The invention provides a preparation method of a flexible 
polyaniline conductive composite hydrogel material, and belongs to the technical field of functional 
polymer materials. According to the method, a flexible conductive material with good 
mechanical strength and electrochemical property is prepared by utilizing the properties and characteristics of polyatomic acid of 
phytic acid, by taking the 
phytic acid as an acid 
doping agent and a gel crosslinking factor and taking 
polyvinyl alcohol hydrogel as a skeleton. The method comprises the following steps: dissolving 
polyvinyl alcohol into water to form a solution and matching the solution with phenylamine and 
phytic acid at a proportion to form a solution A; dissolving initiating agent 
ammonium persulfate into water to form a solution B; quickly mixing the solution A and the solution B at a low temperature, so that 
in situ polymerization is performed on the phenylamine in a 
polyvinyl alcohol aqueous solution, so as to form phytic acid-
doped polyaniline hydrogel; placing the phytic acid-
doped polyaniline hydrogel into a refrigerator for freezing, so as to form the flexible 
polyaniline conductive composite hydrogel material by a cyclic 
freeze thawing. The flexible 
polyaniline conductive composite hydrogel material prepared by the method has good electrochemical property, 
mechanical strength and flexibility; the preparation method is simple, and the cost is low, and the preparation method has wide application prospect in the fields of flexible 
energy storage materials and 
biomedicine.