809 results about "Light hydrocarbons" patented technology

The present invention belongs to the field of shale oil exploration. Provided are an evaluation method for the content of movable oil in shale, and a device and a storage medium. The evaluation method comprises the following steps: on the basis of pyrolysis test data of a sample to be tested at different aging times, determining a first recovery coefficient; on the basis of pyrolysis test data of said sample in different sample crushing environments, determining a second recovery coefficient; on the basis of pyrolysis test data of said sample at different crushing particle sizes, determining a third recovery coefficient; on the basis of pyrolysis test data of said sample at different pyrolysis temperatures, determining a fourth recovery coefficient; determining the product of the first recovery coefficient, the second recovery coefficient, the third recovery coefficient and the fourth recovery coefficient to be a light hydrocarbon recovery coefficient; and on the basis of the light hydrocarbon recovery coefficient, evaluating the content of movable oil in shale. The method provided in the present invention offers guidance for quantitatively evaluating the oil content of shale, and a finally determined free oil content result has a relatively small difference from the actual situation.

The invention provides a shale oil reservoir oil content evaluation method, which comprises the following steps: coring a shale sample, and carrying out anhydrous wire cutting processing to obtain a plunger sample and a crushed sample in an original state; respectively carrying out two-dimensional T1-T2 nuclear magnetic resonance testing on the plunger samples in the original state and the oil-water recovery state; according to the T1-T2 nuclear magnetic resonance spectrum, oil signal amplitudes of the plunger sample in an original state and an oil-water recovery state are identified, and a light hydrocarbon recovery coefficient is determined; the crushed sample is subjected to conventional pyrolysis and multi-temperature-order pyrolysis, conventional pyrolysis parameters and multi-temperature-order pyrolysis parameters are obtained, a first equation is established, and the first equation represents the relation between the original state oil content and the conventional pyrolysis parameters; according to the light hydrocarbon recovery coefficient and the first equation, a second equation is established, and the second equation represents the relation between the oil content in the oil-water recovery state and the conventional pyrolysis parameters; and evaluating the oil content of the shale oil reservoir in the oil-water recovery state according to the second equation and the measured conventional pyrolysis parameters.

The invention discloses a production method and a production device of an energy-saving sustainable aviation fuel, and the production method comprises the following steps: S1, adsorbing carbon dioxide in air by using an adsorbent, desorbing through high-temperature carrier gas, and cooling and compressing the desorbed carbon dioxide; s2, carbon dioxide and deionized water are preheated and then electrolyzed, and synthesis gas and oxygen are generated; s3, after the synthesis gas is compressed, performing Fischer-Tropsch reaction to generate a mixture of Fischer-Tropsch oil wax, light hydrocarbon and water, cooling and separating, and returning the Fischer-Tropsch reaction heat to preheat the synthesis gas; s4, pressurizing the Fischer-Tropsch oil wax, mixing the Fischer-Tropsch oil wax with hydrogen, carrying out hydrofining reaction to generate a gas-liquid isomerous oil-gas mixture, cooling and separating, and recycling heat energy of a product to And S5, after gas-liquid separation, preheating a liquid phase, carrying out rectification operation, separating and cooling to obtain a sustainable aviation fuel product. By recovering the heat in each link, the heat is efficiently utilized, and the energy-saving performance of production is improved.

A light hydrocarbon aromatization catalyst capable of increasing the yield of light alkane comprises a hydrogen type Silicalite-1 (at) ZSM-5 core-shell molecular sieve, an active metal and / or a binder, the hydrogen type Silicalite-1 (at) ZSM-5 core-shell molecular sieve takes a Silicalite-1 molecular sieve as a core layer and a ZSM-5 molecular sieve as a shell layer, and the particle size of the hydrogen type Silicalite-1 (at) ZSM-5 core-shell molecular sieve is 90-140 nm. The catalyst is applied to light hydrocarbon aromatization reaction, has higher low-carbon alkane yield and lower dry gas yield, and is good in stability, long in one-way reaction period and low in carbon deposit amount.

