172results about How to "Low detection limit" patented technology

This invention discloses a copper-based ternary chalcogenide semiconductor material, its preparation method, and its applications. The material is prepared by mixing CuSn(OH)6 nanomaterials, thioacetamide, ethylenediaminetetraacetic acid, and water and carrying out a hydrothermal reaction to obtain Cu3SnS4 nanomaterials. This semiconductor material exhibits excellent photoelectrochemical properties. Photoelectrochemical sensors constructed based on this material demonstrate high detection accuracy, fast response speed, low detection limit, and strong stability, enabling rapid and accurate real-time detection of microplastic content. The preparation method is simple, low-cost, and suitable for industrial production.

The invention discloses a crystal compound, a preparation method thereof and application of the crystal compound in X-ray detection, imaging and anti-counterfeiting encryption, and belongs to the technical field of crystals. The molecular formula of the crystal compound is [Cu (totp) (CH3CN) 3] [Cu2I3 (totp) (PN)]. (CH3CN), wherein totp is tris (o-tolyl) phosphine; and PN is diphenyl-2-pyridine phosphine. The crystal compound disclosed by the invention is simple in preparation method, and has the characteristics of large mass attenuation coefficient of X-ray energy, high light yield and low detection limit when being used as a material of an X-ray detector. The compound also has the characteristic of structural transformation in solvents such as methanol, ethanol, acetone, dichloromethane, tetrahydrofuran and the like, and meanwhile, the conversion of luminescence color under the excitation of 365nm ultraviolet light and X rays is accompanied. The material can be applied to the aspects of scintillator materials, room-temperature X-ray radiation indirect detection materials, radiation detection dosimeters, X-ray scintillator medical imaging, anti-counterfeiting encryption and the like.

The invention discloses a DSP (Digital Signal Processor) online self-adaptive wavelet denoising and concentration inversion system and method for TDLAS (Tunable Diode Laser Absorption Spectroscopy) measurement, and relates to the technical field of gas spectrum detection. Comprises: a laser module for emitting semiconductor laser light; the absorption cell module is used for absorbing specific components of the laser through a gas absorption cell formed by the to-be-detected gas; the detection and amplification module is used for converting the transmission light signal into an electric signal and amplifying the electric signal through a photoelectric amplifier; the phase-locked amplification module is used for filtering and extracting noise; the digital signal processing module is used for performing digital sampling, performing wavelet denoising and signal reconstruction, performing wavelet inverse transformation reconstruction on a denoised waveform, and extracting a second harmonic characteristic parameter; and the upper computer module is used for obtaining the concentration of the gas to be detected based on a pre-established gas concentration inversion model according to the second harmonic characteristic parameters. The method is suitable for high-precision detection of trace gas, and has the obvious advantages of strong real-time performance, high precision, good system stability, good portability and the like.

This invention provides a CRISPR / Cas12a fluorescence detection method for FocTR4 based on magnetic bead-ssDNA-HRP probes, belonging to the field of nucleic acid detection technology. This invention involves isothermal amplification of the FocTR4 target sequence using RPA primers; then, a magnetic bead-ssDNA-HRP probe is prepared; and the Cas12a / crRNA complex, RPA amplification product, and probe are co-incubated. The activated Cas12a cleaves the probe, releasing HRP. After magnetic separation, a colorimetric solution containing OPD is added, and the presence and concentration of FocTR4 are determined by detecting the fluorescence signal. This invention combines the high efficiency of CRISPR / Cas12a cleavage with the high sensitivity and strong specificity of RPA technology, achieving highly sensitive and specific detection of FocTR4, with a linear detection range of 10. 2 ~10 7 With a detection limit as low as 70 CFU / mL, it can quickly and accurately detect Foc TR4 in soil samples, enabling rapid on-site detection and providing reliable technical support for the early diagnosis and control of banana wilt disease.

