metal Fe < 3 + > ions are complexed to form a chitosan Fe < 3 + > complex, and then the complex, a silicon source, an aluminum source and a template agent are used as raw materials to prepare the Fe-Beta molecular sieve in one step through a hydrothermal method. Hydroxyl, amino and other groups rich in a chitosan molecular chain can effectively complex metal Fe < 3 + > ions to form a stable chitosan Fe < 3 + > complex, and the stable chitosan Fe < 3 + > complex is used as a Fe source to realize uniform dispersion of Fe species in the molecular sieve and effectively reduce formation of FexOy clusters and Fe2O3 nanoparticles, so that the N2O decomposition catalytic performance of the Fe-Beta molecular sieve is improved. Inorganic alkali metal ions are not introduced, so that a large amount of ammonia-nitrogen wastewater generated in a subsequent tedious ammonium exchange process can be avoided, the synthesis period is effectively shortened, and energy consumption, material consumption and environmental pollution are reduced.

The invention discloses a method for preparing tantalum carbide powder by carburization based on a double-effect synergistic effect of molten salt activation and catalytic decomposition, which comprises the following steps: mixing molten salt powder A and tantalum powder to obtain mixed powder, heating the mixed powder to 600-1200 DEG C for activating treatment to obtain activated tantalum powder, separately placing molten salt powder B and the activated tantalum powder in a heating furnace, heating the heating furnace to 100-200 DEG C, heating the heating furnace to 100-200 DEG C, and heating the heating furnace to 100-200 DEG C to obtain the tantalum carbide powder. The heating furnace is heated to enable the molten salt powder B to be converted into molten salt, then carbon source gas firstly flows through the molten salt to form active gas, the active gas makes contact with the activated tantalum powder to react, and the tantalum carbide powder is obtained. On one hand, the tantalum powder is subjected to surface activation treatment through the molten salt, and the reaction activity of the tantalum powder is improved; the molten salt medium assists in organic gas decomposition, the thermal decomposition efficiency of the organic gas is improved, the production energy consumption is effectively reduced under the cooperation of the molten salt auxiliary gas decomposition and the molten salt activation tantalum powder process, and the product purity and uniformity are improved.

The invention relates to the technical field of sewage treatment, and discloses a method and system for oxygenolysis of refractory pollutants based on ozone bubble water. The method comprises the following steps: carrying out grid interception, sand setting and pH regulation pretreatment on sewage; air is compressed, dried and subjected to oxygen generation, and then is introduced into an ozone generator to generate high-concentration ozone gas; enabling the pretreated effluent and ozone gas to form micro-nano bubble water in a shearing spiral-flow type generator; carrying out contact oxidation on the bubble water and the pollutants in a vertical flow reactor; preliminarily oxidized effluent enters a catalytic bed for advanced treatment; and the generated tail gas is absorbed and catalytically decomposed. According to the invention, the solubility and stability of ozone in water are improved, the contact time of ozone and pollutants is prolonged, the oxidation efficiency of ozone is enhanced, and the treatment energy consumption is reduced, so that efficient oxygenolysis of refractory pollutants is realized.

The invention discloses a method for improving the crystallinity and catalytic water decomposition performance of a polyheptazine imino carbon nitride photocatalyst, and belongs to the technical field of photocatalytic material preparation. The preparation method comprises the following steps: firstly, by taking melamine as a precursor, carrying out thermal polymerization to obtain an oligomer melt consisting of heptazine units; then carrying out high-temperature fused salt calcination treatment in a nitrogen atmosphere to obtain carbon nitride with a certain crystallinity; and adding sodium chloride as a structure regulator, fully grinding, calcining in vacuum, washing with water, and drying to obtain the crystalline-phase carbon nitride photocatalyst with high crystallinity. The method is simple, the cost is low, the actual production requirement is met, and the synthesized photocatalyst has good polymerization degree and light absorption performance, has excellent activity of fully decomposing water to produce hydrogen and oxygen under the condition of no sacrificial agent, and has the potential of realizing photocatalytic full-decomposition water diversion and the prospect of industrial application.