The invention belongs to the technical field of shale oil development and research, and discloses a shale oil mobility evaluation method based on a two-dimensional nuclear magnetic resonance experiment, which comprises the following steps: dividing an oil-containing shale sample harvested by a closed coring well into three parts which are respectively marked as a sample 1, a sample 2 and a sample 3; carrying out a TOC determination experiment on the sample 1 to obtain the TOC content of the sample; carrying out a step-by-step pyrolysis experiment on the sample 2 to obtain the contents of the sample S1-1 and the sample S2-2; calculating to obtain a shale oil mobility evaluation factor which is marked as FMO; carrying out a two-dimensional nuclear magnetic resonance experiment on the sample 3 before and after centrifugation to obtain the movable oil content of the sample before and after centrifugation, calculating to obtain the percentage of two-nuclear magnetic resonance movable oil, and recording the percentage as MO2D-NMR; and shale oil mobility evaluation is realized through analysis of the relationship between MO2D-NMR and FMO. According to the method provided by the invention, nondestructive testing of the sample can be realized in the two-dimensional nuclear magnetic resonance experiment process, the loss of light hydrocarbon can be reduced to the greatest extent, and the mobility evaluation precision of shale oil is effectively improved.

The invention relates to a method and a system for producing low-carbon olefin and light aromatic hydrocarbon through catalytic cracking. The method comprises the following steps: (1) carrying out contact reaction on raw oil and a catalytic cracking catalyst in a constant linear velocity fluidized bed reactor to obtain an oil agent mixture; (2) separating the oil agent mixture to obtain reaction oil gas and a spent catalyst; and (3) separating the reaction oil gas to obtain a low-carbon olefin component, a gasoline component and an oil slurry component. In a constant-linear-speed fluidized bed reactor, light petroleum hydrocarbons such as diesel oil are contacted with a catalytic cracking catalyst with a high silica-alumina ratio, and self-heat balance is maintained through regeneration flue gas circulation to produce low-carbon olefins, light aromatic hydrocarbons and the like. According to the method disclosed by the invention, heavy oil such as naphtha, wax oil and residual oil can be processed while light hydrocarbon such as diesel oil is processed, the conversion rate of the diesel oil is high, self-heating balance can be realized, the problem of excessive diesel oil production capacity of a refinery plant is solved, and the processing benefit of crude oil is also improved.

The invention relates to a method for producing high-octane gasoline through hydrocarbon catalytic cracking and a reaction system thereof, and the method comprises the following steps: in a constant linear velocity fluidized bed reactor, diesel oil and other light petroleum hydrocarbons are contacted with a high silica-alumina ratio catalytic cracking catalyst, and self-heat balance is maintained through regeneration flue gas circulation to produce liquefied gas and high-octane gasoline. According to the method disclosed by the invention, heavy oil such as naphtha, wax oil and residual oil can be processed while light hydrocarbon such as diesel oil is processed, the conversion rate of the diesel oil is high, self-heating balance can be realized, the problem of excessive diesel oil production capacity of a refinery plant is solved, and the processing benefit of crude oil is also improved.

The invention provides a method for recovering free hydrocarbon contents of different lithologic shale. The method comprises the following steps: carrying out closed freezing heat release, freezing pyrolysis and freezing multi-temperature-order pyrolysis experiment test analysis on a closed coring well core; performing freezing pyrolysis experiment test analysis on the core of the non-closed coring well; carrying out pyrolysis experiment test analysis on the multi-courtyard core; determining the lithology type of the shale; and recovering the free hydrocarbon content of the shale according to an experimental test analysis result and the lithology type. According to the method, light hydrocarbon loss can be reduced to the greatest extent, the content of free hydrocarbons in different lithology non-closed coring well samples and placed samples is recovered, and the accuracy of shale oiliness evaluation is improved.

The invention discloses an alkynyl functionalized hydrogen bond organic framework (HOF) material for efficient reverse separation of propylene / propane as well as a preparation method and application of the alkynyl functionalized hydrogen bond organic framework (HOF) material. The preparation method comprises the following steps: dissolving a tetracarboxylic acid type organic ligand H4L in a benign organic solvent to obtain an H4L solution, then placing the H4L solution in a poor solvent steam atmosphere, and obtaining an HOF material through a gas phase diffusion method; after a low-boiling-point reagent is adopted to carry out solvent exchange on the HOF material, solvent molecules in pore channels of the HOF material are removed through an activation method, and then the alkynyl functionalized HOF material for propylene / propane efficient reverse separation is obtained. The material shows the characteristics of high propane adsorption capacity, excellent propylene / propane reverse separation performance, good cycle performance, easy repair and reproducibility, fills the technical blank of the HOF material in the field of efficient reverse separation of propylene / propane mixed gas, and provides a brand new thought and technical support for research and development in the field of light hydrocarbon separation.

