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2995 results about "Hydrogen sulfide" patented technology

Hydrogen sulfide is the chemical compound with the formula H₂S. It is a colorless chalcogen hydride gas with the characteristic foul odor of rotten eggs. It is very poisonous, corrosive, and flammable.

Pre-passivation process for a continuous reforming apparatus, and passivation process for a continuous reforming apparatus during the initial reacation

The present invention relates to a pre-passivation process for a continuous reforming apparatus prior to the reaction, or a passivation process for a continuous reforming apparatus during the initial reaction, comprising loading a reforming catalyst into the continuous reforming apparatus, starting the gas circulation and raising the temperature of a reactor, injecting sulfide into the gas at a reactor temperature ranging from 100-650° C., controlling the sulfur amount in the recycle gas within a range of 0.5-100×10−6 L/L so as to passivate the apparatus.
The process of the present invention may also comprise the following steps:
    • (1) loading a reforming catalyst into the continuous reforming apparatus, starting the gas circulation and raising the temperature of a reactor, feeding the reforming feedstock into the reaction system when the temperature of the reactor is increased to 300-460° C., introducing sulfide into the reaction system while or after the reforming feedstock is fed, controlling the ratio of the total sulfur amount introduced into the system to the reforming feedstock within the range of 0.5 μg/g-50 μg/g, reducing the content of sulfide introduced into the system when hydrogen sulfide concentration in the recycle gas reaches to 2.0 μL/L˜30 μL/L; and
    • (2) maintaining the reforming reactor at a temperature of 460-490° C., controlling the ratio of the total sulfur amount introduced into the system to the reforming feedstock within the range of 0.2 μg/g-0.5 μg/g, adjusting the amount of the reforming feedstock to the design value of the apparatus, increasing the reforming reaction temperature to 490-545° C. according to the requirements on the octane number of the liquid product, and letting the reforming apparatus run under normal operating conditions.
Owner:CHINA PETROCHEMICAL CORP +1

Modified thermal processing of heavy hydrocarbon feedstocks

The present invention is directed to the upgrading of heavy petroleum oils of high viscosity and low API gravity that are typically not suitable for pipelining without the use of diluents. It utilizes a short residence-time pyrolytic reactor operating under conditions that result in a rapid pyrolytic distillation with coke formation. Both physical and chemical changes taking place lead to an overall molecular weight reduction in the liquid product and rejection of certain components with the byproduct coke. The liquid product is upgraded primarily because of its substantially reduced viscosity, increased API gravity, and the content of middle and light distillate fractions. While maximizing the overall liquid yield, the improvements in viscosity and API gravity can render the liquid product suitable for pipelining without the use of diluents. This invention particularly relates to reducing sulfur emissions during the combustion of byproduct coke (or coke and gas), to reducing the total acid number (TAN) of the liquid product, and to reducing the hydrogen sulfide content of one, or more than one component of the product stream. The method comprises introducing a particulate heat carrier into an up-flow reactor, introducing the feedstock at a location above the entry of the particulate heat carrier, allowing the heavy hydrocarbon feedstock to interact with the heat carrier for a short time, separating the vapors of the product stream from the particulate heat carrier and liquid and byproduct solid matter, regenerating the particulate heat carrier in the presence of the calcium compound, and collecting a gaseous and liquid product from the product stream.
Owner:IVANHOE HTL GASOLINEEUM

Method for removing hydrogen sulfide in gas phase through oxidization under high gravity field

The invention discloses a method for removing hydrogen sulfide in a gas phase through oxidization under a high gravity field, which comprises the steps of: enabling a desulfurizing agent to be in a countercurrent or cross current contact with a hydrogen sulfide containing gas in a desulfurizing high gravity machine; and then adding the desulfurizing agent rich in sulphur in a sulphur sedimentation agent and then enabling the desulfurizing agent added with the sulphur sedimentation agent to be in a countercurrent or cross current contact with air in a regeneration high gravity machine, whereinthe desulfurizing agent is a mixed solution consisting of complex iron, aqueous alkali, a sulphur modifying agent and a defoaming agent, and in the mixed solution, the concentration of iron ions is 0.1-10g/L, pH is 8.0-9.2, the concentration of the sulphur modifying agent is 10-200ppm, and the concentration of the defoaming agent is 5-50ppm. The high gravity machine is used for replacing the traditional low-transfer-efficiency reactor, and a high gravity rotary packed bed reactor is adopted during hydrogen sulfide oxidization and catalyst regeneration, thus process transfer efficiency is greatly strengthened, and time of oxidization desulfurization and regeneration of a desulfurizing agent is shortened; in addition, the sedimentation agent is adopted in a sulphur sedimentation stage and acts together with the sulphr modifying agent, thus the sulphur sedimentation time is also greatly shortened.
Owner:WUHAN GLT ENERGY & ENVIRONMENTAL TECH CO LTD +1

Device and method for preparing hydrogen through temperature controlled continuous decomposition of hydrogen sulfide