The invention discloses a preparation method and application of octahedral cuprous oxide containing defects, and belongs to the technical field of material preparation. In order to solve the problems that in existing cuprous oxide preparation, a defect structure is difficult to accurately regulate and control, and the crystal form uniformity is insufficient, the method comprises the steps that a copper source solution, a glucose solution, a sodium citrate solution and an ammonium fluoride solution with specific concentrations are mixed according to the volume ratio, the pH is adjusted to 10.5-11, then a hydrothermal reaction is conducted, and a target product is obtained through centrifugation, filtration, washing and drying. The method comprises the following specific steps: mixing solutions, reacting in a high-pressure reaction kettle at 140-165 DEG C for 4-6 hours, and realizing octahedral crystal form construction and defect regulation and control by controlling the raw material ratio and reaction conditions. The preparation method is simple in process and high in controllability, and the prepared octahedral cuprous oxide containing defects can serve as a catalyst to be applied to the fields of catalytic decomposition of ammonium perchlorate and the like and has good industrial application prospects.

The invention discloses an integrated closed circulation system for an RBCC engine, and solves the problems that a constant-pressure extrusion mode of an existing RBCC engine propellant supply system is not suitable for variable working condition adjustment of an RBCC rocket thrust chamber, and a high-pressure storage tank is huge in structure, large in weight and not beneficial to application and expansion of the system on the day. According to the system, high-temperature oxygen is generated through catalytic decomposition of hydrogen peroxide and acts on the turbine, then the hydrogen peroxide pump and the coal oil pump are driven to work, integrated pressurization, supply and adjustment of propellants can be carried out on the multiple rocket thrust chambers and the ramjet combustion chamber at the same time, and therefore wide-range fuel oil adjustment is met, and a widely-applied electric pump system can be replaced; and the structural envelope and weight are greatly reduced, so that the power requirement of a longer voyage is met.

The invention discloses an efficient and lasting multifunctional refrigerator deodorant which comprises the following components: (a) 50-85wt% of a porous adsorption material with a high specific surface area; (b) 5-30 wt% of a catalyst capable of effectively catalyzing and decomposing organic odor molecules in a low-temperature environment of 0-10 DEG C; and (c) 3 to 15 weight percent of long-acting slow-release type broad-spectrum antibacterial agent. According to the efficient and lasting refrigerator deodorant and the preparation method thereof, the dual effects of physical adsorption and low-temperature catalytic decomposition are utilized, multiple types of peculiar smell molecules can be rapidly adsorbed and thoroughly decomposed, and the deodorization efficiency is remarkably higher than that of a single adsorbent; the service life is greatly prolonged and is 3-5 times that of common activated carbon, the food decay speed is reduced, the food fresh-keeping period is indirectly prolonged, and food safety is guaranteed. The use process is safe and reliable, the use is convenient, external conditions such as illumination and heating are not needed, the device can be directly placed in a refrigerator, the replacement frequency is reduced due to long-term effect, and the comprehensive use cost is low.

The invention discloses an antibacterial composite material for water treatment and a preparation method thereof in the technical field of composite materials, and the antibacterial composite material is prepared from the following components in parts by weight: 20-25 parts of a magnetic nano material, 19-22 parts of acrylic acid, 6-9 parts of allylamine, 1.8-2.2 parts of N, N '-methylene bisacrylamide, 1.3-1.6 parts of azodiisobutyronitrile and 4.3-5.5 parts of plant polyphenol. Cobalt ferrite is used as a magnetic core to prepare a magnetic nano material to improve the recovery rate, acrylic acid and allylamine are used as polymeric monomers to form a polymer layer with high adsorption capacity, and plant polyphenols are combined on the surface, so that the adsorption performance and the catalytic decomposition performance are enhanced, and the antibacterial effect of the material is improved at the same time; further, the composite material with the functions of adsorbing heavy metal ions, decomposing organic pollutants and resisting and inhibiting bacteria is obtained.

