304 results about "Metal oxide nanoparticles" patented technology

The invention provides conductive paste, a solar cell, a preparation method of the solar cell and a photovoltaic module. The conductive paste comprises the following components in parts by weight: 70-85 parts of silver powder, 3-8 parts of glass powder, 0.1-2 parts of an additive and 12-25 parts of an organic carrier, wherein the silver powder comprises spherical silver powder and flaky silver powder; the glass powder is prepared from the following components in parts by weight: 65 to 75 parts of Bi2O3, 18 to 25 parts of TeO2 and 8 to 12 parts of V2O5; the additive is a carbon material and / or conductive metal oxide nanoparticles; the organic carrier comprises an infrared absorbing material; the infrared absorption material is selected from any one or more of copper phthalocyanine, a polyaniline-carbon nanotube compound and a tungsten oxide nanowire. The conductive paste can improve the conductivity of the conductive paste and improve the efficiency of the conductive paste in a laser sintering process, so that the contact resistivity is reduced, and the photoelectric conversion efficiency of a photovoltaic solar cell is improved.

The invention belongs to the technical field of preparation of sensor materials, and particularly relates to a room-temperature formaldehyde sensor material based on a catalytic principle as well as preparation and application of the room-temperature formaldehyde sensor material. The polyphenol is adsorbed on the surface of the semiconductor metal oxide through chelation, then noble metal ions are introduced, and the polyphenol on the surface of the semiconductor metal oxide can capture the noble metal ions and reduce and stabilize the noble metal ions on the surface of the semiconductor metal oxide; the noble metal nanoparticles are anchored on the surfaces of the semiconductor metal oxide nanoparticles, the original morphology of the semiconductor metal oxide is maintained, and the noble metal nanoparticles are loaded on the surfaces of the semiconductor metal oxide nanoparticles. The nano composite material not only has the intrinsic electrical and thermodynamic properties of semiconductor metal oxide, but also combines the catalytic characteristics of noble metal nanoparticles, so that the lower detection limit of formaldehyde is reduced to 3ppb, and the sensitivity of the sensor is remarkably improved. The preparation method of the room-temperature formaldehyde sensing material is simple and suitable for large-scale production, the raw materials are simple and easy to obtain, the cost is low, and the materials are environment-friendly.

The invention provides a tip Raman-based metal oxide nanoparticle in-situ detection method, which comprises: S1, dispersing metal oxide nanoparticles in a nanoparticle dispersion liquid, focusing laser to the tip of a nanometer tip through an objective lens, capturing a single nanoparticle by using an optical tweezers technology, and attaching the single nanoparticle to the nanometer tip; s2, focusing Raman laser on a nano needle tip-particle interface, generating a local high-temperature field through a photo-thermal near-field coupling effect, triggering a thermal chemical reaction of nano particles, and synchronously collecting a Raman spectrum; and S3, carrying out pretreatment and characteristic peak analysis on the collected Raman signal of the Raman spectrum, and determining the reaction critical temperature and the dynamic process in combination with temperature calibration data. According to the invention, capture and accurate heating of the nanoparticles are realized through photo-thermal coupling of the optical tweezers and the needle tip, and thermal chemical reaction monitoring of the nanoparticles is realized.

The invention provides an electrolyte for quickly charging a sodium-ion battery without a negative electrode. The electrolyte comprises a sodium salt, a solvent and an additive. According to the electrolyte, metal oxide nanoparticles are introduced as a first additive, and a second additive is supplemented, so that rapid desolvation of sodium ions on an electrode interface and improvement of the ionic conductivity of an electrolyte body are realized at the same time, and compact and dendrite-free sodium deposition under high current density is realized. The negative-electrode-free sodium-ion battery prepared from the electrolyte can be quickly charged, and good cycling stability and high capacity retention ratio can be maintained, so that the use requirements of people can be met.

The present invention relates to the nanoparticles (NP) of the invention, compositions thereof and their use as therapeutic agents, in particular in the field of oncology and / or as imaging agents. The NPs consist of first nanoparticles of at least one high-Z metal oxide material, to which smaller second nanoparticles are covalently bonded at the surface of the first nanoparticles. The second nanoparticles consist of a) at least one noble metal or at least one metal oxide, metal sulfide, metal selenide or metal sulfide / selenide as a Fenton or Fenton-like reaction catalyst. The NPs of the invention produce a surprising therapeutic effect when exposed to ionizing radiation such as X-rays, gamma-rays, protons, neutrons, radioisotopes and / or electron beams. Therefore, these NPs can be used as radiosensitizers in the field of oncology. These nanoparticles can also be used as contrast agents.

