The application discloses a thermodynamic dual-mode composite sensitive material, a preparation method and application thereof. The composite sensitive material comprises a matrix, has a three-dimensional porous structure, and comprises a
polymer material and a sheet-shaped non-metallic conductive material; and
metal oxide nanoparticles are distributed on the surface of the sheet-shaped non-metallic conductive material; wherein the sheet-shaped non-metallic conductive material and the
metal oxide nanoparticles are both materials with negative thermoelectric coefficients. The thermodynamic dual-mode composite sensitive material provided by the application integrates
pressure sensing and thermoelectric performance, which avoids the problems of complex
layout and complex
signal transmission of a traditional dual-mode sensor; meanwhile, the
pressure sensing and the thermoelectric sensing are not interfered with each other, so that the prepared sensor has the advantages of
signal non-interference decoupling, avoidance of wear failure, strong adaptability, non-destructiveness, high safety and the like, can adapt to a higher temperature, and has stable temperature
signal output.