This application discloses an acetone sensor based on an ion-conducting copper ion-organic framework and its preparation method, belonging to the field of gas sensor technology. The sensor uses a glass substrate with indium tin oxide (ITO) interdigitated electrodes. The sensitive layer is an ion-conducting copper-based MOF thin film formed by the in-situ coordination reaction of tetrakis(4-aminophenyl)porphyrin and copper ions at the liquid-phase interface, constituting a capacitive gas sensor. In the preparation process, a ligand methanol solution and a copper nitrate solution are first prepared. After plasma cleaning of the substrate, the ligand solution is sprayed onto the copper salt solution interface to form an in-situ film, which is then vacuum dried to obtain the acetone sensor. This application has advantages such as simple process, low cost, high sensitivity, fast response, and good stability, making it suitable for large-scale production. It can be used for non-invasive detection of acetone in diabetic respiration, environmental monitoring, and industrial VOCs detection, showing promising application prospects.

A quantitative detection method of thallium content in converter graphite ball, steps include: 1) the pretreatment of converter graphite ball; 2) the preparation of standard solution series; 3) the detection of thallium content in converter graphite ball.The application finds that the suitable pretreatment method of converter graphite ball is carbon removal by burning, and then high-chloric acid and dilute nitric acid are used to dissolve salt, by which the converter graphite ball can be completely dissolved, thereby the stability of quantitative determination of thallium content in converter graphite ball is improved, the pretreatment method is simple, fast and operable; the method is suitable for the quantitative detection of thallium content in converter graphite ball with thallium content not less than 0.0062 μg / L, the recovery rate of thallium is as high as 99.1%, the analysis accuracy is high, the detection lower limit is as low as ppb level, the sensitivity is high, and the method has the advantages of simple operation, simple analysis condition and low labor intensity.Therefore, the application has significant economic benefits and the advantages of simplicity and economy.

The application discloses an electrochemical sensor and a preparation method and application thereof. The electrochemical sensor comprises a three-electrode system composed of a working electrode, a reference electrode and a counter electrode, wherein the working electrode is composed of a base electrode, a molybdenum disulfide nanoparticle modification layer and a polyethylene dioxythiophene layer; the molybdenum disulfide nanoparticles are loaded on the surface of the base electrode through a drop coating method, and the polyethylene dioxythiophene is in-situ loaded on the surface of the molybdenum disulfide nanoparticle modification layer through an electro-polymerization reaction. The electrochemical sensor can be used for detecting lead ions in water bodies, has the advantages of simple preparation, stable performance, suitability for an acidic medium and the like, and is suitable for practical application and popularization.

The invention discloses a biosensor based on an ultraviolet light triggered bio-barcode release technology (OBCA) and construction and application of the biosensor. The biosensor comprises nucleic acid functionalized silver nanoparticles, nucleic acid functionalized magnetic beads and a CRISPR (clustered regularly interspaced short palindromic repeats) / Cas12a detection system, the DNA bar code modified on the surface of the silver nanoparticle contains a light cleavable linker, a CRISPR / Cas12a activation sequence and a target capture sequence I, and a DNA capture probe containing a target capture sequence II is fixed on the surface of the magnetic bead through biotin-streptavidin action. During detection, target miRNA mediates two capture sequences to form a sandwich compound, after magnetic separation and thermal denaturation elution, 365nm ultraviolet radiation releases DNA bar code fragments, and the Cas12a trans-cleavage fluorescence quenching reporter probe is activated to generate a signal. According to the method, nucleic acid amplification and reverse transcription are not needed, the detection limits of miR-21, miR-155 and mi-210 respectively reach 158.94 aM, 763.56 aM and 197.82 aM, single-base mismatch and precursor miRNA can be distinguished, the serum sample detection result is highly consistent with that of RT-PCR, and the method is suitable for high-sensitivity quantitative detection of miRNA.

