This invention provides a desulfurization adsorbent, its preparation method, and its application. The preparation method includes: dissolving a complexing agent in water and adjusting its pH value to obtain a treatment solution; wherein the complexing agent includes one or more combinations of
polyethylene glycol,
hexadecyltrimethylammonium bromide, and
ethylenediaminetetraacetic acid; dispersing
activated alumina in the treatment solution and heating under
reflux to obtain modified
alumina; dispersing the modified
alumina in a solution containing an alkaline substance, then mixing it with a solution containing an active
metal, hydrothermally crystallizing, and calcining to obtain the desulfurization adsorbent. The medium- and low-temperature
flue gas solid desulfurization adsorbent provided by this invention has
metal ions bonded to aluminum species in
activated alumina and uniformly distributed on the surface of
activated alumina, exhibiting high stability and
sulfur capacity.