InactiveCN103204466AImprove uniformityContinuous and stable dischargeHydrogen productionChemical industryTemperature control
The invention discloses a device and a method for preparing hydrogen through temperature controlled continuous decomposition of hydrogen sulfide, belongs to the technical field of hydrogen preparation and gas purification, and relates to a dielectric barrier discharge temperature controllable plasma generating device and a method for preparing hydrogen through continuous and stable ionizing decomposition of a hydrogen sulfide gas or a gas containing hydrogen sulfide by using the device. The device is characterized in that a reactor has a coaxial sleeve type structure, a cylinder of the reactor is made of an insulating medium, a central electrode is formed by a metal, a grounding electrode is formed by a temperature controllable circulating liquid, and decomposed sulfur is separated through temperature control, so that continuous and stable operation of preparing the hydrogen through the decomposition of the hydrogen sulfide is ensured. The invention has the advantages that the method is suitable for preparing the hydrogen and elemental sulfur by dissociating the gases containing the hydrogen sulfide in chemical industries of natural gas, petroleum and coal; and the method does not have special requirement or limitation for the source and the composition of the gases, so the method has universal applicability for preparing the hydrogen and the elemental sulfur through the decomposition of the hydrogen sulfide.
Owner:BINZHOU UNIV

Process for extracting tea polyphenol, theanine, tea polysaccharide and tea pigment from tea

The invention discloses an extracting polyphenol, theanine, tea polysaccharide and tea pigment method from tea, which is characterized by the following: using deionized water for lixiviating tea at constant temperature with continuous flow upstream at multi-speed; adopting microstrainer to dislodge the foreign matter of raffinate; using hyperfiltration for putting-off pectin and protein; concentrating by hyperfiltration and dehydration; extracting tea polyphenol by acetic acid ethyl ester and recovering dissolvant; stripping caffeine of extracting extract phase, pesticide residue and dissolvant by CO2 supercritical fluid; getting tea polyphenol by low-temperature nitrogen spray-drying; using alcohol separation and low temperation vacuum drying by hyperfiltration trapped fluid to prepare tea polysaccharide; separating alcohol recrystallization by basic copper carbonate and hydrogen sulfide to get theanine; using enzymatic oxidation and alkaline air to oxygenate remain polyphenols substance of liquid phantom; getting tea pigment by hyperfiltration dehydration compression and vacuum drying; merging caffeine form carbon dioxide above-critical fluid and caffeine from carrene; recovering dissolvent; using deionized water for washing; obtaining caffeine by recrystallization vacuum drying.
Owner:张守政

Deodorizing method, deodorizer, method of manufacturing deodorizer, and deodorizing apparatus

PCT No. PCT/JP96/00748 Sec. 371 Date Nov. 15, 1996 Sec. 102(e) Date Nov. 15, 1996 PCT Filed Mar. 22, 1996 PCT Pub. No. WO96/29099 PCT Pub. Date Sep. 26, 1996Hydrogen sulfide is dehydrogenated to generate a HS group and an S group. The HS group is oxidized to generate sulfuric acid, which is bonded to a metal. The S group is polymerized with a CH3S group to generate methyl trisulfide or methyl tetrasulfide, which is adsorbed to an adsorbent. Methyl mercaptan is dehydrogenated, for example, to generate a CH3S group. A portion of the CH3S group is oxidized to generate methanesulfonic acid, which is bonded to a metal. Another portion of the CH3S group is polymerized with the CH3S group itself to generate methyl disulfide, at least a portion of which is adsorbed to an adsorbent. Still another portion of the CH3S group is polymerized with the S group to generate methyl trisulfide or methyl tetrasulfide, which is physically adsorbed to an adsorbent. In this manner, malodor components including hydrogen sulfide and methyl mercaptan can efficiently be removed without producing or release of harmful secondary products. A simple-structure, compact deodorizing apparatus including appropriate metal oxide catalyst and an adsorbent material suitable for achieving the above deodorizing functions is incorporated in a toilet bowl.
Owner:TOTO LTD

Low temperature Claus sulfur recovery process and device therefor

The invention discloses a low temperature Claus sulfur recovery process. The process mainly comprises a thermal reaction section, a catalytic reaction section and a tail gas incineration section, wherein in a combustion furnace of the thermal reaction section, partial hydrogen sulfide reacts with oxygen to be converted into sulfur dioxide, the hydrogen sulfide and the sulfur dioxide undergo a Claus reaction to generate sulfur, and process gas after sulfur separation enters the catalytic reaction section; in the reactor of each stage of the catalytic reaction section, the hydrogen sulfide and the sulfur dioxide under conventional Claus reaction, catalyst reactivation, sub-dewpoint and sub-solid point low temperature Claus reaction in sequence; after the catalyst reaction section, the tail gas which is subjected to sulfur separation enters the tail gas incineration section, and the tail gas is incinerated and exhausted in the tail gas incineration furnace. The process adopts a lower reaction temperature, contributes to performance of chemical equilibrium towards the direction of sulfur generation, so that conversion rate and recovery rate of sulfur are improved. Moreover, the process has the advantages of simple process flow, relative small equipment and investment, low operation cost and more contribution to environmental protection. The invention also discloses a device for the low temperature Claus sulfur recovery process.
Owner:CHENGDU SEPMEM SCI & TECH
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