The application discloses a high-precision spectral noise elimination method and system based on TDLAS technology and relates to the technical field of gas concentration optical detection. The method obtains the center frequency and half-width parameter of a Lorentz model by fitting the standard gas sampling data, determines the adaptive cutoff frequency according to the center frequency and the half-width parameter, and performs digital low-pass filtering on the to-be-detected gas sampling data. The filtered data is divided into an absorption interval and two non-absorption intervals. The local phase information of the interference fringes in the non-absorption intervals is extracted and weighted third-order polynomial fitting is performed to obtain the baseline of the whole region. The application extracts the local phase of the interference fringes in the non-absorption intervals in real time and converts the local phase into the basis for weighted fitting. The processing link is constructed by combining adaptive filtering and constrained Lorentz fitting. The phase extrapolation compensation is used to eliminate the residual error of the interference fringes caused by temperature fluctuation, the spectral absorption area more accurately reflects the real absorption strength, and thus the precision of low-concentration gas detection is improved.

This application discloses a crystal, a rare-earth-doped crystal, its preparation method, and its applications, belonging to the field of crystal materials. The chemical formula of the crystal is [Gd(L)]. 1.5 (DMA)] n Formula I; in Formula I, L is a ligand formed by deprotonated benzene polycarboxylic acid; benzene polycarboxylic acid is selected from any one of terephthalic acid, phthalic acid, and isophthalic acid; DMA is N , N -Dimethylacetamide; n ∞ represents continuous repetition and infinite extension. The crystal is rare-earth doped, and the chemical formula of the rare-earth doped crystal is [Gd]. 1‑x% (L) 1.5 (DMA)] n :x% Ln 3+ Equation II; in Equation II, x = 0.1~10; Ln 3+ Selected from Tb 3+ Or Eu 3+ Any one of the following. It has potential application value in fields such as fluorescent materials, multicolor display materials, long afterglow materials, X-ray detection and imaging materials, radiation detection dosimeters, and optical information encryption. The preparation method used in this application can be easily achieved through solution reaction under relatively mild conditions, with low cost and strong industrial feasibility.

This invention discloses a method for preparing FeZn-LDH nanosheets and their application in glucose colorimetric detection, belonging to the field of nanoenzyme technology. The preparation method involves introducing arginine and L-histidine into an Fe / Zn metal salt system and combining this with microwave-induced heating to prepare FeZn-LDH nanosheets. The prepared FeZn-LDH nanosheets effectively prevent LDH aggregation, resulting in a thinner, two-dimensional FeZn-LDH nanosheet structure with a larger specific surface area, thereby improving the peroxidase-like catalytic activity and glucose colorimetric detection performance of the material.

The invention discloses a TADF type compound as well as a preparation method and application thereof. The compound has a structural formula as shown in a formula I; the invention provides a series of TADF type compounds with novel structures, and the compounds can effectively improve the X-ray absorption capacity, can be used for preparing organic scintillator materials with low cost and low detection limit, and can be applied to X-ray imaging.

The invention discloses a primer and a kit for rapidly detecting yersinia rouxii through RPA-CRISPR / Cas12a and application of the primer and the kit, and relates to the technical field of disease prevention and control in aquaculture. The invention aims to solve the problems that the existing detection method is time-consuming and labor-consuming, is easy to cause pollution and needs to be matched with professional detection equipment. According to the present invention, the RPA amplification primer is composed of a forward primer yrp1-RPA-F2 and a reverse primer yrp1-RPA-R2, the crRNA is yrp1-crRNA-R1, and the kit for rapid detection of yersinia rouxii contains the RPA amplification primer and the crRNA. The method for rapidly detecting yersinia rouxii comprises a fluorescence method and a test paper method. The method disclosed by the invention has the advantages of good inclusiveness, strong specificity, high sensitivity and the like, detection is carried out based on the RPA primer and the crRNA, and the obtained RPA product is detected by using a lateral flow chromatography test strip and fluorescence, so that the purpose of portable visual rapid detection on site or in a breeding base is achieved, and the method is suitable for large-scale popularization and application. The method has very high clinical application value in the aspects of early discovery of diseases, epidemiological investigation and comprehensive prevention and control.