The invention relates to a method and a system for producing chemical materials including ethylene based on a constant linear velocity fluidized bed reactor, and the method comprises the following steps: (1) carrying out contact reaction on raw oil and a shape-selective molecular sieve catalyst in the constant linear velocity fluidized bed reactor to obtain an oil agent mixture; (2) separating the oil agent mixture to obtain reaction oil gas and a spent catalyst; and (3) separating the reaction oil gas in an oil-gas separation system to obtain chemical materials including ethylene, C4 olefin and the like. In a constant-linear-speed fluidized bed reactor, light petroleum hydrocarbons such as diesel oil are contacted with a shape-selective molecular sieve catalyst, and self-heat balance is maintained through regeneration flue gas circulation to produce ethylene, propylene and the like. According to the method disclosed by the invention, heavy oil such as naphtha, wax oil and residual oil can be processed while light hydrocarbon such as diesel oil is processed, the yield of ethylene and propylene is high, self-heating balance can be realized, the problem of excessive diesel oil production capacity of a refinery plant is solved, and the defects of chemical materials are made up.

The invention relates to the technical field of catalysis, and discloses a catalytic cracking device and method. The device comprises a multi-stage reaction unit and a cracking reaction unit, the multi-stage reaction unit comprises a variable-diameter riser and a multi-stage reaction settler, and the cracking reaction unit comprises a cracking riser and a cracking settler; the variable-diameter lifting pipe comprises a first reaction zone, a second reaction zone and a third reaction zone which are sequentially connected in series in the length direction, the inner diameter of the second reaction zone is larger than that of the first reaction zone and that of the third reaction zone, and an inner conveying pipe extending into the second reaction zone is arranged at the joint of the third reaction zone and the second reaction zone; the cracking settler comprises a cracking steam stripping section, a turbulence reaction section and a cracking settling section which are sequentially arranged along the length direction of the cracking settler, an outlet of the cracking riser is positioned in the turbulence reaction section, and the cracking steam stripping section is provided with a cracking catalyst outlet communicated with the second reaction area. The device can improve the reaction efficiency of catalytic cracking of heavy oil and light hydrocarbon, and realizes tight coupling of heavy oil and light hydrocarbon.

The invention discloses a gradient utilization system based on low-grade heat energy and LNG cold energy, the gradient utilization system based on low-grade heat energy and LNG cold energy comprises a cold energy power generation device and a light hydrocarbon separation system which are communicated with each other, the light hydrocarbon separation system is used for recycling and separating C2 + light hydrocarbon in LNG rich liquor to obtain ethane, LPG and LNG barren liquor respectively, and the LNG barren liquor is used for storing the ethane, the LPG and the LNG barren liquor. The cold energy power generation device carries out cold energy power generation based on ethane and LNG barren liquor obtained by the light hydrocarbon separation system as cold sources. The cold energy power generation device comprises a first circulation pipeline, a second circulation pipeline, a third circulation pipeline and an intermediate heat exchanger. And low-grade heat energy circulates in the intermediate heat exchanger and the third circulating pipeline. The low-grade heat energy is utilized, coupling of the light hydrocarbon separation system and the cold energy power generation device is achieved, the cooling capacity of LNG barren liquor and ethane is fully utilized, external cooling capacity supply is not needed, comprehensive utilization of the low-grade heat energy and LNG cold energy is achieved, and the cold energy utilization rate is effectively increased.