A nano composite, a nanoparticle ink composition including a solvent and the nanocomposite, and a light-emitting device including a first electrode, a second electrode facing the first electrode, and an interlayer between the first electrode and the second electrode, wherein the interlayer includes an emission layer, and at least one layer included in the interlayer is made from the nanoparticle ink composition. The nano composite includes: a metal oxide nanoparticle; and a chelating ligand bonded to a surface of the nanoparticle and including a cyclic moiety.

The invention provides an interface regulation and control method of a perovskite solar cell, a trans-perovskite solar cell and a preparation method of the trans-perovskite solar cell. The interface regulation and control method comprises the following steps: arranging a first metal oxide nanoparticle layer between a hole transport layer and a transparent conductive film glass layer; and a second metal oxide nanoparticle layer is arranged between the hole transport layer and the perovskite light absorption layer. The trans-perovskite solar cell comprises a transparent conductive film glass layer, a first metal oxide nanoparticle layer, a hole transport layer, a second metal oxide nanoparticle layer, a perovskite light absorption layer, an electron transport layer and an electrode. According to the interface regulation and control method provided by the invention, the surface wettability of the hole transport layer is improved, the arrangement uniformity of the hole transport layer is improved, and finally the photoelectric conversion efficiency of the perovskite solar cell is improved.

Provided is a metal oxide dispersion having excellent gap-fill performance, and a method of manufacturing a metal oxide film using the same. A metal oxide dispersion according to a first aspect of the present invention contains carboxylic acid having 9 or more carbon atoms, metal oxide nanoparticles surface-treated with a capping agent, and a solvent. A metal oxide dispersion according to a second aspect of the present invention contains carboxylic acid having a boiling point of 250° C. or higher at an atmospheric pressure, metal oxide nanoparticles surface-treated with a capping agent, and a solvent. A method of manufacturing a metal oxide film according to a third aspect of the present invention comprises: a step for forming a coating film formed of the metal oxide dispersion described above; and a step for heating the coating film at a temperature of 165° C. or higher.

The invention belongs to the technical field of diaphragms, and particularly relates to a cellulose and cellulose derivative doped composite diaphragm as well as a preparation method and application thereof.The preparation method comprises the following steps: adding a thermoplastic organic high-molecular polymer, a cellulose derivative and metal oxide nanoparticles into an organic solvent, dissolving, adding a pore-foaming agent, and uniformly stirring; uniformly mixing, defoaming to obtain a membrane casting solution, and blade-coating to obtain a liquid membrane; the liquid film is placed in a wet air atmosphere with the relative humidity of 30%-80% for pre-phase inversion, in the pre-phase inversion process, water vapor in wet air permeates into the liquid film and exchanges with the organic solvent in the liquid film, and a wet film is obtained; and immersing the wet membrane into an extracting agent for phase conversion to obtain the cellulose and derivative doped composite diaphragm. According to the preparation method, safe operation of the diaphragm can be ensured, the electrolytic efficiency of the diaphragm is remarkably improved, and the diaphragm is excellent in stability of long-time operation.

A ZrO2 / CaSiO3 / g-C3N4 nanocomposite material includes spherical metal oxide nanoparticles which include a ZrO2 phase and a CaSiO3 phase dispersed on a matrix of g-C3N4 nanosheets. The spherical metal oxide nanoparticles have an average particle diameter in a range from 3 to 18 nanometers (nm). The ZrO2 / CaSiO3 / g-C3N4 nanocomposite material has a Brunauer-Emmett-Teller (BET) surface area greater than or equal to 55 square meters per gram (m2·g−1).

The invention discloses a water-based fire extinguishing agent based on inorganic silicon dioxide aerogel loaded metal oxide nanoparticles, a preparation method and application. The fire extinguishing agent is prepared from, by mass, 1%-5% of silicon dioxide aerogel loaded metal oxide nanoparticles, 1%-10% of a foaming agent, 0.1%-2% of a stabilizer, 1%-10% of a flame retardant, 0.5%-5% of an anti-freezing agent, 0.1%-1% of a preservative and the balance water. The silicon dioxide aerogel loaded metal oxide nano-particles are prepared by the following steps: preparing a silicon dioxide aerogel skeleton, preparing metal oxide nano-particles, and modifying, loading and drying silane. The preparation method comprises the following steps: firstly preparing a dispersion liquid A containing the composite particles and a solution B containing the functional additive, and then carrying out mixing and ultrasonic treatment to obtain the product. The fire extinguishing agent can rapidly extinguish 314Ah lithium iron phosphate battery fire, efficiently consumes HF / CO and other gases, and is stable in system, environmentally friendly and suitable for battery fire prevention and control.