The invention provides an MOF-on-MOF composite material, an aptamer probe as well as a preparation method and application of the aptamer probe. The MOF-on-MOF composite material comprises an HKUST-1 material, the surface of the HKUST-1 material is coated with a Cu-BDC nanosheet; the synthesized HKUST-1 (at) Cu-BDC / Apt aptamer probe can specifically recognize AFB1, the aptamer probe can directly capture the AFB1 and adsorb the AFB1 to active sites on the surface of a material to reduce the nano-enzyme activity of the AFB1, so that quantitative colorimetric detection of the AFB1 is realized, and the aptamer probe has low detection limit, wide detection range, good selectivity and anti-interference performance on the AFB1 and can be used for detecting the AFB1. The AFB1 in a food sample can be rapidly, sensitively and selectively detected. In addition, the composite material has an adsorption effect and high catalytic activity on fungaltoxin, and AFB1 can be efficiently removed through the adsorption effect and the catalytic action.

The invention discloses a wearable molecular imprinting sensor and application thereof in cortisol detection, and belongs to the technical field of electrochemical analysis and detection. The molecular imprinting sensor sequentially comprises a sweat absorbing pad, a three-electrode system, an annular polydimethylsiloxane mold and a medical bonding patch from the skin contact surface to the outside, the front surface of the sweat-absorbent pad is in contact with the skin, and KCl and K3 [Fe (CN) 6] are adsorbed on the back surface of the sweat-absorbent pad; the three-electrode system takes an MIP / AuNWs / PET sensor as a working electrode, a platinum wire as a counter electrode and a silver / silver chloride electrode as a reference electrode; the annular polydimethylsiloxane mold and the medical adhesive patch form a sweat collection chamber. The molecular imprinting sensor based on in-situ growth of gold nanowires (AuNWs) on the porous PET film is used for rapidly detecting the cortisol level in human sweat in real time, natural receptor ligand interaction is simulated through the molecular imprinting technology, and high-specificity recognition of cortisol is achieved.

The application discloses a kind of nanocomposite based on Ti3C2 and its preparation method and application.It relates to the field of electrochemistry.The above-mentioned nanocomposite based on Ti3C2 includes the following components: Ti3C2, reduced graphene oxide, beta-cyclodextrin-metal organic framework material, IAA antibody and adhesive.The above-mentioned nanocomposite based on Ti3C2 of the application has excellent specificity for IAA, can realize high sensitivity and high stability detection of IAA, can realize detection of IAA concentration from 0.01-10ng / mL at least, and the detection limit reaches 2.88pg / mL (S / N=3).

This invention provides a method for identifying the authenticity of wheat flour based on the fusion of Raman and near-infrared spectroscopy, belonging to the field of wheat flour authenticity identification technology. The method includes: acquiring Raman and near-infrared spectral data of the wheat flour sample to be tested, and preprocessing them separately; constructing and training a fusion detection model, which includes a data-level fusion module, a feature-level fusion module, and a decision-level fusion module; the data-level fusion module generates full-spectrum fusion data; the feature-level fusion module concatenates core features into a comprehensive feature set; the decision-level fusion module inputs the comprehensive feature set into a hybrid model; and the trained fusion detection model processes the comprehensive feature set to output the authenticity identification result of the wheat flour sample to be tested. This invention, through a three-level spectral fusion architecture and a dynamic adaptive adversarial mechanism, can effectively achieve high-precision and high-robust identification of wheat flour authenticity.

The present application relates to a method for detecting the content of a glycosaminoglycan carboxylated derivative in a sample, and an application thereof. The method comprises: (1) hydrolyzing a sample to obtain a hydrolysate containing a compound as represented by formula (I); (2) testing the hydrolysate by means of liquid chromatography-tandem mass spectrometry; and (3) by using a glycosaminoglycan carboxylated derivative as a standard substance, hydrolyzing solutions thereof having different gradient concentrations according to the method in step (1), detecting, according to the method in step (2), mass spectrum signal peak areas of the compound as represented by formula (I) in the hydrolysates of the standard substance solutions having different concentrations, forming a standard curve on the basis of the mass spectrum signal peak areas against the amounts of the glycosaminoglycan carboxylated derivative standard substance, and according to the standard curve, calculating the content of the glycosaminoglycan carboxylated derivative in the sample according to the mass spectrum peak areas of the compound as represented by formula (I) determined in step (2). According to the method in the present application, hydrolysis products of a specific structure can be stably obtained by hydrolysis of the glycosaminoglycan carboxylated derivative, the structure can be detected by means of MS, and a hydrolysis product having higher mass spectrum abundance is selected, so that the amount of the glycosaminoglycan carboxylated derivative can be indirectly calculated. Moreover, the detection method has strong specificity, high accuracy, good precision, low limit of quantitation, and low limit of detection.