A semi-closed pyrolysis system, including a liquid nitrogen freezing device, a gas-liquid collector and a pyrolysis gas collecting device. The liquid nitrogen freezing device includes a collecting vessel, a liquid nitrogen storage, an air inlet pipe, an air outlet pipe and a temperature detector. The collecting vessel is arranged in the liquid nitrogen storage container, and is provided with a stainless steel cap. The stainless steel cap is provided with three holes respectively for the air inlet pipe, the air outlet pipe and the temperature detector to pass through. The air inlet pipe and the air outlet pipe are each provided with a valve. The temperature detector includes a probe and a temperature sensor electrically connected with the probe. The probe extends into the collecting vessel. A method for determining carbon isotope composition of light hydrocarbon monomers based on such system is further provided.

The invention relates to the field of VOCs treatment, and discloses a composite material for adsorbing VOCs as well as a preparation method and application thereof. The composite material comprises foam metal and a heat-conducting adsorption material filled in a foam metal framework, the heat-conducting adsorption material comprises a porous material and a heat-conducting material. The composite material provided by the invention has the characteristic of good heat conduction effect, meanwhile, the shape and the size of the foam metal can be randomly adjusted according to the requirements of an adsorption bed layer, and the composite material can be used for adsorbing light hydrocarbons, such as small molecules such as ethane and propane.

The invention provides a method for preparing alkane olefin by catalyzing microalgae pyrolysis through an alkali modified molecular sieve, and belongs to the field of biomass energy utilization. According to the method, the ZSM-5 molecular sieve raw powder is modified by adopting the alkaline solution, so that the pore structure of the ZSM-5 molecular sieve can be improved, the distribution of acidic sites can be optimized, the regulation and control of a microalgae pyrolytic reaction path can be realized under relatively mild conditions, the deoxidation reaction can be promoted, the content of oxygen-containing products can be reduced, and the generation of alkane olefin substances can be promoted; the aromatization reaction strength is reduced, and the selectivity of light hydrocarbons is improved, so that the content of alkanes and olefins in the pyrolysis bio-oil reaches 70% or above, and the quality of the pyrolysis bio-oil is remarkably improved. Results of the embodiment show that the pyrolysis bio-oil provided by the invention is subjected to gas chromatography-mass spectrometry detection, and the alkane-olefin peak area content is greater than 70%.

The present invention discloses a kind of mesoporous ZSM 5 molecular sieve and preparation method thereof, the preparation method comprises the following steps:Silicon source, aluminum source, alkali source, crystallization inducer, auxiliary agent, water are mixed to obtain crystallized gel, the crystallized gel is crystallized under hydrothermal conditions, washed, filtered, dried, roasted, and mesoporous ZSM 5 molecular sieve is obtained;Wherein, the silicon source is magadiite, the crystallization inducer is organic ammonium salt and seed crystal, and the auxiliary agent is selected from at least one of alcohol or amine. The molecular sieve obtained by the method of the present invention has the characteristics of high crystallinity, large specific surface area, and large micro-mesopore volume. The preparation method of the present invention adopts cheap silicon source, and in the case of adding a small amount of mesoporous template agent, mesoporous ZSM 5 molecular sieve can be synthesized, which is applied to light hydrocarbon catalytic cracking reaction with good low-carbon olefin selectivity.

The invention provides an efficient technological method and system for preparing aromatic hydrocarbon through CO2 hydrogenation. The process method comprises the following steps: 1) mixing feed gas containing CO2 and H2 with recycle gas to obtain a mixture flow, and carrying out first-stage reaction on the mixture flow after heat exchange heating to obtain a first-stage reaction product; 2) performing heat exchange and separation on the primary reaction product to obtain a water phase, a gas phase and an oil phase, discharging the water phase out of the system, compressing most of the gas phase to obtain continuous circulating gas, and circulating the circulating gas back to the step 1) to continue the reaction; a small part of gas phase is discharged as purge gas; 3) distilling out light hydrocarbon from the top of the tower by rectifying the oil phase to obtain aromatic hydrocarbon-rich oil from a tower kettle; 4) heating the light hydrocarbon and then carrying out secondary reaction to obtain a secondary reaction product; and 5) carrying out heat exchange and separation on the secondary reaction product to obtain a gas-phase product and a liquid-phase product, discharging the gas-phase product as purge gas, and circulating the liquid-phase product back to the light component removal tower for rectification and separation to obtain aromatic hydrocarbon-rich oil. The first-stage reaction realizes high per-pass conversion of CO2, and the two-stage reaction is coupled to realize high selectivity of aromatic hydrocarbon.