The invention provides an organic phosphoric acid molecule modified tungsten oxide ammonia gas sensor as well as a preparation method and application thereof, and belongs to the field of nanostructure materials and ammonia gas detection. According to the invention, the catalytic decomposition capability of organic phosphoric acid molecules on ammonia gas is utilized, so that the adsorption and catalytic oxidation of ammonia gas molecules on the surface of tungsten trioxide are promoted, and the sensitivity and selectivity of tungsten trioxide on ammonia gas are enhanced; on the other hand, phosphorus-oxygen groups in organic phosphoric acid molecules can be bonded with Lewis reaction active sites (uncoordinated W < 6 + >) on the surface of tungsten trioxide in a covalent form, so that the surface activity of tungsten trioxide is protected, and the service life of the sensor is prolonged. The result of the embodiment shows that the sensitivity of the prepared organic phosphoric acid molecule modified tungsten oxide ammonia gas sensor to ammonia gas is remarkably improved, the organic phosphoric acid molecule modified tungsten oxide ammonia gas sensor has good selectivity to ammonia gas, the performance is not obviously attenuated after 5-month test, and the service life is long.

The invention discloses an in-vehicle intelligent mosquito repelling method, and relates to the technical field of intelligent vehicle environment control, and the method comprises the steps: synchronously collecting in-vehicle multi-modal data through a sensor, and carrying out the preprocessing of the in-vehicle multi-modal data, and obtaining the preprocessed in-vehicle multi-modal data; a chemical mosquito repelling mode or a physical mosquito repelling mode is selected based on the preprocessed multi-mode data, and in-vehicle mosquito repelling control is carried out; the mosquito density at the air outlet of the air conditioner is calculated, and if the mosquito density in the unit volume exceeds the preset density, an ultraviolet LED lamp is turned on for catalytic decomposition of dimethyl phthalate residues in the air; according to the method, historical driving data of a user is obtained through a vehicle-mounted T-BOX, an LSTM neural network is adopted for mosquito occurrence probability prediction, a pre-mosquito-repelling request is pushed to a user mobile terminal according to a prediction result, and in-vehicle intelligent mosquito repelling based on multi-modal sensing is completed. Efficient, safe and low-pollution mosquito repelling measures are achieved, response can be conducted quickly, and the health and comfort of passengers are guaranteed.

The invention discloses a preparation method and application of a bimetallic sulfide / three-dimensional porous carbon catalyst, and relates to the technical field of electrolyzed water catalysts.The preparation method comprises the following steps that melamine sponge is cleaned, and the clean melamine sponge is obtained; the preparation method comprises the following steps: dissolving metal salt 1 and metal salt 2 in an ethanol aqueous solution, and adding alkali and an aniline monomer to obtain a precursor solution; completely soaking the clean melamine sponge in a precursor solution, carrying out constant-temperature hydrothermal reaction, and sequentially washing and drying to obtain the melamine sponge anchored with bimetal ions; introducing inert gas for protection, and performing high-temperature vulcanization treatment to obtain the three-dimensional porous carbon catalyst embedded with the bimetallic sulfide heterostructure. The catalyst comprises uniformly dispersed bimetallic sulfide nanoparticles and a spongy three-dimensional porous carbon carrier, shows excellent bifunctional catalytic activity and stability when being applied to an electro-catalytic water decomposition reaction, and has a wide application prospect.

The invention belongs to the technical field of nano-drugs, and discloses a multifunctional nano-drug delivery system for treating neovascular eye diseases and a preparation method of the multifunctional nano-drug delivery system. The nano drug delivery system disclosed by the invention is a composite nano preparation which takes dendritic mesoporous silica nanoparticles as a carrier and co-loads cerium zirconium oxide nano enzyme and an anti-VEGF (vascular endothelial growth factor) drug, various active oxygen can be efficiently removed, oxygen is continuously released through catalytic decomposition of hydrogen peroxide, a retina hypoxia microenvironment is improved, and the retina hypoxia effect is improved. According to the present invention, the anti-VEGF drug delivery system can reduce the oxidative stress induced retinal pigment epithelial cell apoptosis rate, reduce the inflammatory reaction, and simultaneously achieve the slow release and the controlled release of the anti-VEGF drug, and the drug effect maintenance time can achieve more than 60 days, such that the multi-target synergistic treatment can be achieved through the synergistic regulation of the multiple pathological links such as oxygen deficit-oxidative stress-inflammation-angiogenesis, and the anti-VEGF drug delivery effect can be achieved. The choroidal neovascularization can be effectively inhibited by single intravitreal injection, and a new strategy of multi-target collaborative treatment is provided for neovascular macular degeneration and other eye diseases.