This invention discloses an acetone sensor based on MOF-derived oxygen-vacancy-rich α-Fe₂O₃ and its fabrication method. The aforementioned acetone gas sensor has a planar structure, including an Al₂O₃ ceramic sheet, a pair of interdigitated gold electrodes printed on the upper surface of the Al₂O₃ ceramic sheet, a RuO₂ heating film printed on the lower surface of the Al₂O₃ ceramic sheet, a pair of strip-shaped gold electrodes printed on the surface of the RuO₂ heating film, a gas-sensitive film coated and fixed to the surface of the interdigitated gold electrodes, platinum wire leads I, II, III, and IV. The gas-sensitive film uses an oxygen-vacancy-rich α-Fe₂O₃ sensitive material. This invention can produce an acetone sensor with excellent acetone sensitivity characteristics, enabling efficient detection of low concentrations of acetone. It overcomes the problems of insufficient sensitivity and slow response speed of traditional gas sensors in acetone detection. Furthermore, the acetone sensor fabrication process is highly compatible with existing microfabrication technologies, meeting the needs of industrial production.

The invention discloses a preparation method of a high-conductivity multivalent nanowire and application of the high-conductivity multivalent nanowire to a non-enzyme glucose sensor. The copper nanowire with a high length-diameter ratio is prepared, a certain amount of thiourea is directly added into an ethanol solution of the copper nanowire, and conversion from the copper nanowire to the high-conductivity multivalent nanowire can be achieved under the condition of a specific reaction temperature. In the conversion process, the surface of the nanowire is synchronously induced to form a coarse structure, non-single valence copper sulfide active sites are constructed, and the formed synergistic effect can remarkably increase the number of the active sites, reduce an electrocatalytic oxidation reaction energy barrier and strengthen the specific adsorption capacity of glucose molecules, so that the non-enzyme glucose sensor is manufactured. The sensor shows ultrahigh detection sensitivity, ultralow response speed and excellent anti-interference performance, the preparation process is extremely simple, the cost is low, and the sensor has remarkable technical advantages and wide application prospects in the field of quantitative detection of glucose.

This invention provides a rapid colorimetric reagent for the detection of manganese and iron ions. The reagent consists of carbon dots, a 3,3′,5,5′-tetramethylbenzidine solution, and a phosphate buffer solution. The reagent itself is a brown, transparent solution. When manganese ions are added to the 3,3′,5,5′-tetramethylbenzidine solution and phosphate buffer solution, it turns blue (visible to the naked eye) upon irradiation with a 365 nm UV lamp; upon contact with iron ions in the 3,3′,5,5′-tetramethylbenzidine solution, it turns dark green (visible to the naked eye). This reagent exhibits an extremely low detection limit and good selectivity. The detection process does not require complex analytical equipment, enabling rapid trace detection of manganese and iron ions. The reagent is simple to prepare, overcoming the shortcomings of cumbersome and expensive synthesis of manganese and iron ion detection probe molecules, and providing effective technical support for trace detection in food safety.