The present disclosure provides a metal oxide nanoparticle comprising a metal oxide, the metal capable of being a Lewis acid; a polymer comprising an ionisable moiety; and an amino acid; wherein a weight ratio of amino acid to 5 polymer is about 0.1:99.9 to about 99.9:0.1; wherein the amino acid is electrostatically interacting with the polymer; wherein the metal oxide comprises metal ions in a 3+ and 4+ valence state; and wherein the metal oxide is selected from lanthanide oxide and / or zirconium oxide. The present disclosure also provides a method of fabricating a metal oxide particle and use thereof.

Provided is a charge-transporting composition that contains: a charge-transporting substance comprising a polythiophene derivative represented by formula (1); a fluorine-based surfactant; metal oxide nanoparticles; and a solvent.(R1 and R2 are each independently a hydrogen atom, an alkoxy group having 1-40 carbon atoms, —O—[Z—O]p—Re, a sulfonic acid group, or the like, or R1 and R2 bond to each other to form —O—Y—O—. Y is an alkylene group having 1-40 carbon atoms, which may contain an ether bond and which may be substituted with a sulfonic acid group. Z is an alkylene group having 1-40 carbon atoms, which may be substituted with a halogen atom. p is 1 or more, and Re is a hydrogen atom, an alkyl group having a 1-40 carbon atoms, or the like.)

The invention relates to the technical field of solar cells, in particular to a perovskite solar cell. The invention provides a perovskite solar cell. The perovskite solar cell comprises a conductive substrate, a hole transport layer, a perovskite layer, an electron transport layer and an electrode layer which are stacked in sequence, the electron transport layer is made of inorganic metal oxide nanoparticles; the electron transport layer is prepared by a solution method; an interface buffer layer is arranged between the perovskite layer and the electron transport layer, and the material of the interface buffer layer is a first organic material; and / or the material of the electron transport layer further comprises a second organic material; the first organic material and the second organic material independently comprise an organic polymer and / or an organic small molecule material. According to the perovskite solar cell, the electron transport layer can be prepared by a solution method, and the performance requirement can be met.

A method of treating cancer cells includes exposing the cancer cells to a ZrO2 / CaSiO3 / g-C3N4 nanocomposite material. The ZrO2 / CaSiO3 / g-C3N4 nanocomposite material comprises spherical metal oxide nanoparticles comprising a ZrO2 phase and a CaSiO3 phase dispersed on a matrix of g-C3N4 nanosheets, wherein the spherical metal oxide nanoparticles have an average particle diameter in a range from 3 to 18 nm, and wherein the ZrO2 / CaSiO3 / g-C3N4 nanocomposite material has a percent inhibition for human breast carcinoma (MCF-7) cells greater than or equal to 80% inhibition in an in-vitro cellular viability assay.

A light-emitting element includes: a first electrode; a second electrode; a light-emitting layer provided between the first electrode and the second electrode; and a charge transport layer provided between the first electrode and the light-emitting layer, wherein the charge transport layer includes a metal oxide nanoparticle, an organic ligand is chemically bonded to the metal oxide nanoparticle via a surface hydroxyl group of the metal oxide nanoparticle, a bond enthalpy at 298 K between bonding atoms at a bonding site between the organic ligand and the surface hydroxyl group is 326.7 kJ / mol or more, and the organic ligand includes a phosphonic acid.

The invention provides a platinum-based catalyst and a preparation method and application thereof, and belongs to the technical field of fuel cells. The preparation method comprises the following steps: mixing a polymer solution, a conductive agent and a zeolite imidazate framework material to obtain an electrostatic spinning solution; carrying out electrostatic spinning on the electrostatic spinning solution, and then carrying out heat treatment to obtain composite nanofibers containing metal nanoparticles or metal oxide nanoparticles; and mixing the composite nanofiber, a platinum source and an organic solvent, and carrying out a reduction reaction to obtain the platinum-based catalyst. According to the preparation method, the polymer solution, the conductive agent and the zeolite imidazate framework material are mixed, and uniform distribution of all the components on the nanoscale can be ensured by virtue of an electrostatic spinning technology, so that a stable and efficient three-phase interface can be formed; the metal nanoparticles or metal oxide nanoparticles obtained by conversion are compounded with platinum particles, so that the catalyst exposes more active sites, and the efficient proceeding of the catalytic reaction is facilitated.