The invention belongs to the technical field of catalysts and relates to a cobalt-based porous aluminum catalyst for catalytic decomposition of N2O in nitric acid production tail gas as well as a preparation method and application of the cobalt-based porous aluminum catalyst. The catalyst takes Al2O3 as a carrier, Co3O4 as an active component and KF and K2O as auxiliaries, and the preparation method comprises the following steps: firstly, uniformly dispersing a certain amount of cobalt salt, villiaumite and pseudo-boehmite in deionized water to form a turbid liquid, regulating the pH value of the turbid liquid to a certain range by taking potassium salt as a precipitant to obtain a corresponding precipitate mixture, and then carrying out suction filtration and washing on the precipitate. And drying, roasting and forming the obtained filter cake to obtain the catalyst. The preparation method is simple, and industrial amplification is easy to realize. The prepared catalyst can realize direct catalytic decomposition of N2O at a low temperature, has excellent O2 resistance, NO2 resistance and water vapor resistance, has high crushing strength, and can be well applied to emission reduction of N2O in nitric acid production tail gas.

The invention provides a formaldehyde-removing hot-melt composite elastic material and bedding using the same. The material comprises 60-80 parts of a polymer matrix, 15-25 parts of a formaldehyde catalytic decomposition agent, 5-10 parts of a polarity regulator and 0.5-2 parts of a processing aid, and is formed in one step through melt blending-hot pressing foaming. A polymer matrix is in an island phase state constructed by thermoplastic polyurethane and an ethylene-vinyl acetate copolymer through melt blending, the Shore hardness of 80A-95A and the glass transition temperature smaller than or equal to 30 DEG C are both considered, and low-temperature high resilience is achieved. The catalytic decomposition agent is compounded by MIL-101 (Cr)-NH2 and aminated carbon quantum dots according to a ratio of (3-5): 1, and formaldehyde is continuously oxidized into CO2 and H2O at normal temperature without light. The silane-modified tourmaline is used as a polarity regulator, and particle agglomeration is inhibited and an interface polarization electric field is enhanced through epoxy group covalent bonding. The density of the obtained material is 40-60 kg / m < 3 >, the aperture ratio is larger than or equal to 80%, the air permeability is larger than or equal to 500 L / (m < 2 >. S), and the material is applied to comfortable layers of mattresses, pillows or back cushions and keeps efficient formaldehyde removal and mechanical supporting functions for a long time.

The invention provides a composite polymer coconut shell charcoal tufted carpet as well as a preparation method and application thereof, and belongs to the field of polymer composite carpets. The adsorption layer is compounded on the back surface of the bonding layer, so that organic matters and toxic and harmful substances in the carpet are efficiently removed. The coconut shell charcoal in the adsorption layer is acidified by nitric acid, then an active functional group is introduced, the coconut shell charcoal and a titanium source are subjected to a hydrothermal reaction, then calcination is performed to improve the crystallinity and the interface bonding force, and the adsorption-photocatalytic decomposition dynamic cycle of volatile organic compounds is achieved. And meanwhile, interlayer adhesion is enhanced by combining a needling process, and high mechanical strength and environmental protection performance are synchronously realized. Through multi-component cooperation and process optimization, a carpet solution with functionality and durability is provided for the fields of automotive interiors and the like.