The application belongs to the technical field of immune detection, and particularly relates to a quantum dot labeled testosterone propionate direct competition fluorescence immune detection method. The application prepares a monoclonal antibody, and couples CdSe / ZnS (core / shell) quantum dots with the prepared anti-TP monoclonal antibody to synthesize a quantum dot (QDs) labeled anti-TP-mAb-QDs immune fluorescence probe, and construct a quantum dot labeled testosterone propionate direct competition fluorescence immune detection system for detecting testosterone propionate. The method for detecting testosterone propionate by the quantum dot labeled direct competition fluorescence immune detection method is simple in operation, and can detect the residual content of testosterone propionate in a sample to be detected without adding a chromogenic substance. The operation and reaction can be completed in one step. The method is simple, efficient, sensitive, low in detection cost, and can be applied to rapid detection of TP residues in feed, and has good accuracy.

This invention discloses a wide dynamic range substrate reagent, belonging to the field of biological detection reagent technology. The reagent consists of the following components: citric acid, 9.6 g / L; 3,3',5,5'-tetramethylbenzidine, 0.29 g / L; 3% hydrogen peroxide solution, 3 mL / L; 1 g / L polyvinyl alcohol; 0.5 g / L copovidone W-735; 0.5 g / L dimethyldiallylammonium chloride-acrylamide copolymer; 1 g / L PVP K30; and Tween 20, 0.005 g / L. mL / L; polyethylene glycol 10g-50g / L; pure water, balance. This invention, by adding specific polyethylene glycol and synergistically combining with other components, significantly reduces the reagent background signal and improves detection sensitivity; effectively broadens the detection dynamic range and increases the detection upper limit of high-concentration analytes; improves the linear correlation between signal and concentration; and enhances the thermally accelerated stability of the reagent. This reagent has comprehensive performance and is especially suitable for ELISA detection systems with high sensitivity and wide detection range.

The application discloses a method for digesting and separating fluorinated aluminum by program, which comprises the following steps: placing a catalyst with metal elements supported on alumina as a carrier into a reaction container of a cluster digestion device, adding hydrochloric acid and / or nitric acid, setting a digestion program, introducing inert gas for pre-pressurization, performing primary digestion, and simultaneously starting a condensation reflux atomizer; after the program is completed, adding hydrofluoric acid, setting a digestion program, and performing secondary digestion; after the digestion is completed, entering a cooling and crystallization program, performing cooling and crystallization, and separating to obtain a sample solution to be detected and a solid; the solid is dried and calcined to obtain fluorinated aluminum crystals, and the liquid is used for detecting the content of metal elements. The method is applied to the digestion treatment of the alumina sample with metal elements supported thereon, has a large sample treatment range, complete digestion, no volatile loss of elements, and can separate AlF3 in an alpha crystal form through the program digestion of the digestion device.

The invention discloses an NO2 sensor based on an MOF-derived Ni-doped In2O3 core-shell octahedral sensitive material and a preparation method of the NO2 sensor, and belongs to the technical field of semiconductor metal oxide gas sensors. The sensor is composed of a ceramic tube substrate with parallel annular gold electrodes on the surface, an MOF-derived Ni-doped In2O3 core-shell octahedral sensitive material film coated on the surfaces of the electrodes and the substrate, and a nichrome heating coil arranged in the ceramic tube. A core-shell octahedral structure In2O3 nano material with a high specific surface area and abundant pores is constructed by using an MOF template method, and a Ni-doped modulated electronic structure and enhanced surface activity are combined, so that the sensitivity of the sensor to NO2 gas is remarkably improved, the detection lower limit is reduced, the humidity interference is effectively inhibited, and the detection sensitivity of the sensor to NO2 gas is improved. The invention provides a reliable solution for monitoring trace NO2 in a complex environment, and has important practical value and application prospect.

The invention relates to a method for determining the total amount of impurity elements in a natural high-purity quartz mineral, which comprises the following steps of: preparing a laser sheet of the quartz mineral, observing and photographing by using a polarizing microscope, designing an analysis test point on a picture, and carrying out point-by-point analysis and determination on a laser ablation and inductively coupled plasma spectrum according to the design point. Accurate determination of impurity elements of quartz minerals in a natural high-purity quartz raw material is realized, comprehensive analysis and evaluation are carried out, and grade characteristics of the quartz minerals in the high-purity quartz raw material are further determined. The method is suitable for analysis and determination of impurity elements in natural quartz minerals, has the advantages of low detection limit, high sensitivity, wide linear range and the like, can be applied to effective and rapid evaluation, quality monitoring and the like of high-purity quartz raw materials, and provides quartz mineral raw materials with stable grades for the high-purity quartz sand industry.