The invention relates to the technical field of plasmas, and discloses a plasma enhanced reaction device and a low-concentration light hydrocarbon oxidative conversion method. The device comprises a high-voltage electrode, more than two ground electrodes, more than two third electrodes and a plasma reaction tube which are coaxially arranged, the high-voltage electrode is arranged along the axis of the plasma reaction tube, the ground electrodes and the third electrodes are arranged in parallel along the outer wall of the plasma reaction tube, and the ground electrodes and the third electrodes are arranged at intervals; a reaction cavity is formed between the high-voltage electrode and the inner wall of the plasma reaction tube, the high-voltage electrode and the ground electrode form more than two discharge areas in the reaction cavity, the high-voltage electrode and the third electrode form more than two induction electric field areas in the reaction cavity, and the induction electric field areas are filled with metal frame organic materials serving as catalysts. The plasma enhanced reaction device disclosed by the invention is used for carrying out oxidative conversion on low-concentration light hydrocarbon, and a relatively good conversion effect can be obtained.

A process includes flowing a catalyst composition comprising catalyst particles into a radial flow moving bed reactor, wherein the catalyst particles move by gravity through the radial flow moving bed reactor to an exit point of the radial flow moving bed reactor, wherein the catalyst particles form a moving catalyst bed in the radial flow moving bed reactor, flowing a light hydrocarbon feed stream comprising C1 to C3 alkanes into the radial flow moving bed reactor in a manner so that the light hydrocarbon feed stream flows radially inward or radially outward through the moving catalyst bed and thereby contacts the catalyst particles under reaction conditions to produce a product effluent stream comprising a C2 to C10 hydrocarbon product and hydrogen, and flowing the product effluent stream from the radial flow moving bed reactor.

Disclosed are routes for producing liquid hydrocarbon products containing gasoline and / or diesel boiling range hydrocarbons, and optionally renewable products containing non-petroleum derived carbon. In a typical process, a gaseous feed mixture containing a combination of CO 2 and H 2 and / or CH 4 (or other hydrocarbon sources of H 2 ) is converted by a reforming and / or reverse water gas shift (RWGS) reaction optionally used in combination with Fischer-Tropsch (FT) synthesis and / or cracking. Preferred gaseous feed mixtures are biogas or mixtures of CO 2 and H 2 that are not easily upgraded in conventional processes. The catalysts described herein have high activity to catalyze the reforming (including dry reforming) of CH 4 and other light hydrocarbons (e.g., those produced by FT synthesis and recycled to the process as light fractions) and simultaneously catalyze the RWGS reaction. These attributes provide flexibility with respect to compositions that can be efficiently converted. Optionally, the use of an electrically heated reforming reactor in the first reforming stage or initial reforming stage or RWGS stage can improve the economics of small-scale operation.

A testing device for measuring oil, gas and water contents in rock has a heating desorption unit that has a sample chamber for placing a rock sample to be detected, a crushing mechanism arranged within the sample chamber, and a heating mechanism. The heating desorption unit crushes and heats the rock sample in a sealed manner to achieve gas analysis and desorption analysis of oil and water contained therein, thus obtaining components to be detected. The device further has a cold trap collection unit in communication with the sample chamber, a light hydrocarbon capture unit in communication with the cold trap collection unit, a gas measuring unit in communication with the light hydrocarbon capture unit for measuring and calculating a gas volume; and a central control unit for controlling the testing device.

The invention discloses a vehicle-mounted mobile device capable of being remotely controlled and recycling and emptying natural gas by using liquid nitrogen cold energy. The system comprises a liquid nitrogen storage tank, a centrifugal pump, a throttle valve, a plate-fin heat exchanger, a temperature controller and an LNG storage tank, carrying out liquefaction treatment on the vented natural gas by adopting low-temperature liquid nitrogen; liquid nitrogen stored in the liquid nitrogen storage tank is pressurized by the pump and enters the heat exchanger to exchange heat with recycled natural gas, the liquid nitrogen is discharged into air after losing cold energy, and the liquefied natural gas enters the LNG storage tank through the throttling valve to be temporarily stored and then can be injected into an LNG pipeline or directly sold. The process is simple, an expansion machine is not needed, the equipment investment cost is low, the size is small, and vehicle-mounted movement can be achieved; remote dynamic control can be realized, and workers do not need to stay beside the device for a long time; the pressure range of the recovered and vented natural gas comprises but is not limited to 0.2-4 MPa, the liquefaction efficiency is stable, and the minimum liquefaction rate is 98.2%; the device is suitable for gas compression stations and gas transmission stations which are small in emptying amount, large in gas pressure fluctuation range, scattered in gas source distribution, high in methane content and free of operations such as light hydrocarbon removal.