The invention relates to the technical field of combustion equipment, and discloses a pure ammonia combustor carrying ammonia catalytic combustion and decomposition compositing and a control method.The pure ammonia combustor comprises a combustion sleeve, the combustion sleeve comprises an inner sleeve body and an outer sleeve body, an outer cavity is formed between the inner sleeve body and the outer sleeve body, and the inner sleeve body is provided with an inner cavity; the inner cavity comprises a combustion nozzle, a combustion cavity and a to-be-combusted cavity, a first ignition device is arranged between the combustion cavity and the to-be-combusted cavity, the to-be-combusted cavity communicates with a first air inlet, and the outer cavity comprises a preheating cavity, a combustion catalysis cavity and a catalytic decomposition cavity; the preheating cavity is located on the periphery of the combustion cavity. The combustion catalysis cavity is located on the periphery of the to-be-combusted cavity and provided with an ammonia catalytic combustion catalyst and a second ignition device, and the catalytic decomposition cavity is provided with an ammonia catalytic decomposition catalyst and communicates with the to-be-combusted cavity. The problems that pure ammonia ignition is difficult, the laminar flow combustion speed is low, flames are difficult to stabilize, and NOx emission is high are solved.

The invention relates to a self-supporting electrode and a preparation method and application thereof, and belongs to the technical field of new energy and alkaline electro-catalytic water decomposition. A preparation method of a self-supporting electrode comprises the following steps: taking a nickel net, foamed nickel or a stainless steel net as a substrate, taking deionized water containing a ferric iron compound and phosphate as an etching solution, soaking the substrate in the etching solution at room temperature, taking out the substrate, and drying at room temperature to obtain a surface-modified self-supporting electrode; according to the method, PO4 < 3-> is introduced while the Fe / M self-supporting electrode is synthesized through a one-step etching method, so that the free energy of * OH and * O intermediates is adjusted, the valence state is adjusted, and the oxygen evolution reaction rate is increased; meanwhile, PO4 < 3-> and Fe sites act, so that the Fe coordination sites are stabilized, and precipitation of iron is prevented; the self-supporting electrode prepared by using a room-temperature one-step chemical etching method not only has good water electrolysis oxygen evolution reaction activity, stability and repeatability, but also is simple and rapid in preparation process and low in cost, and large-scale industrial production can be realized.

The invention belongs to the technical field of hydrogen production by photothermal catalytic decomposition of seawater / sewage, and particularly relates to a construction method of a gas-gas-solid interface seawater desalination / sewage purification and in-situ hydrogen production reaction system. The reaction system consists of a bifunctional photo-thermal catalysis / evaporation material and a reaction device, solar energy is taken as an energy source, and seawater / sewage is taken as a reactant to carry out gas-steam-solid interface seawater desalination / sewage purification and photo-thermal decomposition of water to produce hydrogen. The bacterial cellulose hydrogel is used as a supporting substrate of a water supply substrate and a photo-thermal evaporation material, and the photo-thermal catalytic material is limited on an air-water interface, so that the stability of the photo-thermal catalyst is improved, and the defects of underwater light attenuation, large hydrogen mass transfer resistance and the like of a traditional liquid phase reaction system are overcome. Seawater desalination / sewage purification is synchronously realized, hydrogen is produced through in-situ decomposition of desalted water vapor, and the synchronous improvement of the seawater desalination / sewage purification rate and the in-situ water decomposition hydrogen production rate is promoted through the design of a gas-steam-solid interface reaction system.

The present invention relates to a catalyst for low-temperature catalytic decomposition of nitrous oxide (N2O), a preparation method, an activation method and a use thereof. The catalyst of the present invention uses rare earth metal elements and alkaline earth metal elements as promoters to assist in dispersing the active components and optimizing their electronic structures. After being pretreated and activated by H2, the activity of N2O catalytic decomposition is stably promoted, and a low-temperature N2O decomposition catalyst with excellent catalytic performance is obtained. In the catalyst preparation method of the present invention, through the co-doping of rare earth elements and alkaline earth Ba elements, the electronic structure of the catalyst is optimized; then it is activated by H2 pretreatment to generate surface defects and adjust the interaction between the active components and the promoters, thereby significantly improving the catalyst activity on the premise of maintaining good catalyst life.