The invention discloses a two-component reworkable heat-conducting adhesive for a power battery and a preparation method of the two-component reworkable heat-conducting adhesive, and relates to the field of heat-conducting adhesives. The preparation method comprises the following steps: preparing carboxymethyl-beta-cyclodextrin modified magnetic metal oxide nanoparticles through a layer-by-layer assembly method, and grafting 2-bromophenylethylamine to the surfaces of the carboxymethyl-beta-cyclodextrin modified magnetic metal oxide nanoparticles through a condensation reaction to form a magnetic core-heat conduction shell structure; a benzene ring conjugated structure, a hydrogen bond sacrifice network formed by an amide group and a substrate, a dynamic covalent bond network and thermal conductivity of metal oxide have a synergistic effect, so that the thermal conductivity is remarkably improved; under an external high-frequency magnetic field, the composite filler is directionally arranged to form a three-dimensional heat conduction network, and the heat conduction efficiency is further enhanced. Hydrogen bonds and covalent bonds are broken at high temperature, the crosslinking density is reduced, the colloid and the substrate can be separated and repaired conveniently, a crosslinking network can be recovered after cooling, and reversible regulation and control of performance are achieved. The prepared double-component reworkable heat-conducting glue for the power battery has the effect of high heat conductivity.

To provide, for example, a curable composition that is useful as an optical material, and a cured product formed by curing the same.SOLUTION: According to one embodiment, there is provided a curable composition containing 30 to 75 pts.mass of metal oxide nanoparticles (A), 5 to 30 pts.mass of an aromatic mono(meth)acrylate (B), and 5 to 30 pts.mass of a polyfunctional (meth)acrylate (C) having a functionality of 3 or more.SELECTED DRAWING: None

A method of making surface-functionalized transition metal oxide nanoparticles comprises: providing a sol comprising transition metal oxide nanoparticles dispersed in an aqueous liquid medium having a pH of less than or equal to 3.5, combining the sol with an extractant composition comprising at least one carboxylic acid and at least one organic amine, and a water-immiscible organic solvent, and separating at least a portion of the organic phase from the aqueous phase and then at least partially removing the water-immiscible organic solvent. The carboxylic acid has from 6 to 30 atoms. The organic amine is represented by the formula R2R3NH, wherein R2 is a hydrocarbyl group having from 6 to 30 carbon atoms, and R3 is H or an alkyl group having from 1 to 4 carbon atoms. The at least one organic amine is present in an amount sufficient raise the pH to at least 5, thereby forming discrete separable aqueous and organic phases. A surface-modified nanoparticle composition, a curable composition and an article comprising the same are also disclosed.

The application discloses a thermodynamic dual-mode composite sensitive material, a preparation method and application thereof. The composite sensitive material comprises a matrix, has a three-dimensional porous structure, and comprises a polymer material and a sheet-shaped non-metallic conductive material; and metal oxide nanoparticles are distributed on the surface of the sheet-shaped non-metallic conductive material; wherein the sheet-shaped non-metallic conductive material and the metal oxide nanoparticles are both materials with negative thermoelectric coefficients. The thermodynamic dual-mode composite sensitive material provided by the application integrates pressure sensing and thermoelectric performance, which avoids the problems of complex layout and complex signal transmission of a traditional dual-mode sensor; meanwhile, the pressure sensing and the thermoelectric sensing are not interfered with each other, so that the prepared sensor has the advantages of signal non-interference decoupling, avoidance of wear failure, strong adaptability, non-destructiveness, high safety and the like, can adapt to a higher temperature, and has stable temperature signal output.

The present invention discloses a light-emitting device, a method for manufacturing a light-emitting device, and a display device including the light-emitting device. The light-emitting device includes: a first electrode and a second electrode, each having surfaces opposite to each other; a light-emitting layer comprising quantum dots disposed between the first electrode and the second electrode; and an electronic auxiliary layer disposed between the light-emitting layer and the second electrode, wherein the electronic auxiliary layer comprises metal oxide nanoparticles, and the metal oxide nanoparticles comprise anions of organic acids bound to the surface of the metal oxide nanoparticles.

As a charge-transporting ink composition for forming a film having charge-transporting properties and excellent flatness, provided is a charge-transporting ink composition containing metal oxide nanoparticles, an alcohol amine compound having a cLogD at pH 10 of-1.35 to-0.1, and an organic solvent.