The invention relates to a method and a device for identifying hydrocarbon source rock types in a well area with less offshore sea-land transition facies. The identification method comprises the following steps: S1, acquiring required data; s2, according to the sporopollen phase analysis data, determining a hydrocarbon source rock division threshold value based on the sporopollen phase component content; s3, according to the hydrocarbon source rock division threshold value based on the sporopollen phase component content, determining the threshold value of the biogenic indication parameter of the biomarker compound corresponding to the hydrocarbon source rock and the condensate oil; s4, according to the threshold value of the biogenic indication parameter of the biomarker compound corresponding to the condensate oil, determining the threshold value of the natural gas light hydrocarbon parameter; and S5, drawing a cross plot according to the natural gas light hydrocarbon parameters, and dividing ranges corresponding to different types of hydrocarbon source rocks according to the threshold values of the natural gas light hydrocarbon parameters. According to the identification method and device provided by the invention, the identification accuracy of the hydrocarbon source rock type of the offshore sea-land transition facies sedimentary environment less-well area is remarkably improved, and the problem of limited samples in the less-well area is solved.

The invention relates to an oil-containing rock sample batch freezing device, an analysis system and an analysis method, and relates to the technical field of oil exploration. A plurality of samples can be placed on the sample plate provided with the plurality of sample cavities at a time, and the sample plate can be quickly frozen by introducing the refrigerating fluid into the first flow channel in the sample plate, so that low-temperature storage of all the samples is realized. The heat preservation box is of a split structure, the heat preservation box is kept in a closed state when the samples do not need to be taken, and the heat preservation box is temporarily opened under the action of the driving mechanism when the samples need to be taken, so that the samples are always in a low-temperature state, and the analysis result is prevented from being influenced by loss of light hydrocarbon components. The oil-containing rock sample batch freezing device is arranged on the pyrolysis instrument, the manipulator of the pyrolysis instrument can grab samples in the sample cavity nearby and send the samples to the detection mechanism for analysis, the time for exposing the samples in the air is short, the analysis efficiency is high, and the result is accurate.

A liquefied natural gas (LNG) production facility includes gravity-based structures (GBSs) with process lines for liquefying natural gas. A GBS contains: tanks for each component of a mixed refrigerant, wherein a GBS process line includes a fractionating apparatus for mixed refrigerant component production from a broad fraction of light hydrocarbons; a stabilized gas condensate (SGC) storage tank; and a berth for offloading LNG and SGC into tankers. Each GBS contains an LNG storage tank. One tank per mixed refrigerant component from each GBS is connected by pipe to systems for preparing and compressing all process line refrigerants, thus forming a common component feed system. The SGC storage tank is connected by pipes to condensate-stabilizing apparatus for all process lines, thus forming a common system for storing and offloading SGC. The LNG storage tanks are interconnected by pipes, forming a common system for storing and offloading LNG.

The invention discloses a catalytic cracking catalyst containing alkaline metal and rare earth as well as a preparation method and application of the catalytic cracking catalyst, and belongs to the technical field of catalysts. The catalytic cracking catalyst containing the alkaline metal and the rare earth comprises 5-35% of a phosphorus-silicon composite binder, 10-60% of a shape-selective cracking molecular sieve, 0-25% of other molecular sieves, 0.01-5% of an alkaline metal compound in terms of oxide, 0.2-5% of a rare earth compound in terms of oxide, 0-15% of activated aluminum oxide and the balance of natural clay, wherein the total percentage is 100%. The phosphorus-silicon composite binder is prepared from the following components in percentage by weight: 15 to 55 percent of P2O5, 10 to 45 percent of SiO2 and 0.1 to 3 percent of RE2O3. The prepared catalytic cracking catalyst containing the alkaline metal and the rare earth not only improves the catalytic cracking activity of light hydrocarbon, but also is suitable for cracking of naphtha and mixed C4 raw materials, and can obviously reduce the hydrogen transfer activity in the reaction process, so that the yield of alkane such as methane and ethane is reduced, and the yield of diene is effectively improved.