The invention relates to the technical field of petroleum engineering well cementation, and discloses a well cementation construction process of a highly-deviated well, which comprises the following steps of: cleaning an oscillating foundation, and stripping well wall pollutants by generating an oscillating effect through periodically changing circulating pressure and flow velocity; electrochemical synergistic cleaning is carried out, and organic pollutants are decomposed through the electrolysis effect; catalytic decomposition cleaning accelerates fracture of a mud cake polymer molecular chain; carrying out ion exchange treatment to change a pollutant charge distribution state; and a circulating purification step: removing reaction products in real time and recovering reaction conditions. Physical and chemical composite cleaning is achieved through the synergistic effect of multiple processes, highly-deviated well annulus pollutants are thoroughly removed, and the well cementation quality and the shaft sealing performance are remarkably improved.

The invention relates to the technical field of fresh air ventilator filtering, and discloses a multiple filtering system which comprises a multi-layer composite filtering unit, the multi-layer composite filtering unit is composed of a primary filtering layer, an electrostatic adsorption layer, a catalytic decomposition layer and an activated carbon adsorption layer which are sequentially arranged in the air flow direction, the primary filtering layer is made of gradient density melt-blown fiber materials, and the electrostatic adsorption layer is made of an electrostatic adsorption layer; the porosity range is 30%-50%, particulate matter with the particle size larger than or equal to 5 microns is intercepted, the electrostatic adsorption layer is integrated with a nanoscale titanium dioxide electrode array, the applied voltage range is 5-15 kV, PM2.5-level particles are captured through electrostatic force, the catalytic decomposition layer is loaded with a noble metal catalyst (such as Pt / TiO2), volatile organic compounds (VOCs) are decomposed under ultraviolet excitation, the activated carbon adsorption layer is filled with modified bamboo charcoal particles, and the particle size of the particulate matter is larger than or equal to 5 microns. According to the multi-filtration system, the technical breakthrough of efficient purification, precise regulation and control and long-term operation and maintenance is realized by constructing an organic cooperation system of the four-layer composite filtration unit, the distributed sensor network and the intelligent control center.

The invention discloses an indoor intelligent formaldehyde detection and purification device and a use method thereof. The device comprises a movable shell, a self-adaptive intelligent control system, a pretreatment unit, an efficient adsorption unit and a core catalysis unit. The pre-treatment unit is used for filtering and dehumidifying, the efficient adsorption unit is used for adsorbing formaldehyde and desorbing to realize regeneration of a composite adsorbent layer, and the core catalysis unit is used for catalytically decomposing formaldehyde and desorbed formaldehyde; and the self-adaptive intelligent control system is used for acquiring outdoor air data, dynamically tracking formaldehyde pollution and regulating and controlling purification. Through three stages of units, in combination with a multi-stage cooperative processing and intelligent feedback control technology, formaldehyde is efficiently and directionally removed by virtue of a three-stage linkage mechanism of pre-adsorption enrichment, gradient desorption regeneration and catalytic deep decomposition, the selectivity is good, safety is realized, no extra volatile organic compound is released, and the catalytic efficiency is high; adsorbent regeneration improves stability and reduces cost.

The utility model belongs to the technical field of wastewater treatment, and relates to a two-stage oxidation device for sintering desulfurization and denitrification wastewater treatment. The device comprises a primary ozone treatment module, a secondary ozone treatment module, an ozone generator and an activating and dosing device. The process flow comprises two stages of primary ozone process treatment and secondary ozone process treatment. The wastewater directly reacts and indirectly reacts with ozone in sequence in the treatment process, organic waste in the wastewater is effectively and fully catalyzed and decomposed, and finally up-to-standard discharge is achieved. The device and equipment provided by the utility model are simple, do not need a complex treatment process, are easy to maintain, and are relatively low in maintenance medicament cost. The device provided by the utility model has continuity, can realize continuous water production, and does not generate secondary chemical pollution.