The present invention relates to light emitting devices and display apparatuses including the same. The light emitting device includes an emissive layer including a plurality of quantum dots, and an electron auxiliary layer disposed on the emissive layer, the electron auxiliary layer transporting electrons to the emissive layer, wherein the electron auxiliary layer includes a plurality of metal oxide nanoparticles, wherein the metal oxide nanoparticles include zinc and a dopant metal, wherein the dopant metal includes Mg, Mn, Ni, Sn, Al, Y, Ga, Zr, Li, Co, or a combination thereof, wherein a concentration of the dopant metal in at least one of the metal oxide nanoparticles increases in a direction from an inner portion to an outer portion of the nanoparticle, or increases in a direction from an outer portion to an inner portion of the nanoparticle.

The application discloses a catalyst for a hydrogen production device for electrolysis of water by a proton exchange membrane and a preparation method and application thereof, the catalyst is manganese ruthenium metal oxide nanoparticles loaded on a conductive network of nitrogen-doped carbon nanotubes grown on a carbon cloth, and the mass ratio of manganese to ruthenium is 5-9:1-5; the nitrogen-doped carbon nanotubes have excellent conductive performance, the fine reticular structure is beneficial to more attachment of active substances, and the nitrogen-doped carbon nanotubes also have a high specific surface area and a stable three-dimensional structure, so that a good precursor is provided for subsequent hydrothermal growth of manganese ruthenium metal oxide, and the agglomeration of nanoparticles is avoided; PECVD makes the manganese ruthenium metal oxide nanoparticles more dispersed and uniform, further improves the specific surface area, exposes more active sites, and improves the catalytic activity; the interaction has greater conductive electron performance, and the basic skeleton of the manganese ruthenium metal oxide can also provide conditions for mass transfer of electrolysis of water, so that the electrode catalyst provides a larger channel for electron transfer.

The disclosure relates to methods to prepare metal oxide nanoparticles (MONs) from the cathodes of lithium-ion batteries (LIBs), and related compositions and systems. The MONs can be used to improve the properties of drilling fluids, such as those used in underground drilling methods to produce oil and / or natural gas.

The present invention relates to an inverted perovskite prepared by providing a surface-modified metal oxide nanoparticle as a coating agent for forming an electron transporting layer (or electron transport layer), and using the surface-modified metal oxide nanoparticle as a coating agent prepared in a dispersion type.

The invention belongs to the technical field of batteries, and particularly relates to a composite solid electrolyte membrane, a preparation method thereof and a battery. The method comprises the following steps: mixing a perfluorosulfonic acid type polymer with an alkali metal compound, and carrying out a neutralization reaction to obtain a first mixed solution; stirring and mixing the first mixed solution and an alcohol solvent to obtain a second mixed solution; stirring and mixing the second mixed solution, a multivalent metal ion compound and metal oxide nanoparticles to form composite slurry; and coating the composite slurry on the surface of a current collector and carrying out gradient drying to obtain the composite solid electrolyte membrane. According to the method, the ionic conductivity of the solid electrolyte membrane is improved, and the coating uniformity or the membrane layer compactness is improved.

The application provides a preparation method of a Pickering type SCR catalytic functional emulsion containing composite metal oxide particles. The composite metal oxide particles prepared by a wet chemical method are used as emulsifiers, water is used as a continuous phase, and a water-insoluble organic solvent is used as a dispersed phase. The stable O / W type catalytic functional emulsion is obtained by high-speed shearing homogenization and emulsification in a sealed container. The composite metal oxide nanoparticles with no irritation, high low-temperature catalytic activity and easily available raw materials are used as the SCR catalyst and emulsifier to replace the traditional surfactant. The Pickering type SCR catalytic functional emulsion prepared by the application has better dispersion performance and stability than the catalytic functional emulsion stabilized by the traditional surfactant. The preparation method is simple, the prepared emulsion can be uniformly loaded on the surface of various filter carriers, the reaction activity of the catalyst is well reserved, and the binding firmness between the catalyst and the filter carrier is high.

The invention provides an electrode material and a preparation method thereof, a negative plate, a battery, a battery pack and electric equipment, the electrode material comprises a shell, the shell comprises a shell wall and a cavity enclosed by the shell wall, and the shell wall comprises a carbon matrix and metal oxide nanoparticles arranged on at least part of the surface of the carbon matrix. The electrode material disclosed by the invention has a special shell structure, so that the rate capability and the cycling stability of the metal oxide electrode material can be remarkably improved.