The invention relates to the technical field of biochemical sensing, in particular to an aminoglycoside antibiotic dual-mode visual detection card and a preparation method and application thereof, and the detection card is composed of two parts: an aminoglycoside antibiotic dual-mode labeling reagent and qualitative filter paper. The dual-mode labeling reagent is formed by self-assembling ninhydrin and lanthanide metal ions, and is used for providing a color development / ratio fluorescence dual-mode detection signal; the qualitative filter paper is used for efficient adsorption and enrichment of aminoglycoside antibiotics, and can significantly enhance color development and fluorescence signals. The detection card provided by the invention can realize double-mode (color development and fluorescence) visual detection and identification of aminoglycoside antibiotics only by using one labeling reagent, and is good in response selectivity, high in sensitivity, strong in anti-interference capability, mild in condition and easy to popularize. The detection accuracy and reliability can be remarkably improved through cross validation of double-signal-channel visual detection results.

The application relates to the technical field of compound synthesis, and discloses an aromatic dipeptide functionalized mercapto compound, 3,5-di(triphenylmethylthio)benzoic acid is obtained by adding 3,5-di(methylmercapto)benzoic acid and pyridine into a solution of chloromethyl triphenylphosphonium, purifying after sufficient reaction; then the 3,5-di(triphenylmethylthio)benzoic acid is mixed with N-hydroxysuccinimide and dissolved in an organic solvent, EDC.HCl is added, purifying after sufficient reaction; then 2,5-dioxopyrrolidin-1-yl 3,5-bis(triphenylmethylthiomethyl)benzoate is obtained; then phenylalanine-tryptophan and triethylamine are added, purifying after sufficient reaction; then (3,5-bis(triphenylmethylthiomethyl)benzoyl)tryptophylphenylalanine is obtained; then trifluoroacetic acid and triethylsilane are added, purifying after sufficient reaction; and finally the aromatic dipeptide functionalized mercapto compound is obtained. The aromatic dipeptide functionalized mercapto compound can quickly and effectively identify sodium and potassium ions, and has relatively low detection limit and relatively loose detection condition.

This invention discloses a method for quantitatively detecting muscle inositol in blood. It employs an electrochemical method and specifically includes the following steps: a) preparation of a series of standard working solutions; b) preparation of a blank sample solution; c) plotting a standard curve using differential pulse voltammetry (DPV) with the blank sample solution and the series of standard working solutions; d) preparation of the test sample solution; e) determination of the muscle inositol content in the test sample. Experiments have demonstrated that the method of this invention yields accurate and reliable results and can be used for clinical blood testing.

The invention relates to the field of atmospheric environment monitoring and high-altitude sampling, and discloses an atmospheric trace nitrous acid and formaldehyde profile detection device carried by a small aircraft and a detection method. The absorption liquid is fed into the double-channel miniature spiral trapping trap through a peristaltic pump to be mixed and contacted with the sample gas to form a sample solution; a liquid storage bottle is arranged on the automatic sample disc, and the top of the first liquid inlet needle is connected with a liquid outlet of the dual-channel miniature spiral trapping trap; a color developing solution in the color developing solution storage bottle is injected into the liquid storage bottle through a second liquid inlet needle, and the constant-temperature reaction kettle controls the color developing reaction temperature to form a sample solution to be detected; a to-be-detected sample solution is pumped into the absorption cell through the liquid pumping needle, and the liquid pumping needle is driven by the liquid pumping arm to move up and down; the absorption cell is connected with a detector, and the detector is used for detecting the component concentration of the sample solution to be detected; the automatic sampler and the rapid reaction detector comprise the same automatic sample disc to realize rapid sample transfer.