The invention relates to the field of titanium dioxide photocatalytic water decomposition, in particular to a preparation method of doped rutile titanium dioxide with selective exposure of {101} and {110} crystal faces and low defect concentration. The preparation method comprises the following steps: by taking a titanium elementary substance or a titanium-containing compound as a precursor, adding a heterogeneous metal element compound of which the valence state is lower than positive tetravalence as a morphology control agent and a defect inhibitor, fully mixing with an ionic compound serving as a molten salt medium, carrying out one-step high-temperature heat treatment in an oxidizing or reducing atmosphere, cooling, and washing off the molten salt medium, thereby obtaining the titanium-containing composite material. The rutile-doped titanium dioxide nano or micron particles with specific crystal face selective exposure and low defect concentration are obtained. According to the invention, a specific heterogeneously doped metal element compound is used as a morphology regulating agent and a defect inhibitor, so that the synergistic regulation and control of the microstructure and surface and bulk phase defects of rutile titanium dioxide are realized. Therefore, the separation efficiency of rutile titanium dioxide bulk phase photo-generated charges and the activity of photocatalytic decomposition of water to produce hydrogen are greatly improved.

The invention belongs to the technical field of hydrogen production by electrocatalytic decomposition of water, and provides an iron-doped nickel hydroxide composite iron-doped cerium oxide electrocatalyst and application thereof in electrolyzed water. The iron-doped nickel hydroxide composite iron-doped cerium oxide electrocatalyst comprises a nickel substrate, wherein a porous catalytic activity layer of three-dimensional flower-shaped spherical nanoparticles formed by stacking two-dimensional nanosheets is loaded on the surface of the nickel substrate. The catalytic active layer comprises an iron-doped hexagonal stacked nickel hydroxide structure, the catalytic active layer comprises an iron-doped cubic stacked cerium oxide structure, and no iron with a crystalline structure exists in the catalytic active layer. The iron-doped nickel hydroxide composite iron-doped cerium oxide electrocatalyst disclosed by the invention shows excellent oxygen evolution performance in an oxygen evolution reaction of electrocatalytic water decomposition.

The present invention relates to reactors and reactor components which have good resistance to NH3 and N2 and possibly to H2O at high temperatures and moderate pressures and thus can be used in industrial-scale reactions for the catalytic decomposition of NH3 into N2 and H2.

The application discloses a bifunctional In-doped Ni2Mo3N@Mo2C binary heterojunction catalyst and a preparation method and application thereof. A dimethyl imidazole solution is slowly added into a Mo salt solution to obtain a suspension liquid containing a Mo metal organic framework Mo-MOF; the suspension liquid is left to stand, and a precipitate is centrifuged and washed, and vacuum dried to obtain the Mo-MOF containing the Mo metal organic framework; a Ni salt, an In salt and the Mo-MOF are added into an anhydrous ethanol solution to perform ion exchange, and the precursor is vacuum dried to obtain the bifunctional In-doped Ni2Mo3N@Mo2C binary heterojunction catalyst. The catalyst material has excellent basic oxygen evolution and urea oxidation activity, and has a good application prospect in electrocatalytic decomposition of water, urea-assisted electrolysis of water and treatment of sewage containing urea.

The invention discloses a low-temperature catalytic degreasing and rapid densifying process of an MIM (metal injection molding) forming part, which comprises the following steps: (1) low-temperature catalytic degreasing: in a nitrogen atmosphere, catalytically decomposing a POM (polyoxymethylene) binder by a nitric acid / organic acid composite catalytic system at 80-120 DEG C; (2) surface activation treatment of the degreased green body: performing vacuum plasma cleaning to remove surface catalyst residues, and switching to H2 / N2 mixed gas to reduce residual impurities; and (3) gradient rapid sintering densification: gradient rapid sintering densification is adopted, three-stage gradient temperature control-pressure control is adopted, and the total sintering time is less than or equal to 3 hours. According to the method, low-temperature catalytic degreasing is adopted, the degreasing time is shortened, the surface of a degreased green body is activated, a traditional acid pickling or secondary degreasing step is avoided, gradient rapid sintering densification is achieved, and the density and performance of the material are improved.