The invention discloses a low-energy-consumption natural gas low-temperature rectification decarburization process. The process comprises the following steps: S1, firstly removing water and sulfur-containing compounds in raw material gas; s2, cooling the raw material gas without water and sulfur-containing compounds to-30 DEG C to-27 DEG C, and introducing a separated gas-phase material without C4 and above light hydrocarbon substances into a tower kettle reboiler of a low-temperature rectifying tower as a heat source of the tower kettle reboiler to form a gas-liquid mixed material at-37 DEG C; and S3, controlling the pressure of the gas-liquid mixture at-37 DEG C to be 2.5-3.5 MpaA, introducing the gas-liquid mixture into a low-temperature rectifying tower, and finally harvesting methane-rich natural gas at the top of the tower and liquid-phase carbon dioxide at the bottom of the tower. The method has the advantages that the energy consumption is low, and the natural gas with complex components and ultrahigh carbon dioxide content can be decarbonized.

The invention relates to the technical field of freezing pyrolysis analysis, and discloses an ultralow-temperature freezing sample table, a freezing platform and a pyrolysis analysis cooperative work system. According to the ultra-low temperature freezing sample table, a sample placing box is provided with an opening; the refrigeration pipeline is fixed in the sample placing box; the movable bin door is connected above the sample placing box; the driving device is connected with the movable bin door and used for driving the movable bin door to open and close the opening. The pyrolysis analysis cooperative work system comprises a pyrolysis instrument and an ultralow-temperature freezing platform, and the ultralow-temperature freezing sample table supplies a sample to the pyrolysis instrument. The ultra-low temperature freezing sample table and the ultra-low temperature freezing platform can be matched with the pyrolysis instrument to perform pyrolysis work. Compared with a traditional pyrolysis experiment, the technical scheme provided by the invention can ensure that a sample to be pyrolyzed and analyzed is kept in an ultralow temperature state, so that the loss of light hydrocarbon is avoided, and the use effect is better. Compared with frozen closed crushed sample pyrolysis, the technical scheme provided by the invention can realize batch analysis of samples in cooperation with a pyrolysis instrument, and the working efficiency is greatly improved.

The invention provides a method for identifying the water content of a reservoir based on light hydrocarbon logging. The method comprises the following steps: acquiring light hydrocarbon logging data of an oil and gas reservoir to be evaluated; selecting total hydrocarbon abundance, benzene and toluene / benzene in the light hydrocarbon logging data as light hydrocarbon parameters; establishing a two-dimensional atlas through the intersection of benzene and toluene / benzene in the light hydrocarbon parameters, establishing a three-dimensional atlas through the total hydrocarbon abundance and the change of benzene and toluene / benzene, dividing the boundaries of an oil layer, an oil-water layer and an oil-containing water layer, and quantitatively explaining and evaluating the fluid properties of the reservoir. According to the method, the light hydrocarbon logging technology is utilized, two-dimensional and three-dimensional interpretation maps are formed through intersection by selecting light hydrocarbon parameters such as total hydrocarbon abundance, benzene and methylbenzene, the interface and the water content of the reservoir fluid are quantitatively recognized, the coincidence rate of actual interpretation and evaluation of the reservoir fluid is increased, the exploration and development cost of an oil field is effectively reduced, and the purpose of improving the oil testing effect is achieved; the method is easy to operate, high in identification and evaluation accuracy, high in universality and wide in application range.

A continuous process includes supplying, to a hydrogen production unit, an energy source in the form of mechanical energy or electrical energy produced from thermal energy generated in a hydrogenation process in a hydrogenation reactor unit, and flowing a light hydrocarbon feed stream into the hydrogen production unit in the presence of a catalyst to produce a hydrogen gas enriched stream using the energy source.